page source_page_order layout_page_order layout_order ref label role_guess included_in_body excluded_risk_level body_decision_reason parser_body_decision_reason production_usage visual_asset_type visual_asset_label visual_asset_caption_preview truncation_marker inside_body_region body_region_id zone column column_index column_count region_id background_rgb background_class is_gray_background has_frame_evidence bbox text_preview cleaned_text_preview 1 1 1 0 #/texts/0 page_header page_header False low docling_page_header docling_page_header True p1:body_region:0 top_margin column_2_of_2 2 2 p1:top_margin:column_2_of_2:white [254, 254, 254] white False False [224.67, 47.78, 136.29, 6.37] Journal of Power Sources 332 (2016) 230 e 239 Journal of Power Sources 332 (2016) 230 e 239 1 2 2 1 #/texts/1 text front_matter_heading False low first_page_metadata first_page_metadata True p1:body_region:0 front_matter column_2_of_2 2 2 p1:front_matter:front_panel:gray [229, 229, 229] gray True False [216.51, 79.77, 156.17, 1.59] Contents lists available at ScienceDirect Contents lists available at ScienceDirect 1 3 3 2 #/texts/2 section_header title_candidate False low first_page_front_matter_heading first_page_front_matter_heading True p1:body_region:0 front_matter column_2_of_2 2 2 p1:front_matter:front_panel:gray [229, 229, 229] gray True False [210.56, 98.49, 167.92, 12.99] Journal of Power Sources Journal of Power Sources 1 4 4 3 #/texts/3 text metadata False low first_page_metadata first_page_metadata True p1:body_region:0 front_matter column_2_of_2 2 2 p1:front_matter:front_panel:gray [229, 229, 229] gray True False [165.09, 135.72, 258.93, 1.59] j o urnal homepage: www.elsevier.com/locate/jpowsour j o urnal homepage: 1 5 5 4 #/texts/4 section_header title_candidate False low first_page_front_matter_heading first_page_front_matter_heading True p1:body_region:0 front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.82, 178.39, 414.73, 47.0] Suppressing capacity fading and voltage decay of Li-rich layered cathode material by a surface nano-protective layer of CoF2 for lithium-ion batteries Suppressing capacity fading and voltage decay of Li-rich layered cathode material by a surface nano-protective layer of CoF2 for lithium-ion batteries 1 6 6 5 #/texts/5 text affiliation False medium front_matter_author_line front_matter_author_line True p1:body_region:0 front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.83, 235.4, 399.71, 25.14] Shaokun Chong a , Yuanzhen Chen a , Wuwei Yan a , Shengwu Guo a , Qiang Tan a , Yifang Wu b , Tao Jiang a , Yongning Liu a, * Shaokun Chong a , Yuanzhen Chen a , Wuwei Yan a , Shengwu Guo a , Qiang Tan a , Yifang Wu b , Tao Jiang a , Yongning Liu a, * 1 7 7 6 #/texts/6 list_item front_matter_candidate False low outside_body_flow_list_item outside_body_flow_list_item True p1:body_region:0 front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.83, 267.32, 446.32, 7.46] a State Key Laboratory for Mechanical Behavior of Materials, School of Material Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049, PR China a State Key Laboratory for Mechanical Behavior of Materials, School of Material Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049, PR China 1 8 8 7 #/texts/7 footnote affiliation False low first_page_author_or_affiliation first_page_author_or_affiliation False None front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.83, 275.88, 225.32, 7.46] b Northwest Institute for Nonferrous Metal Research, Xi'an, 710016, PR China b Northwest Institute for Nonferrous Metal Research, Xi'an, 710016, PR China 1 9 9 8 #/texts/8 section_header front_matter_heading False low front_matter_heading front_matter_heading False None front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:unknown None unknown False False [32.83, 313.97, 86.34, 0.06] h i g h l i g h t s h i g h l i g h t s 1 21 10 9 #/texts/20 section_header title_candidate False low first_page_front_matter_heading first_page_front_matter_heading True p1:body_region:0 front_matter column_2_of_2 2 2 p1:front_matter:column_2_of_2:unknown None unknown False False [197.22, 313.97, 152.63, 0.06] g r a p h i c a l a b s t r a c t g r a p h i c a l a b s t r a c t 1 10 11 10 #/texts/9 list_item body True None recovered_body_same_page_outside_flow recovered_body_same_page_outside_flow False None front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.83, 327.92, 133.2, 26.17]  Nano-CoF2 is fi rstly coated on Li1.2Ni0.2Mn0.6O2 via a wet chemistry method.  Nano-CoF2 is fi rstly coated on Li1.2Ni0.2Mn0.6O2 via a wet chemistry method. 1 11 12 11 #/texts/10 list_item body True None recovered_body_outside_flow recovered_body_outside_flow False None front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.83, 356.69, 133.16, 26.1]  0.5% CoF2-coated sample delivers the improved initial coulombic ef fi ciency of 86.2%.  0.5% CoF2-coated sample delivers the improved initial coulombic ef fi ciency of 86.2%. 1 12 13 12 #/texts/11 list_item body True None recovered_body_outside_flow recovered_body_outside_flow False None front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.83, 385.37, 133.19, 26.1]  Excellent stability of capacity and voltage are observed for 1.0% CoF2coating.  Excellent stability of capacity and voltage are observed for 1.0% CoF2coating. 1 13 14 13 #/texts/12 list_item body True None recovered_body_outside_flow recovered_body_outside_flow False None front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.83, 414.12, 133.22, 26.04]  The mechanisms of serious fading of capacity and voltage are discussed in details.  The mechanisms of serious fading of capacity and voltage are discussed in details. 1 14 15 14 #/texts/13 list_item body True None recovered_body_outside_flow recovered_body_outside_flow False None front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.83, 442.8, 133.26, 26.04]  Structure transition is suppressed by CoF2 nano-coating evidenced by TEM analysis.  Structure transition is suppressed by CoF2 nano-coating evidenced by TEM analysis. 1 15 16 15 #/texts/14 section_header front_matter_heading False low front_matter_heading front_matter_heading False None front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:unknown None unknown False False [32.83, 497.82, 95.61, 0.06] a r t i c l e i n f o a r t i c l e i n f o 1 22 17 16 #/texts/21 section_header abstract_heading False low abstract_heading abstract_heading True p1:body_region:0 front_matter column_2_of_2 2 2 p1:front_matter:column_2_of_2:unknown None unknown False False [197.23, 497.82, 67.73, 0.06] a b s t r a c t a b s t r a c t 1 16 18 17 #/texts/15 text front_matter_candidate False low outside_body_flow outside_body_flow False None front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.83, 511.33, 85.09, 40.53] Article history: Received 8 July 2016 Received in revised form 2 September 2016 Accepted 6 September 2016 Article history: Received 8 July 2016 Received in revised form 2 September 2016 Accepted 6 September 2016 1 17 19 18 #/texts/16 text metadata False low first_page_metadata first_page_metadata False None front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.83, 554.53, 109.97, 5.94] Available online 29 September 2016 Available online 29 September 2016 1 18 20 19 #/texts/17 text front_matter_heading False low front_matter_heading front_matter_heading False None front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [32.83, 573.97, 59.83, 49.14] Keywords: Lithium-ion battery Cathode material CoF2 coating layer Capacity fading Voltage decay Keywords: Lithium-ion battery Cathode material CoF2 coating layer Capacity fading Voltage decay 1 23 21 20 #/texts/22 text front_matter_candidate False low first_page_summary first_page_summary True p1:body_region:0 front_matter column_2_of_2 2 2 p1:front_matter:column_2_of_2:white [255, 255, 255] white False False [197.23, 512.05, 355.76, 102.32] Li-rich layered oxides have been regarded as valuable cathode materials for high energy density lithium-ion batteries. However, high initial irreversible capacity, bad rate capability, as well as serious capacity fading… Li-rich layered oxides have been regarded as valuable cathode materials for high energy density lithium-ion batteries. However, high initial irreversible capacity, bad rate capability, as well as serious capacity fading… 1 24 22 21 #/texts/23 text metadata False low first_page_metadata first_page_metadata True p1:body_region:0 front_matter column_2_of_2 2 2 p1:front_matter:column_2_of_2:white [255, 255, 255] white False False [416.24, 615.67, 136.59, 8.36] © 2016 Elsevier B.V. All rights reserved. © 2016 Elsevier B.V. All rights reserved. 1 25 23 22 #/texts/24 section_header body_heading False low body_heading body_heading True p1:body_region:0 body_zone column_2_of_2 2 2 p1:body_zone:column_2_of_2:white [255, 255, 255] white False False [301.83, 675.65, 62.13, 7.42] 1. Introduction 1. Introduction 1 19 24 23 #/texts/18 footnote footnote False low docling_footnote docling_footnote False None body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [37.87, 700.81, 3.32, 6.91] * 1 20 25 24 #/texts/19 footnote footnote False low first_page_metadata first_page_metadata False None body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [44.56, 701.71, 141.56, 14.59] Corresponding author. E-mail address: ynliu@mail.xjtu.edu.cn (Y. Liu). Corresponding author. E-mail address: ynliu@mail.xjtu.edu.cn (Y. Liu). 1 26 26 25 #/texts/25#prov0 text body True None body body True p1:body_region:0 body_zone column_2_of_2 2 2 p1:body_zone:column_2_of_2:white [255, 255, 255] white False False [301.83, 696.57, 251.04, 17.91] To meet more demanding requirements for portable electronics, electric vehicles and hybrid electric vehicles, rechargeable lithium- To meet more demanding requirements for portable electronics, electric vehicles and hybrid electric vehicles, rechargeable lithium- 1 27 27 26 #/texts/26 page_footer page_footer False low first_page_metadata first_page_metadata False None bottom_margin column_1_of_2 1 2 p1:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [32.83, 728.64, 156.13, 14.57] http://dx.doi.org/10.1016/j.jpowsour.2016.09.028 0378-7753/ © 2016 Elsevier B.V. All rights reserved. 0378-7753/ © 2016 Elsevier B.V. All rights reserved. 4 54 1 27 #/texts/65 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:gray [95, 95, 95] gray True True [133.4, 378.9, 18.05, 5.94] Fig. 4. Fig. 4. 4 55 2 28 #/texts/66 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:gray [117, 117, 117] gray True True [154.66, 378.9, 316.99, 5.94] XPS spectra of LNMO, CF-0.1, CF-0.5 and CF-1.0 in the region of (a) Ni 2p, (b) Mn 2p, (c) Co 2p and (d) F 1s. XPS spectra of LNMO, CF-0.1, CF-0.5 and CF-1.0 in the region of (a) Ni 2p, (b) Mn 2p, (c) Co 2p and (d) F 1s. 4 1 3 29 #/texts/25#prov1 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False True [42.52, 411.97, 251.03, 7.42] ion vacancy in TM layers during initial discharge procedure resulting ion vacancy in TM layers during initial discharge procedure resulting 4 2 4 30 #/texts/25#prov2 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False True [42.52, 422.4, 251.06, 7.42] in a large irreversible capacity loss [31,42,43], corresponding sche- in a large irreversible capacity loss [31,42,43], corresponding sche- 4 3 5 31 #/texts/25#prov3 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 432.89, 20.86, 7.42] matic matic 4 4 6 32 #/texts/25#prov4 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [68.26, 432.89, 17.91, 7.42] view view 4 6 7 33 #/texts/25#prov6 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [91.05, 432.89, 7.2, 7.42] of of 4 7 8 34 #/texts/25#prov7 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False True [103.24, 432.89, 73.15, 7.42] extraction/insertion extraction/insertion 4 5 9 35 #/texts/25#prov5 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 443.32, 35.43, 7.42] discharge discharge 4 8 10 36 #/texts/25#prov8 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [82.37, 443.32, 27.82, 7.42] process process 4 9 11 37 #/texts/25#prov9 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [114.57, 443.32, 7.42, 7.42] in in 4 24 12 38 #/texts/35 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:gray [167, 167, 167] gray True True [126.37, 443.32, 88.32, 7.42] LNMO active materials LNMO active materials 4 10 13 39 #/texts/25#prov10 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False True [42.52, 453.81, 251.07, 7.42] Fig. 5(b) presents the CV pro fi les of all the samples for the initial Fig. 5(b) presents the CV pro fi les of all the samples for the initial 4 28 14 40 #/texts/39 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:unknown None unknown False True [161.18, 461.98, 4.79, 10.33] þ 4 27 15 41 #/texts/38 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:unknown None unknown False True [157.72, 462.19, 3.56, 5.57] 2 2 4 30 16 42 #/texts/41 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:unknown None unknown False True [177.0, 462.19, 3.56, 5.57] 3 3 4 11 17 43 #/texts/25#prov11 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False True [42.52, 464.24, 115.38, 7.42] cycle. The oxidation peaks of Ni cycle. The oxidation peaks of Ni 4 29 18 44 #/texts/40 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:unknown None unknown False True [166.0, 464.24, 11.18, 7.42] /Ni /Ni 4 12 19 45 #/texts/25#prov12 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False True [42.52, 474.73, 251.13, 7.42] well as the peaks of the release of O2 at about 4.75 V can be observed well as the peaks of the release of O2 at about 4.75 V can be observed 4 13 20 46 #/texts/25#prov13 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False True [42.52, 485.16, 251.03, 7.42] clearly for all the samples during initial charge process, while the clearly for all the samples during initial charge process, while the 4 14 21 47 #/texts/25#prov14 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False True [42.52, 495.65, 251.04, 7.43] peak intensity of the release of O2 weakens gradually as the increase peak intensity of the release of O2 weakens gradually as the increase 4 16 22 48 #/texts/27 page_header page_header False low docling_page_header docling_page_header False None top_margin column_2_of_2 2 2 p4:top_margin:column_2_of_2:white [255, 255, 255] white False False [213.68, 47.78, 177.75, 6.46] S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239 S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239 4 17 23 49 #/texts/28 page_header page_header False low docling_page_header docling_page_header True p4:body_region:1 top_margin column_2_of_2 2 2 p4:top_margin:column_2_of_2:white [255, 255, 255] white False False [551.68, 48.21, 10.94, 5.94] 235 235 4 38 24 50 #/texts/49 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [323.49, 411.97, 38.8, 7.42] Especially, Especially, 4 39 25 51 #/texts/50 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:gray [87, 97, 90] gray True True [366.58, 411.97, 12.33, 7.42] the the 4 40 26 52 #/texts/51 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [383.24, 411.97, 21.9, 7.42] initial initial 4 41 27 53 #/texts/52 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [409.49, 411.97, 36.11, 7.42] discharge discharge 4 42 28 54 #/texts/53 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [449.97, 411.97, 31.04, 7.42] capacity capacity 4 63 29 55 #/texts/71#prov1 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False True [485.17, 411.97, 77.41, 7.42] and coulombic ef fi - and coulombic ef fi - 4 64 30 56 #/texts/72 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False True [311.53, 422.4, 251.05, 7.42] ciency of CF-1.0 slightly decrease compared to CF-0.5, which is ciency of CF-1.0 slightly decrease compared to CF-0.5, which is 4 20 31 57 #/texts/31 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [199.79, 430.57, 4.79, 10.33] þ 4 43 32 58 #/texts/54 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [311.53, 432.89, 43.25, 7.42] responsible responsible 4 44 33 59 #/texts/55 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [359.94, 432.89, 10.69, 7.42] for for 4 45 34 60 #/texts/56 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [375.76, 432.89, 12.33, 7.42] the the 4 46 35 61 #/texts/57 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:colored [47, 97, 14] colored False True [393.28, 432.89, 35.13, 7.42] relatively relatively 4 47 36 62 #/texts/58 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [433.47, 432.89, 26.57, 7.42] thicker thicker 4 48 37 63 #/texts/59 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False True [464.99, 432.89, 27.68, 7.42] coating coating 4 65 38 64 #/texts/73#prov0 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [497.82, 432.89, 18.56, 7.42] layer layer 4 66 39 65 #/texts/73#prov1 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [521.51, 432.89, 41.07, 7.42] restraining restraining 4 18 40 66 #/texts/29 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [181.3, 432.89, 7.33, 7.42] of of 4 19 41 67 #/texts/30 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [193.49, 432.89, 6.47, 7.42] Li Li 4 21 42 68 #/texts/32 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [209.65, 432.89, 24.61, 7.42] during during 4 22 43 69 #/texts/33 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [239.24, 432.89, 21.35, 7.42] initial initial 4 23 44 70 #/texts/34 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [265.55, 432.89, 28.08, 7.42] charge- charge- 4 49 45 71 #/texts/60 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [311.53, 443.32, 93.23, 7.43] overmuch the loss of O2. overmuch the loss of O2. 4 25 46 72 #/texts/36 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [219.11, 443.32, 53.83, 7.42] shown in Fig. shown in Fig. 4 26 47 73 #/texts/37 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [277.4, 443.32, 16.19, 7.42] 5(c). 5(c). 4 31 48 74 #/texts/42 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [180.45, 461.98, 4.79, 10.33] þ 4 34 49 75 #/texts/45 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [199.79, 461.98, 4.79, 10.33] þ 4 33 50 76 #/texts/44 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [196.27, 462.19, 3.56, 5.57] 4 4 4 36 51 77 #/texts/47 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [259.14, 463.71, 6.22, 7.96] e e 4 50 52 78 #/texts/61 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [311.53, 463.81, 19.15, 7.97] 3.2.2. 3.2.2. 4 51 53 79 #/texts/62 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [335.62, 463.81, 141.35, 7.97] Cyclic performance and rate capability Cyclic performance and rate capability 4 32 54 80 #/texts/43 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [185.27, 464.24, 11.09, 7.42] /Ni /Ni 4 35 55 81 #/texts/46 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:colored [95, 99, 19] colored False True [206.59, 464.24, 52.65, 7.42] at about 3.875 at about 3.875 4 37 56 82 #/texts/48 text visual_text False low visual_text visual_text True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [265.38, 464.24, 28.32, 7.42] 4.0 V as 4.0 V as 4 67 57 83 #/texts/74 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False True [323.49, 474.73, 239.06, 7.42] Fig. 6(a) shows the cycling stability of all the cathode materials Fig. 6(a) shows the cycling stability of all the cathode materials 4 53 58 84 #/texts/64 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [480.98, 484.62, 6.22, 7.96] e e 4 52 59 85 #/texts/63 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:unknown None unknown False True [311.53, 485.16, 169.49, 7.42] measured at 0.1C in the voltage range of 2.0 measured at 0.1C in the voltage range of 2.0 4 68 60 86 #/texts/75 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False True [487.28, 485.16, 75.28, 7.42] 4.8 V. CF-0.1, CF-0.5 4.8 V. CF-0.1, CF-0.5 4 71 61 87 #/texts/78 text unknown_text False medium empty_after_cleaning empty_after_cleaning True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [552.98, 493.33, 4.79, 10.33] 4 72 62 88 #/texts/79 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [557.8, 493.54, 3.56, 5.57] 1 1 4 57 63 89 #/texts/68#prov0 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:gray [234, 231, 231] gray True True [311.53, 495.65, 14.15, 7.42] and and 4 58 64 90 #/texts/68#prov1 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:gray [233, 231, 231] gray True True [331.03, 495.65, 23.14, 7.42] CF-1.0 CF-1.0 4 15 65 91 #/texts/25#prov15 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:gray [230, 230, 230] gray True True [359.54, 495.65, 26.3, 7.42] exhibit exhibit 4 59 66 92 #/texts/69#prov0 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:gray [230, 230, 230] gray True True [391.24, 495.65, 12.33, 7.42] the the 4 60 67 93 #/texts/69#prov1 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:gray [231, 231, 230] gray True True [408.98, 495.65, 36.11, 7.42] discharge discharge 4 62 68 94 #/texts/71#prov0 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:gray [231, 231, 230] gray True True [450.53, 495.65, 31.04, 7.42] capacity capacity 4 69 69 95 #/texts/76 text visual_text False low visual_text visual_text True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False True [486.87, 495.65, 7.33, 7.42] of of 4 70 70 96 #/texts/77 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [499.63, 495.65, 53.35, 7.42] 207.2 mAh g 207.2 mAh g 4 73 71 97 #/texts/80 text unknown_text False medium empty_after_cleaning empty_after_cleaning True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [560.69, 495.65, 1.9, 7.42] , 4 74 72 98 #/texts/81 caption body True None recovered_unbound_docling_caption recovered_unbound_docling_caption False None page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 503.82, 520.07, 31.25] of CoF2 coating amount in consequence of effective suppression of the loss of O2 by nano-coating layer. And the reduction peaks of Ni 4 þ / Ni 3 þ /Ni 2 þ at approximately 3.75 V as well as the weak reduction 225.3 mAh … of CoF2 coating amount in consequence of effective suppression of the loss of O2 by nano-coating layer. And the reduction peaks of Ni 4 þ / Ni 3 þ /Ni 2 þ at approximately 3.75 V as well as the weak reduction 225.3 mAh … 4 76 73 99 #/texts/83 text unknown_text False medium empty_after_cleaning empty_after_cleaning True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [149.27, 535.17, 4.79, 10.33] þ 4 78 74 100 #/texts/85 text unknown_text False medium empty_after_cleaning empty_after_cleaning True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [172.8, 535.17, 4.79, 10.33] þ 4 75 75 101 #/texts/82 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 535.38, 106.85, 9.53] peaks corresponding to Mn 4 peaks corresponding to Mn 4 4 77 76 102 #/texts/84 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [154.03, 535.38, 18.81, 9.53] /Mn 3 /Mn 3 4 80 77 103 #/texts/87 caption body True None recovered_unbound_docling_caption recovered_unbound_docling_caption True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 547.92, 251.12, 29.31] initial discharge process are observed. Besides, the intensity of reduction peaks of Mn 4 þ /Mn 3 þ wanes with increasing the amount of CoF2 coating as a result of the reduction of MnO2 with electro- initial discharge process are observed. Besides, the intensity of reduction peaks of Mn 4 þ /Mn 3 þ wanes with increasing the amount of CoF2 coating as a result of the reduction of MnO2 with electro- 4 84 78 104 #/texts/90 text unknown_text False medium empty_after_cleaning empty_after_cleaning True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [107.21, 629.34, 4.79, 10.33] 4 85 79 105 #/texts/91 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [111.97, 629.55, 3.56, 5.57] 1 1 4 81 80 106 #/texts/88#prov0 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 631.6, 64.69, 7.42] and 259.1 mAh g and 259.1 mAh g 4 82 81 107 #/texts/88#prov1 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [118.15, 631.6, 175.42, 7.42] as well as larger fi rst coulombic ef fi ciencies of as well as larger fi rst coulombic ef fi ciencies of 4 83 82 108 #/texts/89 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 642.09, 22.5, 7.42] 82.1%, 82.1%, 4 86 83 109 #/texts/92 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [69.67, 642.09, 188.56, 7.42] 86.2% and 84.4% than bare LNMO (244.0 mAh 86.2% and 84.4% than bare LNMO (244.0 mAh 4 92 84 110 #/texts/98 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 652.57, 251.07, 38.78] 75.5%), respectively, which mainly attributed to the suppression of side reaction between electrolyte and active material at high potential by CoF2 protective layer, less electrolyte oxidation resulting from less oxygen… 75.5%), respectively, which mainly attributed to the suppression of side reaction between electrolyte and active material at high potential by CoF2 protective layer, less electrolyte oxidation resulting from less oxygen… 4 93 85 111 #/texts/99 text body True None body body True p4:body_region:0 bottom_margin column_1_of_2 1 2 p4:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [42.52, 694.41, 251.08, 55.33] additional capacity provided by reduction reaction of CoF2 during initial discharge process, the electrochemical conversion reactions of CoF2 shown as follows: CoF2 þ 2Li þ þ 2e / Co þ 2LiF [31]. additional capacity provided by reduction reaction of CoF2 during initial discharge process, the electrochemical conversion reactions of CoF2 shown as follows: CoF2 þ 2Li þ þ 2e / Co þ 2LiF [31]. 4 56 86 112 #/texts/67 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [365.39, 504.03, 3.56, 5.57] 1 1 4 61 87 113 #/texts/70 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [441.52, 504.03, 3.56, 5.57] 1 1 4 94 88 114 #/texts/100 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [311.53, 537.49, 251.03, 7.42] of 63.0% for bare LNMO is obtained at 0.1C. The reason for this of 63.0% for bare LNMO is obtained at 0.1C. The reason for this 4 79 89 115 #/texts/86 text body True None body body True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [180.51, 537.49, 113.05, 7.42] couple at about 3.25 V during couple at about 3.25 V during 4 95 90 116 #/texts/101 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [311.53, 547.92, 251.06, 59.75] superior cyclic stability, which generally enhances as the content of CoF2 nano-coating increases, involves two aspects. One reason can be the subdued interfacial reaction and the reduction of TM dissolution bene fi tin… superior cyclic stability, which generally enhances as the content of CoF2 nano-coating increases, involves two aspects. One reason can be the subdued interfacial reaction and the reduction of TM dissolution bene fi tin… 4 96 91 117 #/texts/102#prov0 text body True None body body True p4:body_region:1 bottom_margin column_2_of_2 2 2 p4:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [311.53, 610.68, 251.07, 133.0] phase transformation from layer to spinel structure upon cycling. Voltage decay resulting from the layer-spinel structure conversion, which gives rise to serious decrease in energy density upon cycling, is one of the ma… phase transformation from layer to spinel structure upon cycling. Voltage decay resulting from the layer-spinel structure conversion, which gives rise to serious decrease in energy density upon cycling, is one of the ma… 4 89 92 118 #/texts/95 text unknown_text False medium empty_after_cleaning empty_after_cleaning True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [266.46, 639.83, 4.79, 10.33] 4 90 93 119 #/texts/96 text body True None body body True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [271.22, 640.03, 3.56, 5.57] 1 1 4 87 94 120 #/texts/93 text unknown_text False medium empty_after_cleaning empty_after_cleaning True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [258.24, 641.55, 3.71, 7.96] $ 4 88 95 121 #/texts/94 text body True None body body True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [261.92, 642.09, 4.48, 7.42] g g 4 91 96 122 #/texts/97 text body True None body body True p4:body_region:0 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [279.44, 642.09, 14.15, 7.42] and and 5 2 1 123 #/texts/103 page_header page_header False low docling_page_header docling_page_header True p5:body_region:0 top_margin column_1_of_2 1 2 p5:top_margin:column_1_of_2:white [255, 255, 255] white False False [32.82, 48.21, 10.94, 5.94] 236 236 5 3 2 124 #/texts/104 page_header page_header False low docling_page_header docling_page_header False None top_margin column_2_of_2 2 2 p5:top_margin:column_2_of_2:white [255, 255, 255] white False False [203.98, 47.78, 177.75, 6.46] S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239 S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239 5 4 3 125 #/texts/105 text visual_text False low visual_text visual_text True p5:body_region:1 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [253, 253, 253] white False True [53.46, 516.44, 499.38, 5.94] (a) Initial charge-discharge curves of bare LNMO, CF-0.1, CF-0.5 and CF-1.0 from 2.0 V to 4.8 V at 0.1C and (b) corresponding cyclic voltammetry pro fi les; (c) schematic view of (a) Initial charge-discharge curves of bare LNMO, CF-0.1, CF-0.5 and CF-1.0 from 2.0 V to 4.8 V at 0.1C and (b) corresponding cyclic voltammetry pro fi les; (c) schematic view of 5 1 4 126 #/texts/102#prov1 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [32.83, 516.44, 17.49, 5.94] Fig. 5. Fig. 5. 5 57 5 127 #/texts/147 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [105.39, 523.41, 3.68, 7.71] þ 5 5 6 128 #/texts/106 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [32.83, 525.0, 72.55, 5.94] extraction/insertion of Li extraction/insertion of Li 5 23 7 129 #/texts/124 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:gray [185, 184, 184] gray True True [111.17, 525.0, 194.81, 5.94] during initial charge-discharge process for LNMO active materials. during initial charge-discharge process for LNMO active materials. 5 6 8 130 #/texts/107 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [32.83, 558.41, 31.89, 7.42] stability. stability. 5 7 9 131 #/texts/108 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False True [44.79, 568.84, 239.09, 7.42] Fig. 6(c) presents energy density fading curves upon cycling, Fig. 6(c) presents energy density fading curves upon cycling, 5 8 10 132 #/texts/109 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False True [32.83, 579.33, 251.04, 7.42] which re fl ect the integration stability of capacity and voltage. CF- which re fl ect the integration stability of capacity and voltage. CF- 5 9 11 133 #/texts/110 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False True [32.83, 589.76, 251.04, 7.42] 0.1, CF-0.5 and CF-1.0 reveal much higher initial energy densities 0.1, CF-0.5 and CF-1.0 reveal much higher initial energy densities 5 11 12 134 #/texts/112 text unknown_text False medium empty_after_cleaning empty_after_cleaning True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [90.03, 597.93, 4.79, 10.33] 5 14 13 135 #/texts/115 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False True [149.73, 597.93, 4.79, 10.33] 5 12 14 136 #/texts/113 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [94.79, 598.14, 3.56, 5.57] 1 1 5 15 15 137 #/texts/116 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:gray [82, 82, 82] gray True True [154.49, 598.14, 3.56, 5.57] 1 1 5 10 16 138 #/texts/111 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [32.83, 600.25, 57.19, 7.42] of 914.9 Wh kg of 914.9 Wh kg 5 13 17 139 #/texts/114 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False True [97.68, 600.25, 52.03, 7.42] , 949.1 Wh kg , 949.1 Wh kg 5 16 18 140 #/texts/117 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False True [160.44, 600.25, 64.79, 7.42] and 926.7 Wh kg and 926.7 Wh kg 5 25 19 141 #/texts/126 text unknown_text False medium empty_after_cleaning empty_after_cleaning True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [142.58, 608.42, 4.79, 10.33] 5 26 20 142 #/texts/127 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [147.34, 608.63, 3.56, 5.57] 1 1 5 24 21 143 #/texts/125 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [32.83, 610.68, 109.74, 7.42] compared with 872.9 Wh kg compared with 872.9 Wh kg 5 27 22 144 #/texts/128#prov0 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [153.69, 610.68, 130.15, 7.42] for LNMO, as a result of improved for LNMO, as a result of improved 5 28 23 145 #/texts/128#prov1 text visual_text False low visual_text visual_text True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [253, 253, 253] white False False [301.83, 558.41, 251.01, 7.42] the one hand, the relatively thicker coating layer not only sup- the one hand, the relatively thicker coating layer not only sup- 5 20 24 146 #/texts/121 text visual_text False low visual_text visual_text True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [253, 252, 252] white False False [301.83, 568.84, 138.43, 8.39] presses excessively the release of O2 presses excessively the release of O2 5 29 25 147 #/texts/128#prov2 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [442.94, 568.84, 109.91, 7.42] but also prevents the extrac- but also prevents the extrac- 5 22 26 148 #/texts/123 text visual_text False low visual_text visual_text True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [252, 252, 252] white False False [372.25, 577.01, 4.79, 10.33] þ 5 21 27 149 #/texts/122 text visual_text False low visual_text visual_text True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [252, 252, 252] white False False [301.83, 579.33, 70.41, 7.42] tion/insertion of Li tion/insertion of Li 5 30 28 150 #/texts/128#prov3 text visual_text False low visual_text visual_text True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [254, 254, 253] white False False [379.5, 579.33, 173.33, 7.42] in layered structure, resulting in low capacity. in layered structure, resulting in low capacity. 5 31 29 151 #/texts/129 text visual_text False low visual_text visual_text True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [253, 253, 253] white False False [301.83, 589.76, 251.04, 7.42] On the other hand, the low reduction potential of 2.854 V for CoF2/ On the other hand, the low reduction potential of 2.854 V for CoF2/ 5 17 30 152 #/texts/118 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False True [225.24, 597.93, 4.79, 10.33] 5 18 31 153 #/texts/119 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:unknown None unknown False True [230.0, 598.14, 3.56, 5.57] 1 1 5 32 32 154 #/texts/130 text visual_text False low visual_text visual_text True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [253, 253, 253] white False False [301.83, 600.25, 251.02, 7.42] LiF can reduce the operating voltage of CF-2.0. Moreover, CF-2.0 LiF can reduce the operating voltage of CF-2.0. Moreover, CF-2.0 5 19 33 155 #/texts/120 text visual_text False low visual_text visual_text True p5:body_region:0 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False True [232.89, 600.25, 50.99, 7.42] , respectively, , respectively, 5 33 34 156 #/texts/131#prov0 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [301.83, 610.68, 29.93, 7.42] exhibits exhibits 5 34 35 157 #/texts/131#prov1 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [336.58, 610.68, 12.33, 7.42] the the 5 35 36 158 #/texts/131#prov2 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [353.82, 610.68, 36.38, 7.42] improved improved 5 36 37 159 #/texts/131#prov3 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [395.03, 610.68, 30.35, 7.42] stability stability 5 37 38 160 #/texts/131#prov4 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [430.24, 610.68, 17.51, 7.42] with with 5 38 39 161 #/texts/131#prov5 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [452.63, 610.68, 12.33, 7.42] the the 5 39 40 162 #/texts/131#prov6 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [469.81, 610.68, 31.04, 7.42] capacity capacity 5 40 41 163 #/texts/131#prov7 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [505.75, 610.68, 34.9, 7.42] retention retention 5 41 42 164 #/texts/131#prov8 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [545.55, 610.68, 7.33, 7.42] of of 5 42 43 165 #/texts/132 caption body True None recovered_unbound_docling_caption recovered_unbound_docling_caption False None page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [32.82, 621.17, 520.06, 17.86] initial discharge capacities and similar operating voltage after CoF2 coating. Accordingly, the excellent stability of capacity and voltage 93.6% and the value of voltage drop of 0.299 V after 100 cycles as shown in Fig… initial discharge capacities and similar operating voltage after CoF2 coating. Accordingly, the excellent stability of capacity and voltage 93.6% and the value of voltage drop of 0.299 V after 100 cycles as shown in Fig… 5 43 44 166 #/texts/133 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [32.83, 642.09, 251.07, 7.42] for CF-1.0 delivers the highest retention value of 84.9% after 100 for CF-1.0 delivers the highest retention value of 84.9% after 100 5 44 45 167 #/texts/134 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [32.83, 652.57, 251.05, 7.42] cycles despite reducing on the fi rst discharge capacity than CF-0.5, cycles despite reducing on the fi rst discharge capacity than CF-0.5, 5 45 46 168 #/texts/135 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [32.83, 663.0, 215.53, 7.42] while LNMO exhibits the lowest retention value of 51.1%. while LNMO exhibits the lowest retention value of 51.1%. 5 46 47 169 #/texts/136 section_header body_heading False low body_heading body_heading True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [44.79, 673.49, 239.1, 7.42] In order to investigate the capacity and voltage stability for the In order to investigate the capacity and voltage stability for the 5 47 48 170 #/texts/137 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [32.83, 683.92, 251.03, 7.43] sample whose CoF2 coating content is higher than 1.0 wt%, Fig. S1 in sample whose CoF2 coating content is higher than 1.0 wt%, Fig. S1 in 5 48 49 171 #/texts/138 section_header back_matter_heading False low back_matter_heading back_matter_heading stop_trigger True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [32.83, 694.41, 251.02, 7.42] supplementary materials presents the operation voltages versus supplementary materials presents the operation voltages versus 5 49 50 172 #/texts/139 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p5:body_region:0 bottom_margin column_1_of_2 1 2 p5:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [32.83, 704.84, 251.08, 38.83] speci fi c capacities of 2.0 wt% CoF2-coated sample (CF-2.0) and other four samples after 1st cycle and 100 th cycle, respectively. The initial discharge capacity of 236.0 mAh g 1 and operating potential of 3.444 V fo… speci fi c capacities of 2.0 wt% CoF2-coated sample (CF-2.0) and other four samples after 1st cycle and 100 th cycle, respectively. The initial discharge capacity of 236.0 mAh g 1 and operating potential of 3.444 V fo… 5 50 51 173 #/texts/140 text body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [301.83, 642.08, 251.04, 7.42] 1.0. However, CF-2.0 delivers the much lower energy density of 1.0. However, CF-2.0 delivers the much lower energy density of 5 52 52 174 #/texts/142 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [349.0, 650.26, 4.79, 10.33] 5 53 53 175 #/texts/143 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [353.76, 650.47, 3.56, 5.57] 1 1 5 51 54 176 #/texts/141 text body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [301.83, 652.57, 47.16, 7.42] 694.6 Wh kg 694.6 Wh kg 5 54 55 177 #/texts/144 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [359.15, 652.57, 193.75, 7.42] than CF-0.5 and CF-1.0 owing to its low capacity and than CF-0.5 and CF-1.0 owing to its low capacity and 5 55 56 178 #/texts/145 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [301.83, 663.01, 251.03, 7.42] voltage. Thus, CF-1.0 reaches the optimal integrated performance voltage. Thus, CF-1.0 reaches the optimal integrated performance 5 56 57 179 #/texts/146 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p5:body_region:1 bottom_margin column_2_of_2 2 2 p5:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [301.83, 673.49, 251.04, 70.18] between high capacity, high operating voltage and outstanding cycling stability. The excellence in rate capability, performed at various current densities from 0.1 C to 5 C between 2.0 and 4.8 V, further highlights the … between high capacity, high operating voltage and outstanding cycling stability. The excellence in rate capability, performed at various current densities from 0.1 C to 5 C between 2.0 and 4.8 V, further highlights the … 6 1 1 180 #/texts/148 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p6:top_margin:column_2_of_2:white [255, 255, 255] white False False [213.68, 47.78, 177.75, 6.46] S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239 S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239 6 2 2 181 #/texts/149 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 top_margin column_2_of_2 2 2 p6:top_margin:column_2_of_2:white [255, 255, 255] white False False [551.79, 48.21, 10.79, 5.94] 237 237 6 4 3 182 #/texts/151 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 page_body column_1_of_2 1 2 p6:page_body:column_1_of_2:white [254, 254, 254] white False False [63.67, 359.17, 498.87, 5.94] (a) Cycling performance, (b) discharge median voltage, (c) energy density and (d) rate discharge capability curves of all the samples at 0.1C between 2.0 V and 4.8 V upon (a) Cycling performance, (b) discharge median voltage, (c) energy density and (d) rate discharge capability curves of all the samples at 0.1C between 2.0 V and 4.8 V upon 6 3 4 183 #/texts/150 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 page_body column_1_of_2 1 2 p6:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 359.17, 17.94, 5.94] Fig. 6. Fig. 6. 6 5 5 184 #/texts/152 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 page_body column_1_of_2 1 2 p6:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 367.73, 21.75, 5.94] cycling. cycling. 6 8 6 185 #/texts/155 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 page_body column_1_of_2 1 2 p6:page_body:column_1_of_2:white [255, 255, 255] white False False [129.6, 547.84, 432.99, 70.26] fi tted with the equivalent circuits in the inset. Fig. 7(a) presents the EIS curves of the cells at open circuit potential before cycling. The intercept on the x-axis at the highest frequency is related to ohmic resist… fi tted with the equivalent circuits in the inset. Fig. 7(a) presents the EIS curves of the cells at open circuit potential before cycling. The intercept on the x-axis at the highest frequency is related to ohmic resist… 6 6 7 186 #/texts/153 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 page_body column_1_of_2 1 2 p6:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 547.84, 251.06, 49.98] 5 C, CF-1.0 exhibits the highest capacity of 167.5 mAh g 1 , yet that of LNMOis only 120.1 mAh g 1 . Moreover, when the current density is Fig. 7. 5 C, CF-1.0 exhibits the highest capacity of 167.5 mAh g 1 , yet that of LNMOis only 120.1 mAh g 1 . Moreover, when the current density is Fig. 7. 6 7 8 187 #/texts/154 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 page_body column_1_of_2 1 2 p6:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 600.25, 251.08, 122.51] back to 0.1 C, the discharge capacity returns to 98.7% of its initial value for CF-1.0, implying good reversibility and structural stability after high-rate measurements. The primary reason for the signi fi cantly impro… back to 0.1 C, the discharge capacity returns to 98.7% of its initial value for CF-1.0, implying good reversibility and structural stability after high-rate measurements. The primary reason for the signi fi cantly impro… 6 9 9 188 #/texts/156 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 bottom_margin column_1_of_2 1 2 p6:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [42.52, 725.76, 251.05, 7.42] surements of all fi ve samples were performed respectively, whose surements of all fi ve samples were performed respectively, whose 6 10 10 189 #/texts/158#prov0 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 bottom_margin column_2_of_2 2 2 p6:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [311.53, 621.17, 251.07, 123.42] represents charge-transfer resistance (Rct), and the slope line at the low frequency is assigned to the Warburg impedance (Zw) exhibiting the diffusion of Li þ in the electrode material. It can be obviously seen that a … represents charge-transfer resistance (Rct), and the slope line at the low frequency is assigned to the Warburg impedance (Zw) exhibiting the diffusion of Li þ in the electrode material. It can be obviously seen that a … 7 2 1 190 #/texts/159 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 top_margin column_1_of_2 1 2 p7:top_margin:column_1_of_2:white [255, 255, 255] white False False [32.82, 48.21, 10.94, 5.94] 238 238 7 3 2 191 #/texts/160 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 top_margin column_2_of_2 2 2 p7:top_margin:column_2_of_2:white [255, 255, 255] white False False [203.98, 47.78, 177.75, 6.46] S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239 S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239 7 5 3 192 #/texts/162 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 page_body column_1_of_2 1 2 p7:page_body:column_1_of_2:white [255, 255, 255] white False False [53.69, 540.02, 499.18, 5.94] (a) Schematic view of structural transformation from layered to spinel phase upon cycling for LNMO active materials; (b1) TEM image, (b2) corresponding SAED pattern and (a) Schematic view of structural transformation from layered to spinel phase upon cycling for LNMO active materials; (b1) TEM image, (b2) corresponding SAED pattern and 7 1 4 193 #/texts/158#prov1 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 page_body column_1_of_2 1 2 p7:page_body:column_1_of_2:white [255, 255, 255] white False False [32.83, 540.02, 17.66, 5.94] Fig. 8. Fig. 8. 7 4 5 194 #/texts/161 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 page_body column_1_of_2 1 2 p7:page_body:column_1_of_2:white [255, 255, 255] white False False [32.82, 548.58, 8.69, 6.64] (b3 (b3 7 6 6 195 #/texts/163 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 page_body column_1_of_2 1 2 p7:page_body:column_1_of_2:white [255, 255, 255] white False False [43.88, 548.58, 312.39, 6.64] and b4) dark fi eld images of LNMO after 50 cycles; TEM images and corresponding SAED patterns of: (c1 and b4) dark fi eld images of LNMO after 50 cycles; TEM images and corresponding SAED patterns of: (c1 7 7 7 196 #/texts/164 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p7:page_body:column_2_of_2:white [255, 255, 255] white False False [358.64, 548.58, 100.87, 6.64] and c2) LNMO after 100cycles, (d1 and c2) LNMO after 100cycles, (d1 7 8 8 197 #/texts/165 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p7:page_body:column_2_of_2:white [255, 255, 255] white False False [461.88, 548.58, 90.94, 5.94] and d2) CF-1.0 after 100 cycles and d2) CF-1.0 after 100 cycles 7 9 9 198 #/texts/166 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 page_body column_1_of_2 1 2 p7:page_body:column_1_of_2:white [255, 255, 255] white False False [32.82, 557.14, 520.13, 134.85] growth of the unacceptable SEI fi lm as well as the interfacial reaction have been mitigated by CoF2 coating layer. Thus, the improvement of electrochemical kinetics, the suppression of the formation of SEI fi lm and si… growth of the unacceptable SEI fi lm as well as the interfacial reaction have been mitigated by CoF2 coating layer. Thus, the improvement of electrochemical kinetics, the suppression of the formation of SEI fi lm and si… 7 11 10 199 #/texts/168#prov0 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 bottom_margin column_1_of_2 1 2 p7:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [32.82, 673.06, 251.09, 70.61] cycling To disclose the reasons for improving the capacity fading and voltage decay upon cycling of CoF2-coated samples, LNMO and CF1.0 after several cycles were observed using TEM. Fig. 8 (b1 and b2) presents TEM image… cycling To disclose the reasons for improving the capacity fading and voltage decay upon cycling of CoF2-coated samples, LNMO and CF1.0 after several cycles were observed using TEM. Fig. 8 (b1 and b2) presents TEM image… 7 10 11 200 #/texts/167 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop False None bottom_margin column_2_of_2 2 2 p7:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [301.83, 694.41, 251.07, 49.26] serious capacity fading and voltage decay, as illustrated in Fig. 8(a). After 100 cycles for LNMO, a thick layer, namely, SEI fi lm formed on the surface of grain, indicative of the severe side reaction between electrol… serious capacity fading and voltage decay, as illustrated in Fig. 8(a). After 100 cycles for LNMO, a thick layer, namely, SEI fi lm formed on the surface of grain, indicative of the severe side reaction between electrol… 8 1 1 201 #/texts/168#prov1 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 66.77, 251.12, 7.42] particle in Fig. 8(c2), indicating complete structure transition after particle in Fig. 8(c2), indicating complete structure transition after 8 4 2 202 #/texts/171 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 77.2, 251.06, 7.42] 100 cycles. However, the thin SEI fi lm mixed with CoF2 coating layer 100 cycles. However, the thin SEI fi lm mixed with CoF2 coating layer 8 5 3 203 #/texts/172 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 87.69, 251.06, 7.42] can be observed in Fig. 8(d1) for CF-1.0 after 100 cycles owing to the can be observed in Fig. 8(d1) for CF-1.0 after 100 cycles owing to the 8 6 4 204 #/texts/173#prov0 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 98.12, 37.08, 7.42] inhibition inhibition 8 7 5 205 #/texts/173#prov1 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [83.56, 98.12, 7.33, 7.42] of of 8 10 6 206 #/texts/174#prov2 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [94.9, 98.12, 42.72, 7.42] the release the release 8 37 7 207 #/texts/200 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:off_white [250, 249, 247] off_white False True [141.56, 98.12, 7.33, 7.42] of of 8 38 8 208 #/texts/201 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [253, 253, 253] white False True [152.84, 98.12, 112.48, 7.42] oxygen during initial several oxygen during initial several 8 8 9 209 #/texts/174#prov0 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 108.6, 42.08, 7.42] meanwhile meanwhile 8 9 10 210 #/texts/174#prov1 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [89.29, 108.6, 5.43, 7.42] it it 8 11 11 211 #/texts/174#prov3 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [99.38, 108.6, 13.88, 7.42] still still 8 40 12 212 #/texts/203 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [117.92, 108.6, 26.81, 7.42] remain remain 8 41 13 213 #/texts/204 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [149.44, 108.6, 7.42, 7.42] in in 8 42 14 214 #/texts/205 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False True [161.51, 108.6, 12.33, 7.42] the the 8 12 15 215 #/texts/175 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 119.04, 251.06, 7.42] which is in good agreement with the best stability of capacity and which is in good agreement with the best stability of capacity and 8 13 16 216 #/texts/176 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 129.52, 251.04, 7.42] operating voltage. Therefore, the phase transition from layered to operating voltage. Therefore, the phase transition from layered to 8 14 17 217 #/texts/177 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 139.96, 251.08, 7.43] spinel can be delayed effectively by CoF2 nano-coating layer upon spinel can be delayed effectively by CoF2 nano-coating layer upon 8 15 18 218 #/texts/178 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 150.44, 28.26, 7.42] cycling. cycling. 8 16 19 219 #/texts/179 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 171.36, 6.81, 7.42] 4. 4. 8 17 20 220 #/texts/180 text body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [54.31, 171.36, 47.69, 7.42] Conclusions Conclusions 8 18 21 221 #/texts/181 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [54.48, 192.28, 239.1, 7.43] In this paper, a nano protective layer of CoF2, in situ synthesized In this paper, a nano protective layer of CoF2, in situ synthesized 8 19 22 222 #/texts/182 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 202.72, 251.06, 7.42] by means of a common wet chemistry technology, was coated on by means of a common wet chemistry technology, was coated on 8 20 23 223 #/texts/183 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 213.2, 251.05, 7.42] LNMO. The results of SEM, TEM, EDS and XPS demonstrate that LNMO. The results of SEM, TEM, EDS and XPS demonstrate that 8 21 24 224 #/texts/184 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 223.63, 251.03, 7.43] CoF2 coating, belong to cubic structure, distributes homogeneously CoF2 coating, belong to cubic structure, distributes homogeneously 8 22 25 225 #/texts/185 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 234.12, 171.44, 7.42] on the surface of LNMO, and the cell tests on the surface of LNMO, and the cell tests 8 23 26 226 #/texts/186 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False True [42.52, 244.55, 251.08, 7.43] chemical performances are enhanced obviously for CoF2-coated chemical performances are enhanced obviously for CoF2-coated 8 24 27 227 #/texts/187 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 255.04, 251.04, 7.42] samples. CF-0.5 delivers the highest initial discharge capacity of samples. CF-0.5 delivers the highest initial discharge capacity of 8 27 28 228 #/texts/190 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [91.11, 263.21, 4.79, 10.33] 8 26 29 229 #/texts/189 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [95.87, 263.42, 3.56, 5.57] 1 1 8 25 30 230 #/texts/188 text body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 265.47, 48.59, 7.42] 264.4 mAh g 264.4 mAh g 8 49 31 231 #/texts/212 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [101.99, 265.47, 191.65, 7.42] and coulombic ef fi ciency of 86.2%, bene fi ting from and coulombic ef fi ciency of 86.2%, bene fi ting from 8 28 32 232 #/texts/191 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 275.96, 251.04, 7.42] the electrochemical conversion reaction based on CoF2/LiF, as well the electrochemical conversion reaction based on CoF2/LiF, as well 8 29 33 233 #/texts/192 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 286.45, 246.27, 7.42] as the reduction in the amount of irreversible O2 release and the Li as the reduction in the amount of irreversible O2 release and the Li 8 30 34 234 #/texts/193 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 296.88, 251.07, 7.42] vacancies proved by the CV measurements. In addition, the higher vacancies proved by the CV measurements. In addition, the higher 8 31 35 235 #/texts/194 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 307.0, 147.23, 7.79] fi rst discharge capacity of 259.1 mAh g fi rst discharge capacity of 259.1 mAh g 8 34 36 236 #/texts/197 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [101.37, 315.54, 4.79, 10.33] 8 33 37 237 #/texts/196 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [106.19, 315.75, 3.56, 5.57] 1 1 8 32 38 238 #/texts/195 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 317.8, 58.85, 7.42] of 244.0 mAh g of 244.0 mAh g 8 54 39 239 #/texts/217 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [109.02, 317.8, 184.56, 7.42] , the excellent cycling stability with the capacity , the excellent cycling stability with the capacity 8 35 40 240 #/texts/198 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 328.29, 251.03, 7.42] retention rate of 93.0% after 100 cycles at 0.1 C, the improved rate retention rate of 93.0% after 100 cycles at 0.1 C, the improved rate 8 36 41 241 #/texts/199 text body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [254, 254, 254] white False False [42.52, 338.72, 177.84, 7.42] performance with the capacity of 167.5 mAh g performance with the capacity of 167.5 mAh g 8 146 42 242 #/texts/309 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 349.21, 251.08, 7.42] the restraining operating voltage decay with the drop of 0.312 V the restraining operating voltage decay with the drop of 0.312 V 8 2 43 243 #/texts/169 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p8:top_margin:column_2_of_2:white [255, 255, 255] white False False [213.68, 47.78, 177.75, 6.46] S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239 S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239 8 3 44 244 #/texts/170 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p8:top_margin:column_2_of_2:white [255, 255, 255] white False False [551.62, 48.21, 10.94, 5.94] 239 239 8 274 45 245 #/texts/427 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [423.33, 66.32, 4.97, 6.37] e e 8 272 46 246 #/texts/425#prov2 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.4, 66.74, 95.96, 5.94] J. Mater. Chem. 17 (2007) 3112 J. Mater. Chem. 17 (2007) 3112 8 273 47 247 #/texts/426 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [428.32, 66.74, 16.71, 5.94] 3125. 3125. 8 58 48 248 #/texts/221 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [252, 251, 251] white False False [314.93, 74.74, 8.49, 5.94] [4] [4] 8 275 49 249 #/texts/428 text affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.4, 74.74, 235.14, 5.94] X. Bian, Q. Fu, Q. Pang, Y. Gao, Y. Wei, B. Zou, F. Du, G. Chen, ACS Appl. Mater. X. Bian, Q. Fu, Q. Pang, Y. Gao, Y. Wei, B. Zou, F. Du, G. Chen, ACS Appl. Mater. 8 60 50 250 #/texts/223 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [402.58, 82.25, 4.97, 6.37] e e 8 59 51 251 #/texts/222 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.4, 82.67, 75.15, 5.94] Interfaces 8 (2016) 3308 Interfaces 8 (2016) 3308 8 61 52 252 #/texts/224 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [407.57, 82.67, 16.66, 5.94] 3318. 3318. 8 62 53 253 #/texts/225 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [252, 252, 252] white False False [314.93, 90.67, 8.49, 5.94] [5] [5] 8 276 54 254 #/texts/429 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False True [327.4, 90.67, 235.14, 5.94] Q.Y. Wang, J. Liu, A.V. Murugan, A. Manthiram, J. Mater. Chem. 19 (2009) Q.Y. Wang, J. Liu, A.V. Murugan, A. Manthiram, J. Mater. Chem. 19 (2009) 8 39 55 255 #/texts/202 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:colored [217, 216, 247] colored False True [269.23, 98.12, 24.34, 7.42] cycles, cycles, 8 64 56 256 #/texts/227 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [342.6, 98.18, 4.97, 6.37] e e 8 63 57 257 #/texts/226 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.4, 98.6, 15.17, 5.94] 4965 4965 8 65 58 258 #/texts/228 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [347.53, 98.6, 16.71, 5.94] 4972. 4972. 8 66 59 259 #/texts/229 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [253, 253, 252] white False True [314.93, 106.6, 8.49, 5.94] [6] [6] 8 277 60 260 #/texts/430 text affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.4, 106.6, 235.14, 5.94] Z. Wang, E. Liu, L. Guo, C. Shi, C. He, J. Li, N. Zhao, Surf. Coat. Technol. 235 Z. Wang, E. Liu, L. Guo, C. Shi, C. He, J. Li, N. Zhao, Surf. Coat. Technol. 235 8 43 61 261 #/texts/206 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False True [178.52, 108.6, 54.03, 7.42] rhombohedral rhombohedral 8 44 62 262 #/texts/207 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False True [237.25, 108.6, 27.65, 7.42] layered layered 8 45 63 263 #/texts/208 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False True [269.63, 108.6, 23.98, 7.42] phase, phase, 8 68 64 264 #/texts/231 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [361.02, 114.16, 4.97, 6.37] e e 8 67 65 265 #/texts/230 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.4, 114.59, 33.6, 5.94] (2013) 570 (2013) 570 8 69 66 266 #/texts/232 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [365.95, 114.59, 12.91, 5.94] 576. 576. 8 77 67 267 #/texts/240 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [460.74, 121.75, 3.32, 6.38]  8 70 68 268 #/texts/233 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [314.93, 122.53, 8.49, 5.94] [7] [7] 8 71 69 269 #/texts/234 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.4, 122.53, 11.46, 5.94] A.R. A.R. 8 72 70 270 #/texts/235 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [345.37, 122.53, 33.96, 5.94] Armstrong, Armstrong, 8 73 71 271 #/texts/236 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [385.85, 122.53, 7.67, 5.94] M. M. 8 74 72 272 #/texts/237 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [400.08, 122.53, 30.14, 5.94] Holzapfel, Holzapfel, 8 75 73 273 #/texts/238 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [436.76, 122.53, 5.24, 5.94] P. P. 8 76 74 274 #/texts/239 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [448.55, 122.53, 12.15, 5.94] Nov Nov 8 78 75 275 #/texts/241 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [460.69, 122.53, 8.56, 5.94] ak, ak, 8 79 76 276 #/texts/242 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [475.81, 122.53, 10.42, 5.94] C.S. C.S. 8 278 77 277 #/texts/431#prov0 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [492.76, 122.53, 25.89, 5.94] Johnson, Johnson, 8 279 78 278 #/texts/431#prov1 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [525.19, 122.53, 14.08, 5.94] S.-H. S.-H. 8 295 79 279 #/texts/447 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [545.77, 122.53, 16.77, 5.94] Kang, Kang, 8 281 80 280 #/texts/433 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [520.16, 130.09, 4.97, 6.37] e e 8 80 81 281 #/texts/243 text affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.4, 130.52, 192.72, 5.94] M.M. Thackeray, P.G. Bruce, J. Am. Chem. Soc. 128 (2006) 8694 M.M. Thackeray, P.G. Bruce, J. Am. Chem. 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Yan, X. Liu, B. Li, RSC Adv. 4 (2014) 63268 J. Yan, X. Liu, B. Li, RSC Adv. 4 (2014) 63268 8 84 86 286 #/texts/247 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [467.32, 138.46, 20.51, 5.94] 63284. 63284. 8 85 87 287 #/texts/248 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [251, 251, 250] white False True [314.93, 146.45, 8.49, 5.94] [9] [9] 8 282 88 288 #/texts/434 text affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.4, 146.45, 235.14, 5.94] M. Hou, J. Liu, S. Guo, J. Yang, C. Wang, Y. Xia, Electrochem. Commun. 49 M. Hou, J. Liu, S. Guo, J. Yang, C. Wang, Y. Xia, Electrochem. Commun. 49 8 87 89 289 #/texts/250 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [357.22, 153.96, 4.97, 6.37] e e 8 86 90 290 #/texts/249 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.4, 154.39, 29.81, 5.94] (2014) 83 (2014) 83 8 88 91 291 #/texts/251 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [362.15, 154.39, 9.12, 5.94] 87. 87. 8 91 92 292 #/texts/254 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [253, 253, 253] white False True [452.24, 161.96, 4.97, 6.37] e e 8 89 93 293 #/texts/252 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:gray [241, 242, 239] gray True True [311.53, 162.38, 12.28, 5.94] [10] [10] 8 90 94 294 #/texts/253 text affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 162.38, 124.41, 5.94] M. 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Li, J. Mater. Chem. A 3 (2015) 21290 B. Li, J. Mater. Chem. A 3 (2015) 21290 8 96 99 299 #/texts/259 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [252, 252, 253] white False False [451.84, 170.38, 20.51, 5.94] 21297. 21297. 8 97 100 300 #/texts/260 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [311.53, 178.31, 12.28, 5.94] [12] [12] 8 283 101 301 #/texts/435 text affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 178.31, 234.74, 5.94] P.R. Ilango, T. Subburaj, K. Prasanna, Y.N. Jo, C.W. Lee, Mater. Chem. Phys. 158 P.R. Ilango, T. Subburaj, K. Prasanna, Y.N. Jo, C.W. Lee, Mater. Chem. Phys. 158 8 99 102 302 #/texts/262 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [357.62, 185.88, 4.97, 6.37] e e 8 98 103 303 #/texts/261 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 186.31, 29.81, 5.94] (2015) 45 (2015) 45 8 100 104 304 #/texts/263 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [362.55, 186.31, 9.12, 5.94] 51. 51. 8 101 105 305 #/texts/264 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [311.53, 194.24, 12.28, 5.94] [13] [13] 8 284 106 306 #/texts/436 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 194.24, 234.74, 5.94] F. 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Acta 88 8 107 112 312 #/texts/270 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [361.42, 217.74, 4.97, 6.37] e e 8 106 113 313 #/texts/269 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 218.17, 33.6, 5.94] (2013) 671 (2013) 671 8 108 114 314 #/texts/271 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [366.35, 218.17, 12.91, 5.94] 679. 679. 8 288 115 315 #/texts/440 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [544.7, 225.73, 4.97, 6.37] e e 8 109 116 316 #/texts/272 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [311.53, 226.16, 12.28, 5.94] [15] [15] 8 286 117 317 #/texts/438 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 226.16, 216.88, 5.94] Y. Liu, S. Liu, Y. Wang, L. Chen, X. Chen, J. Power Sources 222 (2013) 455 Y. Liu, S. Liu, Y. Wang, L. Chen, X. Chen, J. Power Sources 222 (2013) 455 8 287 118 318 #/texts/439 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [549.64, 226.16, 12.91, 5.94] 460. 460. 8 110 119 319 #/texts/273 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [311.53, 234.1, 12.28, 5.94] [16] [16] 8 289 120 320 #/texts/441 text affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 234.1, 234.74, 5.94] S. Shi, J. Tu, Y. Zhang, Y. Zhang, X. Zhao, X. Wang, C. Gu, Electrochim. Acta 108 S. Shi, J. 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Acta 108 8 46 121 321 #/texts/209 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False True [218.09, 234.12, 22.98, 7.42] reveal reveal 8 47 122 322 #/texts/210 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [245.08, 234.12, 15.27, 7.42] that that 8 48 123 323 #/texts/211 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [264.35, 234.12, 29.23, 7.42] electro- electro- 8 112 124 324 #/texts/275 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [361.42, 241.66, 4.97, 6.37] e e 8 111 125 325 #/texts/274 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 242.09, 33.6, 5.94] (2013) 441 (2013) 441 8 113 126 326 #/texts/276 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False True [366.35, 242.09, 12.91, 5.94] 448. 448. 8 294 127 327 #/texts/446 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [540.9, 249.66, 4.97, 6.37] e e 8 114 128 328 #/texts/277 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:gray [228, 229, 229] gray True True [311.53, 250.09, 12.28, 5.94] [17] [17] 8 290 129 329 #/texts/442 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 250.09, 213.08, 5.94] J. 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Yang, Solid State Ion. 179 (2008) 1794 8 293 130 330 #/texts/445 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [545.84, 250.09, 16.71, 5.94] 1799. 1799. 8 291 131 331 #/texts/443 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [516.87, 257.6, 4.97, 6.37] e e 8 115 132 332 #/texts/278 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [311.53, 258.02, 12.28, 5.94] [18] [18] 8 116 133 333 #/texts/279 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 258.02, 189.05, 5.94] X. Liu, J. Liu, T. Huang, A. Yu, Electrochim. Acta 109 (2013) 52 X. Liu, J. Liu, T. Huang, A. Yu, Electrochim. Acta 109 (2013) 52 8 292 134 334 #/texts/444 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [521.86, 258.02, 9.12, 5.95] 58. 58. 8 148 135 335 #/texts/311 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [498.33, 265.6, 4.97, 6.37] e e 8 117 136 336 #/texts/280 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:off_white [248, 249, 247] off_white False True [311.53, 266.02, 12.28, 5.94] [19] [19] 8 118 137 337 #/texts/281 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 266.02, 170.52, 5.94] X. Liu, T. Huang, A. Yu, Electrochim. Acta 163 (2015) 82 X. Liu, T. Huang, A. Yu, Electrochim. Acta 163 (2015) 82 8 147 138 338 #/texts/310 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [503.26, 266.02, 9.12, 5.94] 92. 92. 8 119 139 339 #/texts/282 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False True [311.53, 273.96, 12.28, 5.94] [20] [20] 8 149 140 340 #/texts/312 text affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 273.96, 234.74, 5.94] J.-H. Kim, M.-S. Park, J.-H. Song, D.-J. Byun, Y.-J. Kim, J.-S. Kim, J. Alloy. Compd. J.-H. Kim, M.-S. Park, J.-H. Song, D.-J. Byun, Y.-J. Kim, J.-S. Kim, J. Alloy. Compd. 8 121 141 341 #/texts/284 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [371.22, 281.53, 4.97, 6.37] e e 8 120 142 342 #/texts/283 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 281.95, 43.41, 5.94] 517 (2012) 20 517 (2012) 20 8 122 143 343 #/texts/285 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [376.16, 281.95, 9.12, 5.94] 25. 25. 8 50 144 344 #/texts/213 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [288.79, 284.13, 4.79, 10.33] þ 8 123 145 345 #/texts/286 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [251, 250, 251] white False True [311.53, 289.89, 12.28, 5.94] [21] [21] 8 150 146 346 #/texts/313 text affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 289.89, 234.76, 5.94] T. Zhao, L. Li, R. Chen, H. Wu, X. Zhang, S. Chen, M. Xie, F. Wu, J. Lu, K. Amine, T. Zhao, L. Li, R. Chen, H. Wu, X. Zhang, S. Chen, M. Xie, F. Wu, J. Lu, K. Amine, 8 125 147 347 #/texts/288 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [412.61, 297.46, 4.97, 6.37] e e 8 124 148 348 #/texts/287 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 297.88, 84.79, 5.94] Nano Energy 15 (2015) 164 Nano Energy 15 (2015) 164 8 126 149 349 #/texts/289 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [417.6, 297.88, 12.91, 5.94] 176. 176. 8 51 150 350 #/texts/214 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [189.75, 305.05, 4.79, 10.33] 8 52 151 351 #/texts/215 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [194.51, 305.26, 3.56, 5.57] 1 1 8 127 152 352 #/texts/290 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [253, 254, 253] white False True [311.53, 305.88, 12.28, 5.94] [22] [22] 8 151 153 353 #/texts/314 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 305.88, 234.74, 5.94] J. Ma, B. Li, L. An, H. Wei, X. Wang, P. Yu, D. Xia, J. Power Sources 277 (2015) J. Ma, B. Li, L. An, H. Wei, X. Wang, P. Yu, D. Xia, J. Power Sources 277 (2015) 8 53 154 354 #/texts/216 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [200.58, 307.37, 93.04, 7.42] compared to bare LNMO compared to bare LNMO 8 129 155 355 #/texts/292 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [339.19, 313.39, 4.97, 6.37] e e 8 128 156 356 #/texts/291 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 313.81, 11.38, 5.94] 393 393 8 130 157 357 #/texts/293 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [344.12, 313.81, 12.91, 5.94] 402. 402. 8 131 158 358 #/texts/294 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [311.53, 321.81, 12.28, 5.94] [23] [23] 8 132 159 359 #/texts/295 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 321.81, 12.56, 5.94] H.G. H.G. 8 133 160 360 #/texts/296 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [345.09, 321.81, 16.29, 5.94] Song, Song, 8 134 161 361 #/texts/297 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [366.06, 321.81, 9.11, 5.94] J.Y. J.Y. 8 135 162 362 #/texts/298 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [379.89, 321.81, 13.8, 5.94] Kim, Kim, 8 136 163 363 #/texts/299 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [398.43, 321.81, 10.97, 5.94] K.T. K.T. 8 137 164 364 #/texts/300 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [414.14, 321.81, 13.8, 5.94] Kim, Kim, 8 138 165 365 #/texts/301 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [432.67, 321.81, 9.11, 5.94] Y.J. Y.J. 8 139 166 366 #/texts/302 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 253] white False False [446.51, 321.81, 14.98, 5.94] Park, Park, 8 140 167 367 #/texts/303 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:gray [246, 245, 244] gray True True [466.23, 321.81, 3.52, 5.94] J. J. 8 141 168 368 #/texts/304 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 253] white False False [474.45, 321.81, 19.26, 5.94] Power Power 8 152 169 369 #/texts/315 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [498.43, 321.81, 23.25, 5.94] Sources Sources 8 153 170 370 #/texts/316 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [526.44, 321.81, 11.38, 5.94] 196 196 8 154 171 371 #/texts/317 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [542.54, 321.81, 20.0, 5.94] (2011) (2011) 8 143 172 372 #/texts/306 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [342.99, 329.32, 4.97, 6.37] e e 8 142 173 373 #/texts/305 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 329.74, 15.17, 5.94] 6847 6847 8 144 174 374 #/texts/307 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [347.92, 329.74, 16.71, 5.94] 6855. 6855. 8 55 175 375 #/texts/218 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [252, 252, 252] white False False [220.37, 336.46, 4.79, 10.33] 8 56 176 376 #/texts/219 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [225.18, 336.67, 3.56, 5.57] 1 1 8 145 177 377 #/texts/308 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [311.53, 337.74, 12.28, 5.94] [24] [24] 8 155 178 378 #/texts/318 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [327.8, 337.74, 234.74, 5.94] J. Lu, Q. Peng, W. Wang, C. Nan, L. Li, Y. Li, J. Am. Chem. Soc. 135 (2013) J. Lu, Q. Peng, W. Wang, C. Nan, L. Li, Y. Li, J. Am. Chem. Soc. 135 (2013) 8 57 179 379 #/texts/220 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [254, 254, 254] white False False [231.48, 338.72, 62.11, 7.42] even at 5 C, and even at 5 C, and 8 157 180 380 #/texts/320 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [342.99, 345.3, 4.97, 6.37] e e 8 156 181 381 #/texts/319 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [327.8, 345.73, 15.17, 5.94] 1649 1649 8 158 182 382 #/texts/321 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [347.92, 345.73, 16.71, 5.94] 1652. 1652. 8 159 183 383 #/texts/322 caption caption False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 353.67, 520.04, 24.8] after 100 cycles at 0.1 C are obtained for CF-1.0 sample. The outstanding electrochemical performances are ascribed to the CoF2 [25] L.-N. Cong, X.-G. Gao, S.-C. Ma, X. Guo, Y.-P. Zeng, L.-H. Tai, R.-S. Wang, H.M. Xie, … after 100 cycles at 0.1 C are obtained for CF-1.0 sample. The outstanding electrochemical performances are ascribed to the CoF2 [25] L.-N. Cong, X.-G. Gao, S.-C. Ma, X. Guo, Y.-P. Zeng, L.-H. Tai, R.-S. Wang, H.M. Xie, … 8 160 184 384 #/texts/323 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 380.56, 251.08, 7.42] nano-coating in protection electrode material from deterioration in nano-coating in protection electrode material from deterioration in 8 161 185 385 #/texts/324#prov0 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 391.05, 12.33, 7.42] the the 8 162 186 386 #/texts/324#prov1 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [61.0, 391.05, 41.88, 7.42] electrolyte, electrolyte, 8 163 187 387 #/texts/324#prov2 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [108.96, 391.05, 12.33, 7.42] the the 8 164 188 388 #/texts/324#prov3 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [127.44, 391.05, 51.67, 7.42] enhancement enhancement 8 166 189 389 #/texts/325 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 401.48, 154.03, 7.42] involving better electron transfer and Li involving better electron transfer and Li 8 167 190 390 #/texts/326#prov0 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 411.97, 22.25, 7.42] bition bition 8 170 191 391 #/texts/327#prov1 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [69.16, 411.97, 7.33, 7.42] of of 8 168 192 392 #/texts/326#prov1 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [80.84, 411.97, 53.71, 7.42] layered-spinel layered-spinel 8 208 193 393 #/texts/363 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False True [138.95, 411.97, 63.1, 7.42] phase transition phase transition 8 169 194 394 #/texts/327#prov0 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 422.4, 17.92, 7.42] edge edge 8 171 195 395 #/texts/327#prov2 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [64.97, 422.4, 43.9, 7.42] and spread and spread 8 211 196 396 #/texts/366 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [113.38, 422.4, 14.98, 7.42] into into 8 212 197 397 #/texts/367 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [132.89, 422.4, 20.1, 7.42] inner inner 8 213 198 398 #/texts/368 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [157.49, 422.4, 16.64, 7.42] bulk bulk 8 172 199 399 #/texts/328 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 432.89, 251.04, 7.42] migration of TM ions into Li layers. Therefore, the novel design of migration of TM ions into Li layers. Therefore, the novel design of 8 173 200 400 #/texts/329 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 443.32, 251.03, 7.43] CoF2 nano-coating not only provides a tactic to surmount the de- CoF2 nano-coating not only provides a tactic to surmount the de- 8 174 201 401 #/texts/330 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 453.81, 251.06, 7.42] fects of LNMO and displays the superior comprehensive effect on fects of LNMO and displays the superior comprehensive effect on 8 175 202 402 #/texts/331#prov0 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 464.24, 39.18, 7.42] improving improving 8 176 203 403 #/texts/331#prov1 text body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [86.12, 464.24, 59.58, 7.42] electrochemical electrochemical 8 216 204 404 #/texts/371 text body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [150.18, 464.24, 48.3, 7.42] performance performance 8 177 205 405 #/texts/332 text metadata False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 474.73, 251.04, 7.42] published data, but also illuminates in depth the mechanism of published data, but also illuminates in depth the mechanism of 8 178 206 406 #/texts/333 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 485.16, 180.7, 7.42] capacity fading and voltage decay upon cycling. capacity fading and voltage decay upon cycling. 8 179 207 407 #/texts/334 text back_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 506.08, 73.96, 7.42] Acknowledgement Acknowledgement 8 180 208 408 #/texts/335 text back_matter_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [54.48, 527.0, 239.17, 7.42] This work was supported by National Natural Science Founda- This work was supported by National Natural Science Founda- 8 181 209 409 #/texts/336 text back_matter_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 537.49, 251.07, 7.42] tion of China (Grant no. E51504196), the China Postdoctoral Science tion of China (Grant no. E51504196), the China Postdoctoral Science 8 262 210 410 #/texts/417 caption caption False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [90.03, 544.52, 413.34, 14.36] (no. 2012M521760) and the Fundamental Research X.-Q. Yang, J.-G. Zhang, Nano Energy 16 (2015) 143 e 151. [39] M.E. Spahr, P. Nov  (no. 2012M521760) and the Fundamental Research X.-Q. Yang, J.-G. Zhang, Nano Energy 16 (2015) 143 e 151. [39] M.E. Spahr, P. Nov  8 259 211 411 #/texts/414 text back_matter_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 547.92, 42.84, 7.42] Foundation Foundation 8 260 212 412 #/texts/415 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 558.41, 193.56, 7.42] Funds for the Central Universities (no. xjj2014052). Funds for the Central Universities (no. xjj2014052). 8 261 213 413 #/texts/416 text reference False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [42.52, 579.32, 251.03, 93.4] Appendix A. Supplementary data Supplementary data related to this article can be found at http:// dx.doi.org/10.1016/j.jpowsour.2016.09.028. References [1] M.S. Whittingham, Chem. Rev. 104 (2004) 4271 e 4302. [2] J.B. G… Appendix A. Supplementary data Supplementary data related to this article can be found at http:// dx.doi.org/10.1016/j.jpowsour.2016.09.028. References [1] M.S. Whittingham, Chem. Rev. 104 (2004) 4271 e 4302. [2] J.B. G… 8 188 214 414 #/texts/343 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [450.31, 377.17, 4.97, 6.37] e e 8 185 215 415 #/texts/340 text affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [327.8, 377.59, 122.49, 5.94] Y. Wei, J. Mater. Chem. A 2 (2014) 7555 Y. Wei, J. Mater. Chem. 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Yu, Nanoscale 4 (2012) 6743 8 190 220 420 #/texts/345 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [448.04, 385.53, 16.71, 5.94] 6747. 6747. 8 165 221 421 #/texts/324#prov4 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [185.15, 391.05, 7.33, 7.42] of of 8 270 222 422 #/texts/425#prov0 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [198.59, 391.05, 29.23, 7.42] kinetics kinetics 8 271 223 423 #/texts/425#prov1 text body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [233.97, 391.05, 59.58, 7.42] electrochemical electrochemical 8 183 224 424 #/texts/338 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [249, 250, 250] white False True [311.52, 393.52, 12.28, 5.94] [28] [28] 8 191 225 425 #/texts/346 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [327.79, 393.52, 234.74, 5.94] Y. 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Dou, Ionics 21 (2015) 8 206 226 426 #/texts/361 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [196.55, 399.22, 4.79, 10.33] þ 8 220 227 427 #/texts/375 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [342.99, 401.09, 4.97, 6.37] e e 8 207 228 428 #/texts/362 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [204.43, 401.48, 89.12, 7.42] diffusion, and the inhi- diffusion, and the inhi- 8 219 229 429 #/texts/374 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [253, 253, 253] white False True [327.79, 401.52, 15.17, 5.94] 2725 2725 8 221 230 430 #/texts/376 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [347.92, 401.52, 16.71, 5.94] 2733. 2733. 8 222 231 431 #/texts/377 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [311.52, 409.45, 12.28, 5.94] [29] [29] 8 192 232 432 #/texts/347 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [327.79, 409.45, 234.74, 5.94] X. 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Eng. 4 (2015) 8 209 233 433 #/texts/364 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [206.41, 411.97, 31.73, 7.42] initiated initiated 8 210 234 434 #/texts/365 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [242.47, 411.97, 51.1, 7.42] from particle from particle 8 224 235 435 #/texts/379 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [339.19, 417.02, 4.97, 6.37] e e 8 223 236 436 #/texts/378 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [327.79, 417.45, 11.38, 5.94] 255 255 8 225 237 437 #/texts/380 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [249, 250, 251] white False False [344.12, 417.45, 12.91, 5.94] 263. 263. 8 214 238 438 #/texts/369 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [178.63, 422.4, 98.09, 7.42] by means of minimizing by means of minimizing 8 215 239 439 #/texts/370 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [281.25, 422.4, 12.33, 7.42] the the 8 226 240 440 #/texts/381 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [311.52, 425.38, 12.28, 5.94] [30] [30] 8 193 241 441 #/texts/348 text affiliation False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [327.79, 425.38, 234.74, 5.94] Y. Liu, Q. Wang, Y. Lu, B. Yang, M. Su, Y. Gao, A. Dou, J. Alloy. Compd. 638 Y. Liu, Q. Wang, Y. Lu, B. Yang, M. Su, Y. Gao, A. Dou, J. Alloy. Compd. 638 8 228 242 442 #/texts/383 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [353.82, 432.95, 4.97, 6.37] e e 8 227 243 443 #/texts/382 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [327.79, 433.38, 26.02, 5.94] (2015) 1 (2015) 1 8 229 244 444 #/texts/384 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [358.75, 433.38, 5.32, 5.94] 6. 6. 8 230 245 445 #/texts/385 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False True [311.52, 441.37, 12.28, 5.94] [31] [31] 8 231 246 446 #/texts/386 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [327.79, 441.37, 3.52, 5.94] J. J. 8 232 247 447 #/texts/387 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [334.71, 441.37, 23.39, 5.94] Cabana, Cabana, 8 233 248 448 #/texts/388 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [361.52, 441.37, 4.76, 5.94] L. L. 8 234 249 449 #/texts/389 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [369.69, 441.37, 75.56, 5.94] Monconduit, D. Larcher, Monconduit, D. 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A1885. 8 217 261 461 #/texts/372 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [203.01, 464.24, 78.64, 7.42] among the coatings among the coatings 8 218 262 462 #/texts/373 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [286.18, 464.24, 7.42, 7.42] in in 8 242 263 463 #/texts/397 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [311.52, 465.24, 12.28, 5.94] [33] [33] 8 198 264 464 #/texts/353 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [327.79, 465.24, 234.74, 5.94] X. 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