page source_page_order layout_page_order layout_order ref label role_guess included_in_body excluded_risk_level body_decision_reason parser_body_decision_reason production_usage visual_asset_type visual_asset_label visual_asset_caption_preview truncation_marker inside_body_region body_region_id zone column column_index column_count region_id background_rgb background_class is_gray_background has_frame_evidence bbox text_preview cleaned_text_preview 1 1 1 0 #/texts/0 page_header page_header False low docling_page_header docling_page_header True p1:body_region:0 top_margin column_2_of_3 2 3 p1:top_margin:column_2_of_3:white [255, 255, 255] white False False [224.33, 47.98, 146.5, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 1 2 2 1 #/texts/1 text front_matter_heading False low first_page_metadata first_page_metadata True p1:body_region:0 front_matter column_2_of_3 2 3 p1:front_matter:front_panel:gray [229, 229, 229] gray True False [223.6, 79.88, 151.02, 1.59] Contents lists available at ScienceDirect Contents lists available at ScienceDirect 1 3 3 2 #/texts/2 section_header title_candidate False low first_page_front_matter_heading first_page_front_matter_heading True p1:body_region:0 front_matter column_2_of_3 2 3 p1:front_matter:front_panel:gray [229, 229, 229] gray True False [204.04, 98.03, 190.03, 12.98] Journal of Energy Chemistry Journal of Energy Chemistry 1 5 4 3 #/texts/4 section_header title_candidate False low first_page_front_matter_heading first_page_front_matter_heading True p1:body_region:0 front_matter column_1_of_3 1 3 p1:front_matter:column_1_of_3:white [255, 255, 255] white False False [37.59, 178.96, 407.61, 29.75] A versatile strategy to activate self-sacrificial templated Li2MnO3 by defect engineering toward advanced lithium storage A versatile strategy to activate self-sacrificial templated Li2MnO3 by defect engineering toward advanced lithium storage 1 6 5 4 #/texts/5 text front_matter_candidate False low before_body_started before_body_started True p1:body_region:0 front_matter column_1_of_3 1 3 p1:front_matter:column_1_of_3:white [255, 255, 255] white False False [37.59, 218.76, 497.29, 26.45] Jian-En Zhou a,1 , Yanhua Peng a,1 , Xiaoyan Sang b , Chunlei Wu c , Yiqing Liu a , Zhijian Peng a , Hong Ou a , Yongbo Wu d , Xiaoming Lin a, ⇑ , Yuepeng Cai a, ⇑ Jian-En Zhou a,1 , Yanhua Peng a,1 , Xiaoyan Sang b , Chunlei Wu c , Yiqing Liu a , Zhijian Peng a , Hong Ou a , Yongbo Wu d , Xiaoming Lin a, ⇑ , Yuepeng Cai a, ⇑ 1 7 6 5 #/texts/6 footnote footnote False low first_page_summary first_page_summary True p1:body_region:0 front_matter column_1_of_3 1 3 p1:front_matter:column_1_of_3:white [255, 255, 255] white False False [37.59, 250.75, 505.2, 24.33] a Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, Joint Laboratory of Energy and Materials Chemistry (South China Normal University-Guangzhou Tianci New Materials Co., Ltd.), Key Laboratory of T… a Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, Joint Laboratory of Energy and Materials Chemistry (South China Normal University-Guangzhou Tianci New Materials Co., Ltd.), Key Laboratory of T… 1 8 7 6 #/texts/7 footnote footnote False low docling_footnote docling_footnote True p1:body_region:0 front_matter column_1_of_3 1 3 p1:front_matter:column_1_of_3:white [255, 255, 255] white False False [37.59, 276.43, 487.59, 15.77] b National Engineering Research Center for Carbohydrate Synthesis, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Jiangxi Normal University, Nanchang 330022, Jiangxi, China b National Engineering Research Center for Carbohydrate Synthesis, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Jiangxi Normal University, Nanchang 330022, Jiangxi, China 1 9 8 7 #/texts/8 footnote affiliation False low first_page_author_or_affiliation first_page_author_or_affiliation False None front_matter column_1_of_3 1 3 p1:front_matter:column_1_of_3:white [255, 255, 255] white False False [37.64, 293.55, 300.24, 7.21] c Guangzhou Huifu Research Institute Co., Ltd, Nanxiang San Lu, Guangzhou 510663, Guangdong, China c Guangzhou Huifu Research Institute Co., Ltd, Nanxiang San Lu, Guangzhou 510663, Guangdong, China 1 10 9 8 #/texts/9 footnote affiliation False medium first_page_author_or_affiliation first_page_author_or_affiliation True p1:body_region:0 front_matter column_1_of_3 1 3 p1:front_matter:column_1_of_3:white [255, 255, 255] white False False [37.59, 302.17, 509.06, 15.77] d Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, National Demonstration Center for Experimental Physics Education, School of Physics and Telecommunication Engineering, South China Norm… d Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, National Demonstration Center for Experimental Physics Education, School of Physics and Telecommunication Engineering, South China Norm… 1 11 10 9 #/texts/10 section_header front_matter_heading False low front_matter_heading front_matter_heading False None front_matter column_1_of_3 1 3 p1:front_matter:column_1_of_3:white [255, 255, 255] white False False [37.7, 338.58, 94.35, 11.02] a r t i c l e i n f o a r t i c l e i n f o 1 20 11 10 #/texts/19 section_header abstract_heading False low abstract_heading abstract_heading True p1:body_region:0 front_matter column_2_of_3 2 3 p1:front_matter:column_2_of_3:white [255, 255, 255] white False False [202.22, 338.86, 65.22, 11.02] a b s t r a c t a b s t r a c t 1 12 12 11 #/texts/11 text front_matter_candidate False low outside_body_flow outside_body_flow False None front_matter column_1_of_3 1 3 p1:front_matter:column_1_of_3:white [255, 255, 255] white False False [37.59, 361.66, 70.81, 31.61] Article history: Received 14 April 2023 Revised 11 May 2023 Accepted 14 May 2023 Article history: Received 14 April 2023 Revised 11 May 2023 Accepted 14 May 2023 1 13 13 12 #/texts/12 text metadata False low first_page_metadata first_page_metadata False None front_matter column_1_of_3 1 3 p1:front_matter:column_1_of_3:white [255, 255, 255] white False False [37.59, 395.91, 91.28, 5.93] Available online 26 May 2023 Available online 26 May 2023 1 14 14 13 #/texts/13 text front_matter_heading False low front_matter_heading front_matter_heading False None front_matter column_1_of_3 1 3 p1:front_matter:column_1_of_3:white [255, 255, 255] white False False [37.59, 415.97, 77.77, 48.79] Keywords: Li2MnO3 Metal-organic framework Oxygen vacancy Lithium-ion battery Electrochemical activity Keywords: Li2MnO3 Metal-organic framework Oxygen vacancy Lithium-ion battery Electrochemical activity 1 21 15 14 #/texts/20 text front_matter_candidate False low first_page_summary first_page_summary True p1:body_region:0 front_matter column_2_of_3 2 3 p1:front_matter:column_2_of_3:white [255, 255, 255] white False False [202.17, 362.1, 355.49, 169.21] Despite the dazzling theoretical capacity, the devasting electrochemical activity of Li2MnO3 (LMO) caused by the difficult oxidation of Mn 4+ impedes its practical application as the lithium-ion battery (LIB) cathode. T… Despite the dazzling theoretical capacity, the devasting electrochemical activity of Li2MnO3 (LMO) caused by the difficult oxidation of Mn 4+ impedes its practical application as the lithium-ion battery (LIB) cathode. T… 1 22 16 15 #/texts/21 text metadata False low first_page_metadata first_page_metadata True p1:body_region:0 front_matter column_2_of_3 2 3 p1:front_matter:column_2_of_3:white [255, 255, 255] white False False [202.17, 532.25, 355.42, 18.23] Ó 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved. Ó 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. 1 15 17 16 #/texts/14 section_header body_heading False low body_heading body_heading False None body_zone column_1_of_3 1 3 p1:body_zone:column_1_of_3:white [255, 255, 255] white False False [37.7, 605.71, 60.13, 7.96] 1. Introduction 1. Introduction 1 16 18 17 #/texts/15 text body True None body body False None body_zone column_1_of_3 1 3 p1:body_zone:column_1_of_3:white [255, 255, 255] white False False [37.59, 627.06, 251.11, 49.26] Lithium-ion batteries (LIBs) have become indispensable electrochemical energy storage and conversion devices due to their remarkable power density, satisfying cyclability, negligible memory effect, and environmental fri… Lithium-ion batteries (LIBs) have become indispensable electrochemical energy storage and conversion devices due to their remarkable power density, satisfying cyclability, negligible memory effect, and environmental fri… 1 17 19 18 #/texts/16 footnote footnote False low first_page_metadata first_page_metadata False None body_zone column_1_of_3 1 3 p1:body_zone:column_1_of_3:white [255, 255, 255] white False False [42.07, 692.51, 78.23, 13.76] ⇑ Corresponding authors. ⇑ Corresponding authors. 1 18 20 19 #/texts/17 footnote footnote False low first_page_metadata first_page_metadata False None body_zone column_1_of_3 1 3 p1:body_zone:column_1_of_3:off_white [247, 250, 251] off_white False False [48.81, 705.11, 220.95, 5.93] E-mail addresses: linxm@scnu.edu.cn (X. Lin), caiyp@scnu.edu.cn (Y. Cai). E-mail addresses: linxm@scnu.edu.cn (X. Lin), caiyp@scnu.edu.cn (Y. Cai). 1 19 21 20 #/texts/18 footnote footnote False low docling_footnote docling_footnote False None body_zone column_1_of_3 1 3 p1:body_zone:column_1_of_3:white [255, 255, 255] white False False [43.09, 712.68, 148.31, 7.21] 1 These authors contributed equally to this work. 1 These authors contributed equally to this work. 1 25 22 21 #/texts/24 page_footer page_footer False low first_page_metadata first_page_metadata False None bottom_margin column_1_of_3 1 3 p1:bottom_margin:column_1_of_3:white [255, 255, 255] white False True [37.59, 731.92, 136.91, 5.93] https://doi.org/10.1016/j.jechem.2023.05.014 1 4 23 22 #/texts/3 text front_matter_candidate False low outside_body_flow outside_body_flow True p1:body_region:0 front_matter column_2_of_3 2 3 p1:front_matter:front_panel:gray [229, 229, 229] gray True True [176.71, 135.67, 247.4, 1.59] j o u r n a l homepage: www.elsevier.com/locate/jechem j o u r n a l homepage: 1 23 24 23 #/texts/22 text body True None body body True p1:body_region:0 front_matter column_3_of_3 3 3 p1:front_matter:column_3_of_3:white [255, 255, 255] white False False [306.6, 597.64, 251.08, 91.09] [1]. Nevertheless, the development of the next-generation LIBs is bottlenecked by the dissatisfying electrochemical properties of the prevailing electrode materials. Following this, the exploration of high-performance c… [1]. Nevertheless, the development of the next-generation LIBs is bottlenecked by the dissatisfying electrochemical properties of the prevailing electrode materials. Following this, the exploration of high-performance c… 1 24 25 24 #/texts/23 text body True None body body True p1:body_region:0 body_zone column_3_of_3 3 3 p1:body_zone:column_3_of_3:white [255, 255, 255] white False False [306.6, 691.8, 251.07, 29.12] Owing to the enticing theoretical capacities that can better meet the future requirements of battery endurance, Li-rich layered materials have been extensively studied. Among them, Li2MnO3 Owing to the enticing theoretical capacities that can better meet the future requirements of battery endurance, Li-rich layered materials have been extensively studied. Among them, Li2MnO3 1 26 26 25 #/texts/25 page_footer page_footer False low first_page_metadata first_page_metadata True p1:body_region:0 bottom_margin column_1_of_3 1 3 p1:bottom_margin:column_1_of_3:white [255, 255, 255] white False False [37.59, 738.73, 520.05, 8.3] 2095-4956/ Ó 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved. 2095-4956/ Ó 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. 2 1 1 26 #/texts/26 page_header page_header False low docling_page_header docling_page_header True p2:body_region:0 top_margin column_1_of_2 1 2 p2:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 2 3 2 27 #/texts/28 text body True None body body True p2:body_region:0 front_matter column_1_of_2 1 2 p2:front_matter:column_1_of_2:white [255, 255, 255] white False False [37.59, 67.96, 251.14, 237.53] (LMO) has been regarded as a promising alternative for the mercantile LIB cathode materials such as LiCoO2 (LCO), Li[Ni x Co yMn1 x y ]O2 (NCM), and LiFePO4 (LFP) due to its superiority in theoretical capacity (460,… (LMO) has been regarded as a promising alternative for the mercantile LIB cathode materials such as LiCoO2 (LCO), Li[Ni x Co yMn1 x y ]O2 (NCM), and LiFePO4 (LFP) due to its superiority in theoretical capacity (460,… 2 4 3 28 #/texts/29 text body True None body body True p2:body_region:0 front_matter column_1_of_2 1 2 p2:front_matter:column_1_of_2:white [255, 255, 255] white False False [37.59, 308.56, 251.13, 279.37] It is widely substantiated and acknowledged that morphological features are crucial metrics in LIB electrode design and can be facilely adjusted by synthetic routes. The morphologyperformance relationship has been exten… It is widely substantiated and acknowledged that morphological features are crucial metrics in LIB electrode design and can be facilely adjusted by synthetic routes. The morphologyperformance relationship has been exten… 2 5 4 29 #/texts/30#prov0 text body True None body body True p2:body_region:0 bottom_margin column_1_of_2 1 2 p2:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 591.0, 251.13, 164.29] Apart from morphology control, the atomic structure and electronic configuration can significantly tune the electrochemical behaviors of LMO materials. Pristine LMO is confronted with the intrinsic undesirable electroch… Apart from morphology control, the atomic structure and electronic configuration can significantly tune the electrochemical behaviors of LMO materials. Pristine LMO is confronted with the intrinsic undesirable electroch… 2 2 5 30 #/texts/27 page_header page_header False low docling_page_header docling_page_header True p2:body_region:1 top_margin column_2_of_2 2 2 p2:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.77, 48.15, 139.86, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 2 6 6 31 #/texts/30#prov1 text body True None body body True p2:body_region:1 front_matter column_2_of_2 2 2 p2:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.59, 67.95, 251.09, 70.18] space, and suppressed oxygen shearing leading to detrimental structural change, the as-reported oxygen vacancy-enriched LMO materials display expected superiority in lithium storage with superior reversible capacity, pr… space, and suppressed oxygen shearing leading to detrimental structural change, the as-reported oxygen vacancy-enriched LMO materials display expected superiority in lithium storage with superior reversible capacity, pr… 2 7 7 32 #/texts/31 text body True None body body True p2:body_region:1 front_matter column_2_of_2 2 2 p2:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.59, 141.14, 251.12, 258.51] Inspired by these research advances, we systematically develop a multifunctional synthetic protocol to integrate the MOFtemplated method and oxygen-deficient strategy for optimizing morphological and atomic structure. T… Inspired by these research advances, we systematically develop a multifunctional synthetic protocol to integrate the MOFtemplated method and oxygen-deficient strategy for optimizing morphological and atomic structure. T… 2 8 8 33 #/texts/32 section_header body_heading False low body_heading body_heading True p2:body_region:1 body_zone column_2_of_2 2 2 p2:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.65, 433.65, 62.99, 7.96] 2. Experimental 2. Experimental 2 9 9 34 #/texts/33 section_header body_heading False low body_heading body_heading True p2:body_region:1 body_zone column_2_of_2 2 2 p2:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.65, 455.0, 90.87, 7.42] 2.1. Material preparation 2.1. Material preparation 2 10 10 35 #/texts/34 text body True None body body True p2:body_region:1 body_zone column_2_of_2 2 2 p2:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.59, 475.92, 251.09, 174.78] The Mn-MOFs with carboxyl-based ligands were prepared by solvothermal reactions according to the previous study [22,23]. Mn(CH3COO)2  4H2O (1 mmol) was dissolved in 6 mL of N,N -dimethylformamide (DMF)/methanol ( V D: … The Mn-MOFs with carboxyl-based ligands were prepared by solvothermal reactions according to the previous study [22,23]. Mn(CH3COO)2  4H2O (1 mmol) was dissolved in 6 mL of N,N -dimethylformamide (DMF)/methanol ( V D: … 2 11 11 36 #/texts/35 text body True None body body True p2:body_region:1 bottom_margin column_2_of_2 2 2 p2:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.6, 653.76, 251.1, 102.29] The LMO materials without oxygen vacancy were fabricated via pyrolysis of the Mn-MOF templates with Li2CO3 as the Li source with a molar ratio of Li: Mn = 2.05:1. The dried MOFs were mixed with Li2CO3 by ball-milling an… The LMO materials without oxygen vacancy were fabricated via pyrolysis of the Mn-MOF templates with Li2CO3 as the Li source with a molar ratio of Li: Mn = 2.05:1. The dried MOFs were mixed with Li2CO3 by ball-milling an… 2 12 12 37 #/texts/36 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p2:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 165 165 3 1 1 38 #/texts/37 page_header page_header False low docling_page_header docling_page_header True p3:body_region:0 top_margin column_1_of_2 1 2 p3:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 3 3 2 39 #/texts/39 text body True None body body True p3:body_region:0 front_matter column_1_of_2 1 2 p3:front_matter:column_1_of_2:white [255, 255, 255] white False False [37.59, 67.96, 251.06, 17.85] 8 h after mixing with stearic acid with a molar ratio of 20:1 in N2 according to the prior report [21]. 8 h after mixing with stearic acid with a molar ratio of 20:1 in N2 according to the prior report [21]. 3 4 3 40 #/texts/40 section_header body_heading False low body_heading body_heading True p3:body_region:0 body_zone column_1_of_2 1 2 p3:body_zone:column_1_of_2:white [255, 255, 255] white False False [37.7, 99.31, 106.87, 7.42] 2.2. Material characterization 2.2. Material characterization 3 5 4 41 #/texts/41 text body True None body body True p3:body_region:0 body_zone column_1_of_2 1 2 p3:body_zone:column_1_of_2:white [255, 255, 255] white False False [37.59, 120.23, 251.1, 227.1] The crystallographic data and phase analyses of the Mn-MOFs and LMO materials were implemented with an X-ray diffraction spectrophotometer (XRD, Ultima IV, Japan) using Cu K a radiation with a scanning rate of 10 ° min … The crystallographic data and phase analyses of the Mn-MOFs and LMO materials were implemented with an X-ray diffraction spectrophotometer (XRD, Ultima IV, Japan) using Cu K a radiation with a scanning rate of 10 ° min … 3 6 5 42 #/texts/42 section_header body_heading False low body_heading body_heading True p3:body_region:0 body_zone column_1_of_2 1 2 p3:body_zone:column_1_of_2:white [255, 255, 255] white False False [37.7, 360.83, 123.51, 7.42] 2.3. Electrochemical measurement 2.3. Electrochemical measurement 3 7 6 43 #/texts/43 text body True None body body True p3:body_region:0 body_zone column_1_of_2 1 2 p3:body_zone:column_1_of_2:white [255, 255, 255] white False False [37.59, 381.75, 251.13, 310.78] Electrochemical measurements of LMO were investigated using CR2032 coin cells. The cathode electrodes were prepared by using as-prepared LMO, acetylene black, and polyvinylidene fluoride (PVDF) with a weight ratio of 7:… Electrochemical measurements of LMO were investigated using CR2032 coin cells. The cathode electrodes were prepared by using as-prepared LMO, acetylene black, and polyvinylidene fluoride (PVDF) with a weight ratio of 7:… 3 8 7 44 #/texts/44 section_header body_heading False low body_heading body_heading True p3:body_region:0 body_zone column_1_of_2 1 2 p3:body_zone:column_1_of_2:white [255, 255, 255] white False False [37.7, 706.04, 77.39, 7.42] 2.4. Theoretical study 2.4. Theoretical study 3 9 8 45 #/texts/45#prov0 text body True None body body True p3:body_region:0 bottom_margin column_1_of_2 1 2 p3:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 726.95, 251.1, 28.34] All the spin-polarized (AFM) density functional theoretical (DFT) calculations were conducted based on the Vienna Ab-inito Simulation Package (VASP) [24]. The electron-ion interactions were All the spin-polarized (AFM) density functional theoretical (DFT) calculations were conducted based on the Vienna Ab-inito Simulation Package (VASP) [24]. The electron-ion interactions were 3 2 9 46 #/texts/38 page_header page_header False low docling_page_header docling_page_header True p3:body_region:1 top_margin column_2_of_2 2 2 p3:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.71, 48.21, 139.91, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 3 10 10 47 #/texts/45#prov1 text body True None body body True p3:body_region:1 front_matter column_2_of_2 2 2 p3:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.6, 67.95, 251.09, 132.94] described by the Projected Augmented-Wave (PAW) potentials, while the exchange-correlation interactions were calculated by employing the Perdew-Burke-Enzerhof (PBE) pseudopotentials of Generalized Gradient Approximation… described by the Projected Augmented-Wave (PAW) potentials, while the exchange-correlation interactions were calculated by employing the Perdew-Burke-Enzerhof (PBE) pseudopotentials of Generalized Gradient Approximation… 3 11 11 48 #/texts/46 section_header body_heading False low body_heading body_heading True p3:body_region:1 body_zone column_2_of_2 2 2 p3:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.65, 213.96, 99.65, 7.96] 3. Results and discussion 3. Results and discussion 3 12 12 49 #/texts/47 section_header body_heading False low body_heading body_heading True p3:body_region:1 body_zone column_2_of_2 2 2 p3:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.65, 235.31, 160.25, 7.42] 3.1. Structural and morphological properties 3.1. Structural and morphological properties 3 13 13 50 #/texts/48 text body True None body body True p3:body_region:1 body_zone column_2_of_2 2 2 p3:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.6, 256.23, 251.09, 133.7] The synthetic procedure of Ov-LMO materials via solvothermal reaction, solid-state lithiation at high temperature, and lowtemperature reduction is schematically illustrated in Fig. 1(a). The high phase purity and crysta… The synthetic procedure of Ov-LMO materials via solvothermal reaction, solid-state lithiation at high temperature, and lowtemperature reduction is schematically illustrated in Fig. 1(a). The high phase purity and crysta… 3 14 14 51 #/texts/49 text body True None body body True p3:body_region:1 body_zone column_2_of_2 2 2 p3:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.59, 392.24, 251.09, 331.7] Powder XRD characterization was utilized to estimate the crystallographic configuration of LMO and Ov-LMO derived from MnBDC, Mn-BTC, and Mn-PTC. The XRD patterns of (Ov-)BDC-LMO (Fig. 1b), (Ov-)BTC-LMO (Fig. 1e), and (… Powder XRD characterization was utilized to estimate the crystallographic configuration of LMO and Ov-LMO derived from MnBDC, Mn-BTC, and Mn-PTC. The XRD patterns of (Ov-)BDC-LMO (Fig. 1b), (Ov-)BTC-LMO (Fig. 1e), and (… 3 15 15 52 #/texts/50#prov0 text body True None body body True p3:body_region:1 bottom_margin column_2_of_2 2 2 p3:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.6, 726.95, 251.09, 28.34] The Raman spectra were conducted to evaluate and compare the structural characteristics of LMO and Ov-LMO. As delivered in Fig. 2(a-c), the strong characteristic peaks at the high-frequency The Raman spectra were conducted to evaluate and compare the structural characteristics of LMO and Ov-LMO. As delivered in Fig. 2(a-c), the strong characteristic peaks at the high-frequency 3 16 16 53 #/texts/51 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p3:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 166 166 4 3 1 54 #/texts/52 page_header page_header False low docling_page_header docling_page_header False None top_margin left None None p4:top_margin:left:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 4 4 2 55 #/texts/53 page_header page_header False low docling_page_header docling_page_header False None top_margin right None None p4:top_margin:right:white [255, 255, 255] white False False [417.77, 48.15, 139.86, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 4 5 3 56 #/texts/54 caption caption False low outside_body_flow_caption outside_body_flow_caption False None page_body full None None p4:page_body:full:white [255, 255, 255] white False False [37.59, 689.57, 520.05, 14.84] Fig. 1. (a) The synthetic procedure of Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO. XRD patterns of (b) (Ov-)BDC-LMO, (e) (Ov-)BTC-LMO, and (h) (Ov-)PTC-LMO. Rietveld refinements of (c) Ov-BDC-LMO, (d) BDC-LMO, (f) Ov-BTC-LM… Fig. 1. (a) The synthetic procedure of Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO. XRD patterns of (b) (Ov-)BDC-LMO, (e) (Ov-)BTC-LMO, and (h) (Ov-)PTC-LMO. Rietveld refinements of (c) Ov-BDC-LMO, (d) BDC-LMO, (f) Ov-BTC-LM… 4 1 4 57 #/texts/50#prov1 text body True None body body False None bottom_margin left_crossing None None p4:bottom_margin:left_crossing:white [255, 255, 255] white False False [37.59, 725.88, 251.09, 28.34] region and the ones at the low-frequency region are related to the Mn A O and Li A O bonds, respectively, manifesting the high purity of all samples [20]. The Raman peak intensities of Ov-LMO are pro- region and the ones at the low-frequency region are related to the Mn A O and Li A O bonds, respectively, manifesting the high purity of all samples [20]. The Raman peak intensities of Ov-LMO are pro- 4 2 5 58 #/texts/50#prov2 text body True None body body False None bottom_margin right_crossing None None p4:bottom_margin:right_crossing:white [255, 255, 255] white False False [306.59, 725.88, 251.07, 28.34] foundly lower than those of LMO, which can be ascribed to the enhanced conductivity caused by the oxygen vacancies [33]. Notably, the Raman peak intensity ratios of the characteristic peaks foundly lower than those of LMO, which can be ascribed to the enhanced conductivity caused by the oxygen vacancies [33]. Notably, the Raman peak intensity ratios of the characteristic peaks 4 6 6 59 #/texts/55 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin left_crossing None None p4:bottom_margin:left_crossing:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 167 167 5 2 1 60 #/texts/56 page_header page_header False low docling_page_header docling_page_header True p5:body_region:0 top_margin column_1_of_2 1 2 p5:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 5 3 2 61 #/texts/57 page_header page_header False low docling_page_header docling_page_header True p5:body_region:1 top_margin column_2_of_2 2 2 p5:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.71, 48.21, 139.91, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 5 4 3 62 #/texts/58 caption caption False low outside_body_flow_caption outside_body_flow_caption False None page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [37.59, 576.81, 520.03, 14.84] Fig. 2. (a-c) The panoramic Raman spectra and the high-resolution XPS spectra of (d-f) Li 1 s , (g-i) O 1 s , and (j-l) Mn 2 p for (Ov-)BDC-LMO, (Ov-)BTC-LMO, and (Ov-)PTC-LMO, respectively. Fig. 2. (a-c) The panoramic Raman spectra and the high-resolution XPS spectra of (d-f) Li 1 s , (g-i) O 1 s , and (j-l) Mn 2 p for (Ov-)BDC-LMO, (Ov-)BTC-LMO, and (Ov-)PTC-LMO, respectively. 5 1 4 63 #/texts/50#prov3 text body True None body body True p5:body_region:0 bottom_margin column_1_of_2 1 2 p5:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 611.37, 251.13, 134.68] centered at  610 and  500 cm 1 increase with the existence of oxygen vacancies (1.34, 1.67, 1.35, 1.54, 1.29, and 1.52 for BDCLMO, Ov-BDC-LMO, BTC-LMO, Ov-BTC-LMO, PTC-LMO, and Ov-PTC-LMO, respectively), among which… centered at  610 and  500 cm 1 increase with the existence of oxygen vacancies (1.34, 1.67, 1.35, 1.54, 1.29, and 1.52 for BDCLMO, Ov-BDC-LMO, BTC-LMO, Ov-BTC-LMO, PTC-LMO, and Ov-PTC-LMO, respectively), among which… 5 5 5 64 #/texts/59 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [306.59, 613.11, 251.09, 59.74] and additional sharp ( g = 2.003) signals compared with their counterparts without oxygen vacancy, corresponding to the unpaired electrons of Mn 4+ and the typical feature of oxygen vacancies, respectively [21,34], whic… and additional sharp ( g = 2.003) signals compared with their counterparts without oxygen vacancy, corresponding to the unpaired electrons of Mn 4+ and the typical feature of oxygen vacancies, respectively [21,34], whic… 5 6 6 65 #/texts/60#prov0 text body True None body body True p5:body_region:1 bottom_margin column_2_of_2 2 2 p5:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.59, 675.87, 251.09, 70.18] XPS measurements were implemented to elucidate the compositional features and chemical states in LMO and Ov-LMO materials. The survey-scan XPS spectra reveal the coexistence of Li, Mn, and O in all samples, in which the… XPS measurements were implemented to elucidate the compositional features and chemical states in LMO and Ov-LMO materials. The survey-scan XPS spectra reveal the coexistence of Li, Mn, and O in all samples, in which the… 5 7 7 66 #/texts/61 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p5:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 168 168 6 2 1 67 #/texts/62 page_header page_header False low docling_page_header docling_page_header True p6:body_region:0 top_margin column_1_of_2 1 2 p6:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 6 1 2 68 #/texts/60#prov1 text body True None body body True p6:body_region:0 page_body column_1_of_2 1 2 p6:page_body:column_1_of_2:white [255, 255, 255] white False False [37.59, 67.96, 251.13, 363.05] strategy. The core-level O 1 s spectra can be deconvoluted into 2 sub-peaks located at 531.8 and 529.3 eV (Fig. 2g-i), correlating to the surficial absorbed and lattice oxygen, respectively, whose intensity ratios (0.73… strategy. The core-level O 1 s spectra can be deconvoluted into 2 sub-peaks located at 531.8 and 529.3 eV (Fig. 2g-i), correlating to the surficial absorbed and lattice oxygen, respectively, whose intensity ratios (0.73… 6 4 3 69 #/texts/64#prov0 text body True None body body True p6:body_region:0 bottom_margin column_1_of_2 1 2 p6:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 434.08, 251.13, 321.21] The morphological features and architecture of the MOF precursors, LMO, and Ov-LMO were systematically analyzed by SEM and TEM characterizations. The SEM image of the Mn-BDC precursor (Fig. 3a) features a spongy lamella… The morphological features and architecture of the MOF precursors, LMO, and Ov-LMO were systematically analyzed by SEM and TEM characterizations. The SEM image of the Mn-BDC precursor (Fig. 3a) features a spongy lamella… 6 3 4 70 #/texts/63 page_header page_header False low docling_page_header docling_page_header True p6:body_region:1 top_margin column_2_of_2 2 2 p6:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.77, 48.15, 139.86, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 6 5 5 71 #/texts/64#prov1 text body True None body body True p6:body_region:1 page_body column_2_of_2 2 2 p6:page_body:column_2_of_2:white [255, 255, 255] white False False [306.59, 67.95, 251.1, 59.69] tributed on the well-retained primary structure, in turn manifesting the negligible destruction of primary particles by the lowtemperature reduction [14,38], which ameliorates the surface property, provides abundant act… tributed on the well-retained primary structure, in turn manifesting the negligible destruction of primary particles by the lowtemperature reduction [14,38], which ameliorates the surface property, provides abundant act… 6 6 6 72 #/texts/65 text body True None body body True p6:body_region:1 page_body column_2_of_2 2 2 p6:page_body:column_2_of_2:white [255, 255, 255] white False False [306.59, 130.71, 251.12, 279.38] Correspondingly, the N2 physisorption isotherms were acquired at 77 K to further demonstrate the porous traits, as elaborated in Fig. S5(a). The BET surface areas of Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO were found to … Correspondingly, the N2 physisorption isotherms were acquired at 77 K to further demonstrate the porous traits, as elaborated in Fig. S5(a). The BET surface areas of Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO were found to … 6 7 7 73 #/texts/66#prov0 text body True None body body True p6:body_region:1 bottom_margin column_2_of_2 2 2 p6:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.59, 413.16, 251.11, 342.13] To further unveil the internal architectures of the LMO and Ov-LMO products, the TEM technique was adopted. As disclosed by the TEM images, BDC-LMO (Fig. 4a) and Ov-BDC-LMO (Fig. 4d) feature a layered architecture compo… To further unveil the internal architectures of the LMO and Ov-LMO products, the TEM technique was adopted. As disclosed by the TEM images, BDC-LMO (Fig. 4a) and Ov-BDC-LMO (Fig. 4d) feature a layered architecture compo… 6 8 8 74 #/texts/67 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p6:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 169 169 7 2 1 75 #/texts/68 page_header page_header False low docling_page_header docling_page_header True p7:body_region:0 top_margin column_1_of_2 1 2 p7:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 7 3 2 76 #/texts/69 page_header page_header False low docling_page_header docling_page_header True p7:body_region:1 top_margin column_2_of_2 2 2 p7:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.71, 48.21, 139.91, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 7 4 3 77 #/texts/70 caption caption False low outside_body_flow_caption outside_body_flow_caption False None front_matter column_1_of_2 1 2 p7:front_matter:column_1_of_2:white [255, 255, 255] white False False [51.02, 441.88, 493.16, 6.37] Fig. 3. The SEM images of (a) Mn-BDC, (b) BDC-LMO, (c) Ov-BDC-LMO, (d) Mn-BTC, (e) BTC-LMO, (f) Ov-BTC-LMO, (g) Mn-PTC, (h) PTC-LMO, and (i) Ov-PTC-LMO. Fig. 3. The SEM images of (a) Mn-BDC, (b) BDC-LMO, (c) Ov-BDC-LMO, (d) Mn-BTC, (e) BTC-LMO, (f) Ov-BTC-LMO, (g) Mn-PTC, (h) PTC-LMO, and (i) Ov-PTC-LMO. 7 1 4 78 #/texts/66#prov1 text body True None body body True p7:body_region:0 front_matter column_1_of_2 1 2 p7:front_matter:column_1_of_2:white [255, 255, 255] white False False [37.59, 475.92, 251.13, 227.1] the predominant layered structure and minority spinel domain. To support this assumption from the atomic level, the spherical aberration-corrected HAADF-STEM and spherical aberrationcorrected annular bright-field STEM(A… the predominant layered structure and minority spinel domain. To support this assumption from the atomic level, the spherical aberration-corrected HAADF-STEM and spherical aberrationcorrected annular bright-field STEM(A… 7 5 5 79 #/texts/71 section_header body_heading False low body_heading body_heading True p7:body_region:0 body_zone column_1_of_2 1 2 p7:body_zone:column_1_of_2:white [255, 255, 255] white False False [37.7, 716.52, 110.65, 7.42] 3.2. Electrochemical properties 3.2. Electrochemical properties 7 6 6 80 #/texts/72#prov0 text body True None body body True p7:body_region:0 bottom_margin column_1_of_2 1 2 p7:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 737.44, 251.08, 17.85] The electrochemical properties of LMO and Ov-LMO were comprehensively studied to illustrate the efficaciousness of the The electrochemical properties of LMO and Ov-LMO were comprehensively studied to illustrate the efficaciousness of the 7 7 7 81 #/texts/72#prov1 text body True None body body True p7:body_region:1 front_matter column_2_of_2 2 2 p7:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.59, 475.92, 251.1, 216.61] oxygen-deficient strategy for the activation and optimization of Li2MnO3 as an advanced LIB cathode. Ov-BDC-LMO (Fig. 6a), Ov-BTC-LMO (Fig. 6b), and Ov-PTC-LMO (Fig. 6c) samples exhibit reversible capacities of 179.2, 1… oxygen-deficient strategy for the activation and optimization of Li2MnO3 as an advanced LIB cathode. Ov-BDC-LMO (Fig. 6a), Ov-BTC-LMO (Fig. 6b), and Ov-PTC-LMO (Fig. 6c) samples exhibit reversible capacities of 179.2, 1… 7 8 8 82 #/texts/73#prov0 text body True None body body True p7:body_region:1 bottom_margin column_2_of_2 2 2 p7:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.6, 695.6, 251.08, 59.7] As expected, the Ov-LMO samples feature superiority in rate performance compared with their counterparts without oxygen vacancy (Fig. 6d-f). Superior reversible capacities are presented by Ov-BDC-LMO (199.5, 187.9, 167.… As expected, the Ov-LMO samples feature superiority in rate performance compared with their counterparts without oxygen vacancy (Fig. 6d-f). Superior reversible capacities are presented by Ov-BDC-LMO (199.5, 187.9, 167.… 7 9 9 83 #/texts/74 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p7:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.38, 5.93] 170 170 8 3 1 84 #/texts/75 page_header page_header False low docling_page_header docling_page_header True p8:body_region:0 top_margin column_1_of_2 1 2 p8:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 8 4 2 85 #/texts/76 page_header page_header False low docling_page_header docling_page_header True p8:body_region:1 top_margin column_2_of_2 2 2 p8:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.77, 48.15, 139.86, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 8 5 3 86 #/texts/77 caption caption False low outside_body_flow_caption outside_body_flow_caption False None page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [37.59, 603.74, 520.03, 14.84] Fig. 4. (a-f) TEM images, (g-l) HRTEM images, (m-r) SAED patterns, and (s-x) HAADF-STEM images and corresponding element mappings of BDC-LMO, BTC-LMO, PTC-LMO, Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO, respectively. Fig. 4. (a-f) TEM images, (g-l) HRTEM images, (m-r) SAED patterns, and (s-x) HAADF-STEM images and corresponding element mappings of BDC-LMO, BTC-LMO, PTC-LMO, Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO, respectively. 8 1 4 87 #/texts/73#prov1 text body True None body body True p8:body_region:0 bottom_margin column_1_of_2 1 2 p8:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 640.04, 251.12, 112.03] respectively), and Ov-PTC-LMO (110.4, 97.6, 80.7, 57.8, and 39.5 mA h g 1 at 0.1, 0.2, 0.4, 1, and 2 C, respectively) at different current densities. In contrast, BDC-LMO (96.2, 76.3, 63.2, 43.4, and 37.9 mA h g 1 a… respectively), and Ov-PTC-LMO (110.4, 97.6, 80.7, 57.8, and 39.5 mA h g 1 at 0.1, 0.2, 0.4, 1, and 2 C, respectively) at different current densities. In contrast, BDC-LMO (96.2, 76.3, 63.2, 43.4, and 37.9 mA h g 1 a… 8 2 5 88 #/texts/73#prov2 text body True None body body True p8:body_region:1 bottom_margin column_2_of_2 2 2 p8:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.6, 638.24, 251.1, 113.82] ities of other samples (198.9, 124.3, 116.2, 53.9, and 45.5 mA h g 1 for Ov-BTC-LMO, Ov-PTC-LMO, BDC-LMO, BTC-LMO, and PTC-LMO, respectively) after the rate recovery. It is noteworthy that the MnBDC-derived samples ou… ities of other samples (198.9, 124.3, 116.2, 53.9, and 45.5 mA h g 1 for Ov-BTC-LMO, Ov-PTC-LMO, BDC-LMO, BTC-LMO, and PTC-LMO, respectively) after the rate recovery. It is noteworthy that the MnBDC-derived samples ou… 8 6 6 89 #/texts/78 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p8:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 171 171 9 2 1 90 #/texts/79 page_header page_header False low docling_page_header docling_page_header False None top_margin column_1_of_2 1 2 p9:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 9 3 2 91 #/texts/80 page_header page_header False low docling_page_header docling_page_header False None top_margin column_2_of_2 2 2 p9:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.71, 48.21, 139.91, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 9 4 3 92 #/texts/81 caption caption False low outside_body_flow_caption outside_body_flow_caption False None page_body column_1_of_2 1 2 p9:page_body:column_1_of_2:white [255, 255, 255] white False False [37.59, 629.65, 520.04, 14.9] Fig. 5. (a-f) Spherical aberration-corrected HAADF-STEM and (g-l) spherical aberration-corrected ABF-STEM images for BDC-LMO, BTC-LMO, PTC-LMO, Ov-BDC-LMO, OvBTC-LMO, and Ov-PTC-LMO, respectively. Fig. 5. (a-f) Spherical aberration-corrected HAADF-STEM and (g-l) spherical aberration-corrected ABF-STEM images for BDC-LMO, BTC-LMO, PTC-LMO, Ov-BDC-LMO, OvBTC-LMO, and Ov-PTC-LMO, respectively. 9 1 4 93 #/texts/73#prov3 text body True None body body False None bottom_margin column_1_of_2 1 2 p9:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 665.95, 251.13, 80.66] cycling durability of Ov-BDC-LMO with a reversible capacity of 100.1 mA h g 1 outperforming those of Ov-BTC-LMO (95.5 mA h g 1 ) and Ov-PTC-LMO (58.9 mA h g 1 ). Moreover, the cross-sectional SEM images are disclo… cycling durability of Ov-BDC-LMO with a reversible capacity of 100.1 mA h g 1 outperforming those of Ov-BTC-LMO (95.5 mA h g 1 ) and Ov-PTC-LMO (58.9 mA h g 1 ). Moreover, the cross-sectional SEM images are disclo… 9 5 5 94 #/texts/82 text body True None body body False None bottom_margin column_2_of_2 2 2 p9:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.6, 665.95, 251.12, 80.67] The galvanostatic charge/discharge (GCD) profiles of all samples performed at 20 mA g 1 were recorded to better demonstrate the working mechanism of the activation process of LMO and Ov-LMO electrodes. As depicted in … The galvanostatic charge/discharge (GCD) profiles of all samples performed at 20 mA g 1 were recorded to better demonstrate the working mechanism of the activation process of LMO and Ov-LMO electrodes. As depicted in … 9 6 6 95 #/texts/83 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p9:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 172 172 10 1 1 96 #/texts/84 page_header page_header False low docling_page_header docling_page_header True p10:body_region:0 top_margin column_1_of_2 1 2 p10:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 10 2 2 97 #/texts/85 page_header page_header False low docling_page_header docling_page_header True p10:body_region:1 top_margin column_2_of_2 2 2 p10:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.77, 48.15, 139.86, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 10 3 3 98 #/texts/86 caption caption False low outside_body_flow_caption outside_body_flow_caption False None page_body column_1_of_2 1 2 p10:page_body:column_1_of_2:white [255, 255, 255] white False False [37.59, 530.55, 520.08, 24.48] Fig. 6. The cycling performance at 20 mA g 1 for 200 loops of (a) (Ov-)BDC-LMO, (b) (Ov-)BTC-LMO, and (c) (Ov-)PTC-LMO. The rate performance at 0.1, 0.2, 0.4, 1, and 2 C (1 C = 200 mA g 1 ) of (d) (Ov-)BDC-LMO, (e) … Fig. 6. The cycling performance at 20 mA g 1 for 200 loops of (a) (Ov-)BDC-LMO, (b) (Ov-)BTC-LMO, and (c) (Ov-)PTC-LMO. The rate performance at 0.1, 0.2, 0.4, 1, and 2 C (1 C = 200 mA g 1 ) of (d) (Ov-)BDC-LMO, (e) … 10 4 4 99 #/texts/87 text body True None body body True p10:body_region:0 bottom_margin column_1_of_2 1 2 p10:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 576.49, 251.1, 153.85] 38.2%, respectively. Two successive charge plateaus can be observed at  3.9 and  4.4 V in the Ov-LMO samples during the first cycle, while merely a long voltage plateau appears above 4.4 V in the LMO samples, which ca… 38.2%, respectively. Two successive charge plateaus can be observed at  3.9 and  4.4 V in the Ov-LMO samples during the first cycle, while merely a long voltage plateau appears above 4.4 V in the LMO samples, which ca… 10 5 5 100 #/texts/88#prov0 text body True None body body True p10:body_region:0 bottom_margin column_1_of_2 1 2 p10:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 733.36, 251.1, 17.91] Furthermore, to unravel the lithium storage behaviors of all samples during cycling from electronic conductivity and lithium Furthermore, to unravel the lithium storage behaviors of all samples during cycling from electronic conductivity and lithium 10 6 6 101 #/texts/88#prov1 text body True None body body True p10:body_region:1 bottom_margin column_2_of_2 2 2 p10:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.59, 576.49, 251.09, 174.78] diffusivity, EIS measurements were conducted for better comparison. As illustrated in Fig. S9(a-c) and Fig. 6(j-l), Nyquist plots of all samples before and after cycling can be divided into semicircles at high and middl… diffusivity, EIS measurements were conducted for better comparison. As illustrated in Fig. S9(a-c) and Fig. 6(j-l), Nyquist plots of all samples before and after cycling can be divided into semicircles at high and middl… 10 7 7 102 #/texts/89 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p10:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 173 173 11 2 1 103 #/texts/90 page_header page_header False low docling_page_header docling_page_header True p11:body_region:0 top_margin column_1_of_2 1 2 p11:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 11 1 2 104 #/texts/88#prov2 text body True None body body True p11:body_region:0 page_body column_1_of_2 1 2 p11:page_body:column_1_of_2:white [255, 255, 255] white False False [37.59, 67.96, 251.1, 122.45] induced by the oxygen vacancies. The resistance values after 100 cycles were also estimated and compared to further illustrate the enhanced electron/ion conductivity related to the activation process, as tabulated in Ta… induced by the oxygen vacancies. The resistance values after 100 cycles were also estimated and compared to further illustrate the enhanced electron/ion conductivity related to the activation process, as tabulated in Ta… 11 4 3 105 #/texts/92 text body True None body body True p11:body_region:0 page_body column_1_of_2 1 2 p11:page_body:column_1_of_2:white [255, 255, 255] white False False [37.59, 193.47, 251.14, 279.37] To further investigate the lithium diffusion kinetics, the formula D Li+ = R 2 T 2 /(2 A 2 n 4 F 4 c 2 r 2 ) was applied, where D Li+ , R, T , A , n , F, c , and r symbolize the lithium-ion diffusion coefficient, gas co… To further investigate the lithium diffusion kinetics, the formula D Li+ = R 2 T 2 /(2 A 2 n 4 F 4 c 2 r 2 ) was applied, where D Li+ , R, T , A , n , F, c , and r symbolize the lithium-ion diffusion coefficient, gas co… 11 5 4 106 #/texts/93 text body True None body body True p11:body_region:0 bottom_margin column_1_of_2 1 2 p11:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 475.92, 251.13, 258.45] The CV curves were further studied to unveil the working mechanisms of LMO and Ov-LMO in lithium storage. The CV curves for the initial three cycles of six samples are recorded in Fig. 7(a-f), which differentiate the wo… The CV curves were further studied to unveil the working mechanisms of LMO and Ov-LMO in lithium storage. The CV curves for the initial three cycles of six samples are recorded in Fig. 7(a-f), which differentiate the wo… 11 6 5 107 #/texts/94#prov0 text body True None body body True p11:body_region:0 bottom_margin column_1_of_2 1 2 p11:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 737.44, 251.08, 17.85] The above observations expound the different working mechanisms of the Ov-LMO compared with the primitive materials with- The above observations expound the different working mechanisms of the Ov-LMO compared with the primitive materials with- 11 3 6 108 #/texts/91 page_header page_header False low docling_page_header docling_page_header True p11:body_region:1 top_margin column_2_of_2 2 2 p11:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.71, 48.21, 139.91, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 11 7 7 109 #/texts/94#prov1 text body True None body body True p11:body_region:1 page_body column_2_of_2 2 2 p11:page_body:column_2_of_2:white [255, 255, 255] white False False [306.59, 67.95, 251.08, 216.62] out oxygen vacancy, particularly during the first cycle. For better understanding, the redox activities at the first (de)lithiation cycle are schematically illustrated. Fig. 7(g) portrays the reversible transformation o… out oxygen vacancy, particularly during the first cycle. For better understanding, the redox activities at the first (de)lithiation cycle are schematically illustrated. Fig. 7(g) portrays the reversible transformation o… 11 8 8 110 #/texts/95 text body True None body body True p11:body_region:1 page_body column_2_of_2 2 2 p11:page_body:column_2_of_2:white [255, 255, 255] white False False [306.59, 287.64, 251.1, 394.46] The quantitation of pseudocapacitive behaviors can be utilized to interpret the electrochemical kinetics, reflect the Li + diffusion velocity, and further demonstrate the rate capability of electrode materials [5,52]. W… The quantitation of pseudocapacitive behaviors can be utilized to interpret the electrochemical kinetics, reflect the Li + diffusion velocity, and further demonstrate the rate capability of electrode materials [5,52]. W… 11 9 9 111 #/texts/96#prov0 text body True None body body True p11:body_region:1 bottom_margin column_2_of_2 2 2 p11:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.6, 685.11, 251.08, 70.18] Predictably, the Ov-LMO samples (89.8%, 86.6%, and 79.7% for Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO, respectively) hold superior pseudocapacitive contributions compared to their corresponding counterparts (51.9%, 45.2%,… Predictably, the Ov-LMO samples (89.8%, 86.6%, and 79.7% for Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO, respectively) hold superior pseudocapacitive contributions compared to their corresponding counterparts (51.9%, 45.2%,… 11 10 10 112 #/texts/97 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p11:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 174 174 12 1 1 113 #/texts/98 page_header page_header False low docling_page_header docling_page_header False None top_margin left None None p12:top_margin:left:white [255, 255, 255] white False False [37.59, 48.2, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 12 2 2 114 #/texts/99 page_header page_header False low docling_page_header docling_page_header False None top_margin right None None p12:top_margin:right:white [255, 255, 255] white False False [417.77, 48.15, 139.86, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 12 3 3 115 #/texts/100 caption caption False low outside_body_flow_caption outside_body_flow_caption False None bottom_margin full None None p12:bottom_margin:full:white [255, 255, 255] white False False [37.59, 714.69, 520.07, 24.53] Fig. 7. The CV curves for the first 3 cycles at 0.2 mV s 1 for (a) Ov-BDC-LMO, (b) Ov-BTC-LMO, (c) Ov-PTC-LMO, (d) BDC-LMO, (e) BTC-LMO, and (f) PTC-LMO. The schematic illustrations of the first cycle for (g) Ov-LMO a… Fig. 7. The CV curves for the first 3 cycles at 0.2 mV s 1 for (a) Ov-BDC-LMO, (b) Ov-BTC-LMO, (c) Ov-PTC-LMO, (d) BDC-LMO, (e) BTC-LMO, and (f) PTC-LMO. The schematic illustrations of the first cycle for (g) Ov-LMO a… 12 4 4 116 #/texts/101 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin right_crossing None None p12:bottom_margin:right_crossing:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 175 175 13 2 1 117 #/texts/102 page_header page_header False low docling_page_header docling_page_header True p13:body_region:0 top_margin column_1_of_2 1 2 p13:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 13 1 2 118 #/texts/96#prov1 text body True None body body True p13:body_region:0 front_matter column_1_of_2 1 2 p13:front_matter:column_1_of_2:white [255, 255, 255] white False False [37.59, 67.96, 251.12, 185.26] samples are also evaluated, as disclosed in Figs. S13-S18. All samples perform increasing pseudocapacitive-dominant behaviors as the sweep rate upgrades, among which the Ov-LMO samples (Fig. 7l-n) significantly outperfo… samples are also evaluated, as disclosed in Figs. S13-S18. All samples perform increasing pseudocapacitive-dominant behaviors as the sweep rate upgrades, among which the Ov-LMO samples (Fig. 7l-n) significantly outperfo… 13 4 3 119 #/texts/104 text body True None body body True p13:body_region:0 front_matter column_1_of_2 1 2 p13:front_matter:column_1_of_2:white [255, 255, 255] white False False [37.59, 256.23, 251.13, 242.64] The galvanostatic intermittent titration technique (GITT) measurement was conducted to further support the effectiveness of the oxygen-deficient strategy for exalted lithium diffusivity of LMO materials. The whole-step … The galvanostatic intermittent titration technique (GITT) measurement was conducted to further support the effectiveness of the oxygen-deficient strategy for exalted lithium diffusivity of LMO materials. The whole-step … 13 5 4 120 #/texts/105#prov0 text body True None body body True p13:body_region:0 bottom_margin column_1_of_2 1 2 p13:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 501.88, 251.11, 248.02] For a better understanding, the working mechanism of the advantageous Li + diffusion of the Ov-LMO samples is schematically illustrated in Fig. 8(h) to emphasize the optimized lithium storage behaviors brought by oxygen… For a better understanding, the working mechanism of the advantageous Li + diffusion of the Ov-LMO samples is schematically illustrated in Fig. 8(h) to emphasize the optimized lithium storage behaviors brought by oxygen… 13 3 5 121 #/texts/103 page_header page_header False low docling_page_header docling_page_header True p13:body_region:1 top_margin column_2_of_2 2 2 p13:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.71, 48.21, 139.91, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 13 6 6 122 #/texts/105#prov1 text body True None body body True p13:body_region:1 front_matter column_2_of_2 2 2 p13:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.6, 67.95, 251.08, 38.77] rating lithium diffusivity and intriguing pseudocapacitivedominant behaviors, which is in uniformity with the pseudocapacitive observations and constitutionally interprets the oxygen vacancy-intervened electrochemical p… rating lithium diffusivity and intriguing pseudocapacitivedominant behaviors, which is in uniformity with the pseudocapacitive observations and constitutionally interprets the oxygen vacancy-intervened electrochemical p… 13 7 7 123 #/texts/106 text body True None body body True p13:body_region:1 front_matter column_2_of_2 2 2 p13:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.6, 109.79, 251.11, 227.11] Additionally, a series of ex situ characterizations were conducted to further unearth the working mechanisms of the (Ov-)LMO during electrochemical measurements. It is widely substantiated that LMO materials undergo oxy… Additionally, a series of ex situ characterizations were conducted to further unearth the working mechanisms of the (Ov-)LMO during electrochemical measurements. It is widely substantiated that LMO materials undergo oxy… 13 8 8 124 #/texts/107 text body True None body body True p13:body_region:1 front_matter column_2_of_2 2 2 p13:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.6, 339.91, 251.1, 321.27] Ex situ XPS spectra were employed to decipher the reaction mechanism during charge/discharge processes of (Ov-)LMO materials during the initial cycle, by which the exalted structural stability of Ov-LMO can be investiga… Ex situ XPS spectra were employed to decipher the reaction mechanism during charge/discharge processes of (Ov-)LMO materials during the initial cycle, by which the exalted structural stability of Ov-LMO can be investiga… 13 9 9 125 #/texts/108 section_header body_heading False low body_heading body_heading True p13:body_region:1 body_zone column_2_of_2 2 2 p13:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.65, 680.01, 97.57, 7.42] 3.3. DFT calculation results 3.3. DFT calculation results 13 10 10 126 #/texts/109#prov0 text body True None body body True p13:body_region:1 bottom_margin column_2_of_2 2 2 p13:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.6, 700.93, 251.1, 49.26] DFT calculation was implemented to theoretically verify the superiority of the Ov-LMO materials in lithium storage compared with the parent materials. Herein, the models of LMO (Fig. 9a and Fig. S30a) and Ov-LMO (Fig. 9… DFT calculation was implemented to theoretically verify the superiority of the Ov-LMO materials in lithium storage compared with the parent materials. Herein, the models of LMO (Fig. 9a and Fig. S30a) and Ov-LMO (Fig. 9… 13 11 11 127 #/texts/110 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p13:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 176 176 14 2 1 128 #/texts/111 page_header page_header False low docling_page_header docling_page_header True p14:body_region:0 top_margin column_1_of_2 1 2 p14:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 14 3 2 129 #/texts/112 page_header page_header False low docling_page_header docling_page_header True p14:body_region:1 top_margin column_2_of_2 2 2 p14:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.77, 48.15, 139.86, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 14 4 3 130 #/texts/113 caption caption False low outside_body_flow_caption outside_body_flow_caption False None page_body column_1_of_2 1 2 p14:page_body:column_1_of_2:white [255, 255, 255] white False False [37.59, 575.68, 520.03, 31.96] Fig. 8. The single-step profiles of GITT titration during the charging process for (a) Ov-BDC-LMO, (b) Ov-BTC-LMO, and (c) Ov-PTC-LMO. The GITT curves of (d) Ov-BDC-LMO, (e) Ov-BTC-LMO, and (f) Ov-PTC-LMO. (g) The calcu… Fig. 8. The single-step profiles of GITT titration during the charging process for (a) Ov-BDC-LMO, (b) Ov-BTC-LMO, and (c) Ov-PTC-LMO. The GITT curves of (d) Ov-BDC-LMO, (e) Ov-BTC-LMO, and (f) Ov-PTC-LMO. (g) The calcu… 14 1 4 131 #/texts/109#prov1 text body True None body body True p14:body_region:0 page_body column_1_of_2 1 2 p14:page_body:column_1_of_2:white [255, 255, 255] white False False [37.59, 620.6, 251.14, 59.74] configuration induced by oxygen vacancies. The calculated lattice parameters of LMO and Ov-LMO after optimization are enumerated in Table S5, which elucidates the enlarged lattice parameters and cell volume of the Ov-LM… configuration induced by oxygen vacancies. The calculated lattice parameters of LMO and Ov-LMO after optimization are enumerated in Table S5, which elucidates the enlarged lattice parameters and cell volume of the Ov-LM… 14 5 5 132 #/texts/114#prov0 text body True None body body True p14:body_region:0 bottom_margin column_1_of_2 1 2 p14:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 683.36, 251.12, 70.18] To further unearth the difference in electronic configuration, the three-dimensional (3D) differential charge density distributions of LMO and Ov-LMO were explored, as presented in Fig. S30 (c) and Fig. 9(c), respective… To further unearth the difference in electronic configuration, the three-dimensional (3D) differential charge density distributions of LMO and Ov-LMO were explored, as presented in Fig. S30 (c) and Fig. 9(c), respective… 14 6 6 133 #/texts/114#prov1 text body True None body body True p14:body_region:1 page_body column_2_of_2 2 2 p14:page_body:column_2_of_2:white [255, 255, 255] white False False [306.59, 620.6, 251.09, 70.18] and plausibility of the local built-in electric field assumption, thereby verifying the exalted lithium diffusivity related to the adventitious Coulomb force generated by the self-adaptive electric field around the vaca… and plausibility of the local built-in electric field assumption, thereby verifying the exalted lithium diffusivity related to the adventitious Coulomb force generated by the self-adaptive electric field around the vaca… 14 7 7 134 #/texts/115#prov0 text body True None body body True p14:body_region:1 bottom_margin column_2_of_2 2 2 p14:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.59, 693.84, 251.07, 59.69] Electronic conductivity is a crucial prerequisite condition for LIB electrodes, which was holistically investigated by calculating the total density of states (TDOS) profiles bound up with the Fermi level (denoted as E … Electronic conductivity is a crucial prerequisite condition for LIB electrodes, which was holistically investigated by calculating the total density of states (TDOS) profiles bound up with the Fermi level (denoted as E … 14 8 8 135 #/texts/116 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p14:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 177 177 15 1 1 136 #/texts/117 page_header page_header False low docling_page_header docling_page_header False None top_margin left None None p15:top_margin:left:white [255, 255, 255] white False False [37.59, 48.2, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 15 2 2 137 #/texts/118 page_header page_header False low docling_page_header docling_page_header False None top_margin right None None p15:top_margin:right:white [255, 255, 255] white False False [417.71, 48.2, 139.91, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 15 3 3 138 #/texts/119 caption caption False low outside_body_flow_caption outside_body_flow_caption False None bottom_margin full None None p15:bottom_margin:full:white [255, 255, 255] white False False [37.59, 715.76, 520.05, 23.46] Fig. 9. The optimized models of (a) LMO and (b) Ov-LMO. (c) The 3D differential charge density distribution of Ov-LMO. (d) The TDOS curves of LMO and Ov-LMO. The PDOS curves of (e) LMO and (f) Ov-LMO. The energy barrier… Fig. 9. The optimized models of (a) LMO and (b) Ov-LMO. (c) The 3D differential charge density distribution of Ov-LMO. (d) The TDOS curves of LMO and Ov-LMO. The PDOS curves of (e) LMO and (f) Ov-LMO. The energy barrier… 15 4 4 139 #/texts/120 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin left_crossing None None p15:bottom_margin:left_crossing:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 178 178 16 2 1 140 #/texts/121 page_header page_header False low docling_page_header docling_page_header True p16:body_region:0 top_margin column_1_of_2 1 2 p16:top_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 48.2, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 16 1 2 141 #/texts/115#prov1 text body True None body body True p16:body_region:0 front_matter column_1_of_2 1 2 p16:front_matter:column_1_of_2:white [255, 255, 255] white False False [37.59, 67.96, 251.12, 153.85] and conduction bands. The reduced band gap and pronouncedly denser DOS adjacent to the Fermi energy level delivered by the Ov-LMO indicate enhanced metallicity and impressive electronic conductivity. To further unravel … and conduction bands. The reduced band gap and pronouncedly denser DOS adjacent to the Fermi energy level delivered by the Ov-LMO indicate enhanced metallicity and impressive electronic conductivity. To further unravel … 16 4 3 142 #/texts/123 text body True None body body True p16:body_region:0 front_matter column_1_of_2 1 2 p16:front_matter:column_1_of_2:white [255, 255, 255] white False False [37.59, 223.26, 251.14, 144.99] As stated earlier, the ease of Li + extraction is vital to the reconstruction and activation of the LMO electrodes to sustain electrochemical activity, especially during the first cycle. To support this statement with m… As stated earlier, the ease of Li + extraction is vital to the reconstruction and activation of the LMO electrodes to sustain electrochemical activity, especially during the first cycle. To support this statement with m… 16 5 4 143 #/texts/124 text body True None body body True p16:body_region:0 front_matter column_1_of_2 1 2 p16:front_matter:column_1_of_2:white [255, 255, 255] white False False [37.59, 371.32, 251.11, 153.85] The experimental observations extensively illuminate the significantly expedited Li + diffusion, which can be theoretically expounded by the calculated energy barriers of lithium vacancy migration. As displayed in Fig. … The experimental observations extensively illuminate the significantly expedited Li + diffusion, which can be theoretically expounded by the calculated energy barriers of lithium vacancy migration. As displayed in Fig. … 16 6 5 144 #/texts/125 text body True None body body True p16:body_region:0 front_matter column_1_of_2 1 2 p16:front_matter:column_1_of_2:white [255, 255, 255] white False False [37.59, 528.19, 251.12, 164.34] Benefitting from the morphological and microstructural merits, the Ov-BDC-LMO reported in this study outperforms most of the counterparts mentioned in prior works in lithium storage capacity at various current densities… Benefitting from the morphological and microstructural merits, the Ov-BDC-LMO reported in this study outperforms most of the counterparts mentioned in prior works in lithium storage capacity at various current densities… 16 7 6 145 #/texts/126 section_header body_heading False low body_heading body_heading True p16:body_region:0 body_zone column_1_of_2 1 2 p16:body_zone:column_1_of_2:white [255, 255, 255] white False False [37.7, 716.09, 57.15, 7.96] 4. Conclusions 4. Conclusions 16 8 7 146 #/texts/127#prov0 text body True None body body True p16:body_region:0 bottom_margin column_1_of_2 1 2 p16:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [37.59, 737.44, 251.1, 17.85] In conclusion, we have proposed a conceptual synthetic protocol with MOFs as self-sacrificial templates and stearic acid as the In conclusion, we have proposed a conceptual synthetic protocol with MOFs as self-sacrificial templates and stearic acid as the 16 3 8 147 #/texts/122 page_header page_header False low docling_page_header docling_page_header True p16:body_region:1 top_margin column_2_of_2 2 2 p16:top_margin:column_2_of_2:white [255, 255, 255] white False False [417.77, 48.15, 139.86, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 16 9 9 148 #/texts/127#prov1 text body True None body body True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.6, 67.95, 251.12, 216.61] reductant for the introduction of oxygen vacancies to ameliorate the electrochemical activity of LMO as an advanced cathode material for LIBs. The rational selection of MOF precursors efficaciously modulates the morphol… reductant for the introduction of oxygen vacancies to ameliorate the electrochemical activity of LMO as an advanced cathode material for LIBs. The rational selection of MOF precursors efficaciously modulates the morphol… 16 10 10 149 #/texts/128 section_header back_matter_heading False low back_matter_heading back_matter_heading stop_trigger True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.6, 298.54, 134.88, 7.96] Declaration of competing interest Declaration of competing interest 16 11 11 150 #/texts/129 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.6, 319.9, 251.12, 28.34] The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. 16 12 12 151 #/texts/130 section_header back_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.6, 362.22, 73.61, 7.96] Acknowledgments Acknowledgments 16 13 13 152 #/texts/131 text back_matter_text False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.6, 383.57, 251.08, 101.58] We gratefully acknowledge the financial support from the Special Funds for the Cultivation of Guangdong College Students' Scientific and Technological Innovation (''Climbing Program' Special Funds, pdjh2023b0145), the R… We gratefully acknowledge the financial support from the Special Funds for the Cultivation of Guangdong College Students' Scientific and Technological Innovation (''Climbing Program' Special Funds, pdjh2023b0145), the R… 16 14 14 153 #/texts/132 section_header unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.65, 500.83, 147.31, 7.96] Appendix A. Supplementary material Appendix A. Supplementary material 16 15 15 154 #/texts/133 text reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.6, 522.18, 251.04, 17.91] Supplementary data to this article can be found online at https://doi.org/10.1016/j.jechem.2023.05.014. Supplementary data to this article can be found online at 16 16 16 155 #/texts/134 section_header back_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.65, 554.06, 43.1, 7.96] References References 16 17 17 156 #/texts/135 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [309.83, 573.7, 247.83, 13.93] R. Liu, N. Li, E. Zhao, J. Zhao, L. Yang, W. Wang, H. Liu, C. Zeng, Mater. Futures 1 (2022). R. Liu, N. Li, E. Zhao, J. Zhao, L. Yang, W. Wang, H. Liu, C. Zeng, Mater. Futures 1 (2022). 16 18 18 157 #/texts/136 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [309.83, 589.68, 247.79, 13.87] Z.H. Zhang, X.Y. Xie, H.X. Xie, X.K. Ding, J.X. Cui, C.Y. Liu, D. Luo, Z. Lin, Chin. J. Struct. Chem. 41 (2022) 2204061-2204067. Z.H. Zhang, X.Y. Xie, H.X. Xie, X.K. Ding, J.X. Cui, C.Y. Liu, D. Luo, Z. Lin, Chin. J. Struct. Chem. 41 (2022) 2204061-2204067. 16 19 19 158 #/texts/137 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [309.83, 605.61, 247.78, 13.87] C. Zheng, S. Tang, F. Wen, J. Peng, W. Yang, Z. Lv, Y. Wu, W. Tang, Z. Gong, Y. Yang, Mater. Futures 1 (2022). C. Zheng, S. Tang, F. Wen, J. Peng, W. Yang, Z. Lv, Y. Wu, W. Tang, Z. Gong, Y. Yang, Mater. Futures 1 (2022). 16 20 20 159 #/texts/138 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [309.83, 621.54, 208.72, 5.93] S. Wang, J. Liu, Q. Sun, J. Mater. Chem. A 5 (2017) 16936-16943. S. Wang, J. Liu, Q. Sun, J. Mater. Chem. A 5 (2017) 16936-16943. 16 21 21 160 #/texts/139 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [309.83, 629.48, 155.32, 5.93] J. Lin, Y.-H. Sun, X. Lin, Nano Energy 91 (2022). J. Lin, Y.-H. Sun, X. Lin, Nano Energy 91 (2022). 16 22 22 161 #/texts/140 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [309.83, 637.47, 247.83, 13.93] F. Wang, Z. Chang, X. Wang, Y. Wang, B. Chen, Y. Zhu, Y. Wu, J. Mater. Chem. A 3 (2015) 4840-4845. F. Wang, Z. Chang, X. Wang, Y. Wang, B. Chen, Y. Zhu, Y. Wu, J. Mater. Chem. A 3 (2015) 4840-4845. 16 23 23 162 #/texts/141 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [309.83, 653.41, 247.82, 13.93] M. Zhang, L. Qiu, Y. Sun, Y. Song, Z. Wu, Y. Liu, Z. Yang, Y. Liu, J. Zhang, B. Zhong, X. Guo, ACS. Appl. Mater. Interfaces 13 (2021) 40995-41003. M. Zhang, L. Qiu, Y. Sun, Y. Song, Z. Wu, Y. Liu, Z. Yang, Y. Liu, J. Zhang, B. Zhong, X. Guo, ACS. Appl. Mater. Interfaces 13 (2021) 40995-41003. 16 24 24 163 #/texts/142 list_item affiliation False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [309.83, 669.34, 247.8, 5.93] B. Wu, Z. Lin, G. Zhang, D. Zhang, W. Zhang, G. Li, Y. Che, L. Chen, H. Wang, W. B. Wu, Z. Lin, G. Zhang, D. Zhang, W. Zhang, G. Li, Y. Che, L. Chen, H. Wang, W. 16 25 25 164 #/texts/143 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [321.56, 677.33, 190.24, 5.93] Li, M. Chen, G. Cao, Energy Storage Mater. 53 (2022) 212-221. Li, M. Chen, G. Cao, Energy Storage Mater. 53 (2022) 212-221. 16 26 26 165 #/texts/144 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [309.83, 685.32, 247.83, 13.87] F. Ning, H. Shang, B. Li, N. Jiang, R. Zou, D. Xia, Energy Storage Mater. 22 (2019) 113-119. F. Ning, H. Shang, B. Li, N. Jiang, R. Zou, D. Xia, Energy Storage Mater. 22 (2019) 113-119. 16 27 27 166 #/texts/145 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 front_matter column_2_of_2 2 2 p16:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.65, 701.25, 240.53, 5.93] W. Zhao, L. Xiong, Y. Xu, H. Li, Z. Ren, J. Power Sources 349 (2017) 11-17. W. Zhao, L. Xiong, Y. Xu, H. Li, Z. Ren, J. Power Sources 349 (2017) 11-17. 16 28 28 167 #/texts/146 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 bottom_margin column_2_of_2 2 2 p16:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.65, 709.19, 251.0, 21.92] S.F. Amalraj, D. Sharon, M. Talianker, C.M. Julien, L. Burlaka, R. Lavi, E. Zhecheva, B. Markovsky, E. Zinigrad, D. Kovacheva, R. Stoyanova, D. Aurbach, Electrochim. Acta 97 (2013) 259-270. S.F. Amalraj, D. Sharon, M. Talianker, C.M. Julien, L. Burlaka, R. Lavi, E. Zhecheva, B. Markovsky, E. Zinigrad, D. Kovacheva, R. Stoyanova, D. Aurbach, Electrochim. Acta 97 (2013) 259-270. 16 29 29 168 #/texts/147 list_item page_margin_footer False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 bottom_margin column_2_of_2 2 2 p16:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.65, 733.12, 238.99, 5.93] Y. Shin, K.A. Persson, ACS. Appl. Mater. Interfaces 8 (2016) 25595-25602. Y. Shin, K.A. Persson, ACS. Appl. Mater. Interfaces 8 (2016) 25595-25602. 16 30 30 169 #/texts/148 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p16:body_region:1 bottom_margin column_2_of_2 2 2 p16:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [306.65, 741.11, 250.98, 13.87] A.S. Menon, D.O. Ojwang, T. Willhammar, V.K. Peterson, K. Edstrom, C.P. Gomez, W.R. Brant, ACS. Appl. Mater. Interfaces 12 (2020) 5939-5950. A.S. Menon, D.O. Ojwang, T. Willhammar, V.K. Peterson, K. Edstrom, C.P. Gomez, W.R. Brant, ACS. Appl. Mater. Interfaces 12 (2020) 5939-5950. 16 31 31 170 #/texts/149 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop False None bottom_margin column_2_of_2 2 2 p16:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [291.91, 764.24, 11.45, 5.93] 179 179 17 1 1 171 #/texts/150 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin left None None p17:top_margin:left:white [255, 255, 255] white False False [37.59, 48.21, 93.88, 5.93] J.-E. Zhou, Y. Peng, X. Sang et al. J.-E. Zhou, Y. Peng, X. Sang et al. 17 2 2 172 #/texts/151 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin right None None p17:top_margin:right:white [255, 255, 255] white False False [417.71, 48.21, 139.91, 5.93] Journal of Energy Chemistry 85 (2023) 164-180 Journal of Energy Chemistry 85 (2023) 164-180 17 3 3 173 #/texts/152 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.64, 67.94, 250.98, 13.93] Y. Sun, M. Guo, S. Shu, D. Ding, C. Wang, Y. Zhang, J. Yan, Appl. Surf. Sci. 585 (2022). Y. Sun, M. Guo, S. Shu, D. Ding, C. Wang, Y. Zhang, J. Yan, Appl. Surf. Sci. 585 (2022). 17 29 4 174 #/texts/178 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 67.94, 250.97, 13.93] S. Cheng, Q. Ru, Y. Gao, M. Zhen, F. Chen, L. Wei, F.-C.-C. Ling, Chem. Eng. J. 406 (2021). S. Cheng, Q. Ru, Y. Gao, M. Zhen, F. Chen, L. Wei, F.-C.-C. Ling, Chem. Eng. J. 406 (2021). 17 4 5 175 #/texts/153 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left None None p17:page_body:left:white [255, 255, 255] white False False [37.64, 83.87, 179.07, 5.93] Y. Wu, Y. Li, J. Gao, Q. Zhang, SusMat 1 (2021) 66-87. Y. Wu, Y. Li, J. Gao, Q. Zhang, SusMat 1 (2021) 66-87. 17 5 6 176 #/texts/154 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.65, 91.86, 251.01, 5.93] R.C.K. Reddy, X. Lin, A. Zeb, C.Y. Su, Electrochem. Energ. Rev. 5 (2021) 312-347. R.C.K. Reddy, X. Lin, A. Zeb, C.Y. Su, Electrochem. Energ. Rev. 5 (2021) 312-347. 17 30 7 177 #/texts/179 list_item affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 83.87, 163.65, 5.93] A.P. Chernyshev, Mater. Chem. Phys. 282 (2022). A.P. Chernyshev, Mater. Chem. Phys. 282 (2022). 17 31 8 178 #/texts/180 list_item affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 91.86, 143.64, 5.93] M. Choi, W. Lee, Chem. Eng. J. 431 (2022). M. Choi, W. Lee, Chem. Eng. J. 431 (2022). 17 6 9 179 #/texts/155 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.65, 99.8, 250.99, 13.93] J. Rana, M. Stan, R. Kloepsch, J. Li, G. Schumacher, E. Welter, I. Zizak, J. Banhart, M. Winter, Adv. Energy Mater. 4 (2014) 1300998. J. Rana, M. Stan, R. Kloepsch, J. Li, G. Schumacher, E. Welter, I. Zizak, J. Banhart, M. Winter, Adv. Energy Mater. 4 (2014) 1300998. 17 32 10 180 #/texts/181 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 99.8, 250.96, 13.93] R. Jia, J. Yue, Q. Xia, J. Xu, X. Zhu, S. Sun, T. Zhai, H. Xia, Energy Storage Mater. 13 (2018) 303-311. R. Jia, J. Yue, Q. Xia, J. Xu, X. Zhu, S. Sun, T. Zhai, H. Xia, Energy Storage Mater. 13 (2018) 303-311. 17 7 11 181 #/texts/156 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.64, 115.79, 251.01, 13.87] K. Hikima, Y. Hinuma, K. Shimizu, K. Suzuki, S. Taminato, M. Hirayama, T. Masuda,K.Tamura,R.Kanno,ACS.Appl.Mater.Interfaces13(2021)7650-7663. K. Hikima, Y. Hinuma, K. Shimizu, K. Suzuki, S. Taminato, M. Hirayama, T. Masuda,K.Tamura,R.Kanno,ACS.Appl.Mater.Interfaces13(2021)7650-7663. 17 33 12 182 #/texts/182 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 115.79, 250.96, 13.87] C.R. Fell, D. Qian, K.J. Carroll, M. Chi, J.L. Jones, Y.S. Meng, Chem. Mater. 25 (2013) 1621-1629. C.R. Fell, D. Qian, K.J. Carroll, M. Chi, J.L. Jones, Y.S. Meng, Chem. Mater. 25 (2013) 1621-1629. 17 8 13 183 #/texts/157 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.65, 131.72, 251.01, 13.87] K. Kubota, T. Kaneko, M. Hirayama, M. Yonemura, Y. Imanari, K. Nakane, R. Kanno, J. Power Sources 216 (2012) 249-255. K. Kubota, T. Kaneko, M. Hirayama, M. Yonemura, Y. Imanari, K. Nakane, R. Kanno, J. Power Sources 216 (2012) 249-255. 17 34 14 184 #/texts/183 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 131.72, 250.96, 13.87] Y. Zhang, C. Yin, B. Qiu, G. Chen, Y. Shang, Z. Liu, Energy Storage Mater. 53 (2022) 763-773. Y. Zhang, C. Yin, B. Qiu, G. Chen, Y. Shang, Z. Liu, Energy Storage Mater. 53 (2022) 763-773. 17 9 15 185 #/texts/158 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left None None p17:page_body:left:white [255, 255, 255] white False False [37.64, 147.65, 222.72, 5.93] X. Tan, R. Liu, C. Xie, Q. Shen, J. Power Sources 374 (2018) 134-141. X. Tan, R. Liu, C. Xie, Q. Shen, J. Power Sources 374 (2018) 134-141. 17 10 16 186 #/texts/159 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left None None p17:page_body:left:white [255, 255, 255] white False False [37.65, 155.64, 199.54, 5.93] Y. Sun, L. Zan, Y. Zhang, Appl. Surf. Sci. 483 (2019) 270-277. Y. Sun, L. Zan, Y. Zhang, Appl. Surf. Sci. 483 (2019) 270-277. 17 35 17 187 #/texts/184 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 147.65, 250.99, 13.93] R. Wang, X. He, L. He, F. Wang, R. Xiao, L. Gu, H. Li, L. Chen, Adv. Energy Mater. 3 (2013) 1358-1367. R. Wang, X. He, L. He, F. Wang, R. Xiao, L. Gu, H. Li, L. Chen, Adv. Energy Mater. 3 (2013) 1358-1367. 17 11 18 188 #/texts/160 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.64, 163.58, 251.0, 13.93] S. Yadav, S. Sharma, S. Dutta, A. Sharma, A. Adholeya, R.K. Sharma, Inorg. Chem. 59 (2020) 8334-8344. S. Yadav, S. Sharma, S. Dutta, A. Sharma, A. Adholeya, R.K. Sharma, Inorg. Chem. 59 (2020) 8334-8344. 17 36 19 189 #/texts/185 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 163.58, 251.01, 13.93] P.J. Phillips, J. Bareño, Y. Li, D.P. Abraham, R.F. Klie, Adv. Energy Mater. 5 (2015) 1501252. P.J. Phillips, J. Bareño, Y. Li, D.P. Abraham, R.F. Klie, Adv. Energy Mater. 5 (2015) 1501252. 17 12 20 190 #/texts/161 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.64, 179.51, 251.01, 5.93] J.-E. Zhou, J. Chen, X. Zhang, A. Zeb, X. Lin, J. Energy Chem. 75 (2022) 216-228. J.-E. Zhou, J. Chen, X. Zhang, A. Zeb, X. Lin, J. Energy Chem. 75 (2022) 216-228. 17 13 21 191 #/texts/162 list_item affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left None None p17:page_body:left:white [251, 253, 253] white False False [37.65, 187.5, 201.75, 5.93] G. Kresse, J. Furthmüller, Comput. Mater. Sci 6 (1996) 15-50. G. Kresse, J. Furthmüller, Comput. Mater. Sci 6 (1996) 15-50. 17 37 22 192 #/texts/186 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 179.51, 250.96, 13.93] D. Ye, G. Zeng, K. Nogita, K. Ozawa, M. Hankel, D.J. Searles, L. Wang, Adv. Funct. Mater. 25 (2015) 7488-7496. D. Ye, G. Zeng, K. Nogita, K. Ozawa, M. Hankel, D.J. Searles, L. Wang, Adv. Funct. Mater. 25 (2015) 7488-7496. 17 15 23 193 #/texts/164 list_item affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left None None p17:page_body:left:white [255, 255, 255] white False False [37.64, 203.43, 218.98, 5.93] P.E. Blochl, Phys. Rev. B: Condens. Matter 50 (1994) 17953-17979. P.E. Blochl, Phys. Rev. B: Condens. Matter 50 (1994) 17953-17979. 17 14 24 194 #/texts/163 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left None None p17:page_body:left:white [255, 255, 255] white False False [37.65, 195.44, 240.58, 5.93] J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 77 (1996) 3865-3868. J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 77 (1996) 3865-3868. 17 38 25 195 #/texts/187 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 195.44, 250.98, 13.93] P. Yan, L. Xiao, J. Zheng, Y. Zhou, Y. He, X. Zu, S.X. Mao, J. Xiao, F. Gao, J.-G. Zhang, C.-M. Wang, Chem. Mater. 27 (2015) 975-982. P. Yan, L. Xiao, J. Zheng, Y. Zhou, Y. He, X. Zu, S.X. Mao, J. Xiao, F. Gao, J.-G. Zhang, C.-M. Wang, Chem. Mater. 27 (2015) 975-982. 17 16 26 196 #/texts/165 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left None None p17:page_body:left:white [255, 255, 255] white False False [37.64, 211.43, 222.33, 5.93] S. Grimme, J. Antony, S. Ehrlich, H. Krieg, J. Chem. Phys. 132 (2010). S. Grimme, J. Antony, S. Ehrlich, H. Krieg, J. Chem. Phys. 132 (2010). 17 17 27 197 #/texts/166 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.65, 219.36, 251.01, 5.93] J. Zheng, P. Yan, L. Estevez, C. Wang, J.G. Zhang, Nano Energy 49 (2018) 538-548. J. Zheng, P. Yan, L. Estevez, C. Wang, J.G. Zhang, Nano Energy 49 (2018) 538-548. 17 18 28 198 #/texts/167 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left None None p17:page_body:left:white [255, 255, 255] white False False [37.65, 227.36, 229.87, 5.93] C. Yin, Z. Bao, H. Tan, H. Zhou, J. Li, Chem. Eng. J. 372 (2019) 408-419. C. Yin, Z. Bao, H. Tan, H. Zhou, J. Li, Chem. Eng. J. 372 (2019) 408-419. 17 39 29 199 #/texts/188 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 211.43, 250.96, 5.93] C.O. Ehi-Eromosele, S.O. Ajayi, C.N. Onwucha, Mater. Chem. Phys. 259 (2021). C.O. Ehi-Eromosele, S.O. Ajayi, C.N. Onwucha, Mater. Chem. Phys. 259 (2021). 17 40 30 200 #/texts/189 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 219.36, 251.01, 13.93] M. Cheng, K. Zhu, L. Yang, L. Zhu, Y. Li, W. Tang, J. Alloys Compd. 686 (2016) 496-502. M. Cheng, K. Zhu, L. Yang, L. Zhu, Y. Li, W. Tang, J. Alloys Compd. 686 (2016) 496-502. 17 19 31 201 #/texts/168 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.65, 235.29, 251.01, 13.93] A. Quesne-Turin, D. Flahaut, G. Salvato Vallverdu, L. Croguennec, J. Allouche, F. Weill, M. Ménétrier, I. Baraille, Appl. Surf. Sci. 542 (2021). A. Quesne-Turin, D. Flahaut, G. Salvato Vallverdu, L. Croguennec, J. Allouche, F. Weill, M. Ménétrier, I. Baraille, Appl. Surf. Sci. 542 (2021). 17 41 32 202 #/texts/190 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 235.29, 251.01, 13.93] J. Lin, C. Zeng, Y. Chen, X. Lin, C. Xu, C. Su, J. Mater. Chem. A 8 (2020) 66076618. J. Lin, C. Zeng, Y. Chen, X. Lin, C. Xu, C. Su, J. Mater. Chem. A 8 (2020) 66076618. 17 20 33 203 #/texts/169 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.64, 251.28, 251.02, 13.87] M. Chen, D. Chen, Y. Liao, X. Zhong, W. Li, Y. Zhang, ACS. Appl. Mater. Interfaces 8 (2016) 4575-4584. M. Chen, D. Chen, Y. Liao, X. Zhong, W. Li, Y. Zhang, ACS. Appl. Mater. Interfaces 8 (2016) 4575-4584. 17 42 34 204 #/texts/191 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 251.28, 251.01, 13.87] F. Li, X. Zhang, J. Lin, J. Ma, S. Zhang, G. Yang, J. Phys. Chem. C 123 (2019) 23403-23409. F. Li, X. Zhang, J. Lin, J. Ma, S. Zhang, G. Yang, J. Phys. Chem. C 123 (2019) 23403-23409. 17 21 35 205 #/texts/170 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.64, 267.21, 251.03, 13.87] G. Zhang, M. Chen, C. Li, B. Wu, J. Chen, W. Xiang, X. Wen, D. Zhang, G. Cao, W. Li, Chem. Eng. J. 443 (2022). G. Zhang, M. Chen, C. Li, B. Wu, J. Chen, W. Xiang, X. Wen, D. Zhang, G. Cao, W. Li, Chem. Eng. J. 443 (2022). 17 43 36 206 #/texts/192 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 267.21, 250.98, 13.87] A. Klein, P. Axmann, C. Yada, M. Wohlfahrt-Mehrens, J. Power Sources 288 (2015) 302-307. A. Klein, P. Axmann, C. Yada, M. Wohlfahrt-Mehrens, J. Power Sources 288 (2015) 302-307. 17 22 37 207 #/texts/171 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left None None p17:page_body:left:white [255, 255, 255] white False False [37.64, 283.14, 232.98, 5.93] P. Lanz, C. Villevieille, P. Novák, Electrochim. Acta 109 (2013) 426-432. P. Lanz, C. Villevieille, P. Novák, Electrochim. Acta 109 (2013) 426-432. 17 23 38 208 #/texts/172 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.65, 291.14, 251.01, 13.87] Y. Liu, T. Zhou, Y. Zheng, Z. He, C. Xiao, W.K. Pang, W. Tong, Y. Zou, B. Pan, Z. Guo, Y. Xie, ACS Nano 11 (2017) 8519-8526. Y. Liu, T. Zhou, Y. Zheng, Z. He, C. Xiao, W.K. Pang, W. Tong, Y. Zou, B. Pan, Z. Guo, Y. Xie, ACS Nano 11 (2017) 8519-8526. 17 44 39 209 #/texts/193 list_item unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:off_white [246, 249, 251] off_white False False [306.65, 283.14, 155.49, 5.93] J.-M. Savéant, ACS Catal. 8 (2018) 7608-7611. J.-M. Savéant, ACS Catal. 8 (2018) 7608-7611. 17 45 40 210 #/texts/194 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 291.14, 250.98, 13.87] X. Zhang, J. Li, J. Li, L. Han, T. Lu, X. Zhang, G. Zhu, L. Pan, Chem. Eng. J. 385 (2020). X. Zhang, J. Li, J. Li, L. Han, T. Lu, X. Zhang, G. Zhu, L. Pan, Chem. Eng. J. 385 (2020). 17 24 41 211 #/texts/173 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.64, 307.07, 251.01, 13.87] B. Qiu, M. Zhang, L. Wu, J. Wang, Y. Xia, D. Qian, H. Liu, S. Hy, Y. Chen, K. An, Y. Zhu, Z. Liu, Y.S. Meng, Nat. Commun. 7 (2016) 12108. B. Qiu, M. Zhang, L. Wu, J. Wang, Y. Xia, D. Qian, H. Liu, S. Hy, Y. Chen, K. An, Y. Zhu, Z. Liu, Y.S. Meng, Nat. Commun. 7 (2016) 12108. 17 46 42 212 #/texts/195 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 307.07, 250.97, 13.87] Y. Hao, W. Liu, Q. Zhang, X. Wang, H. Yang, L. Kou, Z. Tian, L. Shao, H. Maleki Kheimeh Sari, J. Wang, H. Shan, X. Li, Nano Energy 88 (2021). Y. Hao, W. Liu, Q. Zhang, X. Wang, H. Yang, L. Kou, Z. Tian, L. Shao, H. Maleki Kheimeh Sari, J. Wang, H. Shan, X. Li, Nano Energy 88 (2021). 17 25 43 213 #/texts/174 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.65, 323.0, 251.01, 13.87] A. Zhu, Q. Wang, Y. Zhang, Y. Zhang, X. He, K. Wu, H. Wu, Q. Wang, W. Cai, Y. Zhang, J. Energy Chem. 71 (2022) 384-391. A. Zhu, Q. Wang, Y. Zhang, Y. Zhang, X. He, K. Wu, H. Wu, Q. Wang, W. Cai, Y. Zhang, J. Energy Chem. 71 (2022) 384-391. 17 47 44 214 #/texts/196 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 323.0, 250.98, 13.87] X. Huang, J. Zhao, W. Zhu, M. Hou, T. Zhou, L. Bu, L. Gao, W. Zhang, J. Energy Chem. 63 (2021) 376-384. X. Huang, J. Zhao, W. Zhu, M. Hou, T. Zhou, L. Bu, L. Gao, W. Zhang, J. Energy Chem. 63 (2021) 376-384. 17 26 45 215 #/texts/175 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.65, 338.93, 251.01, 13.93] Y. Wang, L. Feng, W. Fan, K.Y. Wang, X. Wang, X. Wang, K. Zhang, X. Zhang, F. Dai, D. Sun, H.C. Zhou, J. Am. Chem. Soc. 141 (2019) 6967-6975. Y. Wang, L. Feng, W. Fan, K.Y. Wang, X. Wang, X. Wang, K. Zhang, X. Zhang, F. Dai, D. Sun, H.C. Zhou, J. Am. Chem. Soc. 141 (2019) 6967-6975. 17 48 46 216 #/texts/197 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 338.93, 233.89, 5.93] J. Yang, J. Xian, Q. Liu, Y. Sun, G. Li, J. Energy Chem. 69 (2022) 524-530. J. Yang, J. Xian, Q. Liu, Y. Sun, G. Li, J. Energy Chem. 69 (2022) 524-530. 17 49 47 217 #/texts/198 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 346.92, 244.72, 5.93] J. Lin, T. Huang, M. Lu, X. Lin, R.C.K. Reddy, X. Xu, Chem. Eng. J. 433 (2022). J. Lin, T. Huang, M. Lu, X. Lin, R.C.K. Reddy, X. Xu, Chem. Eng. J. 433 (2022). 17 27 48 218 #/texts/176 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.64, 354.86, 251.04, 13.93] L. Xiao, J. Xiao, X. Yu, P. Yan, J. Zheng, M. Engelhard, P. Bhattacharya, C. Wang, X.-Q. Yang, J.-G. Zhang, Nano Energy 16 (2015) 143-151. L. Xiao, J. Xiao, X. Yu, P. Yan, J. Zheng, M. Engelhard, P. Bhattacharya, C. Wang, X.-Q. Yang, J.-G. Zhang, Nano Energy 16 (2015) 143-151. 17 50 49 219 #/texts/199 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 354.86, 250.96, 13.93] Q. Li, Y. Zhao, H. Liu, P. Xu, L. Yang, K. Pei, Q. Zeng, Y. Feng, P. Wang, R. Che, ACS Nano 13 (2019) (1934) 11921-11931. Q. Li, Y. Zhao, H. Liu, P. Xu, L. Yang, K. Pei, Q. Zeng, Y. Feng, P. Wang, R. Che, ACS Nano 13 (2019) (1934) 11921-11931. 17 28 50 220 #/texts/177 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body left_crossing None None p17:page_body:left_crossing:white [255, 255, 255] white False False [37.65, 370.79, 250.98, 13.93] J.-E. Zhou, J. Chen, Y. Peng, Y. Zheng, A. Zeb, X. Lin, Coord. Chem. Rev. 472 (2022). J.-E. Zhou, J. Chen, Y. Peng, Y. Zheng, A. Zeb, X. Lin, Coord. Chem. Rev. 472 (2022). 17 51 51 221 #/texts/200 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p17:page_body:right_crossing:white [255, 255, 255] white False False [306.65, 370.79, 250.97, 13.93] M.A. Kebede, M.J. Phasha, N. Kunjuzwa, L.J. le Roux, D. Mkhonto, K.I. Ozoemena, M.K. Mathe, Sustain. Energy Technol. Assess. 5 (2014) 44-49. M.A. Kebede, M.J. Phasha, N. Kunjuzwa, L.J. le Roux, D. Mkhonto, K.I. Ozoemena, M.K. Mathe, Sustain. Energy Technol. Assess. 5 (2014) 44-49. 17 52 52 222 #/texts/201 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop False None bottom_margin left_crossing None None p17:bottom_margin:left_crossing:white [255, 255, 255] white False False [291.91, 764.24, 11.38, 5.93] 180 180