{
  "sample": "03-wiley-early-stop",
  "threshold": 0.35,
  "cache_status": {
    "exists": true,
    "usable": true,
    "reason": "cache_page_count_ok",
    "expected_pdf_pages": 12,
    "cached_docling_pages": 12,
    "cached_docling_max_page": 12,
    "formula_enrichment_enabled": false,
    "formula_enrichment_scale": 3.0,
    "formula_nodes": 5,
    "recognized_formula_nodes": 2
  },
  "candidate_blocks": [
    {
      "page": 1,
      "page_count": 12,
      "bbox": [
        51.03,
        203.28,
        362.78,
        421.1
      ],
      "text": "Structural changes in Li 2 MnO 3 cathode material for rechargeable Li-ion bat- teries are investigated during the fi rst and 33 rd cycles. It is found that both the participation of oxygen anions in redox processes and Li + -H + exchange play an important role in the electrochemistry of Li 2 MnO 3 . During activation, oxygen removal from the material along with Li gives rise to the formation of a layered MnO 2 -type structure, while the presence of protons in the interslab region, as a result of electrolyte oxidation and Li + -H + exchange, alters the stacking sequence of oxygen layers. Li re-insertion by exchanging already pre- sent protons reverts the stacking sequence of oxygen layers. The re-lithiated structure closely resembles the parent Li 2 MnO 3 , except that it contains less Li and O. Mn 4+ ions remain electrochemically inactive at all times. Irrevers- ible oxygen release occurs only during activation of the material in the fi rst cycle. During subsequent cycles, electrochemical processes seem to involve unusual redox processes of oxygen anions of active material along with the repetitive, irreversible oxidation of electrolyte species. The deteriorating electrochemical performance of Li 2 MnO 3 upon cycling is attributed to the structural degradation caused by repetitive shearing of oxygen layers.",
      "category": "front_summary",
      "coverage": 0.961,
      "words": 208
    },
    {
      "page": 1,
      "page_count": 12,
      "bbox": [
        51.01,
        467.41,
        294.22,
        520.58
      ],
      "text": "The exploration of electrochemical activation in Li 2 MnO 3 is important for two main reasons: fi rst, to enhance the funda- mental understanding concerning the electrochemistry of Mn 4+ -containing cathode materials: and second, to obtain the knowledge necessary for designing a possible class of “Li-rich”",
      "category": "front_summary",
      "coverage": 0.905,
      "words": 46
    },
    {
      "page": 1,
      "page_count": 12,
      "bbox": [
        51.01,
        545.39,
        233.73,
        700.46
      ],
      "text": "Dr. J. Rana, Dr. G. Schumacher, Dr. I. Zizak, Prof. J. Banhart Helmholtz-Zentrum Berlin für Materialien und Energie Hahn-Meitner-Platz 1 , 14109 , Berlin , Germany E-mail: jatinkumar.rana@helmholtz-berlin.de ; banhart@helmholtz-berlin.de Dr. M. Stan, R. Kloepsch, Dr. J. Li, Prof. M. Winter Institute of Physical Chemistry MEET Battery Research Centre University of Muenster Corrensstrasse 46 , 48149 , Muenster , Germany Dr. E. Welter Deutsches Elektronen-Synchrotron Notkestrasse 85 , 22607 , Hamburg , Germany Prof. J. Banhart Technische Universität Berlin Hardenbergstrasse 36 , 10623 , Berlin , Germany",
      "category": "metadata",
      "coverage": 0.0,
      "words": 88
    },
    {
      "page": 1,
      "page_count": 12,
      "bbox": [
        51.01,
        191.34,
        549.33,
        718.57
      ],
      "text": "cathode materials, [ 1–9 ] in which Li 2 MnO 3 is an important component. Li 2 MnO 3 has an O3 structure where close-packed oxygen layers are stacked in an ABCABC sequence. In a layer notation, Li 2 MnO 3 can be written as Li[Li 1/3 Mn 2/3 ]O 2 where the interslab octahedral sites are occu- pied by Li only, while the octahedral sites within the [Li 1/3 Mn 2/3 ]O 2 slabs are occu- pied by both Li and Mn in a ratio of 1:2. [ 10 ] The fact that in Li 2 MnO 3 Mn 4+ ions are octahedrally coordinated by oxygen led to the initial belief that the material is elec- trochemically inactive. [ 11 ] However, this belief was disproven when a substantial charge could be extracted from the mate- rial during an activation process that occurs at 4.5 V vs. Li/Li + . [ 12 ] Over the past few years, several mech- anisms concerning electrochemical activation of Li 2 MnO 3 during the fi rst charge have been postulated. It has been proposed that Li extraction from Li 2 MnO 3 occurs with the simultaneous release of oxygen. [ 11 ] Later, it was observed that Li extraction occurs via two competitive pro- cesses, namely oxygen removal and Li + -H + exchange. [ 13–15 ] The presence of structural defects such as oxygen vacancies also plays an important role in the electrochemical performance of Li 2 MnO 3 . [ 16,17 ] While most of these reports elucidate the struc- tural changes upon Li extraction, [ 13–15,18 ] none provide infor- mation obtained by direct experimental evidence from electro- chemically treated samples about what the structural modifi ca- tions during Li re-insertion and upon prolonged cycling are. We study structural modifi cations in Li 2 MnO 3 cathode mate- rial during the fi rst and 33 rd cycles by X-ray absorption spec- troscopy (XAS). The elemental selectivity of XAS provides a unique opportunity to probe chemical, electronic and struc- tural changes at and around an absorbing atom. The near-edge region of the absorption spectra is called the X-ray absorption near edge structure (XANES) and provides qualitative informa- tion about the average valence state of absorbing atoms, their local symmetry, and electronic confi guration. On the other hand, the extended region of the absorption spectra is called the extended X-ray absorption fi ne structure (EXAFS) and provides quantitative information about geometrical changes in the vicinity of absorbing atoms. In the present study, the average valence state of Mn and its local symmetry in various Li 2 MnO 3 samples are qualitatively discussed in comparison with various DOI: 10.1002/aenm.201300998",
      "category": "front_summary",
      "coverage": 0.925,
      "words": 431
    },
    {
      "page": 2,
      "page_count": 12,
      "bbox": [
        302.03,
        293.29,
        545.23,
        335.46
      ],
      "text": "in Figure 1 b, the electrochemical performance of Li 2 MnO 3 degrades upon cycling. During the 33 rd cycle, the cell delivers a specifi c capacity of ≈110 mAh g −1 both during charge and dis- charge, which is just ≈55% of that of the fi rst discharge.",
      "category": "scientific_body",
      "coverage": 0.837,
      "words": 47
    },
    {
      "page": 2,
      "page_count": 12,
      "bbox": [
        46.9,
        380.79,
        290.1,
        499.96
      ],
      "text": "As shown in Figure 1 a, the cell delivered a specifi c capacity of 388 mAh g −1 when charged to 5 V and of 200 mAh g −1 when discharged to 2 V with a fi rst cycle effi ciency of ≈50% (Figure 1 b). The long plateau above 4.5 V vs. Li/Li + during the fi rst charge that delivers most of the capacity is a characteristic of Li 2 MnO 3 [ 13–15,18,19 ] and Li 2 MnO 3 -containing cathode mate- rials. [ 1–9 ] The capacity delivered during the fi rst charge (i.e., activation) depends on the rate at which the cell is charged. However, the capacity during subsequent cycles is independent of the rate. Therefore, the cell was fi rst-charged to 5 V at C/50, while subsequent cycling was carried out at C/10. As shown",
      "category": "scientific_body",
      "coverage": 0.825,
      "words": 141
    },
    {
      "page": 2,
      "page_count": 12,
      "bbox": [
        302.03,
        380.79,
        545.24,
        499.96
      ],
      "text": "As shown in Figure 2 a, the absorption edge is characterized by a variety of edge-features such as 1) an absorption threshold (or the fi rst peak in the derivative spectrum, not shown), 2) a 1s → 3d transition, corresponding to the pre-edge peak, 3) the main edge, corresponding to the vertically rising portion of the edge (or the second peak in the derivative spectrum, not shown), and 4) a 1s → 4p transition, corresponding to the max- imum of the vertically rising portion of the edge. [ 20 ] A relative shift in the position of these features, often called a chemical shift, provides an empirical mean for the estimation of the average valence state of the central absorbing atom. The inset in",
      "category": "metadata",
      "coverage": 0.966,
      "words": 120
    },
    {
      "page": 3,
      "page_count": 12,
      "bbox": [
        306.15,
        70.93,
        549.35,
        234.1
      ],
      "text": "compounds (refer to Figure S1 and Table S1 in the Supporting Information). As shown in Figure 3 , the absorption spectra for various Li 2 MnO 3 samples appear more complex than those of man- ganese reference compounds due to the presence of several points of intersection along the main edge where some of the spectra cross. Closer examination of these spectra reveals that the trend in chemical shifts varies widely before and after the intersection points. As shown in the inset, the pre-edge region in the pristine state is characterized by a splitting of the Mn 3d orbitals into t 2g and e g orbitals. As the cathode is charged to 5 V, the intensity of the pre-edge peak increases and the peak splitting becomes less clear. When the cathode is discharged to 2 V, the intensity of the pre-edge peak decreases. For the cycled samples, changes in the pre-edge region are less obvious.",
      "category": "scientific_body",
      "coverage": 1.0,
      "words": 157
    },
    {
      "page": 3,
      "page_count": 12,
      "bbox": [
        306.15,
        279.22,
        549.35,
        508.6
      ],
      "text": "The comparison between the χ ( k ) signals of various Li 2 MnO 3 samples in Figure 4 a reveals that the EXAFS oscillations are reduced as soon as the cathode is charged to 5 V. In the cor- responding Fourier transforms (Figure 4 b), this is refl ected by a preferential reduction in the amplitude of the fi rst shell of O atoms in addition to an overall damping of other shells. Quali- tatively, the χ ( k ) signal of the cycled-charged sample (i.e., the sample charged to 5 V during the 33 rd cycle) appears similar to that of the sample charged during the fi rst cycle, except that the signal is further damped. Along with the clear reduction in the peak amplitudes, the higher order shells of Mn atoms (at ≈4.7 Å) and O atoms (at ≈5.3 Å) largely disappear upon cycling. As shown in Figure 5 a, every feature of the χ ( k ) signal cor- responding to the pristine sample is reproduced when the cathode is discharged to 2 V during the fi rst cycle, however, with reduced amplitudes. This is also indicated by similarities in the Fourier transforms (Figure 5 b). Again, the EXAFS sig- nals corresponding to the cycled-discharged sample (i.e., the sample discharged to 2 V during the 33 rd cycle) appear similar to those of the sample discharged during the fi rst cycle, how- ever, the higher order shells are damped.",
      "category": "scientific_body",
      "coverage": 0.907,
      "words": 229
    },
    {
      "page": 4,
      "page_count": 12,
      "bbox": [
        46.95,
        290.86,
        290.16,
        498.03
      ],
      "text": "EXAFS data in the pristine state were fi tted by the mono- clinic structure of Li 2 MnO 3 ( C2 / m ) [ 22 ] ( Figure 6 ). Best-fi t param- eters are reported in Table S2 in the Supporting Information. A product of S2 0 and the number of coordinating atoms ( N ) in a given shell determines its amplitude. As a result, these two parameters for a given shell cannot be varied independently in a fi t. This can be realized by the fact that when the number of oxygen nearest neighbors ( O N-N ) in the pristine Li 2 MnO 3 was constrained to that obtained from the theoretical model, the fi t refi ned S2 0 to 0.76(4), which is consistent with S2 0 values obtained by fi tting the EXAFS data of other manganese refer- ence compounds. Conversely, when S2 0 was constrained to 0.76, the fi t refi ned O N-N to 6.0(4), which is consistent with the fact that in Li 2 MnO 3 Mn 4+ ions are octahedrally coordinated by oxygen. Additionally, F 2 values, which represent disorder in the material also affect the amplitude and, therefore, the terms S2 0 × N and F 2 for a given coordination shell, are highly correlated. Thus, determining N in highly disordered systems remains a challenge. The most signifi cant contribution to the",
      "category": "scientific_body",
      "coverage": 0.747,
      "words": 221
    },
    {
      "page": 4,
      "page_count": 12,
      "bbox": [
        302.06,
        290.89,
        545.32,
        720.25
      ],
      "text": "EXAFS signal is due to backscattering of ejected photoelectrons from the nearest neighbors (i.e., O N-N in case of Li 2 MnO 3 ). The contribution from outer coordination shells decreases due to increased inelastic losses as photoelectrons propagate in the material. Since S2 0 is the property of absorbing atoms, it is transferable between compounds where the absorbing atom in question is coordinated by the same type of nearest neigh- bors. On the other hand, F 2 cannot be estimated a priori. Thus, in situations where structural changes are to be followed as a result of any physical or chemical change that the sample has undergone, S2 0 can be estimated from the starting material. From this aspect, S2 0 determined from the pristine sample of Li 2 MnO 3 was regarded as the best estimate because it has a known oxygen coordination. The S2 0 value thus determined was constrained when structural changes due to changes in O N-N in the material were to be estimated. It has been reported that Li extraction from Li 2 MnO 3 occurs with a simultaneous loss of oxygen, giving rise to the forma- tion of a layered MnO 2 -type structure (trigonal, R 3 m ) with the average valence state of Mn remaining unchanged at +4. [ 11 ] There are also reports claiming the formation of either a layered MnO 2 -type structure or an α -MnO 2 -type structure (tetragonal, I4/m ) upon chemical delithiation of Li 2 MnO 3 . [ 23,24 ] In order to assess such reports, the EXAFS data of the sample charged to 5 V during the fi rst cycle were fi tted using the crystal struc- tures of α -MnO 2 and layered MnO 2 . The best fi t was obtained assuming the layered MnO 2 structure ( Figure 7 a). Best-fi t parameters are reported in Table S3 in the Supporting Informa- tion. The fi t constraining S2 0 to 0.76 refi ned O N-N to 5.6(8), which is high considering that oxygen is released from the material. It has been proposed that Li re-insertion into layered MnO 2 occurs with the simultaneous reduction of Mn 4+ to Mn 3+ , thus forming LiMnO 2 . [ 6,25 ] Therefore, an attempt was made to fi t the EXAFS data of the sample discharged to 2 V during the fi rst cycle by a layered LiMnO 2 structure ( R 3 m ). However, there was no agreement between the data and theory. The data were rather explained by a Li 2 MnO 3 structure (Figure 7 b). Best-fi t param- eters are reported in Table S4 in the Supporting Information. The fi t refi ned O N-N to 4.3(4) when S2 0 was constrained to 0.76.",
      "category": "scientific_body",
      "coverage": 0.844,
      "words": 452
    },
    {
      "page": 5,
      "page_count": 12,
      "bbox": [
        51.04,
        280.11,
        294.24,
        521.43
      ],
      "text": "It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] There- fore, an attempt was made to refi ne the fraction of such spinel phase in the cycled samples. However, there was no good agree- ment between the data and theory. For comparison, the EXAFS data for the LiMn 2 O 4 spinel are shown in Figure 8 . Qualitatively, the EXAFS data of the cycled samples appear similar to those of their counterparts during the fi rst cycle. As a result, a layered MnO 2 structure was assumed to fi t the data of the cycled-charged sample. When S2 0 was constrained to 0.76, the fi t refi ned O N-N to 3.3(4), which is very low considering the weak pre-edge peak of the cycled samples (inset in Figure 3 ), suggesting octahedral coordination. This fi t result emphasizes the effect of the observed reduction in the EXAFS signals upon cycling. A gradually declining electrochemical performance of the cell during cycling (Figure 1 b) suggests a gradual loss in the intercalation ability of the material. Therefore, a para- meter describing an effective concentration of electrochemi- cally active material, X eff , was introduced to the model such that the amplitude of each coordination shell of the cycled samples was represented by the term S2 0 × N × X eff . A fi t constraining S2 0 to 0.76 and O N-N to 4.3, refi ned X eff to 0.73(6) (Table S5 in the",
      "category": "scientific_body",
      "coverage": 0.822,
      "words": 257
    },
    {
      "page": 5,
      "page_count": 12,
      "bbox": [
        306.15,
        489.11,
        549.34,
        521.43
      ],
      "text": "Supporting Information) with a good agreement with the data as shown in Figure 9 a. Similarly, the EXAFS data of the cycled- discharged sample were explained by a Li 2 MnO 3 structure",
      "category": "back_matter",
      "coverage": 0.214,
      "words": 32
    },
    {
      "page": 6,
      "page_count": 12,
      "bbox": [
        302.01,
        70.93,
        545.21,
        245.1
      ],
      "text": "disorder. As shown in Figure 11 a, the pristine sample exhibits the smallest, while the charged sample exhibits the largest dis- order for all shells during the fi rst cycle. The structural disorder for the discharged sample is intermediate and in fact, appears to revert back to that of the pristine state. Note that F 2 asso- ciated with the fourth shell is particularly large and ill-refi ned for the charged sample, while it is small and better refi ned for the discharged sample. The structural disorder associated with the cycled samples is shown in Figure 11 b. The cycled-charged sample has larger disorder than the cycled-discharged sample for all shells. However, the trend is less clear beyond the second shell. The statistical EXAFS fi t parameters for various Li 2 MnO 3 samples are reported in Table S7 in the Supporting Informa- tion. A good agreement between the data and theory for all samples can be seen by their R -factors, which are <0.02.",
      "category": "metadata",
      "coverage": 0.056,
      "words": 164
    },
    {
      "page": 6,
      "page_count": 12,
      "bbox": [
        302.01,
        309.97,
        545.21,
        506.35
      ],
      "text": "1s → 3d transitions are forbidden by dipole rules in centrosym- metric confi gurations such as in regular octahedral symmetry. However, with increasing distortion from ideal octahedral sym- metry, the probability of a transition to d-orbitals increases. For tetrahedral symmetry, the metal-ligand orbital intermixing results in dipole-allowed 1s → 3d transitions with an intense pre-edge peak. [ 21,28 ] As shown in Figure 2 a, MnO with perfect octahedral symmetry has the lowest pre-edge peak intensity. As the distortion in octahedral symmetry increases in the order Mn 2 O 3 [ 29 ] → LiMn 2 O 4 [ 30 ] → MnO 2 , [ 31 ] the intensity of the pre-edge peak increases correspondingly. KMnO 4 with tetrahedral sym- metry [ 32 ] has the highest pre-edge peak intensity. Moreover, MnO with Mn 2+ exhibits the longest Mn-O bond length, while KMnO 4 with Mn 7+ has the shortest Mn-O bond length among all manganese reference compounds. Thus, the strength of the pre-edge peak can be correlated to the local coordination sym- metry around the absorbing atom and the average metal-ligand bond length.",
      "category": "metadata",
      "coverage": 0.057,
      "words": 178
    },
    {
      "page": 6,
      "page_count": 12,
      "bbox": [
        46.9,
        321.7,
        290.11,
        507.85
      ],
      "text": "(Figure 9 b). A fi t constraining S2 0 to 0.76 and O N-N to 4.3, refi ned X eff to 0.61(5) (Table S6 in the Supporting Information). A comparison between the metal-ligand bond lengths of var- ious Li 2 MnO 3 samples is shown in Figure 10 . The average Mn-O bond length in the pristine state is slightly higher than that of Mn 4+ -O. As the cathode is charged to 5 V, this bond length shortens and becomes similar to that of Mn 4+ -O. The bond length, however, remains unchanged during subsequent cycling. F 2 is the distribution of the backscattering atoms around their mean position measured with respect to the central absorbing atom. This distribution can be either caused by thermal vibrations (thermal disorder) or by static displacement of atoms (structural disorder). [ 26,27 ] Since all samples in the present study are characterized at the same temperature (i.e., room temperature), a systematic variation in their F 2 can be attributed to structural disorder introduced in the material as a result of electrochemical cycling, while neglecting thermal",
      "category": "scientific_body",
      "coverage": 0.093,
      "words": 186
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.14,
        70.9,
        549.35,
        212.07
      ],
      "text": "atoms in the second shell (see Table S2 in the Supporting Information). Thus, the ratio of the amplitudes of the fi rst two Fourier transform peaks, i.e., the Mn−O Mn−Mn ratio, being >1 is the EXAFS signature refl ecting the atomic arrangements of the Li 2 MnO 3 structure. A preferential reduction in the amplitude of the fi rst shell of O atoms besides an overall damping of other shells at 5 V (Figure 4 b) is consistent with previous reports [ 18 ] and can be attributed, respectively, to the oxygen loss and structural disorder introduced thereby upon Li extraction. This can be explained by the fact that the best fi t to the EXAFS data at 5 V (Figure 7 a) is based on a layered MnO 2 structure which has not only a reduced concentration of O",
      "category": "scientific_body",
      "coverage": 0.082,
      "words": 138
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.15,
        202.9,
        549.35,
        300.07
      ],
      "text": "Mn atoms, but is also a disordered form of Li 2 MnO 3 . [ 14 ] Also, an increase in the F 2 parameter for each coordination shell of the charged sample (Figure 11 a) confi rms the disorder introduced into the material by Li extraction. Consistent observation has been reported in the form of a loss of superlattice refl ections in the XRD pattern of Li 2 MnO 3 upon Li extraction. [ 18 ] Thus, Li extraction occurs with a concurrent removal of oxygen through its oxidation according to: [ 35 ]",
      "category": "scientific_body",
      "coverage": 0.048,
      "words": 88
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.15,
        327.04,
        549.35,
        539.82
      ],
      "text": "“ ’’ (1) However, fi tting the EXAFS data of the charged sample refi ned O N-N to 5.6(8) (Table S3 in the Supporting Informa- tion), which is high considering the fact that oxygen is released from the material during activation. Nevertheless, changes in the characteristic EXAFS signals of the material during charge clearly suggest atomic rearrangements as a result of oxygen loss. The static disorder introduced into the material increases F 2 corresponding to the fi rst shell of oxygen atoms (Figure 11 a) and as a result of its high correlation with O N-N (of the order of 0.88), the fi t overestimated the value of O N-N despite oxygen defi ciency in the material. The observed shortening of the average Mn-O bond length upon charge (Figure 10 ) can be attributed to these atomic rearrangements in the material due to oxygen release. Consistent observations have been reported in the form of a lattice contraction upon Li extraction from Li 2 MnO 3 . [ 18,25 ] Despite this structural modifi cation, the Mn−O",
      "category": "scientific_body",
      "coverage": 0.082,
      "words": 175
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        51.04,
        70.88,
        294.25,
        553.05
      ],
      "text": "The metal-ligand bond length determines the extent to which orbital intermixing takes place. As a result of this inter- mixing, the repulsive forces between the electrons increase the energies of these orbitals. Thus, metal d-orbitals split into t 2g and e g orbitals. [ 21,28 ] This can be realized by observing the pre- edge peaks of various manganese reference compounds (inset in Figure 2 a). MnO is a model octahedral compound, and thus exhibits a very faint pre-edge peak. A higher valence state of Mn in Mn 2 O 3 implies a shorter average Mn-O bond length than in MnO, which leads to higher electronic repulsions and higher orbital energies. As a result, the onset of pre-edge peak splitting in the Mn 2 O 3 spectrum is clearly visible. This peak splitting becomes more pronounced with a further increase in the average valence state of Mn to Mn 3.5+ or shortening of the average Mn-O bond length in LiMn 2 O 4 . For Li 2 MnO 3 , where Mn 4+ ions are octahedrally coordinated by oxygen, the peak splitting is maximum and best resolved (inset in Figure 3 ), as has been also reported previously. [ 18,33 ] A similar peak splitting phenomenon is also observed at the Fe K-edge of LiFePO 4 , [ 21,28 ] and is often known as crystal fi eld splitting. Empirically, a chemical shift in the absorption spectra can be correlated to the formal valence state of an absorbing atom. [ 20,34 ] However, in addition to the valence of an absorbing atom, chemical shifts are also affected by other structural features such as type, symmetry, number of nearest neighbors, char- acter of the bond, etc. [ 20 ] Also, the extent to which each of these features contributes to the chemical shift varies widely from material to material. The observed unambiguous chemical shift for various manganese reference compounds in Figure 2 a is the simplest example. However, for the samples of interest deter- mining the chemical shift can be quite complex. For instance, it is diffi cult to judge the chemical shift among various Li 2 MnO 3 samples in Figure 3 because there are several points along the main edge where spectra cross. In this situation, an estimation of the valence state depends on the reference point chosen. Thus, the approach involving the determination of the valence state of an absorbing atom from the observed chemical shift is strictly empirical, highly subjective, [ 18,19 ] and sometimes confusing. [ 33 ] Contrary to this, the average metal-ligand bond length obtained by fi tting the EXAFS data provides more reli- able information about the valence state of an absorbing atom because this bond length primarily depends on the ionic radius of the absorbing atom and, in turn, on its valence state as dem- onstrated in Figure 2 b.",
      "category": "scientific_body",
      "coverage": 0.039,
      "words": 466
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.15,
        530.65,
        549.35,
        715.82
      ],
      "text": "Mn−Mn ratio remains >1 for the charged sample (Figure 7 a), which suggests that the material retains its original Li 2 MnO 3 -like character even upon Li extraction. Thus, Li extraction does not completely destroy the ordering of Li and Mn within the [Li 1/3 Mn 2/3 ]O 2 slabs [ 25 ] and not all the extracted charge corresponds to oxygen release. Partial oxidation of oxygen anions can also supply electrons to the external circuit without releasing oxygen from the mate- rial. [ 33,36–38 ] Similarly, electrolyte oxidation [ 39–41 ] can also con- tribute to the observed charge capacity during activation. It is possible that H + generated as a result of electrolyte oxidation could displace electrochemically extracted Li + in the struc- ture. [ 13–15,25,35 ] A similar Li + -H + exchange mechanism has been observed for lithium manganese oxide spinels. [ 42,43 ] The Li + -H + exchange mechanism is also supported in Li 2 MnO 3 by the observed change in the stacking sequence of oxygen layers from O3-type (ABCABC) to P3-type (ABBCCA)",
      "category": "scientific_body",
      "coverage": 0.071,
      "words": 174
    },
    {
      "page": 8,
      "page_count": 12,
      "bbox": [
        46.9,
        255.71,
        290.1,
        473.88
      ],
      "text": "due to the presence of protons in the interslab region and strong O-H-O bonding. [ 14,25 ] For comparison, O3-type and P3-type structures are shown in Figure 12 . The ordered atomic arrangements of O3 structure in the pristine state produced well-defi ned Fourier transform peaks between 3 and 4.2 Å in Figure 6 . These peaks correspond to O atoms located at the boundaries of the neighboring [Li 1/3 Mn 2/3 ]O 2 slabs and are separated by interslab Li + -ions (Figure 12 a). For the charged sample, these peaks are replaced by a broad diffuse struc- ture (Figure 7 a). Correspondingly, F 2 associated with the fourth shell, which represents O atoms of the neighboring slabs increases abruptly and remains ill-refi ned upon charge (Figure 11 a). Both, smeared EXAFS peaks and large ill-refi ned F 2 suggest a large static displacement in the position of O atoms of the neighboring slabs and, in turn, can be correlated to a change in the stacking sequence of oxygen layers. Thus, the presence of H + in the interslab region, as a result of Li + - H + exchange, shears the oxygen layers due to strong O-H-O bonding and alters their stacking sequence from O3-type to P3-type according to:",
      "category": "scientific_body",
      "coverage": 0.076,
      "words": 215
    },
    {
      "page": 8,
      "page_count": 12,
      "bbox": [
        302.01,
        255.74,
        545.21,
        671.91
      ],
      "text": "Li is re-inserted into the material. This could have happened by exchanging already present H + in the structure with Li + . [ 14 ] Discharge could then involve the reduction of partially oxidized oxygen anions of active material, [ 43,46–48 ] and possibly that of electrolyte species which could consume H + driven out of the material. [ 14 ] Qualitative similarities between the EXAFS data of the pris- tine and discharged samples suggest structural re-ordering upon Li re-insertion. This is consistent with a reduction in the F 2 parameter for the coordination shells of the discharged sample (Figure 11 a). However, since permanent disorder caused by oxygen removal cannot be reverted, the discharged sample exhibits slightly higher disorder than the pristine sample. Due to this and despite qualitative similarities, the EXAFS amplitudes for the discharged sample are slightly reduced compared to those of the pristine sample. The value of O N-N refi ned to 4.3(4) for the discharged sample (Table S4 in the Supporting Information) should not be interpreted as tetrahedral coordination around Mn atoms, since the pre-edge region for the discharged sample is characterized by a weak pre-edge peak quite similar to that of the pristine sample (inset in Figure 3 ) rather suggesting octahedral coordination. These evidences suggest that the material regains its ordered Li 2 MnO 3 -type character upon Li re-insertion. As a result, F 2 corresponding the fi rst shell of O atoms decreases and becomes similar to that of the pristine state (Figure 11 a). Due to this, the fi t could correctly estimate oxygen defi ciency in the material by refi ning O N-N to 4.3(4) for the discharged sample. The Fourier transform peaks between 3 and 4.2 Å repre- senting O atoms of the neighboring slabs reappear upon dis- charge (Figure 7 b). Correspondingly, F 2 associated with these O atoms (fourth shell) decreases (Figure 11 a). Both these results suggest a change in the stacking sequence of oxygen layers from P3-type back to the original O3-type and are in good agreement with an earlier report of Rossouw et al. [ 44 ] where the XRD pattern of a re-lithiated sample closely resembled that of the parent Li 2 MnO 3 . Thus, Li re-insertion reverts the stacking sequence of oxygen layers from P3-type back to the original O3-type according to:",
      "category": "scientific_body",
      "coverage": 0.044,
      "words": 393
    },
    {
      "page": 8,
      "page_count": 12,
      "bbox": [
        46.9,
        566.21,
        290.11,
        718.38
      ],
      "text": "Several reports have claimed that Li re-insertion into layered MnO 2 gives rise to the formation of LiMnO 2 with a concurrent reduction of Mn 4+ to Mn 3+ . [ 6,25 ] According to these reports, the local structure of the discharged sample should be identical to that of the charged sample and the proposed reduction of Mn 4+ to Mn 3+ should be accompanied by an increase in the average Mn-O bond length. Contrary to these, the EXAFS data of the discharged sample (Figure 7 b) appear identical to those of the pristine sample (Figure 6 ), however, with reduced amplitudes and the average Mn-O bond length remains unchanged from that of the charged sample (Figure 10 ). Both these results con- tradict the proposed hypothesis about Li re-insertion into lay- ered MnO 2 . A specifi c discharge capacity of 200 mAh g −1 during the fi rst cycle (Figure 1 a) suggests that a signifi cant amount of",
      "category": "scientific_body",
      "coverage": 0.11,
      "words": 158
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        51.04,
        70.88,
        294.25,
        124.05
      ],
      "text": "The resultant structure upon discharge is similar to that of the parent Li 2 MnO 3 , except that it contains less Li and O. The driving force for such structural reversion is believed to be the relaxation of strained oxygen layers by displacing H + in the interslab region by Li + .",
      "category": "scientific_body",
      "coverage": 0.239,
      "words": 50
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        51.04,
        157.68,
        294.25,
        408.85
      ],
      "text": "It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] This claim is supported by qualitative similarities between the elec- trochemical profi les of cycled Li 2 MnO 3 and LiMn 2 O 4 [ 14 ] and the fact that the formation of LiMn 2 O 4 spinel phase from lay- ered LiMnO 2 that presumably forms during the fi rst discharge is favored. [ 45,46 ] However, the EXAFS data of the discharged sample during the fi rst cycle (Figure 7 b) clearly suggest that Li re-insertion into layered MnO 2 gives rise to the formation of Li 2 MnO 3 -type structure. This result is in confl ict with the existing hypothesis and raises doubts about the formation of a spinel-like phase upon cycling. Previously, Paik et al. [ 25 ] have also expressed ambiguity about the formation of a spinel-like phase upon cycling. Quite contrarily, a transmission electron microscopy (TEM) investigation by Gu et al. [ 47 ] revealed the presence of randomly oriented, extremely small domains of LiMn 2 O 4 -type spinel phase embedded within the amorphous surrounding resulting from the breakdown of the parent lattice of Li 2 MnO 3 upon cycling. Thus, there exist contradicting views about the structural modifi cations in Li 2 MnO 3 upon cycling. The crystallographic difference between the layered Li 2 MnO 3 and spinel LiMn 2 O 4 gives rise to distinct EXAFS signals (Figure 6 and Figure 8 ). A major difference lies in their Mn−O",
      "category": "scientific_body",
      "coverage": 0.176,
      "words": 259
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        306.15,
        70.9,
        549.35,
        597.07
      ],
      "text": "and to those of the cycled-discharged sample is by a Li 2 MnO 3 structure. These fi t results suggest that the fraction of elec- trochemically active material is reduced to ≈60–70% up to the 33 rd cycle, which is consistent with the reported structural deg- radation of the material [ 47 ] and, in turn, explains the observed decline in its electrochemical performance during cycling. It is reasonable to constrain the value of O N-N for the cycled samples to that obtained during the fi rst cycle for the obvious reason that oxygen is not released during each subsequent cycle, since under this situation the material would be completely depleted of oxygen anions after a few cycles. However, the weak pre-edge peak corresponding to the charged and discharged samples during the 33 rd cycle (inset in Figure 3 ) clearly suggests that local coordination symmetry around central Mn atoms is main- tained as octahedral. These results lead us to two major conclusions. First, the structural changes during the 33 rd cycle are similar to those observed during the fi rst, however, the fraction of electrochemi- cally active material is gradually reduced up to the 33 rd cycle. Second, oxygen removal occurs only during activation of the material in the fi rst cycle. As observed during the fi rst cycle, structural disorder for the cycled-charged sample is higher than for the cycled-discharged sample (Figure 11 b). However, the trend is less clear beyond the second shell. It should be noted that structural “visibility” for the cycled samples is also lim- ited to the fi rst two shells as indicated by well-defi ned Fourier transform peaks. Higher order shells of Mn atoms (at ≈4.7 Å) and O atoms (at ≈5.4 Å) clearly visible during the fi rst cycle are reduced during the 33 rd cycle (Figure 4 b and Figure 5 b). These shells represent Mn and O atoms from the neighboring [Li 1/3 Mn 2/3 ]O 2 slabs. These results suggest that atomic arrange- ments within an individual [Li 1/3 Mn 2/3 ]O 2 slab are intact. How- ever, the stacking sequence of subsequent slabs is disturbed upon cycling. The average Mn-O bond length for the cycled samples (Figure 10 ) remains unchanged from that of Mn 4+ -O, which rules out the conventional charge compensation mecha- nism involving the Mn 3+ /Mn 4+ redox reaction. Therefore, the observed charge-discharge capacities during subsequent cycles must have different origins. Possibly, oxygen anions of active material participate in unusual redox processes [ 33,36–38 ] and repetitive, irreversible oxidation of electrolyte species occurs because both of these processes can supply electrons to the external circuit and contribute to the observed charge capacity. Protons generated as a result of electrolyte oxidation could dis- place electrochemically extracted Li in the interslab region and alter the stacking sequence of oxygen layers from O3-type to P3-type according to:",
      "category": "scientific_body",
      "coverage": 0.083,
      "words": 476
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        51.04,
        399.68,
        294.25,
        718.0
      ],
      "text": "Mn−Mn ratios. Based on this criterion, the local structure of the cycled samples (Figure 9 ) is more similar to their counterparts during the fi rst cycle (Figure 7 ) than to LiMn 2 O 4 . While the forma- tion of the domains of LiMn 2 O 4 -type spinel phase upon cycling as observed during TEM investigation [ 47 ] cannot be ruled out, the presented EXAFS data of the cycled samples suggest oth- erwise. This discrepancy between the TEM and XAS investiga- tions should be judged in the context of the investigated sample volume by both these techniques. Previously, Shao-Horn et al. [ 48 ] reported that an extremely small sampling size in the TEM investigation may lead to systematically biased conclu- sions. In case of the formation of a spinel-like phase even on the particle surface, [ 47 ] a corresponding change in the EXAFS data of the material is expected since XAS in the transmis- sion mode provides information from both surface and bulk of all particles within the illuminated sample volume of at least a few cubic millimeters. Contrary to this, the observed reduc- tion in the EXAFS data of the cycled samples (Figure 4 b and Figure 5 b), while maintaining the similar characteristic fea- tures as observed for the samples during the fi rst cycle sug- gests structural degradation of the material during cycling. This effect is analogous to the broadening of diffraction peaks in the XRD pattern of a material that loses crystallinity. In our opinion, random atomic arrangements caused by deteriorating structural changes that occur in the material during cycling may appear on an extremely local fi eld of view of TEM as randomly oriented “spinel-like” domains. The best fi t to the EXAFS data of the cycled-charged sample is by a layered MnO 2 structure",
      "category": "scientific_body",
      "coverage": 0.059,
      "words": 290
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        306.15,
        654.31,
        549.36,
        718.48
      ],
      "text": "Subsequent discharge could involve the reduction of partially oxidized oxygen anions along with electrolyte species and Li re- insertion could occur by displacing already present protons in the material with a concurrent change in the oxygen stacking sequence from P3-type back to the original O3-type (Equation 4 ). Such repetitive shearing of oxygen layers during each",
      "category": "scientific_body",
      "coverage": 0.019,
      "words": 56
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        46.9,
        70.88,
        290.11,
        278.05
      ],
      "text": "subsequent cycle could lead to the loss of crystallinity of the material and consequently to the loss of its intercalation ability during cycling. The observed cleavage in Li 2 MnO 3 particles along the (001) plane [ 35 ] can be explained in terms of shearing of individual [Li 1/3 Mn 2/3 ]O 2 slab due to changing stacking sequence of oxygen layers. Moreover, the cycling curve of Li 2 MnO 3 in Figure 1 b does not show any plateau where fading levels off and at which the electrochemical performance of Li 2 MnO 3 corresponds to that of LiMn 2 O 4 spinel. In fact, fading starts right from the fi rst cycle and continues even beyond the 33 rd cycle. This suggests a continuous loss in the intercalation ability of the material as a result of continuous structural deg- radation during cycling. Since the suggested Li + -H + exchange mechanism could involve the repetitive consumption of electro- lyte species, it would inevitably deteriorate the cell performance on the long term. However, the presented results clearly sug- gest that the capacity degradation is more likely to be caused by the structural degradation of active material rather than the drying-out of electrolyte.",
      "category": "scientific_body",
      "coverage": 0.087,
      "words": 199
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        46.9,
        322.88,
        290.11,
        596.05
      ],
      "text": "Both XANES and EXAFS provide complementary informa- tion that helps to understand structural changes in Li 2 MnO 3 . The total charge capacity during activation can be attributed to the oxidation of oxygen anions and that of the electrolyte. The concurrent removal of oxygen along with Li gives rise to the formation of a layered MnO 2 -type structure, while maintaining a certain degree of Li and Mn ordering within its [Li 1/3 Mn 2/3 ] O 2 slabs. Protons generated as a result of electrolyte oxidation displace electrochemically extracted Li + in the structure. The presence of protons in the interslab region shears the oxygen layers due to strong O-H-O bonding and alters their stacking sequence from O3-type (ABCABC) to P3-type (ABBCCA). Li re-insertion into layered MnO 2 -type structure occurs by exchanging already present protons in the interslab region. The relaxation of strained oxygen layers caused by exchanging H + with Li + reverts their stacking sequence from P3-type back to the original O3-type. The resultant structure upon discharge closely resembles the parent Li 2 MnO 3 , however, it contains less Li and O. Mn 4+ does not participate in electrochemical pro- cesses and its average valence state remains unchanged at +4 at all times. Irreversible oxygen release occurs only during activa- tion of the material in the fi rst cycle. During subsequent cycles, electrochemical processes could possibly involve unusual redox processes of oxygen anions of active material together with the repetitive, irreversible oxidation of electrolyte species:",
      "category": "scientific_body",
      "coverage": 0.264,
      "words": 250
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        302.01,
        88.95,
        544.99,
        714.53
      ],
      "text": "Li 2 MnO 3 was synthesized by a modifi ed Pechini method from acetate precursors. [ 49 ] The precursor powders, Mn(OCOCH 3 ) 2 •4H 2 O and Li(OCOCH 3 )•H 2 O were dissolved in an aqueous mixture of ethylene glycol and citric acid (molar ratio 4:1). The mole ratio of ethylene glycol and Mn 2+ was 10:1. Dissolution of reagents was completed by heating to 90 °C with constant stirring followed by a temperature increase to 140 ° C to promote esterifi cation. Subsequently, the temperature was increased to 180 ° C and maintained for 12 h, during which period the polyester formed. Then, the temperature was increased to 250 °C and held for 6 h during which the ethylene glycol dried out and the material caramelized. Calcination at 450 °C for 5 h decomposed the precursors and formed Li 2 MnO 3 . The calcined Li 2 MnO 3 powder was pressed into pellets and annealed at 600 °C for 12 h. The annealed material was characterized for phase purity by X-ray diffraction. The cathodes for electrochemical characterization were prepared by mixing 80 wt% active material, 10 wt% carbon black, and 10 wt% of a solution of polyvinylidene di-fl uoride in N -methyl-2-pyrrolidone acting as a binder. The mixture was applied to an aluminum current collector. Electrochemical measurements were carried out in three- electrode Swagelok cells using metallic lithium as a counter and reference electrode. A mixture of ethylene carbonate (EC) and dimethyl carbonate (DMC) (1:1 V/V) containing 1 m LiPF 6 was used as electrolyte and a glass fi ber fi lter (Whatman GF/D) as separator. The cells were cycled between 2 V and 5 V vs. Li/Li + with a constant current density of 4.6 mA g −1 (i.e., C/50 with 1C = 230 mA g −1 ) during the fi rst charge and of 23 mA g −1 (i.e., C/10) during the subsequent cycles using a Maccor Series 4000 battery testing unit. The open circuit voltage (OCV) of the cell was measured to be ≈4.3 V for the charged states and ≈2.2 V for the discharged states. The cells were opened in a dry room and cathodes were washed with DMC solution. The active material was scraped off the aluminum current collector and ground using mortar and pestle. The fi nely ground powder was uniformly applied to the adhesive-coated Kapton tape using a brush. The powder-coated Kapton tape was cut into several pieces which were stacked on top of each other to form a thin, uniform transmission XAS sample. XAS measurements were carried out in the transmission mode at the Mn K-edge of various Li 2 MnO 3 samples. The samples charged and discharged during the fi rst cycle were measured at beamline A1 of the Hamburger Synchrotron Radiation Laboratory (HASYLAB), Hamburg, Germany, while those made during the 33 rd cycle were measured at beamline KMC-2 of the BESSY-II synchrotron light source, Berlin, Germany. The former is equipped with a Si (111) double crystal monochromator, while the latter has a graded Si-Ge (111) double crystal monochromator. Higher harmonics were rejected by detuning the monochromator such that the intensity of the beam on the sample was 65% of the maximum possible intensity. Absolute energy calibration of the monochromator was carried out by measuring a reference foil of pure manganese simultaneously with the sample. The intensities of the incident beam and beams transmitted through the sample and the reference foil were measured using gas-fi lled ionization chambers. The incident beam of 4 mm width and 1 mm height was used at both beamlines. Thus, any structural or compositional inhomogeneities within the individual particle of active material inside the illuminated sample volume were averaged over the entire spectrum. Besides Li 2 MnO 3 samples of interest, various manganese reference compounds such as MnO, Mn 2 O 3 , LiMn 2 O 4 , MnO 2 -Pyrolusite, and KMnO 4 were also measured. All spectra were energy-calibrated with respect to the fi rst peak in the derivative spectrum of pure manganese. Various data pre-processing operations such as deglitching, averaging the scans, energy calibration, normalization, background subtraction etc., [ 50 ] were performed using the software ATHENA of the package IFEFFIT . [ 51 ] The normalized component of the EXAFS signal was transformed to k -space and the resultant χ ( k ) signal was multiplied by k 3 to emphasize the data at high k . The k 3 -weighted χ ( k ) signal was then Fourier transformed and left uncorrected for a phase shift. The theoretical χ ( k ) was generated by performing ab initio calculations",
      "category": "back_matter",
      "coverage": 0.013,
      "words": 766
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        46.9,
        636.91,
        290.11,
        714.58
      ],
      "text": "(5) The proposed Li + -H + exchange during each subsequent charge and discharge could involve a structural fl ip-over between O3-type ( C2 / m ) and P3-type ( R 3 m ) by repeated shearing of oxygen layers. This could deteriorate crystallinity of the material and consequently its electrochemical performance during cycling.",
      "category": "scientific_body",
      "coverage": 0.0,
      "words": 49
    },
    {
      "page": 11,
      "page_count": 12,
      "bbox": [
        50.76,
        69.98,
        293.99,
        373.49
      ],
      "text": "using the code FEFF8.2. [ 52 ] The model function was least-square fi tted to the data using the software ARTEMIS of the package IFEFFIT which uses the algorithm FEFFIT. [ 51 ] The fi tting parameters involved a single amplitude reduction factor (S2 0 ) and an overall energy parameter ( Δ E 0 ) for each data set. S2 0 accounts for damping of EXAFS signals as a result of multi-electron excitations or many-body effects. [ 53–55 ] S2 0 is less than 1 and it remains constant for given absorbing atoms over the k-range used for EXAFS analysis. [ 55 ] The origin of EXAFS signal in k -space (i.e., k = 0) is defi ned by the threshold energy, E 0 . Unfortunately, there is no simple way to determine E 0 from the observed experimental spectrum. Therefore, E 0 is chosen arbitrarily for the experimental data. On the other hand, a model function is calculated by assuming the theoretical absorption threshold for given electronic level of absorbing atom. Thus, in order to align the phase of theoretical χ ( k ) with that of the experimental one, Δ E 0 is left as an adjustable parameter in a fi t. [ 55 ] A fractional change in the bond length ( α fi t ) was refi ned for each coordination shell such that a change in the bond length Δ R was given by Δ R = α fi t × R theory . Each coordination shell was assigned a separate mean-squared relative displacement parameter (F 2 ) depending on the type of atoms it contained and its mean distance from the central absorber. The parameters for multiple scattering paths were constrained in terms of those of corresponding single scattering paths. [ 56 ] Various statistical parameters such as χ 2 , reduced chi-square (P 2 < ) and the R -factor were used to assess the quality of an EXAFS fi t. However, since χ 2 and P 2 < were evaluated based on measurement uncertainties and FEFFIT poorly estimates the true measurement uncertainties, [ 56–58 ] both these parameters do not refl ect the true quality of the fi t. Nevertheless, both χ 2 and P 2 < were used to assess which model fi ts best the data. The statistical quality of the fi t was given by its R -factor, which is independent of measurement uncertainties. [ 56–58 ] A fi t with an R -factor less than 0.02 (i.e., 98% agreement between data and theory) is considered to be a good fi t. [ 56–58 ]",
      "category": "metadata",
      "coverage": 0.0,
      "words": 394
    }
  ],
  "low_coverage_blocks": [
    {
      "page": 1,
      "page_count": 12,
      "bbox": [
        51.01,
        545.39,
        233.73,
        700.46
      ],
      "text": "Dr. J. Rana, Dr. G. Schumacher, Dr. I. Zizak, Prof. J. Banhart Helmholtz-Zentrum Berlin für Materialien und Energie Hahn-Meitner-Platz 1 , 14109 , Berlin , Germany E-mail: jatinkumar.rana@helmholtz-berlin.de ; banhart@helmholtz-berlin.de Dr. M. Stan, R. Kloepsch, Dr. J. Li, Prof. M. Winter Institute of Physical Chemistry MEET Battery Research Centre University of Muenster Corrensstrasse 46 , 48149 , Muenster , Germany Dr. E. Welter Deutsches Elektronen-Synchrotron Notkestrasse 85 , 22607 , Hamburg , Germany Prof. J. Banhart Technische Universität Berlin Hardenbergstrasse 36 , 10623 , Berlin , Germany",
      "category": "metadata",
      "coverage": 0.0,
      "words": 88
    },
    {
      "page": 5,
      "page_count": 12,
      "bbox": [
        306.15,
        489.11,
        549.34,
        521.43
      ],
      "text": "Supporting Information) with a good agreement with the data as shown in Figure 9 a. Similarly, the EXAFS data of the cycled- discharged sample were explained by a Li 2 MnO 3 structure",
      "category": "back_matter",
      "coverage": 0.214,
      "words": 32
    },
    {
      "page": 6,
      "page_count": 12,
      "bbox": [
        302.01,
        70.93,
        545.21,
        245.1
      ],
      "text": "disorder. As shown in Figure 11 a, the pristine sample exhibits the smallest, while the charged sample exhibits the largest dis- order for all shells during the fi rst cycle. The structural disorder for the discharged sample is intermediate and in fact, appears to revert back to that of the pristine state. Note that F 2 asso- ciated with the fourth shell is particularly large and ill-refi ned for the charged sample, while it is small and better refi ned for the discharged sample. The structural disorder associated with the cycled samples is shown in Figure 11 b. The cycled-charged sample has larger disorder than the cycled-discharged sample for all shells. However, the trend is less clear beyond the second shell. The statistical EXAFS fi t parameters for various Li 2 MnO 3 samples are reported in Table S7 in the Supporting Informa- tion. A good agreement between the data and theory for all samples can be seen by their R -factors, which are <0.02.",
      "category": "metadata",
      "coverage": 0.056,
      "words": 164
    },
    {
      "page": 6,
      "page_count": 12,
      "bbox": [
        302.01,
        309.97,
        545.21,
        506.35
      ],
      "text": "1s → 3d transitions are forbidden by dipole rules in centrosym- metric confi gurations such as in regular octahedral symmetry. However, with increasing distortion from ideal octahedral sym- metry, the probability of a transition to d-orbitals increases. For tetrahedral symmetry, the metal-ligand orbital intermixing results in dipole-allowed 1s → 3d transitions with an intense pre-edge peak. [ 21,28 ] As shown in Figure 2 a, MnO with perfect octahedral symmetry has the lowest pre-edge peak intensity. As the distortion in octahedral symmetry increases in the order Mn 2 O 3 [ 29 ] → LiMn 2 O 4 [ 30 ] → MnO 2 , [ 31 ] the intensity of the pre-edge peak increases correspondingly. KMnO 4 with tetrahedral sym- metry [ 32 ] has the highest pre-edge peak intensity. Moreover, MnO with Mn 2+ exhibits the longest Mn-O bond length, while KMnO 4 with Mn 7+ has the shortest Mn-O bond length among all manganese reference compounds. Thus, the strength of the pre-edge peak can be correlated to the local coordination sym- metry around the absorbing atom and the average metal-ligand bond length.",
      "category": "metadata",
      "coverage": 0.057,
      "words": 178
    },
    {
      "page": 6,
      "page_count": 12,
      "bbox": [
        46.9,
        321.7,
        290.11,
        507.85
      ],
      "text": "(Figure 9 b). A fi t constraining S2 0 to 0.76 and O N-N to 4.3, refi ned X eff to 0.61(5) (Table S6 in the Supporting Information). A comparison between the metal-ligand bond lengths of var- ious Li 2 MnO 3 samples is shown in Figure 10 . The average Mn-O bond length in the pristine state is slightly higher than that of Mn 4+ -O. As the cathode is charged to 5 V, this bond length shortens and becomes similar to that of Mn 4+ -O. The bond length, however, remains unchanged during subsequent cycling. F 2 is the distribution of the backscattering atoms around their mean position measured with respect to the central absorbing atom. This distribution can be either caused by thermal vibrations (thermal disorder) or by static displacement of atoms (structural disorder). [ 26,27 ] Since all samples in the present study are characterized at the same temperature (i.e., room temperature), a systematic variation in their F 2 can be attributed to structural disorder introduced in the material as a result of electrochemical cycling, while neglecting thermal",
      "category": "scientific_body",
      "coverage": 0.093,
      "words": 186
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.14,
        70.9,
        549.35,
        212.07
      ],
      "text": "atoms in the second shell (see Table S2 in the Supporting Information). Thus, the ratio of the amplitudes of the fi rst two Fourier transform peaks, i.e., the Mn−O Mn−Mn ratio, being >1 is the EXAFS signature refl ecting the atomic arrangements of the Li 2 MnO 3 structure. A preferential reduction in the amplitude of the fi rst shell of O atoms besides an overall damping of other shells at 5 V (Figure 4 b) is consistent with previous reports [ 18 ] and can be attributed, respectively, to the oxygen loss and structural disorder introduced thereby upon Li extraction. This can be explained by the fact that the best fi t to the EXAFS data at 5 V (Figure 7 a) is based on a layered MnO 2 structure which has not only a reduced concentration of O",
      "category": "scientific_body",
      "coverage": 0.082,
      "words": 138
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.15,
        202.9,
        549.35,
        300.07
      ],
      "text": "Mn atoms, but is also a disordered form of Li 2 MnO 3 . [ 14 ] Also, an increase in the F 2 parameter for each coordination shell of the charged sample (Figure 11 a) confi rms the disorder introduced into the material by Li extraction. Consistent observation has been reported in the form of a loss of superlattice refl ections in the XRD pattern of Li 2 MnO 3 upon Li extraction. [ 18 ] Thus, Li extraction occurs with a concurrent removal of oxygen through its oxidation according to: [ 35 ]",
      "category": "scientific_body",
      "coverage": 0.048,
      "words": 88
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.15,
        327.04,
        549.35,
        539.82
      ],
      "text": "“ ’’ (1) However, fi tting the EXAFS data of the charged sample refi ned O N-N to 5.6(8) (Table S3 in the Supporting Informa- tion), which is high considering the fact that oxygen is released from the material during activation. Nevertheless, changes in the characteristic EXAFS signals of the material during charge clearly suggest atomic rearrangements as a result of oxygen loss. The static disorder introduced into the material increases F 2 corresponding to the fi rst shell of oxygen atoms (Figure 11 a) and as a result of its high correlation with O N-N (of the order of 0.88), the fi t overestimated the value of O N-N despite oxygen defi ciency in the material. The observed shortening of the average Mn-O bond length upon charge (Figure 10 ) can be attributed to these atomic rearrangements in the material due to oxygen release. Consistent observations have been reported in the form of a lattice contraction upon Li extraction from Li 2 MnO 3 . [ 18,25 ] Despite this structural modifi cation, the Mn−O",
      "category": "scientific_body",
      "coverage": 0.082,
      "words": 175
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        51.04,
        70.88,
        294.25,
        553.05
      ],
      "text": "The metal-ligand bond length determines the extent to which orbital intermixing takes place. As a result of this inter- mixing, the repulsive forces between the electrons increase the energies of these orbitals. Thus, metal d-orbitals split into t 2g and e g orbitals. [ 21,28 ] This can be realized by observing the pre- edge peaks of various manganese reference compounds (inset in Figure 2 a). MnO is a model octahedral compound, and thus exhibits a very faint pre-edge peak. A higher valence state of Mn in Mn 2 O 3 implies a shorter average Mn-O bond length than in MnO, which leads to higher electronic repulsions and higher orbital energies. As a result, the onset of pre-edge peak splitting in the Mn 2 O 3 spectrum is clearly visible. This peak splitting becomes more pronounced with a further increase in the average valence state of Mn to Mn 3.5+ or shortening of the average Mn-O bond length in LiMn 2 O 4 . For Li 2 MnO 3 , where Mn 4+ ions are octahedrally coordinated by oxygen, the peak splitting is maximum and best resolved (inset in Figure 3 ), as has been also reported previously. [ 18,33 ] A similar peak splitting phenomenon is also observed at the Fe K-edge of LiFePO 4 , [ 21,28 ] and is often known as crystal fi eld splitting. Empirically, a chemical shift in the absorption spectra can be correlated to the formal valence state of an absorbing atom. [ 20,34 ] However, in addition to the valence of an absorbing atom, chemical shifts are also affected by other structural features such as type, symmetry, number of nearest neighbors, char- acter of the bond, etc. [ 20 ] Also, the extent to which each of these features contributes to the chemical shift varies widely from material to material. The observed unambiguous chemical shift for various manganese reference compounds in Figure 2 a is the simplest example. However, for the samples of interest deter- mining the chemical shift can be quite complex. For instance, it is diffi cult to judge the chemical shift among various Li 2 MnO 3 samples in Figure 3 because there are several points along the main edge where spectra cross. In this situation, an estimation of the valence state depends on the reference point chosen. Thus, the approach involving the determination of the valence state of an absorbing atom from the observed chemical shift is strictly empirical, highly subjective, [ 18,19 ] and sometimes confusing. [ 33 ] Contrary to this, the average metal-ligand bond length obtained by fi tting the EXAFS data provides more reli- able information about the valence state of an absorbing atom because this bond length primarily depends on the ionic radius of the absorbing atom and, in turn, on its valence state as dem- onstrated in Figure 2 b.",
      "category": "scientific_body",
      "coverage": 0.039,
      "words": 466
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.15,
        530.65,
        549.35,
        715.82
      ],
      "text": "Mn−Mn ratio remains >1 for the charged sample (Figure 7 a), which suggests that the material retains its original Li 2 MnO 3 -like character even upon Li extraction. Thus, Li extraction does not completely destroy the ordering of Li and Mn within the [Li 1/3 Mn 2/3 ]O 2 slabs [ 25 ] and not all the extracted charge corresponds to oxygen release. Partial oxidation of oxygen anions can also supply electrons to the external circuit without releasing oxygen from the mate- rial. [ 33,36–38 ] Similarly, electrolyte oxidation [ 39–41 ] can also con- tribute to the observed charge capacity during activation. It is possible that H + generated as a result of electrolyte oxidation could displace electrochemically extracted Li + in the struc- ture. [ 13–15,25,35 ] A similar Li + -H + exchange mechanism has been observed for lithium manganese oxide spinels. [ 42,43 ] The Li + -H + exchange mechanism is also supported in Li 2 MnO 3 by the observed change in the stacking sequence of oxygen layers from O3-type (ABCABC) to P3-type (ABBCCA)",
      "category": "scientific_body",
      "coverage": 0.071,
      "words": 174
    },
    {
      "page": 8,
      "page_count": 12,
      "bbox": [
        46.9,
        255.71,
        290.1,
        473.88
      ],
      "text": "due to the presence of protons in the interslab region and strong O-H-O bonding. [ 14,25 ] For comparison, O3-type and P3-type structures are shown in Figure 12 . The ordered atomic arrangements of O3 structure in the pristine state produced well-defi ned Fourier transform peaks between 3 and 4.2 Å in Figure 6 . These peaks correspond to O atoms located at the boundaries of the neighboring [Li 1/3 Mn 2/3 ]O 2 slabs and are separated by interslab Li + -ions (Figure 12 a). For the charged sample, these peaks are replaced by a broad diffuse struc- ture (Figure 7 a). Correspondingly, F 2 associated with the fourth shell, which represents O atoms of the neighboring slabs increases abruptly and remains ill-refi ned upon charge (Figure 11 a). Both, smeared EXAFS peaks and large ill-refi ned F 2 suggest a large static displacement in the position of O atoms of the neighboring slabs and, in turn, can be correlated to a change in the stacking sequence of oxygen layers. Thus, the presence of H + in the interslab region, as a result of Li + - H + exchange, shears the oxygen layers due to strong O-H-O bonding and alters their stacking sequence from O3-type to P3-type according to:",
      "category": "scientific_body",
      "coverage": 0.076,
      "words": 215
    },
    {
      "page": 8,
      "page_count": 12,
      "bbox": [
        302.01,
        255.74,
        545.21,
        671.91
      ],
      "text": "Li is re-inserted into the material. This could have happened by exchanging already present H + in the structure with Li + . [ 14 ] Discharge could then involve the reduction of partially oxidized oxygen anions of active material, [ 43,46–48 ] and possibly that of electrolyte species which could consume H + driven out of the material. [ 14 ] Qualitative similarities between the EXAFS data of the pris- tine and discharged samples suggest structural re-ordering upon Li re-insertion. This is consistent with a reduction in the F 2 parameter for the coordination shells of the discharged sample (Figure 11 a). However, since permanent disorder caused by oxygen removal cannot be reverted, the discharged sample exhibits slightly higher disorder than the pristine sample. Due to this and despite qualitative similarities, the EXAFS amplitudes for the discharged sample are slightly reduced compared to those of the pristine sample. The value of O N-N refi ned to 4.3(4) for the discharged sample (Table S4 in the Supporting Information) should not be interpreted as tetrahedral coordination around Mn atoms, since the pre-edge region for the discharged sample is characterized by a weak pre-edge peak quite similar to that of the pristine sample (inset in Figure 3 ) rather suggesting octahedral coordination. These evidences suggest that the material regains its ordered Li 2 MnO 3 -type character upon Li re-insertion. As a result, F 2 corresponding the fi rst shell of O atoms decreases and becomes similar to that of the pristine state (Figure 11 a). Due to this, the fi t could correctly estimate oxygen defi ciency in the material by refi ning O N-N to 4.3(4) for the discharged sample. The Fourier transform peaks between 3 and 4.2 Å repre- senting O atoms of the neighboring slabs reappear upon dis- charge (Figure 7 b). Correspondingly, F 2 associated with these O atoms (fourth shell) decreases (Figure 11 a). Both these results suggest a change in the stacking sequence of oxygen layers from P3-type back to the original O3-type and are in good agreement with an earlier report of Rossouw et al. [ 44 ] where the XRD pattern of a re-lithiated sample closely resembled that of the parent Li 2 MnO 3 . Thus, Li re-insertion reverts the stacking sequence of oxygen layers from P3-type back to the original O3-type according to:",
      "category": "scientific_body",
      "coverage": 0.044,
      "words": 393
    },
    {
      "page": 8,
      "page_count": 12,
      "bbox": [
        46.9,
        566.21,
        290.11,
        718.38
      ],
      "text": "Several reports have claimed that Li re-insertion into layered MnO 2 gives rise to the formation of LiMnO 2 with a concurrent reduction of Mn 4+ to Mn 3+ . [ 6,25 ] According to these reports, the local structure of the discharged sample should be identical to that of the charged sample and the proposed reduction of Mn 4+ to Mn 3+ should be accompanied by an increase in the average Mn-O bond length. Contrary to these, the EXAFS data of the discharged sample (Figure 7 b) appear identical to those of the pristine sample (Figure 6 ), however, with reduced amplitudes and the average Mn-O bond length remains unchanged from that of the charged sample (Figure 10 ). Both these results con- tradict the proposed hypothesis about Li re-insertion into lay- ered MnO 2 . A specifi c discharge capacity of 200 mAh g −1 during the fi rst cycle (Figure 1 a) suggests that a signifi cant amount of",
      "category": "scientific_body",
      "coverage": 0.11,
      "words": 158
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        51.04,
        70.88,
        294.25,
        124.05
      ],
      "text": "The resultant structure upon discharge is similar to that of the parent Li 2 MnO 3 , except that it contains less Li and O. The driving force for such structural reversion is believed to be the relaxation of strained oxygen layers by displacing H + in the interslab region by Li + .",
      "category": "scientific_body",
      "coverage": 0.239,
      "words": 50
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        51.04,
        157.68,
        294.25,
        408.85
      ],
      "text": "It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] This claim is supported by qualitative similarities between the elec- trochemical profi les of cycled Li 2 MnO 3 and LiMn 2 O 4 [ 14 ] and the fact that the formation of LiMn 2 O 4 spinel phase from lay- ered LiMnO 2 that presumably forms during the fi rst discharge is favored. [ 45,46 ] However, the EXAFS data of the discharged sample during the fi rst cycle (Figure 7 b) clearly suggest that Li re-insertion into layered MnO 2 gives rise to the formation of Li 2 MnO 3 -type structure. This result is in confl ict with the existing hypothesis and raises doubts about the formation of a spinel-like phase upon cycling. Previously, Paik et al. [ 25 ] have also expressed ambiguity about the formation of a spinel-like phase upon cycling. Quite contrarily, a transmission electron microscopy (TEM) investigation by Gu et al. [ 47 ] revealed the presence of randomly oriented, extremely small domains of LiMn 2 O 4 -type spinel phase embedded within the amorphous surrounding resulting from the breakdown of the parent lattice of Li 2 MnO 3 upon cycling. Thus, there exist contradicting views about the structural modifi cations in Li 2 MnO 3 upon cycling. The crystallographic difference between the layered Li 2 MnO 3 and spinel LiMn 2 O 4 gives rise to distinct EXAFS signals (Figure 6 and Figure 8 ). A major difference lies in their Mn−O",
      "category": "scientific_body",
      "coverage": 0.176,
      "words": 259
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        306.15,
        70.9,
        549.35,
        597.07
      ],
      "text": "and to those of the cycled-discharged sample is by a Li 2 MnO 3 structure. These fi t results suggest that the fraction of elec- trochemically active material is reduced to ≈60–70% up to the 33 rd cycle, which is consistent with the reported structural deg- radation of the material [ 47 ] and, in turn, explains the observed decline in its electrochemical performance during cycling. It is reasonable to constrain the value of O N-N for the cycled samples to that obtained during the fi rst cycle for the obvious reason that oxygen is not released during each subsequent cycle, since under this situation the material would be completely depleted of oxygen anions after a few cycles. However, the weak pre-edge peak corresponding to the charged and discharged samples during the 33 rd cycle (inset in Figure 3 ) clearly suggests that local coordination symmetry around central Mn atoms is main- tained as octahedral. These results lead us to two major conclusions. First, the structural changes during the 33 rd cycle are similar to those observed during the fi rst, however, the fraction of electrochemi- cally active material is gradually reduced up to the 33 rd cycle. Second, oxygen removal occurs only during activation of the material in the fi rst cycle. As observed during the fi rst cycle, structural disorder for the cycled-charged sample is higher than for the cycled-discharged sample (Figure 11 b). However, the trend is less clear beyond the second shell. It should be noted that structural “visibility” for the cycled samples is also lim- ited to the fi rst two shells as indicated by well-defi ned Fourier transform peaks. Higher order shells of Mn atoms (at ≈4.7 Å) and O atoms (at ≈5.4 Å) clearly visible during the fi rst cycle are reduced during the 33 rd cycle (Figure 4 b and Figure 5 b). These shells represent Mn and O atoms from the neighboring [Li 1/3 Mn 2/3 ]O 2 slabs. These results suggest that atomic arrange- ments within an individual [Li 1/3 Mn 2/3 ]O 2 slab are intact. How- ever, the stacking sequence of subsequent slabs is disturbed upon cycling. The average Mn-O bond length for the cycled samples (Figure 10 ) remains unchanged from that of Mn 4+ -O, which rules out the conventional charge compensation mecha- nism involving the Mn 3+ /Mn 4+ redox reaction. Therefore, the observed charge-discharge capacities during subsequent cycles must have different origins. Possibly, oxygen anions of active material participate in unusual redox processes [ 33,36–38 ] and repetitive, irreversible oxidation of electrolyte species occurs because both of these processes can supply electrons to the external circuit and contribute to the observed charge capacity. Protons generated as a result of electrolyte oxidation could dis- place electrochemically extracted Li in the interslab region and alter the stacking sequence of oxygen layers from O3-type to P3-type according to:",
      "category": "scientific_body",
      "coverage": 0.083,
      "words": 476
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        51.04,
        399.68,
        294.25,
        718.0
      ],
      "text": "Mn−Mn ratios. Based on this criterion, the local structure of the cycled samples (Figure 9 ) is more similar to their counterparts during the fi rst cycle (Figure 7 ) than to LiMn 2 O 4 . While the forma- tion of the domains of LiMn 2 O 4 -type spinel phase upon cycling as observed during TEM investigation [ 47 ] cannot be ruled out, the presented EXAFS data of the cycled samples suggest oth- erwise. This discrepancy between the TEM and XAS investiga- tions should be judged in the context of the investigated sample volume by both these techniques. Previously, Shao-Horn et al. [ 48 ] reported that an extremely small sampling size in the TEM investigation may lead to systematically biased conclu- sions. In case of the formation of a spinel-like phase even on the particle surface, [ 47 ] a corresponding change in the EXAFS data of the material is expected since XAS in the transmis- sion mode provides information from both surface and bulk of all particles within the illuminated sample volume of at least a few cubic millimeters. Contrary to this, the observed reduc- tion in the EXAFS data of the cycled samples (Figure 4 b and Figure 5 b), while maintaining the similar characteristic fea- tures as observed for the samples during the fi rst cycle sug- gests structural degradation of the material during cycling. This effect is analogous to the broadening of diffraction peaks in the XRD pattern of a material that loses crystallinity. In our opinion, random atomic arrangements caused by deteriorating structural changes that occur in the material during cycling may appear on an extremely local fi eld of view of TEM as randomly oriented “spinel-like” domains. The best fi t to the EXAFS data of the cycled-charged sample is by a layered MnO 2 structure",
      "category": "scientific_body",
      "coverage": 0.059,
      "words": 290
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        306.15,
        654.31,
        549.36,
        718.48
      ],
      "text": "Subsequent discharge could involve the reduction of partially oxidized oxygen anions along with electrolyte species and Li re- insertion could occur by displacing already present protons in the material with a concurrent change in the oxygen stacking sequence from P3-type back to the original O3-type (Equation 4 ). Such repetitive shearing of oxygen layers during each",
      "category": "scientific_body",
      "coverage": 0.019,
      "words": 56
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        46.9,
        70.88,
        290.11,
        278.05
      ],
      "text": "subsequent cycle could lead to the loss of crystallinity of the material and consequently to the loss of its intercalation ability during cycling. The observed cleavage in Li 2 MnO 3 particles along the (001) plane [ 35 ] can be explained in terms of shearing of individual [Li 1/3 Mn 2/3 ]O 2 slab due to changing stacking sequence of oxygen layers. Moreover, the cycling curve of Li 2 MnO 3 in Figure 1 b does not show any plateau where fading levels off and at which the electrochemical performance of Li 2 MnO 3 corresponds to that of LiMn 2 O 4 spinel. In fact, fading starts right from the fi rst cycle and continues even beyond the 33 rd cycle. This suggests a continuous loss in the intercalation ability of the material as a result of continuous structural deg- radation during cycling. Since the suggested Li + -H + exchange mechanism could involve the repetitive consumption of electro- lyte species, it would inevitably deteriorate the cell performance on the long term. However, the presented results clearly sug- gest that the capacity degradation is more likely to be caused by the structural degradation of active material rather than the drying-out of electrolyte.",
      "category": "scientific_body",
      "coverage": 0.087,
      "words": 199
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        46.9,
        322.88,
        290.11,
        596.05
      ],
      "text": "Both XANES and EXAFS provide complementary informa- tion that helps to understand structural changes in Li 2 MnO 3 . The total charge capacity during activation can be attributed to the oxidation of oxygen anions and that of the electrolyte. The concurrent removal of oxygen along with Li gives rise to the formation of a layered MnO 2 -type structure, while maintaining a certain degree of Li and Mn ordering within its [Li 1/3 Mn 2/3 ] O 2 slabs. Protons generated as a result of electrolyte oxidation displace electrochemically extracted Li + in the structure. The presence of protons in the interslab region shears the oxygen layers due to strong O-H-O bonding and alters their stacking sequence from O3-type (ABCABC) to P3-type (ABBCCA). Li re-insertion into layered MnO 2 -type structure occurs by exchanging already present protons in the interslab region. The relaxation of strained oxygen layers caused by exchanging H + with Li + reverts their stacking sequence from P3-type back to the original O3-type. The resultant structure upon discharge closely resembles the parent Li 2 MnO 3 , however, it contains less Li and O. Mn 4+ does not participate in electrochemical pro- cesses and its average valence state remains unchanged at +4 at all times. Irreversible oxygen release occurs only during activa- tion of the material in the fi rst cycle. During subsequent cycles, electrochemical processes could possibly involve unusual redox processes of oxygen anions of active material together with the repetitive, irreversible oxidation of electrolyte species:",
      "category": "scientific_body",
      "coverage": 0.264,
      "words": 250
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        302.01,
        88.95,
        544.99,
        714.53
      ],
      "text": "Li 2 MnO 3 was synthesized by a modifi ed Pechini method from acetate precursors. [ 49 ] The precursor powders, Mn(OCOCH 3 ) 2 •4H 2 O and Li(OCOCH 3 )•H 2 O were dissolved in an aqueous mixture of ethylene glycol and citric acid (molar ratio 4:1). The mole ratio of ethylene glycol and Mn 2+ was 10:1. Dissolution of reagents was completed by heating to 90 °C with constant stirring followed by a temperature increase to 140 ° C to promote esterifi cation. Subsequently, the temperature was increased to 180 ° C and maintained for 12 h, during which period the polyester formed. Then, the temperature was increased to 250 °C and held for 6 h during which the ethylene glycol dried out and the material caramelized. Calcination at 450 °C for 5 h decomposed the precursors and formed Li 2 MnO 3 . The calcined Li 2 MnO 3 powder was pressed into pellets and annealed at 600 °C for 12 h. The annealed material was characterized for phase purity by X-ray diffraction. The cathodes for electrochemical characterization were prepared by mixing 80 wt% active material, 10 wt% carbon black, and 10 wt% of a solution of polyvinylidene di-fl uoride in N -methyl-2-pyrrolidone acting as a binder. The mixture was applied to an aluminum current collector. Electrochemical measurements were carried out in three- electrode Swagelok cells using metallic lithium as a counter and reference electrode. A mixture of ethylene carbonate (EC) and dimethyl carbonate (DMC) (1:1 V/V) containing 1 m LiPF 6 was used as electrolyte and a glass fi ber fi lter (Whatman GF/D) as separator. The cells were cycled between 2 V and 5 V vs. Li/Li + with a constant current density of 4.6 mA g −1 (i.e., C/50 with 1C = 230 mA g −1 ) during the fi rst charge and of 23 mA g −1 (i.e., C/10) during the subsequent cycles using a Maccor Series 4000 battery testing unit. The open circuit voltage (OCV) of the cell was measured to be ≈4.3 V for the charged states and ≈2.2 V for the discharged states. The cells were opened in a dry room and cathodes were washed with DMC solution. The active material was scraped off the aluminum current collector and ground using mortar and pestle. The fi nely ground powder was uniformly applied to the adhesive-coated Kapton tape using a brush. The powder-coated Kapton tape was cut into several pieces which were stacked on top of each other to form a thin, uniform transmission XAS sample. XAS measurements were carried out in the transmission mode at the Mn K-edge of various Li 2 MnO 3 samples. The samples charged and discharged during the fi rst cycle were measured at beamline A1 of the Hamburger Synchrotron Radiation Laboratory (HASYLAB), Hamburg, Germany, while those made during the 33 rd cycle were measured at beamline KMC-2 of the BESSY-II synchrotron light source, Berlin, Germany. The former is equipped with a Si (111) double crystal monochromator, while the latter has a graded Si-Ge (111) double crystal monochromator. Higher harmonics were rejected by detuning the monochromator such that the intensity of the beam on the sample was 65% of the maximum possible intensity. Absolute energy calibration of the monochromator was carried out by measuring a reference foil of pure manganese simultaneously with the sample. The intensities of the incident beam and beams transmitted through the sample and the reference foil were measured using gas-fi lled ionization chambers. The incident beam of 4 mm width and 1 mm height was used at both beamlines. Thus, any structural or compositional inhomogeneities within the individual particle of active material inside the illuminated sample volume were averaged over the entire spectrum. Besides Li 2 MnO 3 samples of interest, various manganese reference compounds such as MnO, Mn 2 O 3 , LiMn 2 O 4 , MnO 2 -Pyrolusite, and KMnO 4 were also measured. All spectra were energy-calibrated with respect to the fi rst peak in the derivative spectrum of pure manganese. Various data pre-processing operations such as deglitching, averaging the scans, energy calibration, normalization, background subtraction etc., [ 50 ] were performed using the software ATHENA of the package IFEFFIT . [ 51 ] The normalized component of the EXAFS signal was transformed to k -space and the resultant χ ( k ) signal was multiplied by k 3 to emphasize the data at high k . The k 3 -weighted χ ( k ) signal was then Fourier transformed and left uncorrected for a phase shift. The theoretical χ ( k ) was generated by performing ab initio calculations",
      "category": "back_matter",
      "coverage": 0.013,
      "words": 766
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        46.9,
        636.91,
        290.11,
        714.58
      ],
      "text": "(5) The proposed Li + -H + exchange during each subsequent charge and discharge could involve a structural fl ip-over between O3-type ( C2 / m ) and P3-type ( R 3 m ) by repeated shearing of oxygen layers. This could deteriorate crystallinity of the material and consequently its electrochemical performance during cycling.",
      "category": "scientific_body",
      "coverage": 0.0,
      "words": 49
    },
    {
      "page": 11,
      "page_count": 12,
      "bbox": [
        50.76,
        69.98,
        293.99,
        373.49
      ],
      "text": "using the code FEFF8.2. [ 52 ] The model function was least-square fi tted to the data using the software ARTEMIS of the package IFEFFIT which uses the algorithm FEFFIT. [ 51 ] The fi tting parameters involved a single amplitude reduction factor (S2 0 ) and an overall energy parameter ( Δ E 0 ) for each data set. S2 0 accounts for damping of EXAFS signals as a result of multi-electron excitations or many-body effects. [ 53–55 ] S2 0 is less than 1 and it remains constant for given absorbing atoms over the k-range used for EXAFS analysis. [ 55 ] The origin of EXAFS signal in k -space (i.e., k = 0) is defi ned by the threshold energy, E 0 . Unfortunately, there is no simple way to determine E 0 from the observed experimental spectrum. Therefore, E 0 is chosen arbitrarily for the experimental data. On the other hand, a model function is calculated by assuming the theoretical absorption threshold for given electronic level of absorbing atom. Thus, in order to align the phase of theoretical χ ( k ) with that of the experimental one, Δ E 0 is left as an adjustable parameter in a fi t. [ 55 ] A fractional change in the bond length ( α fi t ) was refi ned for each coordination shell such that a change in the bond length Δ R was given by Δ R = α fi t × R theory . Each coordination shell was assigned a separate mean-squared relative displacement parameter (F 2 ) depending on the type of atoms it contained and its mean distance from the central absorber. The parameters for multiple scattering paths were constrained in terms of those of corresponding single scattering paths. [ 56 ] Various statistical parameters such as χ 2 , reduced chi-square (P 2 < ) and the R -factor were used to assess the quality of an EXAFS fi t. However, since χ 2 and P 2 < were evaluated based on measurement uncertainties and FEFFIT poorly estimates the true measurement uncertainties, [ 56–58 ] both these parameters do not refl ect the true quality of the fi t. Nevertheless, both χ 2 and P 2 < were used to assess which model fi ts best the data. The statistical quality of the fi t was given by its R -factor, which is independent of measurement uncertainties. [ 56–58 ] A fi t with an R -factor less than 0.02 (i.e., 98% agreement between data and theory) is considered to be a good fi t. [ 56–58 ]",
      "category": "metadata",
      "coverage": 0.0,
      "words": 394
    }
  ],
  "high_risk_body_missing_blocks": [
    {
      "page": 6,
      "page_count": 12,
      "bbox": [
        46.9,
        321.7,
        290.11,
        507.85
      ],
      "text": "(Figure 9 b). A fi t constraining S2 0 to 0.76 and O N-N to 4.3, refi ned X eff to 0.61(5) (Table S6 in the Supporting Information). A comparison between the metal-ligand bond lengths of var- ious Li 2 MnO 3 samples is shown in Figure 10 . The average Mn-O bond length in the pristine state is slightly higher than that of Mn 4+ -O. As the cathode is charged to 5 V, this bond length shortens and becomes similar to that of Mn 4+ -O. The bond length, however, remains unchanged during subsequent cycling. F 2 is the distribution of the backscattering atoms around their mean position measured with respect to the central absorbing atom. This distribution can be either caused by thermal vibrations (thermal disorder) or by static displacement of atoms (structural disorder). [ 26,27 ] Since all samples in the present study are characterized at the same temperature (i.e., room temperature), a systematic variation in their F 2 can be attributed to structural disorder introduced in the material as a result of electrochemical cycling, while neglecting thermal",
      "category": "scientific_body",
      "coverage": 0.093,
      "words": 186
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.14,
        70.9,
        549.35,
        212.07
      ],
      "text": "atoms in the second shell (see Table S2 in the Supporting Information). Thus, the ratio of the amplitudes of the fi rst two Fourier transform peaks, i.e., the Mn−O Mn−Mn ratio, being >1 is the EXAFS signature refl ecting the atomic arrangements of the Li 2 MnO 3 structure. A preferential reduction in the amplitude of the fi rst shell of O atoms besides an overall damping of other shells at 5 V (Figure 4 b) is consistent with previous reports [ 18 ] and can be attributed, respectively, to the oxygen loss and structural disorder introduced thereby upon Li extraction. This can be explained by the fact that the best fi t to the EXAFS data at 5 V (Figure 7 a) is based on a layered MnO 2 structure which has not only a reduced concentration of O",
      "category": "scientific_body",
      "coverage": 0.082,
      "words": 138
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.15,
        202.9,
        549.35,
        300.07
      ],
      "text": "Mn atoms, but is also a disordered form of Li 2 MnO 3 . [ 14 ] Also, an increase in the F 2 parameter for each coordination shell of the charged sample (Figure 11 a) confi rms the disorder introduced into the material by Li extraction. Consistent observation has been reported in the form of a loss of superlattice refl ections in the XRD pattern of Li 2 MnO 3 upon Li extraction. [ 18 ] Thus, Li extraction occurs with a concurrent removal of oxygen through its oxidation according to: [ 35 ]",
      "category": "scientific_body",
      "coverage": 0.048,
      "words": 88
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.15,
        327.04,
        549.35,
        539.82
      ],
      "text": "“ ’’ (1) However, fi tting the EXAFS data of the charged sample refi ned O N-N to 5.6(8) (Table S3 in the Supporting Informa- tion), which is high considering the fact that oxygen is released from the material during activation. Nevertheless, changes in the characteristic EXAFS signals of the material during charge clearly suggest atomic rearrangements as a result of oxygen loss. The static disorder introduced into the material increases F 2 corresponding to the fi rst shell of oxygen atoms (Figure 11 a) and as a result of its high correlation with O N-N (of the order of 0.88), the fi t overestimated the value of O N-N despite oxygen defi ciency in the material. The observed shortening of the average Mn-O bond length upon charge (Figure 10 ) can be attributed to these atomic rearrangements in the material due to oxygen release. Consistent observations have been reported in the form of a lattice contraction upon Li extraction from Li 2 MnO 3 . [ 18,25 ] Despite this structural modifi cation, the Mn−O",
      "category": "scientific_body",
      "coverage": 0.082,
      "words": 175
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        51.04,
        70.88,
        294.25,
        553.05
      ],
      "text": "The metal-ligand bond length determines the extent to which orbital intermixing takes place. As a result of this inter- mixing, the repulsive forces between the electrons increase the energies of these orbitals. Thus, metal d-orbitals split into t 2g and e g orbitals. [ 21,28 ] This can be realized by observing the pre- edge peaks of various manganese reference compounds (inset in Figure 2 a). MnO is a model octahedral compound, and thus exhibits a very faint pre-edge peak. A higher valence state of Mn in Mn 2 O 3 implies a shorter average Mn-O bond length than in MnO, which leads to higher electronic repulsions and higher orbital energies. As a result, the onset of pre-edge peak splitting in the Mn 2 O 3 spectrum is clearly visible. This peak splitting becomes more pronounced with a further increase in the average valence state of Mn to Mn 3.5+ or shortening of the average Mn-O bond length in LiMn 2 O 4 . For Li 2 MnO 3 , where Mn 4+ ions are octahedrally coordinated by oxygen, the peak splitting is maximum and best resolved (inset in Figure 3 ), as has been also reported previously. [ 18,33 ] A similar peak splitting phenomenon is also observed at the Fe K-edge of LiFePO 4 , [ 21,28 ] and is often known as crystal fi eld splitting. Empirically, a chemical shift in the absorption spectra can be correlated to the formal valence state of an absorbing atom. [ 20,34 ] However, in addition to the valence of an absorbing atom, chemical shifts are also affected by other structural features such as type, symmetry, number of nearest neighbors, char- acter of the bond, etc. [ 20 ] Also, the extent to which each of these features contributes to the chemical shift varies widely from material to material. The observed unambiguous chemical shift for various manganese reference compounds in Figure 2 a is the simplest example. However, for the samples of interest deter- mining the chemical shift can be quite complex. For instance, it is diffi cult to judge the chemical shift among various Li 2 MnO 3 samples in Figure 3 because there are several points along the main edge where spectra cross. In this situation, an estimation of the valence state depends on the reference point chosen. Thus, the approach involving the determination of the valence state of an absorbing atom from the observed chemical shift is strictly empirical, highly subjective, [ 18,19 ] and sometimes confusing. [ 33 ] Contrary to this, the average metal-ligand bond length obtained by fi tting the EXAFS data provides more reli- able information about the valence state of an absorbing atom because this bond length primarily depends on the ionic radius of the absorbing atom and, in turn, on its valence state as dem- onstrated in Figure 2 b.",
      "category": "scientific_body",
      "coverage": 0.039,
      "words": 466
    },
    {
      "page": 7,
      "page_count": 12,
      "bbox": [
        306.15,
        530.65,
        549.35,
        715.82
      ],
      "text": "Mn−Mn ratio remains >1 for the charged sample (Figure 7 a), which suggests that the material retains its original Li 2 MnO 3 -like character even upon Li extraction. Thus, Li extraction does not completely destroy the ordering of Li and Mn within the [Li 1/3 Mn 2/3 ]O 2 slabs [ 25 ] and not all the extracted charge corresponds to oxygen release. Partial oxidation of oxygen anions can also supply electrons to the external circuit without releasing oxygen from the mate- rial. [ 33,36–38 ] Similarly, electrolyte oxidation [ 39–41 ] can also con- tribute to the observed charge capacity during activation. It is possible that H + generated as a result of electrolyte oxidation could displace electrochemically extracted Li + in the struc- ture. [ 13–15,25,35 ] A similar Li + -H + exchange mechanism has been observed for lithium manganese oxide spinels. [ 42,43 ] The Li + -H + exchange mechanism is also supported in Li 2 MnO 3 by the observed change in the stacking sequence of oxygen layers from O3-type (ABCABC) to P3-type (ABBCCA)",
      "category": "scientific_body",
      "coverage": 0.071,
      "words": 174
    },
    {
      "page": 8,
      "page_count": 12,
      "bbox": [
        46.9,
        255.71,
        290.1,
        473.88
      ],
      "text": "due to the presence of protons in the interslab region and strong O-H-O bonding. [ 14,25 ] For comparison, O3-type and P3-type structures are shown in Figure 12 . The ordered atomic arrangements of O3 structure in the pristine state produced well-defi ned Fourier transform peaks between 3 and 4.2 Å in Figure 6 . These peaks correspond to O atoms located at the boundaries of the neighboring [Li 1/3 Mn 2/3 ]O 2 slabs and are separated by interslab Li + -ions (Figure 12 a). For the charged sample, these peaks are replaced by a broad diffuse struc- ture (Figure 7 a). Correspondingly, F 2 associated with the fourth shell, which represents O atoms of the neighboring slabs increases abruptly and remains ill-refi ned upon charge (Figure 11 a). Both, smeared EXAFS peaks and large ill-refi ned F 2 suggest a large static displacement in the position of O atoms of the neighboring slabs and, in turn, can be correlated to a change in the stacking sequence of oxygen layers. Thus, the presence of H + in the interslab region, as a result of Li + - H + exchange, shears the oxygen layers due to strong O-H-O bonding and alters their stacking sequence from O3-type to P3-type according to:",
      "category": "scientific_body",
      "coverage": 0.076,
      "words": 215
    },
    {
      "page": 8,
      "page_count": 12,
      "bbox": [
        302.01,
        255.74,
        545.21,
        671.91
      ],
      "text": "Li is re-inserted into the material. This could have happened by exchanging already present H + in the structure with Li + . [ 14 ] Discharge could then involve the reduction of partially oxidized oxygen anions of active material, [ 43,46–48 ] and possibly that of electrolyte species which could consume H + driven out of the material. [ 14 ] Qualitative similarities between the EXAFS data of the pris- tine and discharged samples suggest structural re-ordering upon Li re-insertion. This is consistent with a reduction in the F 2 parameter for the coordination shells of the discharged sample (Figure 11 a). However, since permanent disorder caused by oxygen removal cannot be reverted, the discharged sample exhibits slightly higher disorder than the pristine sample. Due to this and despite qualitative similarities, the EXAFS amplitudes for the discharged sample are slightly reduced compared to those of the pristine sample. The value of O N-N refi ned to 4.3(4) for the discharged sample (Table S4 in the Supporting Information) should not be interpreted as tetrahedral coordination around Mn atoms, since the pre-edge region for the discharged sample is characterized by a weak pre-edge peak quite similar to that of the pristine sample (inset in Figure 3 ) rather suggesting octahedral coordination. These evidences suggest that the material regains its ordered Li 2 MnO 3 -type character upon Li re-insertion. As a result, F 2 corresponding the fi rst shell of O atoms decreases and becomes similar to that of the pristine state (Figure 11 a). Due to this, the fi t could correctly estimate oxygen defi ciency in the material by refi ning O N-N to 4.3(4) for the discharged sample. The Fourier transform peaks between 3 and 4.2 Å repre- senting O atoms of the neighboring slabs reappear upon dis- charge (Figure 7 b). Correspondingly, F 2 associated with these O atoms (fourth shell) decreases (Figure 11 a). Both these results suggest a change in the stacking sequence of oxygen layers from P3-type back to the original O3-type and are in good agreement with an earlier report of Rossouw et al. [ 44 ] where the XRD pattern of a re-lithiated sample closely resembled that of the parent Li 2 MnO 3 . Thus, Li re-insertion reverts the stacking sequence of oxygen layers from P3-type back to the original O3-type according to:",
      "category": "scientific_body",
      "coverage": 0.044,
      "words": 393
    },
    {
      "page": 8,
      "page_count": 12,
      "bbox": [
        46.9,
        566.21,
        290.11,
        718.38
      ],
      "text": "Several reports have claimed that Li re-insertion into layered MnO 2 gives rise to the formation of LiMnO 2 with a concurrent reduction of Mn 4+ to Mn 3+ . [ 6,25 ] According to these reports, the local structure of the discharged sample should be identical to that of the charged sample and the proposed reduction of Mn 4+ to Mn 3+ should be accompanied by an increase in the average Mn-O bond length. Contrary to these, the EXAFS data of the discharged sample (Figure 7 b) appear identical to those of the pristine sample (Figure 6 ), however, with reduced amplitudes and the average Mn-O bond length remains unchanged from that of the charged sample (Figure 10 ). Both these results con- tradict the proposed hypothesis about Li re-insertion into lay- ered MnO 2 . A specifi c discharge capacity of 200 mAh g −1 during the fi rst cycle (Figure 1 a) suggests that a signifi cant amount of",
      "category": "scientific_body",
      "coverage": 0.11,
      "words": 158
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        51.04,
        70.88,
        294.25,
        124.05
      ],
      "text": "The resultant structure upon discharge is similar to that of the parent Li 2 MnO 3 , except that it contains less Li and O. The driving force for such structural reversion is believed to be the relaxation of strained oxygen layers by displacing H + in the interslab region by Li + .",
      "category": "scientific_body",
      "coverage": 0.239,
      "words": 50
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        51.04,
        157.68,
        294.25,
        408.85
      ],
      "text": "It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] This claim is supported by qualitative similarities between the elec- trochemical profi les of cycled Li 2 MnO 3 and LiMn 2 O 4 [ 14 ] and the fact that the formation of LiMn 2 O 4 spinel phase from lay- ered LiMnO 2 that presumably forms during the fi rst discharge is favored. [ 45,46 ] However, the EXAFS data of the discharged sample during the fi rst cycle (Figure 7 b) clearly suggest that Li re-insertion into layered MnO 2 gives rise to the formation of Li 2 MnO 3 -type structure. This result is in confl ict with the existing hypothesis and raises doubts about the formation of a spinel-like phase upon cycling. Previously, Paik et al. [ 25 ] have also expressed ambiguity about the formation of a spinel-like phase upon cycling. Quite contrarily, a transmission electron microscopy (TEM) investigation by Gu et al. [ 47 ] revealed the presence of randomly oriented, extremely small domains of LiMn 2 O 4 -type spinel phase embedded within the amorphous surrounding resulting from the breakdown of the parent lattice of Li 2 MnO 3 upon cycling. Thus, there exist contradicting views about the structural modifi cations in Li 2 MnO 3 upon cycling. The crystallographic difference between the layered Li 2 MnO 3 and spinel LiMn 2 O 4 gives rise to distinct EXAFS signals (Figure 6 and Figure 8 ). A major difference lies in their Mn−O",
      "category": "scientific_body",
      "coverage": 0.176,
      "words": 259
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        306.15,
        70.9,
        549.35,
        597.07
      ],
      "text": "and to those of the cycled-discharged sample is by a Li 2 MnO 3 structure. These fi t results suggest that the fraction of elec- trochemically active material is reduced to ≈60–70% up to the 33 rd cycle, which is consistent with the reported structural deg- radation of the material [ 47 ] and, in turn, explains the observed decline in its electrochemical performance during cycling. It is reasonable to constrain the value of O N-N for the cycled samples to that obtained during the fi rst cycle for the obvious reason that oxygen is not released during each subsequent cycle, since under this situation the material would be completely depleted of oxygen anions after a few cycles. However, the weak pre-edge peak corresponding to the charged and discharged samples during the 33 rd cycle (inset in Figure 3 ) clearly suggests that local coordination symmetry around central Mn atoms is main- tained as octahedral. These results lead us to two major conclusions. First, the structural changes during the 33 rd cycle are similar to those observed during the fi rst, however, the fraction of electrochemi- cally active material is gradually reduced up to the 33 rd cycle. Second, oxygen removal occurs only during activation of the material in the fi rst cycle. As observed during the fi rst cycle, structural disorder for the cycled-charged sample is higher than for the cycled-discharged sample (Figure 11 b). However, the trend is less clear beyond the second shell. It should be noted that structural “visibility” for the cycled samples is also lim- ited to the fi rst two shells as indicated by well-defi ned Fourier transform peaks. Higher order shells of Mn atoms (at ≈4.7 Å) and O atoms (at ≈5.4 Å) clearly visible during the fi rst cycle are reduced during the 33 rd cycle (Figure 4 b and Figure 5 b). These shells represent Mn and O atoms from the neighboring [Li 1/3 Mn 2/3 ]O 2 slabs. These results suggest that atomic arrange- ments within an individual [Li 1/3 Mn 2/3 ]O 2 slab are intact. How- ever, the stacking sequence of subsequent slabs is disturbed upon cycling. The average Mn-O bond length for the cycled samples (Figure 10 ) remains unchanged from that of Mn 4+ -O, which rules out the conventional charge compensation mecha- nism involving the Mn 3+ /Mn 4+ redox reaction. Therefore, the observed charge-discharge capacities during subsequent cycles must have different origins. Possibly, oxygen anions of active material participate in unusual redox processes [ 33,36–38 ] and repetitive, irreversible oxidation of electrolyte species occurs because both of these processes can supply electrons to the external circuit and contribute to the observed charge capacity. Protons generated as a result of electrolyte oxidation could dis- place electrochemically extracted Li in the interslab region and alter the stacking sequence of oxygen layers from O3-type to P3-type according to:",
      "category": "scientific_body",
      "coverage": 0.083,
      "words": 476
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        51.04,
        399.68,
        294.25,
        718.0
      ],
      "text": "Mn−Mn ratios. Based on this criterion, the local structure of the cycled samples (Figure 9 ) is more similar to their counterparts during the fi rst cycle (Figure 7 ) than to LiMn 2 O 4 . While the forma- tion of the domains of LiMn 2 O 4 -type spinel phase upon cycling as observed during TEM investigation [ 47 ] cannot be ruled out, the presented EXAFS data of the cycled samples suggest oth- erwise. This discrepancy between the TEM and XAS investiga- tions should be judged in the context of the investigated sample volume by both these techniques. Previously, Shao-Horn et al. [ 48 ] reported that an extremely small sampling size in the TEM investigation may lead to systematically biased conclu- sions. In case of the formation of a spinel-like phase even on the particle surface, [ 47 ] a corresponding change in the EXAFS data of the material is expected since XAS in the transmis- sion mode provides information from both surface and bulk of all particles within the illuminated sample volume of at least a few cubic millimeters. Contrary to this, the observed reduc- tion in the EXAFS data of the cycled samples (Figure 4 b and Figure 5 b), while maintaining the similar characteristic fea- tures as observed for the samples during the fi rst cycle sug- gests structural degradation of the material during cycling. This effect is analogous to the broadening of diffraction peaks in the XRD pattern of a material that loses crystallinity. In our opinion, random atomic arrangements caused by deteriorating structural changes that occur in the material during cycling may appear on an extremely local fi eld of view of TEM as randomly oriented “spinel-like” domains. The best fi t to the EXAFS data of the cycled-charged sample is by a layered MnO 2 structure",
      "category": "scientific_body",
      "coverage": 0.059,
      "words": 290
    },
    {
      "page": 9,
      "page_count": 12,
      "bbox": [
        306.15,
        654.31,
        549.36,
        718.48
      ],
      "text": "Subsequent discharge could involve the reduction of partially oxidized oxygen anions along with electrolyte species and Li re- insertion could occur by displacing already present protons in the material with a concurrent change in the oxygen stacking sequence from P3-type back to the original O3-type (Equation 4 ). Such repetitive shearing of oxygen layers during each",
      "category": "scientific_body",
      "coverage": 0.019,
      "words": 56
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        46.9,
        70.88,
        290.11,
        278.05
      ],
      "text": "subsequent cycle could lead to the loss of crystallinity of the material and consequently to the loss of its intercalation ability during cycling. The observed cleavage in Li 2 MnO 3 particles along the (001) plane [ 35 ] can be explained in terms of shearing of individual [Li 1/3 Mn 2/3 ]O 2 slab due to changing stacking sequence of oxygen layers. Moreover, the cycling curve of Li 2 MnO 3 in Figure 1 b does not show any plateau where fading levels off and at which the electrochemical performance of Li 2 MnO 3 corresponds to that of LiMn 2 O 4 spinel. In fact, fading starts right from the fi rst cycle and continues even beyond the 33 rd cycle. This suggests a continuous loss in the intercalation ability of the material as a result of continuous structural deg- radation during cycling. Since the suggested Li + -H + exchange mechanism could involve the repetitive consumption of electro- lyte species, it would inevitably deteriorate the cell performance on the long term. However, the presented results clearly sug- gest that the capacity degradation is more likely to be caused by the structural degradation of active material rather than the drying-out of electrolyte.",
      "category": "scientific_body",
      "coverage": 0.087,
      "words": 199
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        46.9,
        322.88,
        290.11,
        596.05
      ],
      "text": "Both XANES and EXAFS provide complementary informa- tion that helps to understand structural changes in Li 2 MnO 3 . The total charge capacity during activation can be attributed to the oxidation of oxygen anions and that of the electrolyte. The concurrent removal of oxygen along with Li gives rise to the formation of a layered MnO 2 -type structure, while maintaining a certain degree of Li and Mn ordering within its [Li 1/3 Mn 2/3 ] O 2 slabs. Protons generated as a result of electrolyte oxidation displace electrochemically extracted Li + in the structure. The presence of protons in the interslab region shears the oxygen layers due to strong O-H-O bonding and alters their stacking sequence from O3-type (ABCABC) to P3-type (ABBCCA). Li re-insertion into layered MnO 2 -type structure occurs by exchanging already present protons in the interslab region. The relaxation of strained oxygen layers caused by exchanging H + with Li + reverts their stacking sequence from P3-type back to the original O3-type. The resultant structure upon discharge closely resembles the parent Li 2 MnO 3 , however, it contains less Li and O. Mn 4+ does not participate in electrochemical pro- cesses and its average valence state remains unchanged at +4 at all times. Irreversible oxygen release occurs only during activa- tion of the material in the fi rst cycle. During subsequent cycles, electrochemical processes could possibly involve unusual redox processes of oxygen anions of active material together with the repetitive, irreversible oxidation of electrolyte species:",
      "category": "scientific_body",
      "coverage": 0.264,
      "words": 250
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        46.9,
        636.91,
        290.11,
        714.58
      ],
      "text": "(5) The proposed Li + -H + exchange during each subsequent charge and discharge could involve a structural fl ip-over between O3-type ( C2 / m ) and P3-type ( R 3 m ) by repeated shearing of oxygen layers. This could deteriorate crystallinity of the material and consequently its electrochemical performance during cycling.",
      "category": "scientific_body",
      "coverage": 0.0,
      "words": 49
    }
  ],
  "front_summary_missing_blocks": [],
  "back_matter_low_overlap_blocks": [
    {
      "page": 5,
      "page_count": 12,
      "bbox": [
        306.15,
        489.11,
        549.34,
        521.43
      ],
      "text": "Supporting Information) with a good agreement with the data as shown in Figure 9 a. Similarly, the EXAFS data of the cycled- discharged sample were explained by a Li 2 MnO 3 structure",
      "category": "back_matter",
      "coverage": 0.214,
      "words": 32
    },
    {
      "page": 10,
      "page_count": 12,
      "bbox": [
        302.01,
        88.95,
        544.99,
        714.53
      ],
      "text": "Li 2 MnO 3 was synthesized by a modifi ed Pechini method from acetate precursors. [ 49 ] The precursor powders, Mn(OCOCH 3 ) 2 •4H 2 O and Li(OCOCH 3 )•H 2 O were dissolved in an aqueous mixture of ethylene glycol and citric acid (molar ratio 4:1). The mole ratio of ethylene glycol and Mn 2+ was 10:1. Dissolution of reagents was completed by heating to 90 °C with constant stirring followed by a temperature increase to 140 ° C to promote esterifi cation. Subsequently, the temperature was increased to 180 ° C and maintained for 12 h, during which period the polyester formed. Then, the temperature was increased to 250 °C and held for 6 h during which the ethylene glycol dried out and the material caramelized. Calcination at 450 °C for 5 h decomposed the precursors and formed Li 2 MnO 3 . The calcined Li 2 MnO 3 powder was pressed into pellets and annealed at 600 °C for 12 h. The annealed material was characterized for phase purity by X-ray diffraction. The cathodes for electrochemical characterization were prepared by mixing 80 wt% active material, 10 wt% carbon black, and 10 wt% of a solution of polyvinylidene di-fl uoride in N -methyl-2-pyrrolidone acting as a binder. The mixture was applied to an aluminum current collector. Electrochemical measurements were carried out in three- electrode Swagelok cells using metallic lithium as a counter and reference electrode. A mixture of ethylene carbonate (EC) and dimethyl carbonate (DMC) (1:1 V/V) containing 1 m LiPF 6 was used as electrolyte and a glass fi ber fi lter (Whatman GF/D) as separator. The cells were cycled between 2 V and 5 V vs. Li/Li + with a constant current density of 4.6 mA g −1 (i.e., C/50 with 1C = 230 mA g −1 ) during the fi rst charge and of 23 mA g −1 (i.e., C/10) during the subsequent cycles using a Maccor Series 4000 battery testing unit. The open circuit voltage (OCV) of the cell was measured to be ≈4.3 V for the charged states and ≈2.2 V for the discharged states. The cells were opened in a dry room and cathodes were washed with DMC solution. The active material was scraped off the aluminum current collector and ground using mortar and pestle. The fi nely ground powder was uniformly applied to the adhesive-coated Kapton tape using a brush. The powder-coated Kapton tape was cut into several pieces which were stacked on top of each other to form a thin, uniform transmission XAS sample. XAS measurements were carried out in the transmission mode at the Mn K-edge of various Li 2 MnO 3 samples. The samples charged and discharged during the fi rst cycle were measured at beamline A1 of the Hamburger Synchrotron Radiation Laboratory (HASYLAB), Hamburg, Germany, while those made during the 33 rd cycle were measured at beamline KMC-2 of the BESSY-II synchrotron light source, Berlin, Germany. The former is equipped with a Si (111) double crystal monochromator, while the latter has a graded Si-Ge (111) double crystal monochromator. Higher harmonics were rejected by detuning the monochromator such that the intensity of the beam on the sample was 65% of the maximum possible intensity. Absolute energy calibration of the monochromator was carried out by measuring a reference foil of pure manganese simultaneously with the sample. The intensities of the incident beam and beams transmitted through the sample and the reference foil were measured using gas-fi lled ionization chambers. The incident beam of 4 mm width and 1 mm height was used at both beamlines. Thus, any structural or compositional inhomogeneities within the individual particle of active material inside the illuminated sample volume were averaged over the entire spectrum. Besides Li 2 MnO 3 samples of interest, various manganese reference compounds such as MnO, Mn 2 O 3 , LiMn 2 O 4 , MnO 2 -Pyrolusite, and KMnO 4 were also measured. All spectra were energy-calibrated with respect to the fi rst peak in the derivative spectrum of pure manganese. Various data pre-processing operations such as deglitching, averaging the scans, energy calibration, normalization, background subtraction etc., [ 50 ] were performed using the software ATHENA of the package IFEFFIT . [ 51 ] The normalized component of the EXAFS signal was transformed to k -space and the resultant χ ( k ) signal was multiplied by k 3 to emphasize the data at high k . The k 3 -weighted χ ( k ) signal was then Fourier transformed and left uncorrected for a phase shift. The theoretical χ ( k ) was generated by performing ab initio calculations",
      "category": "back_matter",
      "coverage": 0.013,
      "words": 766
    }
  ]
}