08-springer-middle-pages

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Abstract chars: 864

The ever-growing market of electrochemical energy storage impels the advances on cost-effective and environmentally friendly battery chemistries. Lithiumion batteries (LIBs) are currently the most critical energy storage devices for a variety of applications, while sodium-ion batteries (SIBs) are expected to complement LIBs in large-scale applications. In respect to their constituent components, the cathode part is the most significant sector regarding weight fraction and cost. Therefore, the development of cathode materials based on Earth ' s abundant elements (Fe and Mn) largely determines the prospects of the batteries. Herein, we offer a comprehensive review of the up-to-date advances on Fe- and Mnbased cathode materials for LIBs and SIBs, highlighting some promising candidates, such as Li- and Mn-rich layered oxides, LiNi0.5Mn1.5O4, LiFe1-xMnxPO4,

Sections

• Introduction (5383 chars)
• Fe- and Mn-based oxides as LIB cathodes (843 chars)
• LiMnO2 (3160 chars)
• LiFeO2 (2930 chars)
• Li2MnO3-based oxides (4309 chars)
• LiMn2O4 (3317 chars)
• LiNi0.5Mn1.5O4 (5986 chars)
• Fe- and Mn-based polyanion compounds as LIB cathodes (651 chars)
• Fe- and Mn-based phosphates (6868 chars)
• Fe- and Mn-based silicates (2587 chars)
• Fe- and Mn-based borates (1733 chars)
• Fe- and Mn-based oxides as SIB cathodes (1769 chars)
• NaFeO2 (11181 chars)
• Fe- and Mn-based polyanion compounds as SIB cathodes (517 chars)
• Fe-and Mn-based phosphates (4189 chars)
• Fe- and Mn-based pyrophosphates (11382 chars)
• Fe- and Mn-based hexacyanometalates (2697 chars)
• Summary and outlook (4836 chars)

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• p40 scientific_body coverage=0.0: ion batteries. Adv Energy Mater 8(6):1701415. https://doi. org/10.1002/aenm.201701415 Zhu Y, Xu Y, Liu Y, Luo C, Wang C (2013) Comparison of electrochemical performances of olivine NaFePO4 in sodium-ion batteries and olivine LiFePO4 in lithium-ion batteries. N