page source_page_order layout_page_order layout_order ref label role_guess included_in_body excluded_risk_level body_decision_reason parser_body_decision_reason production_usage visual_asset_type visual_asset_label visual_asset_caption_preview truncation_marker inside_body_region body_region_id zone column column_index column_count region_id background_rgb background_class is_gray_background has_frame_evidence bbox text_preview cleaned_text_preview 1 2 1 0 #/texts/1 text page_margin_header False low document_web_address document_web_address True p1:body_region:0 top_margin column_1_of_2 1 2 p1:top_margin:column_1_of_2:white [255, 255, 255] white False False [51.01, 53.34, 83.44, 6.78] www.MaterialsViews.com 1 3 2 1 #/texts/2 text page_margin_header False low document_web_address document_web_address True p1:body_region:1 top_margin column_2_of_2 2 2 p1:top_margin:column_2_of_2:white [255, 255, 255] white False False [473.91, 45.23, 73.35, 6.78] www.advenergymat.de 1 1 3 2 #/texts/0 page_header page_header False low document_ui document_ui False None page_body column_2_of_2 2 2 p1:page_body:column_2_of_2:gray [145, 146, 150] gray True True [571.77, 70.54, 11.89, 80.75] FULL PAPER FULL PAPER 1 4 4 3 #/texts/3 section_header title_candidate False low non_body_heading non_body_heading True p1:body_region:0 page_body column_1_of_2 1 2 p1:page_body:column_1_of_2:white [255, 255, 255] white False False [51.06, 73.52, 411.26, 39.94] Structural Changes in Li 2 MnO 3 Cathode Material for Li-Ion Batteries Structural Changes in Li 2 MnO 3 Cathode Material for Li-Ion Batteries 1 5 5 4 #/texts/4 text affiliation False medium front_matter_author_line front_matter_author_line True p1:body_region:0 page_body column_1_of_2 1 2 p1:page_body:column_1_of_2:white [255, 255, 255] white False False [51.06, 130.55, 448.73, 29.6] Jatinkumar Rana ,* Marian Stan , Richard Kloepsch , Jie Li , Gerhard Schumacher , Edmund Welter , Ivo Zizak , John Banhart ,* and Martin Winter Jatinkumar Rana ,* Marian Stan , Richard Kloepsch , Jie Li , Gerhard Schumacher , Edmund Welter , Ivo Zizak , John Banhart ,* and Martin Winter 1 6 6 5 #/texts/5 text body True None body_before_non_intro_heading body_before_non_intro_heading True p1:body_region:0 page_body column_1_of_2 1 2 p1:page_body:column_1_of_2:gray [209, 210, 211] gray True False [51.03, 204.49, 311.76, 216.26] Structural changes in Li 2 MnO 3 cathode material for rechargeable Li-ion batteries are investigated during the fi rst and 33 rd cycles. It is found that both the participation of oxygen anions in redox processes and Li… Structural changes in Li 2 MnO 3 cathode material for rechargeable Li-ion batteries are investigated during the fi rst and 33 rd cycles. It is found that both the participation of oxygen anions in redox processes and Li… 1 7 7 6 #/texts/6 section_header body_heading False low body_heading body_heading True p1:body_region:0 page_body column_1_of_2 1 2 p1:page_body:column_1_of_2:white [255, 255, 255] white False False [51.01, 449.89, 73.83, 9.74] 1 . Introduction 1 . Introduction 1 8 8 7 #/texts/7 text body True None body body True p1:body_region:0 page_body column_1_of_2 1 2 p1:page_body:column_1_of_2:white [255, 255, 255] white False False [51.01, 467.9, 243.2, 52.52] The exploration of electrochemical activation in Li 2 MnO 3 is important for two main reasons: fi rst, to enhance the fundamental understanding concerning the electrochemistry of Mn 4 + -containing cathode materials: an… The exploration of electrochemical activation in Li 2 MnO 3 is important for two main reasons: fi rst, to enhance the fundamental understanding concerning the electrochemistry of Mn 4 + -containing cathode materials: an… 1 9 9 8 #/texts/8 text metadata False medium first_page_metadata first_page_metadata True p1:body_region:0 page_body column_1_of_2 1 2 p1:page_body:column_1_of_2:white [255, 255, 255] white False False [51.01, 546.37, 182.72, 153.79] Dr. J. Rana, Dr. G. Schumacher, Dr. I. Zizak, Prof. J. Banhart Helmholtz-Zentrum Berlin für Materialien und Energie Hahn-Meitner-Platz 1 , 14109 , Berlin , Germany E-mail: jatinkumar.rana@helmholtz-berlin.de ; banhart@h… Dr. J. Rana, Dr. G. Schumacher, Dr. I. Zizak, Prof. J. Banhart Helmholtz-Zentrum Berlin für Materialien und Energie Hahn-Meitner-Platz 1 , 14109 , Berlin , Germany E-mail: jatinkumar.rana@helmholtz-berlin.de ; banhart@h… 1 10 10 9 #/texts/9 text metadata False low first_page_metadata first_page_metadata True p1:body_region:0 page_body column_1_of_2 1 2 p1:page_body:column_1_of_2:white [255, 255, 255] white False False [51.01, 710.51, 119.31, 7.62] DOI: 10.1002/aenm.201300998 DOI: 10.1002/aenm.201300998 1 16 11 10 #/texts/15 page_footer page_footer False low first_page_metadata first_page_metadata True p1:body_region:0 bottom_margin column_1_of_2 1 2 p1:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [185.77, 742.91, 169.97, 6.29] © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 1 15 12 11 #/texts/14 page_footer page_footer False low docling_page_footer docling_page_footer True p1:body_region:0 bottom_margin column_1_of_2 1 2 p1:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [51.06, 743.21, 104.16, 5.94] Adv. Energy Mater . 2014 , 4 , 1300998 Adv. Energy Mater . 2014 , 4 , 1300998 1 11 13 12 #/texts/10 text body True None body body True p1:body_region:1 page_body column_2_of_2 2 2 p1:page_body:column_2_of_2:white [255, 255, 255] white False False [385.68, 191.69, 163.65, 196.72] cathode materials, [ 1-9 ] in which Li 2 MnO 3 is an important component. Li 2 MnO 3 has an O3 structure where close-packed oxygen layers are stacked in an ABCABC sequence. In a layer notation, Li 2 MnO 3 can be written… cathode materials, [ 1-9 ] in which Li 2 MnO 3 is an important component. Li 2 MnO 3 has an O3 structure where close-packed oxygen layers are stacked in an ABCABC sequence. In a layer notation, Li 2 MnO 3 can be written… 1 12 14 13 #/texts/11 text body True None body body True p1:body_region:1 page_body column_2_of_2 2 2 p1:page_body:column_2_of_2:white [255, 255, 255] white False False [385.68, 390.89, 163.65, 53.71] Over the past few years, several mechanisms concerning electrochemical activation of Li 2 MnO 3 during the fi rst charge have been postulated. It has been proposed that Li extraction from Li 2 MnO 3 Over the past few years, several mechanisms concerning electrochemical activation of Li 2 MnO 3 during the fi rst charge have been postulated. It has been proposed that Li extraction from Li 2 MnO 3 1 13 15 14 #/texts/12 text body True None body body True p1:body_region:1 page_body column_2_of_2 2 2 p1:page_body:column_2_of_2:white [255, 255, 255] white False False [306.13, 444.69, 243.2, 108.72] occurs with the simultaneous release of oxygen. [ 11 ] Later, it was observed that Li extraction occurs via two competitive processes, namely oxygen removal and Li + -H + exchange. [ 13-15 ] The presence of structural d… occurs with the simultaneous release of oxygen. [ 11 ] Later, it was observed that Li extraction occurs via two competitive processes, namely oxygen removal and Li + -H + exchange. [ 13-15 ] The presence of structural d… 1 14 16 15 #/texts/13#prov0 text body True None body body True p1:body_region:1 page_body column_2_of_2 2 2 p1:page_body:column_2_of_2:white [255, 255, 255] white False False [306.13, 555.89, 243.2, 162.52] We study structural modifi cations in Li 2 MnO 3 cathode material during the fi rst and 33 rd cycles by X-ray absorption spectroscopy (XAS). The elemental selectivity of XAS provides a unique opportunity to probe chemic… We study structural modifi cations in Li 2 MnO 3 cathode material during the fi rst and 33 rd cycles by X-ray absorption spectroscopy (XAS). The elemental selectivity of XAS provides a unique opportunity to probe chemic… 1 18 17 16 #/texts/17 page_footer page_footer False low docling_page_footer docling_page_footer True p1:body_region:1 bottom_margin column_2_of_2 2 2 p1:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [494.78, 741.91, 67.85, 7.64] (1 of 12) 1300998 (1 of 12) 1300998 1 17 18 17 #/texts/16 page_footer page_footer False low document_web_address document_web_address True p1:body_region:1 bottom_margin column_2_of_2 2 2 p1:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [388.05, 743.22, 64.38, 5.93] wileyonlinelibrary.com wileyonlinelibrary.com 2 1 1 18 #/texts/13#prov1 text page_margin_header False low page_margin_header page_margin_header True p2:body_region:0 top_margin column_1_of_2 1 2 p2:top_margin:column_1_of_2:white [255, 255, 255] white False True [46.91, 45.16, 73.33, 6.78] www.advenergymat.de 2 4 2 19 #/texts/18 page_header page_header False low docling_page_header docling_page_header False None front_matter column_1_of_2 1 2 p2:front_matter:front_panel:gray [164, 165, 168] gray True True [10.31, 70.11, 11.89, 80.75] FULL PAPER FULL PAPER 2 5 3 20 #/texts/19 page_header page_header False low docling_page_header docling_page_header False None top_margin column_2_of_2 2 2 p2:top_margin:column_2_of_2:white [253, 253, 253] white False False [577.94, 15.66, 4.29, 743.12] 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… 2 2 4 21 #/texts/13#prov2 text page_margin_header False low page_margin_header page_margin_header True p2:body_region:1 top_margin column_2_of_2 2 2 p2:top_margin:column_2_of_2:white [255, 255, 255] white False False [457.98, 53.43, 83.44, 6.78] www.MaterialsViews.com 2 6 5 22 #/texts/20 caption caption False low outside_body_flow_caption outside_body_flow_caption True p2:body_region:0 front_matter column_1_of_2 1 2 p2:front_matter:column_1_of_2:white [255, 255, 255] white False False [46.9, 254.03, 498.08, 17.53] Figure 1. a) Charge-discharge profi les of Li 2 MnO 3 when cycled between 2.0 V and 5.0 V during the fi rst and 33 rd cycles. b) Charge-discharge capacities obtained during each cycle along with electrochemical effi cie… Figure 1. a) Charge-discharge profi les of Li 2 MnO 3 when cycled between 2.0 V and 5.0 V during the fi rst and 33 rd cycles. b) Charge-discharge capacities obtained during each cycle along with electrochemical effi cie… 2 3 6 23 #/texts/13#prov3 text body True None body body True p2:body_region:0 front_matter column_1_of_2 1 2 p2:front_matter:column_1_of_2:white [255, 255, 255] white False False [46.9, 293.79, 243.2, 41.52] manganese reference compounds, while structural changes such as the number of nearest neighbors, interatomic distances, and structural disorder are quantifi ed by fi tting a theoretical model to the EXAFS data. manganese reference compounds, while structural changes such as the number of nearest neighbors, interatomic distances, and structural disorder are quantifi ed by fi tting a theoretical model to the EXAFS data. 2 7 7 24 #/texts/21 section_header body_heading False low body_heading body_heading True p2:body_region:0 body_zone column_1_of_2 1 2 p2:body_zone:column_1_of_2:white [255, 255, 255] white False False [46.9, 363.28, 49.62, 9.74] 2 . Results 2 . Results 2 8 8 25 #/texts/22#prov0 text body True None body body True p2:body_region:0 body_zone column_1_of_2 1 2 p2:body_zone:column_1_of_2:white [255, 255, 255] white False False [46.9, 381.29, 243.2, 118.52] As shown in Figure 1 a, the cell delivered a specifi c capacity of 388 mAh g -1 when charged to 5 V and of 200 mAh g -1 when discharged to 2 V with a fi rst cycle effi ciency of ≈ 50% (Figure 1 b). The long plateau abov… As shown in Figure 1 a, the cell delivered a specifi c capacity of 388 mAh g -1 when charged to 5 V and of 200 mAh g -1 when discharged to 2 V with a fi rst cycle effi ciency of ≈ 50% (Figure 1 b). The long plateau abov… 2 9 9 26 #/texts/22#prov1 text body True None body body True p2:body_region:1 front_matter column_2_of_2 2 2 p2:front_matter:column_2_of_2:white [255, 255, 255] white False False [302.03, 293.79, 243.2, 42.13] in Figure 1 b, the electrochemical performance of Li 2 MnO 3 degrades upon cycling. During the 33 rd cycle, the cell delivers a specifi c capacity of ≈ 110 mAh g -1 both during charge and discharge, which is just ≈ 55% … in Figure 1 b, the electrochemical performance of Li 2 MnO 3 degrades upon cycling. During the 33 rd cycle, the cell delivers a specifi c capacity of ≈ 110 mAh g -1 both during charge and discharge, which is just ≈ 55% … 2 10 10 27 #/texts/23 section_header body_heading False low body_heading body_heading True p2:body_region:1 body_zone column_2_of_2 2 2 p2:body_zone:column_2_of_2:white [255, 255, 255] white False False [302.03, 358.41, 45.23, 7.62] 2.1 . XANES 2.1 . XANES 2 11 11 28 #/texts/24#prov0 text body True None body body True p2:body_region:1 body_zone column_2_of_2 2 2 p2:body_zone:column_2_of_2:white [255, 255, 255] white False False [302.03, 381.29, 243.21, 118.52] As shown in Figure 2 a, the absorption edge is characterized by a variety of edge-features such as 1) an absorption threshold (or the fi rst peak in the derivative spectrum, not shown), 2) a 1s → 3d transition, correspo… As shown in Figure 2 a, the absorption edge is characterized by a variety of edge-features such as 1) an absorption threshold (or the fi rst peak in the derivative spectrum, not shown), 2) a 1s → 3d transition, correspo… 2 12 12 29 #/texts/25 caption caption False low outside_body_flow_caption outside_body_flow_caption True p2:body_region:0 body_zone column_1_of_2 1 2 p2:body_zone:column_1_of_2:white [255, 255, 255] white False False [46.9, 691.43, 498.08, 25.79] Figure 2. a) Normalized absorption spectra for various manganese reference compounds with the inset showing an enlarged pre-edge region of four compounds. b) Variation in the position of the 1s → 4p peak (dashed blue li… Figure 2. a) Normalized absorption spectra for various manganese reference compounds with the inset showing an enlarged pre-edge region of four compounds. b) Variation in the position of the 1s → 4p peak (dashed blue li… 2 13 13 30 #/texts/26 page_footer page_footer False low docling_page_footer docling_page_footer True p2:body_region:0 bottom_margin column_1_of_2 1 2 p2:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [32.48, 741.91, 67.86, 7.64] 1300998 (2 of 12) 1300998 (2 of 12) 2 14 14 31 #/texts/27 page_footer page_footer False low docling_page_footer docling_page_footer True p2:body_region:0 bottom_margin column_1_of_2 1 2 p2:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [137.77, 743.22, 64.38, 5.93] wileyonlinelibrary.com wileyonlinelibrary.com 2 15 15 32 #/texts/28 page_footer page_footer False low docling_page_footer docling_page_footer True p2:body_region:1 bottom_margin column_2_of_2 2 2 p2:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [236.51, 742.89, 169.97, 6.29] © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 2 16 16 33 #/texts/29 page_footer page_footer False low docling_page_footer docling_page_footer True p2:body_region:1 bottom_margin column_2_of_2 2 2 p2:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [440.0, 743.21, 103.42, 5.94] Adv. Energy Mater. 2014 , 4 , 1300998 Adv. Energy Mater. 2014 , 4 , 1300998 3 1 1 34 #/texts/24#prov1 text page_margin_header False low page_margin_header page_margin_header True p3:body_region:0 top_margin column_1_of_2 1 2 p3:top_margin:column_1_of_2:white [255, 255, 255] white False False [51.01, 53.34, 83.44, 6.78] www.MaterialsViews.com 3 4 2 35 #/texts/31 caption caption False low outside_body_flow_caption outside_body_flow_caption True p3:body_region:0 front_matter column_1_of_2 1 2 p3:front_matter:column_1_of_2:white [255, 255, 255] white False False [50.78, 253.26, 242.95, 25.79] Figure 3. Normalized absorption spectra for various Li 2 MnO 3 samples along with those of Mn 3 + and Mn 4 + reference compounds. The inset shows the pre-edge region. Figure 3. Normalized absorption spectra for various Li 2 MnO 3 samples along with those of Mn 3 + and Mn 4 + reference compounds. The inset shows the pre-edge region. 3 2 3 36 #/texts/24#prov2 text body True None body body True p3:body_region:0 body_zone column_1_of_2 1 2 p3:body_zone:column_1_of_2:white [255, 255, 255] white False False [51.04, 301.3, 243.2, 97.71] Figure 2 a shows an enlarged pre-edge region of these spectra. In order to enhance the visibility of the pre-edge peaks of other reference compounds, the intense pre-edge peak of KMnO 4 is omitted from the inset. The pr… Figure 2 a shows an enlarged pre-edge region of these spectra. In order to enhance the visibility of the pre-edge peaks of other reference compounds, the intense pre-edge peak of KMnO 4 is omitted from the inset. The pr… 3 5 4 37 #/texts/32#prov0 text body True None body body True p3:body_region:0 body_zone column_1_of_2 1 2 p3:body_zone:column_1_of_2:white [255, 255, 255] white False False [51.04, 400.3, 243.21, 107.52] Inner d-orbitals are more tightly bound and, therefore, less sensitive to chemical changes than loosely bound outer p-orbitals. Thus, chemical shifts observed at the position of the 1s → 4p peak are more pronounced than… Inner d-orbitals are more tightly bound and, therefore, less sensitive to chemical changes than loosely bound outer p-orbitals. Thus, chemical shifts observed at the position of the 1s → 4p peak are more pronounced than… 3 13 5 38 #/texts/38#prov0 text reference False low empty_after_cleaning empty_after_cleaning False None top_margin column_2_of_2 2 2 p3:top_margin:column_2_of_2:gray [229, 229, 229] gray True True [577.94, 15.66, 4.29, 743.12] 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… 3 6 6 39 #/texts/32#prov1 text page_margin_header False low page_margin_header page_margin_header True p3:body_region:1 top_margin column_2_of_2 2 2 p3:top_margin:column_2_of_2:white [255, 255, 255] white False False [473.91, 45.23, 73.35, 6.78] www.advenergymat.de 3 3 7 40 #/texts/30 page_header page_header False low docling_page_header docling_page_header False None front_matter column_2_of_2 2 2 p3:front_matter:front_panel:gray [127, 129, 133] gray True True [571.77, 70.54, 11.89, 80.75] FULL PAPER FULL PAPER 3 7 8 41 #/texts/32#prov2 text body True None body body True p3:body_region:1 front_matter column_2_of_2 2 2 p3:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.15, 71.43, 243.2, 19.52] compounds (refer to Figure S1 and Table S1 in the Supporting Information). compounds (refer to Figure S1 and Table S1 in the Supporting Information). 3 8 9 42 #/texts/33 text body True None body body True p3:body_region:1 front_matter column_2_of_2 2 2 p3:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.15, 93.43, 243.2, 140.52] As shown in Figure 3 , the absorption spectra for various Li 2 MnO 3 samples appear more complex than those of manganese reference compounds due to the presence of several points of intersection along the main edge wher… As shown in Figure 3 , the absorption spectra for various Li 2 MnO 3 samples appear more complex than those of manganese reference compounds due to the presence of several points of intersection along the main edge wher… 3 9 10 43 #/texts/34 section_header body_heading False low body_heading body_heading True p3:body_region:1 body_zone column_2_of_2 2 2 p3:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.15, 257.05, 43.1, 7.62] 2.2 . EXAFS 2.2 . EXAFS 3 10 11 44 #/texts/35 text body True None body body True p3:body_region:1 body_zone column_2_of_2 2 2 p3:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.15, 277.33, 243.2, 132.73] The comparison between the χ ( k ) signals of various Li 2 MnO 3 samples in Figure 4 a reveals that the EXAFS oscillations are reduced as soon as the cathode is charged to 5 V. In the corresponding Fourier transforms (F… The comparison between the χ ( k ) signals of various Li 2 MnO 3 samples in Figure 4 a reveals that the EXAFS oscillations are reduced as soon as the cathode is charged to 5 V. In the corresponding Fourier transforms (F… 3 11 12 45 #/texts/36 text body True None body body True p3:body_region:1 body_zone column_2_of_2 2 2 p3:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.15, 409.33, 243.2, 99.12] As shown in Figure 5 a, every feature of the χ ( k ) signal corresponding to the pristine sample is reproduced when the cathode is discharged to 2 V during the fi rst cycle, however, with reduced amplitudes. This is als… As shown in Figure 5 a, every feature of the χ ( k ) signal corresponding to the pristine sample is reproduced when the cathode is discharged to 2 V during the fi rst cycle, however, with reduced amplitudes. This is als… 3 12 13 46 #/texts/37 caption caption False low outside_body_flow_caption outside_body_flow_caption True p3:body_region:0 body_zone column_1_of_2 1 2 p3:body_zone:column_1_of_2:white [255, 255, 255] white False False [51.04, 698.84, 498.12, 19.15] Figure 4. a) k 3 -weighted EXAFS signals χ ( k ) and b) their Fourier transforms for Li 2 MnO 3 samples in the pristine state (solid black line), when charged to 5 V during the fi rst cycle (dashed red line) and when ch… Figure 4. a) k 3 -weighted EXAFS signals χ ( k ) and b) their Fourier transforms for Li 2 MnO 3 samples in the pristine state (solid black line), when charged to 5 V during the fi rst cycle (dashed red line) and when ch… 3 14 14 47 #/texts/39 page_footer page_footer False low docling_page_footer docling_page_footer True p3:body_region:0 bottom_margin column_1_of_2 1 2 p3:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [51.06, 743.21, 104.16, 5.94] Adv. Energy Mater . 2014 , 4 , 1300998 Adv. Energy Mater . 2014 , 4 , 1300998 3 17 15 48 #/texts/42 page_footer page_footer False low docling_page_footer docling_page_footer True p3:body_region:1 bottom_margin column_2_of_2 2 2 p3:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [494.77, 741.91, 67.86, 7.64] (3 of 12) 1300998 (3 of 12) 1300998 3 15 16 49 #/texts/40 page_footer page_footer False low docling_page_footer docling_page_footer True p3:body_region:0 bottom_margin column_2_of_2 2 2 p3:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [185.77, 742.91, 169.97, 6.29] © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 3 16 17 50 #/texts/41 page_footer page_footer False low docling_page_footer docling_page_footer True p3:body_region:1 bottom_margin column_2_of_2 2 2 p3:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [388.05, 743.22, 64.38, 5.93] wileyonlinelibrary.com wileyonlinelibrary.com 4 1 1 51 #/texts/38#prov1 text page_margin_header False low page_margin_header page_margin_header True p4:body_region:0 top_margin column_1_of_2 1 2 p4:top_margin:column_1_of_2:white [255, 255, 255] white False True [46.91, 45.16, 73.33, 6.78] www.advenergymat.de 4 5 2 52 #/texts/43 page_header page_header False low docling_page_header docling_page_header False None page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:gray [164, 165, 168] gray True True [10.31, 70.11, 11.89, 80.75] FULL PAPER FULL PAPER 4 6 3 53 #/texts/44 page_header page_header False low docling_page_header docling_page_header False None top_margin column_2_of_2 2 2 p4:top_margin:column_2_of_2:white [253, 253, 253] white False False [577.94, 15.66, 4.29, 743.12] 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… 4 2 4 54 #/texts/38#prov2 text page_margin_header False low page_margin_header page_margin_header True p4:body_region:1 top_margin column_2_of_2 2 2 p4:top_margin:column_2_of_2:white [255, 255, 255] white False False [457.98, 53.43, 83.44, 6.78] www.MaterialsViews.com 4 7 5 55 #/texts/45 caption caption False low outside_body_flow_caption outside_body_flow_caption True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [46.88, 251.21, 496.08, 19.15] Figure 5. a) k 3 -weighted EXAFS signals χ ( k ) and b) their Fourier transforms for Li 2 MnO 3 samples in the pristine state (solid black line), when discharged to 2 V during the fi rst cycle (dashed red line) and when… Figure 5. a) k 3 -weighted EXAFS signals χ ( k ) and b) their Fourier transforms for Li 2 MnO 3 samples in the pristine state (solid black line), when discharged to 2 V during the fi rst cycle (dashed red line) and when… 4 3 6 56 #/texts/38#prov3 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [46.95, 291.36, 243.2, 206.52] EXAFS data in the pristine state were fi tted by the monoclinic structure of Li 2 MnO 3 ( C2 / m ) [ 22 ] ( Figure 6 ). Best-fi t parameters are reported in Table S2 in the Supporting Information. A product of S 2 0 and… EXAFS data in the pristine state were fi tted by the monoclinic structure of Li 2 MnO 3 ( C2 / m ) [ 22 ] ( Figure 6 ). Best-fi t parameters are reported in Table S2 in the Supporting Information. A product of S 2 0 and… 4 8 7 57 #/texts/46 caption caption False low outside_body_flow_caption outside_body_flow_caption True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [46.9, 701.12, 242.95, 16.29] Figure 6. EXAFS fi t to the data of Li 2 MnO 3 sample in the pristine state. The dotted lines indicate the fi tting range. Figure 6. EXAFS fi t to the data of Li 2 MnO 3 sample in the pristine state. The dotted lines indicate the fi tting range. 4 11 8 58 #/texts/49 page_footer page_footer False low docling_page_footer docling_page_footer True p4:body_region:0 bottom_margin column_1_of_2 1 2 p4:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [32.48, 741.91, 67.86, 7.64] 1300998 (4 of 12) 1300998 (4 of 12) 4 12 9 59 #/texts/50 page_footer page_footer False low docling_page_footer docling_page_footer True p4:body_region:0 bottom_margin column_1_of_2 1 2 p4:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [137.77, 743.22, 64.38, 5.93] wileyonlinelibrary.com wileyonlinelibrary.com 4 4 10 60 #/texts/38#prov4 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [302.06, 291.39, 243.22, 173.52] EXAFS signal is due to backscattering of ejected photoelectrons from the nearest neighbors (i.e., O N-N in case of Li 2 MnO 3 ). The contribution from outer coordination shells decreases due to increased inelastic losse… EXAFS signal is due to backscattering of ejected photoelectrons from the nearest neighbors (i.e., O N-N in case of Li 2 MnO 3 ). The contribution from outer coordination shells decreases due to increased inelastic losse… 4 9 11 61 #/texts/47 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [302.06, 467.39, 243.2, 151.52] It has been reported that Li extraction from Li 2 MnO 3 occurs with a simultaneous loss of oxygen, giving rise to the formation of a layered MnO 2 -type structure (trigonal, R 3 m ) with the average valence state of Mn … It has been reported that Li extraction from Li 2 MnO 3 occurs with a simultaneous loss of oxygen, giving rise to the formation of a layered MnO 2 -type structure (trigonal, R 3 m ) with the average valence state of Mn … 4 10 12 62 #/texts/48 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [302.06, 621.39, 243.26, 98.2] It has been proposed that Li re-insertion into layered MnO 2 occurs with the simultaneous reduction of Mn 4 + to Mn 3 + , thus forming LiMnO 2 . [ 6,25 ] Therefore, an attempt was made to fi t the EXAFS data of the samp… It has been proposed that Li re-insertion into layered MnO 2 occurs with the simultaneous reduction of Mn 4 + to Mn 3 + , thus forming LiMnO 2 . [ 6,25 ] Therefore, an attempt was made to fi t the EXAFS data of the samp… 4 13 13 63 #/texts/51 page_footer page_footer False low docling_page_footer docling_page_footer True p4:body_region:1 bottom_margin column_2_of_2 2 2 p4:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [236.51, 742.89, 169.97, 6.29] © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 4 14 14 64 #/texts/52 page_footer page_footer False low docling_page_footer docling_page_footer True p4:body_region:1 bottom_margin column_2_of_2 2 2 p4:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [440.0, 743.21, 103.42, 5.94] Adv. Energy Mater. 2014 , 4 , 1300998 Adv. Energy Mater. 2014 , 4 , 1300998 5 1 1 65 #/texts/53 text page_margin_header False low page_margin_header page_margin_header True p5:body_region:0 top_margin column_1_of_2 1 2 p5:top_margin:column_1_of_2:white [255, 255, 255] white False False [51.01, 53.34, 83.44, 6.78] www.MaterialsViews.com 5 10 2 66 #/texts/59#prov0 text reference False low empty_after_cleaning empty_after_cleaning False None top_margin column_2_of_2 2 2 p5:top_margin:column_2_of_2:gray [229, 229, 229] gray True True [577.94, 15.66, 4.29, 743.12] 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… 5 6 3 67 #/texts/56#prov2 text page_margin_header False low page_margin_header page_margin_header False None top_margin column_2_of_2 2 2 p5:top_margin:column_2_of_2:white [255, 255, 255] white False False [473.91, 45.23, 73.35, 6.78] www.advenergymat.de 5 7 4 68 #/texts/56#prov3 text metadata False low document_ui document_ui False None page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:gray [127, 129, 133] gray True True [571.77, 70.54, 11.89, 80.75] FULL PAPER FULL PAPER 5 2 5 69 #/texts/54 caption caption False low outside_body_flow_caption outside_body_flow_caption True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [51.04, 253.82, 433.44, 7.92] Figure 7. EXAFS fi ts to the data of Li 2 MnO 3 samples a) when charged to 5 V and b) when discharged to 2 V during the fi rst cycle. Figure 7. EXAFS fi ts to the data of Li 2 MnO 3 samples a) when charged to 5 V and b) when discharged to 2 V during the fi rst cycle. 5 3 6 70 #/texts/55 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [51.04, 280.61, 243.2, 64.71] It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] Therefore, an attempt was made to refi ne the fraction of such spinel phase in the cycled sam… It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] Therefore, an attempt was made to refi ne the fraction of such spinel phase in the cycled sam… 5 4 7 71 #/texts/56#prov0 text body True None body body True p5:body_region:0 page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [51.04, 346.61, 243.2, 174.71] Qualitatively, the EXAFS data of the cycled samples appear similar to those of their counterparts during the fi rst cycle. As a result, a layered MnO 2 structure was assumed to fi t the data of the cycled-charged sample… Qualitatively, the EXAFS data of the cycled samples appear similar to those of their counterparts during the fi rst cycle. As a result, a layered MnO 2 structure was assumed to fi t the data of the cycled-charged sample… 5 8 8 72 #/texts/57 caption caption False low outside_body_flow_caption outside_body_flow_caption False None page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [306.15, 462.93, 150.69, 7.92] Figure 8. EXAFS data of the LiMn 2 O 4 spinel. Figure 8. EXAFS data of the LiMn 2 O 4 spinel. 5 5 9 73 #/texts/56#prov1 text back_matter_heading False low back_matter_heading back_matter_heading stop_trigger False None page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [306.15, 489.61, 243.2, 31.71] Supporting Information) with a good agreement with the data as shown in Figure 9 a. Similarly, the EXAFS data of the cycleddischarged sample were explained by a Li 2 MnO 3 structure Supporting Information) with a good agreement with the data as shown in Figure 9 a. Similarly, the EXAFS data of the cycleddischarged sample were explained by a Li 2 MnO 3 structure 5 9 10 74 #/texts/58 caption caption False low after_back_matter_stop after_back_matter_stop after_stop True p5:body_region:0 bottom_margin column_1_of_2 1 2 p5:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [51.04, 714.14, 433.62, 9.15] Figure 9. EXAFS fi ts to the data of Li 2 MnO 3 samples a) when charged to 5 V and b) when discharged to 2 V during the 33 rd cycle. Figure 9. EXAFS fi ts to the data of Li 2 MnO 3 samples a) when charged to 5 V and b) when discharged to 2 V during the 33 rd cycle. 5 11 11 75 #/texts/60 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p5:body_region:0 bottom_margin column_1_of_2 1 2 p5:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [51.06, 743.21, 104.16, 5.94] Adv. Energy Mater . 2014 , 4 , 1300998 Adv. Energy Mater . 2014 , 4 , 1300998 5 14 12 76 #/texts/63 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop False None bottom_margin column_2_of_2 2 2 p5:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [494.77, 741.91, 67.86, 7.64] (5 of 12) 1300998 (5 of 12) 1300998 5 12 13 77 #/texts/61 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p5:body_region:0 bottom_margin column_2_of_2 2 2 p5:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [185.77, 742.91, 169.97, 6.29] © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 5 13 14 78 #/texts/62 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop False None bottom_margin column_2_of_2 2 2 p5:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [388.05, 743.22, 64.38, 5.93] wileyonlinelibrary.com wileyonlinelibrary.com 6 1 1 79 #/texts/59#prov1 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 top_margin column_1_of_2 1 2 p6:top_margin:column_1_of_2:white [255, 255, 255] white False True [46.91, 45.16, 73.33, 6.78] www.advenergymat.de 6 2 2 80 #/texts/64 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None front_matter column_1_of_2 1 2 p6:front_matter:front_panel:gray [164, 165, 168] gray True True [10.31, 70.11, 11.89, 80.75] FULL PAPER FULL PAPER 6 4 3 81 #/texts/66 caption caption False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 front_matter column_1_of_2 1 2 p6:front_matter:column_1_of_2:white [255, 255, 255] white False False [46.9, 253.7, 242.95, 54.29] Figure 10. Comparison of the metal-ligand bond length for the electrochemically cycled Li 2 MnO 3 samples during the fi rst and 33 rd cycles. The asterisk (*) represents the charged-discharged samples during the 33 rd c… Figure 10. Comparison of the metal-ligand bond length for the electrochemically cycled Li 2 MnO 3 samples during the fi rst and 33 rd cycles. The asterisk (*) represents the charged-discharged samples during the 33 rd c… 6 5 4 82 #/texts/67 text affiliation False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 body_zone column_1_of_2 1 2 p6:body_zone:column_1_of_2:white [255, 255, 255] white False False [46.9, 321.28, 243.2, 22.61] (Figure 9 b). A fi t constraining S 2 0 to 0.76 and O N-N to 4.3, refi ned X eff to 0.61(5) (Table S6 in the Supporting Information). (Figure 9 b). A fi t constraining S 2 0 to 0.76 and O N-N to 4.3, refi ned X eff to 0.61(5) (Table S6 in the Supporting Information). 6 6 5 83 #/texts/68 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 body_zone column_1_of_2 1 2 p6:body_zone:column_1_of_2:white [255, 255, 255] white False False [46.9, 345.18, 243.2, 63.52] A comparison between the metal-ligand bond lengths of various Li 2 MnO 3 samples is shown in Figure 10 . The average Mn-O bond length in the pristine state is slightly higher than that of Mn 4 + -O. As the cathode is ch… A comparison between the metal-ligand bond lengths of various Li 2 MnO 3 samples is shown in Figure 10 . The average Mn-O bond length in the pristine state is slightly higher than that of Mn 4 + -O. As the cathode is ch… 6 7 6 84 #/texts/69#prov0 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 body_zone column_1_of_2 1 2 p6:body_zone:column_1_of_2:white [255, 255, 255] white False False [46.9, 409.39, 243.2, 98.31] F 2 is the distribution of the backscattering atoms around their mean position measured with respect to the central absorbing atom. This distribution can be either caused by thermal vibrations (thermal disorder) or by s… F 2 is the distribution of the backscattering atoms around their mean position measured with respect to the central absorbing atom. This distribution can be either caused by thermal vibrations (thermal disorder) or by s… 6 14 7 85 #/texts/74 caption caption False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 body_zone column_1_of_2 1 2 p6:body_zone:column_1_of_2:white [255, 255, 255] white False False [46.9, 709.82, 421.8, 9.15] Figure 11. Structural disorder in charged-discharged samples of Li 2 MnO 3 a) during the fi rst cycle and b) during the 33 rd cycle. Figure 11. Structural disorder in charged-discharged samples of Li 2 MnO 3 a) during the fi rst cycle and b) during the 33 rd cycle. 6 15 8 86 #/texts/75 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 bottom_margin column_1_of_2 1 2 p6:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [32.48, 741.91, 67.86, 7.64] 1300998 (6 of 12) 1300998 (6 of 12) 6 16 9 87 #/texts/76 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 bottom_margin column_1_of_2 1 2 p6:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [137.77, 743.22, 64.38, 5.93] wileyonlinelibrary.com wileyonlinelibrary.com 6 3 10 88 #/texts/65 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p6:top_margin:column_2_of_2:white [253, 253, 253] white False False [577.94, 15.66, 4.29, 743.12] 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… 6 8 11 89 #/texts/69#prov1 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 top_margin column_2_of_2 2 2 p6:top_margin:column_2_of_2:white [255, 255, 255] white False False [457.98, 53.43, 83.44, 6.78] www.MaterialsViews.com 6 9 12 90 #/texts/69#prov2 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 front_matter column_2_of_2 2 2 p6:front_matter:column_2_of_2:white [255, 255, 255] white False False [302.01, 71.43, 243.2, 129.52] disorder. As shown in Figure 11 a, the pristine sample exhibits the smallest, while the charged sample exhibits the largest disorder for all shells during the fi rst cycle. The structural disorder for the discharged sam… disorder. As shown in Figure 11 a, the pristine sample exhibits the smallest, while the charged sample exhibits the largest disorder for all shells during the fi rst cycle. The structural disorder for the discharged sam… 6 10 13 91 #/texts/70 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 front_matter column_2_of_2 2 2 p6:front_matter:column_2_of_2:white [255, 255, 255] white False False [302.01, 203.43, 243.2, 41.52] The statistical EXAFS fi t parameters for various Li 2 MnO 3 samples are reported in Table S7 in the Supporting Information. A good agreement between the data and theory for all samples can be seen by their R -factors, … The statistical EXAFS fi t parameters for various Li 2 MnO 3 samples are reported in Table S7 in the Supporting Information. A good agreement between the data and theory for all samples can be seen by their R -factors, … 6 11 14 92 #/texts/71 section_header unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 front_matter column_2_of_2 2 2 p6:front_matter:column_2_of_2:white [255, 255, 255] white False False [302.01, 267.42, 67.53, 9.74] 3 . Discussion 3 . Discussion 6 12 15 93 #/texts/72 section_header body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 body_zone column_2_of_2 2 2 p6:body_zone:column_2_of_2:white [255, 255, 255] white False False [302.01, 287.8, 45.23, 7.62] 3.1 . XANES 3.1 . XANES 6 13 16 94 #/texts/73 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 body_zone column_2_of_2 2 2 p6:body_zone:column_2_of_2:white [255, 255, 255] white False False [302.01, 308.08, 243.2, 198.12] 1s → 3d transitions are forbidden by dipole rules in centrosymmetric confi gurations such as in regular octahedral symmetry. However, with increasing distortion from ideal octahedral symmetry, the probability of a trans… 1s → 3d transitions are forbidden by dipole rules in centrosymmetric confi gurations such as in regular octahedral symmetry. However, with increasing distortion from ideal octahedral symmetry, the probability of a trans… 6 17 17 95 #/texts/77 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 bottom_margin column_2_of_2 2 2 p6:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [236.51, 742.89, 169.97, 6.29] © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 6 18 18 96 #/texts/78 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 bottom_margin column_2_of_2 2 2 p6:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [440.0, 743.21, 103.42, 5.94] Adv. Energy Mater. 2014 , 4 , 1300998 Adv. Energy Mater. 2014 , 4 , 1300998 7 2 1 97 #/texts/80 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 top_margin column_1_of_2 1 2 p7:top_margin:column_1_of_2:white [255, 255, 255] white False False [51.01, 53.34, 83.44, 6.78] www.MaterialsViews.com 7 3 2 98 #/texts/81 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 front_matter column_1_of_2 1 2 p7:front_matter:column_1_of_2:white [255, 255, 255] white False False [51.04, 71.38, 243.2, 217.52] The metal-ligand bond length determines the extent to which orbital intermixing takes place. As a result of this intermixing, the repulsive forces between the electrons increase the energies of these orbitals. Thus, met… The metal-ligand bond length determines the extent to which orbital intermixing takes place. As a result of this intermixing, the repulsive forces between the electrons increase the energies of these orbitals. Thus, met… 7 4 3 99 #/texts/82 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 front_matter column_1_of_2 1 2 p7:front_matter:column_1_of_2:white [255, 255, 255] white False False [51.04, 291.38, 243.2, 261.52] Empirically, a chemical shift in the absorption spectra can be correlated to the formal valence state of an absorbing atom. [ 20,34 ] However, in addition to the valence of an absorbing atom, chemical shifts are also af… Empirically, a chemical shift in the absorption spectra can be correlated to the formal valence state of an absorbing atom. [ 20,34 ] However, in addition to the valence of an absorbing atom, chemical shifts are also af… 7 5 4 100 #/texts/83 section_header body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 body_zone column_1_of_2 1 2 p7:body_zone:column_1_of_2:white [255, 255, 255] white False False [51.04, 576.0, 43.1, 7.62] 3.2 . EXAFS 3.2 . EXAFS 7 6 5 101 #/texts/84 section_header body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 body_zone column_1_of_2 1 2 p7:body_zone:column_1_of_2:white [255, 255, 255] white False False [51.04, 603.08, 179.46, 7.46] 3.2.1 . Structural Changes During the First Charge 3.2.1 . Structural Changes During the First Charge 7 7 6 102 #/texts/85#prov0 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 body_zone column_1_of_2 1 2 p7:body_zone:column_1_of_2:white [255, 255, 255] white False False [51.04, 619.28, 243.2, 96.52] XAS can distinguish between different atom types based on their ability to scatter the ejected photoelectron, which in turn depends on the atomic number, Z . Despite Mn ( Z = 25) having a higher atomic number than O ( Z… XAS can distinguish between different atom types based on their ability to scatter the ejected photoelectron, which in turn depends on the atomic number, Z . Despite Mn ( Z = 25) having a higher atomic number than O ( Z… 7 15 7 103 #/texts/92 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 bottom_margin column_1_of_2 1 2 p7:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [51.06, 743.21, 104.16, 5.94] Adv. Energy Mater . 2014 , 4 , 1300998 Adv. Energy Mater . 2014 , 4 , 1300998 7 14 8 104 #/texts/91#prov0 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p7:top_margin:column_2_of_2:gray [229, 229, 229] gray True True [577.94, 15.66, 4.29, 743.12] 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… 7 8 9 105 #/texts/85#prov1 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:1 top_margin column_2_of_2 2 2 p7:top_margin:column_2_of_2:white [255, 255, 255] white False False [473.91, 45.23, 73.35, 6.78] www.advenergymat.de 7 1 10 106 #/texts/79 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None front_matter column_2_of_2 2 2 p7:front_matter:front_panel:gray [127, 129, 133] gray True True [571.77, 70.54, 11.89, 80.75] FULL PAPER FULL PAPER 7 9 11 107 #/texts/85#prov2 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:1 front_matter column_2_of_2 2 2 p7:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.15, 71.4, 243.2, 53.71] atoms in the second shell (see Table S2 in the Supporting Information). Thus, the ratio of the amplitudes of the fi rst two Fourier transform peaks, i.e., the Mn -O Mn -Mn ratio, being >1 is the EXAFS signature refl ect… atoms in the second shell (see Table S2 in the Supporting Information). Thus, the ratio of the amplitudes of the fi rst two Fourier transform peaks, i.e., the Mn -O Mn -Mn ratio, being >1 is the EXAFS signature refl ect… 7 10 12 108 #/texts/86 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:1 front_matter column_2_of_2 2 2 p7:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.14, 126.4, 243.2, 173.52] A preferential reduction in the amplitude of the fi rst shell of O atoms besides an overall damping of other shells at 5 V (Figure 4 b) is consistent with previous reports [ 18 ] and can be attributed, respectively, to … A preferential reduction in the amplitude of the fi rst shell of O atoms besides an overall damping of other shells at 5 V (Figure 4 b) is consistent with previous reports [ 18 ] and can be attributed, respectively, to … 7 11 13 109 #/texts/88 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:1 front_matter column_2_of_2 2 2 p7:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.15, 355.14, 243.2, 174.71] However, fi tting the EXAFS data of the charged sample refi ned O N-N to 5.6(8) (Table S3 in the Supporting Information), which is high considering the fact that oxygen is released from the material during activation. N… However, fi tting the EXAFS data of the charged sample refi ned O N-N to 5.6(8) (Table S3 in the Supporting Information), which is high considering the fact that oxygen is released from the material during activation. N… 7 13 14 110 #/texts/90 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:1 front_matter column_2_of_2 2 2 p7:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.15, 528.44, 243.2, 154.22] Despite this structural modifi cation, the Mn -O Mn -Mn ratio remains >1 for the charged sample (Figure 7 a), which suggests that the material retains its original Li 2 MnO 3 -like character even upon Li extraction. Thu… Despite this structural modifi cation, the Mn -O Mn -Mn ratio remains >1 for the charged sample (Figure 7 a), which suggests that the material retains its original Li 2 MnO 3 -like character even upon Li extraction. Thu… 7 12 15 111 #/texts/89 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:1 body_zone column_2_of_2 2 2 p7:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.15, 682.12, 243.2, 33.54] The Li + -H + exchange mechanism is also supported in Li 2 MnO 3 by the observed change in the stacking sequence of oxygen layers from O3-type (ABCABC) to P3-type (ABBCCA) The Li + -H + exchange mechanism is also supported in Li 2 MnO 3 by the observed change in the stacking sequence of oxygen layers from O3-type (ABCABC) to P3-type (ABBCCA) 7 18 16 112 #/texts/95 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:1 bottom_margin column_2_of_2 2 2 p7:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [494.77, 741.91, 67.86, 7.64] (7 of 12) 1300998 (7 of 12) 1300998 7 16 17 113 #/texts/93 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 bottom_margin column_2_of_2 2 2 p7:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [185.77, 742.91, 169.97, 6.29] © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 7 17 18 114 #/texts/94 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:1 bottom_margin column_2_of_2 2 2 p7:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [388.05, 743.22, 64.38, 5.93] wileyonlinelibrary.com wileyonlinelibrary.com 8 1 1 115 #/texts/91#prov1 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 top_margin column_1_of_2 1 2 p8:top_margin:column_1_of_2:white [255, 255, 255] white False True [46.91, 45.16, 73.33, 6.78] www.advenergymat.de 8 4 2 116 #/texts/96 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None front_matter column_1_of_2 1 2 p8:front_matter:front_panel:gray [164, 165, 168] gray True True [10.31, 70.11, 11.89, 80.75] FULL PAPER FULL PAPER 8 5 3 117 #/texts/97 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p8:top_margin:column_2_of_2:white [253, 253, 253] white False False [577.94, 15.66, 4.29, 743.12] 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… 8 2 4 118 #/texts/91#prov2 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 top_margin column_2_of_2 2 2 p8:top_margin:column_2_of_2:white [255, 255, 255] white False False [457.98, 53.43, 83.44, 6.78] www.MaterialsViews.com 8 6 5 119 #/texts/98 caption caption False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 front_matter column_1_of_2 1 2 p8:front_matter:column_1_of_2:white [255, 255, 255] white False False [46.88, 221.33, 498.07, 19.07] Figure 12. Stacking sequence of close-packed oxygen layers in a) O3 structure of Li 2 MnO 3 ( C2 / m ) [ 22 ] and b) P3 structure ( R 3 m ) of proton-exchanged material. [ 59 ] Note that O-H-O bonds are asymmetric in th… Figure 12. Stacking sequence of close-packed oxygen layers in a) O3 structure of Li 2 MnO 3 ( C2 / m ) [ 22 ] and b) P3 structure ( R 3 m ) of proton-exchanged material. [ 59 ] Note that O-H-O bonds are asymmetric in th… 8 3 6 120 #/texts/91#prov3 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 front_matter column_1_of_2 1 2 p8:front_matter:column_1_of_2:white [255, 255, 255] white False False [46.9, 256.2, 243.2, 217.52] due to the presence of protons in the interslab region and strong O-H-O bonding. [ 14,25 ] For comparison, O3-type and P3-type structures are shown in Figure 12 . The ordered atomic arrangements of O3 structure in the p… due to the presence of protons in the interslab region and strong O-H-O bonding. [ 14,25 ] For comparison, O3-type and P3-type structures are shown in Figure 12 . The ordered atomic arrangements of O3 structure in the p… 8 7 7 121 #/texts/100 section_header body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 body_zone column_1_of_2 1 2 p8:body_zone:column_1_of_2:white [255, 255, 255] white False False [46.9, 550.5, 189.09, 7.46] 3.2.2 . Structural Changes During the First Discharge 3.2.2 . Structural Changes During the First Discharge 8 8 8 122 #/texts/101#prov0 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 body_zone column_1_of_2 1 2 p8:body_zone:column_1_of_2:white [255, 255, 255] white False False [46.9, 566.7, 243.2, 151.52] Several reports have claimed that Li re-insertion into layered MnO 2 gives rise to the formation of LiMnO 2 with a concurrent reduction of Mn 4 + to Mn 3 + . [ 6,25 ] According to these reports, the local structure of t… Several reports have claimed that Li re-insertion into layered MnO 2 gives rise to the formation of LiMnO 2 with a concurrent reduction of Mn 4 + to Mn 3 + . [ 6,25 ] According to these reports, the local structure of t… 8 14 9 123 #/texts/106 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 bottom_margin column_1_of_2 1 2 p8:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [32.48, 741.91, 67.86, 7.64] 1300998 (8 of 12) 1300998 (8 of 12) 8 15 10 124 #/texts/107 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 bottom_margin column_1_of_2 1 2 p8:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [137.77, 743.22, 64.38, 5.93] wileyonlinelibrary.com wileyonlinelibrary.com 8 9 11 125 #/texts/101#prov1 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 front_matter column_2_of_2 2 2 p8:front_matter:column_2_of_2:white [255, 255, 255] white False False [302.01, 256.24, 243.2, 63.52] Li is re-inserted into the material. This could have happened by exchanging already present H + in the structure with Li + . [ 14 ] Discharge could then involve the reduction of partially oxidized oxygen anions of activ… Li is re-inserted into the material. This could have happened by exchanging already present H + in the structure with Li + . [ 14 ] Discharge could then involve the reduction of partially oxidized oxygen anions of activ… 8 10 12 126 #/texts/102 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 front_matter column_2_of_2 2 2 p8:front_matter:column_2_of_2:white [255, 255, 255] white False False [302.01, 322.24, 243.2, 229.71] Qualitative similarities between the EXAFS data of the pristine and discharged samples suggest structural re-ordering upon Li re-insertion. This is consistent with a reduction in the F 2 parameter for the coordination s… Qualitative similarities between the EXAFS data of the pristine and discharged samples suggest structural re-ordering upon Li re-insertion. This is consistent with a reduction in the F 2 parameter for the coordination s… 8 11 13 127 #/texts/103 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 body_zone column_2_of_2 2 2 p8:body_zone:column_2_of_2:white [255, 255, 255] white False False [302.01, 553.24, 243.2, 118.52] The Fourier transform peaks between 3 and 4.2 Å representing O atoms of the neighboring slabs reappear upon discharge (Figure 7 b). Correspondingly, F 2 associated with these O atoms (fourth shell) decreases (Figure 11 … The Fourier transform peaks between 3 and 4.2 Å representing O atoms of the neighboring slabs reappear upon discharge (Figure 7 b). Correspondingly, F 2 associated with these O atoms (fourth shell) decreases (Figure 11 … 8 12 14 128 #/texts/104 formula body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 body_zone column_2_of_2 2 2 p8:body_zone:column_2_of_2:white [255, 255, 255] white False False [302.04, 677.01, 239.02, 29.06] H + x Mn 4 + O - 2 + * 3 - y ︸ ︷︷ ︸ R ¯ 3 m (P3 - type) + ( x + * )Li + + ( x + * ) e - - Li + + exchange and discharge Li + x + * Mn 4 + O 2 - 3 - y ︸ ︷︷ ︸ C 2 / m (O3 - type) + x H + H H + x Mn 4 + O - 2 + * 3 - y ︸ ︷︷ ︸ R ¯ 3 m (P3 - type) + ( x + * )Li + + ( x + * ) e - - Li + + exchange and discharge Li + x + * Mn 4 + O 2 - 3 - y ︸ ︷︷ ︸ C 2 / m (O3 - type) + x H + H 8 13 15 129 #/texts/105 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 body_zone column_2_of_2 2 2 p8:body_zone:column_2_of_2:white [255, 255, 255] white False False [532.89, 707.66, 12.31, 8.52] (3) (3) 8 16 16 130 #/texts/108 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 bottom_margin column_2_of_2 2 2 p8:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [236.51, 742.89, 169.97, 6.29] © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 8 17 17 131 #/texts/109 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 bottom_margin column_2_of_2 2 2 p8:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [440.0, 743.21, 103.42, 5.94] Adv. Energy Mater. 2014 , 4 , 1300998 Adv. Energy Mater. 2014 , 4 , 1300998 9 2 1 132 #/texts/111 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:0 top_margin column_1_of_2 1 2 p9:top_margin:column_1_of_2:white [255, 255, 255] white False False [51.01, 53.34, 83.44, 6.78] www.MaterialsViews.com 9 3 2 133 #/texts/112 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:0 front_matter column_1_of_2 1 2 p9:front_matter:column_1_of_2:white [255, 255, 255] white False False [51.04, 71.38, 243.2, 52.52] The resultant structure upon discharge is similar to that of the parent Li 2 MnO 3 , except that it contains less Li and O. The driving force for such structural reversion is believed to be the relaxation of strained ox… The resultant structure upon discharge is similar to that of the parent Li 2 MnO 3 , except that it contains less Li and O. The driving force for such structural reversion is believed to be the relaxation of strained ox… 9 4 3 134 #/texts/113 section_header body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:0 body_zone column_1_of_2 1 2 p9:body_zone:column_1_of_2:white [255, 255, 255] white False False [51.04, 141.98, 142.93, 7.46] 3.2.3 . Structural Changes Upon Cycling 3.2.3 . Structural Changes Upon Cycling 9 5 4 135 #/texts/114 text back_matter_text False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:0 body_zone column_1_of_2 1 2 p9:body_zone:column_1_of_2:white [255, 255, 255] white False False [51.04, 158.18, 243.2, 218.71] It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] This claim is supported by qualitative similarities between the electrochemical profi les of … It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] This claim is supported by qualitative similarities between the electrochemical profi les of … 9 6 5 136 #/texts/115#prov0 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:0 body_zone column_1_of_2 1 2 p9:body_zone:column_1_of_2:white [255, 255, 255] white False False [51.04, 378.18, 243.2, 339.71] The crystallographic difference between the layered Li 2 MnO 3 and spinel LiMn 2 O 4 gives rise to distinct EXAFS signals (Figure 6 and Figure 8 ). A major difference lies in their Mn -O Mn -Mn ratios. Based on this cri… The crystallographic difference between the layered Li 2 MnO 3 and spinel LiMn 2 O 4 gives rise to distinct EXAFS signals (Figure 6 and Figure 8 ). A major difference lies in their Mn -O Mn -Mn ratios. Based on this cri… 9 15 6 137 #/texts/122 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:0 bottom_margin column_1_of_2 1 2 p9:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [51.06, 743.21, 104.16, 5.94] Adv. Energy Mater . 2014 , 4 , 1300998 Adv. Energy Mater . 2014 , 4 , 1300998 9 14 7 138 #/texts/121#prov0 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p9:top_margin:column_2_of_2:gray [229, 229, 229] gray True True [577.94, 15.66, 4.29, 743.12] 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… 9 7 8 139 #/texts/115#prov1 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 top_margin column_2_of_2 2 2 p9:top_margin:column_2_of_2:white [255, 255, 255] white False False [473.91, 45.23, 73.35, 6.78] www.advenergymat.de 9 1 9 140 #/texts/110 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None front_matter column_2_of_2 2 2 p9:front_matter:front_panel:gray [127, 129, 133] gray True True [571.77, 70.54, 11.89, 80.75] FULL PAPER FULL PAPER 9 8 10 141 #/texts/115#prov2 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 front_matter column_2_of_2 2 2 p9:front_matter:column_2_of_2:white [255, 255, 255] white False False [306.15, 71.4, 243.2, 162.52] and to those of the cycled-discharged sample is by a Li 2 MnO 3 structure. These fi t results suggest that the fraction of electrochemically active material is reduced to ≈ 60-70% up to the 33 rd cycle, which is consist… and to those of the cycled-discharged sample is by a Li 2 MnO 3 structure. These fi t results suggest that the fraction of electrochemically active material is reduced to ≈ 60-70% up to the 33 rd cycle, which is consist… 9 9 11 142 #/texts/116 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 body_zone column_2_of_2 2 2 p9:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.15, 236.4, 243.2, 206.52] These results lead us to two major conclusions. First, the structural changes during the 33 rd cycle are similar to those observed during the fi rst, however, the fraction of electrochemically active material is gradual… These results lead us to two major conclusions. First, the structural changes during the 33 rd cycle are similar to those observed during the fi rst, however, the fraction of electrochemically active material is gradual… 9 10 12 143 #/texts/117 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 body_zone column_2_of_2 2 2 p9:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.15, 445.4, 243.2, 151.52] The average Mn-O bond length for the cycled samples (Figure 10 ) remains unchanged from that of Mn 4 + -O, which rules out the conventional charge compensation mechanism involving the Mn 3 + /Mn 4 + redox reaction. Ther… The average Mn-O bond length for the cycled samples (Figure 10 ) remains unchanged from that of Mn 4 + -O, which rules out the conventional charge compensation mechanism involving the Mn 3 + /Mn 4 + redox reaction. Ther… 9 11 13 144 #/texts/118 formula body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 body_zone column_2_of_2 2 2 p9:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.18, 607.15, 241.73, 30.59] Li + x + * Mn 4 + O 2 - 3 - y ︸ ︷︷ ︸ C 2 / m (O3 - type) Li + - H + exchange and charge H + - Li + exchange and discharge H + x Mn 4 + O - 2 + * 3 - y ︸ ︷︷ ︸ R ¯ 3 m (P3 - type) + ( x + * )Li + + ( x + * )e - . Li + x + * Mn 4 + O 2 - 3 - y ︸ ︷︷ ︸ C 2 / m (O3 - type) Li + - H + exchange and charge H + - Li + exchange and discharge H + x Mn 4 + O - 2 + * 3 - y ︸ ︷︷ ︸ R ¯ 3 m (P3 - type) + ( x + * )Li + + ( x + * )e - . 9 12 14 145 #/texts/119 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 body_zone column_2_of_2 2 2 p9:body_zone:column_2_of_2:white [255, 255, 255] white False False [537.03, 639.81, 12.31, 8.52] (4) (4) 9 13 15 146 #/texts/120 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 body_zone column_2_of_2 2 2 p9:body_zone:column_2_of_2:white [255, 255, 255] white False False [306.15, 654.81, 243.21, 63.52] Subsequent discharge could involve the reduction of partially oxidized oxygen anions along with electrolyte species and Li reinsertion could occur by displacing already present protons in the material with a concurrent … Subsequent discharge could involve the reduction of partially oxidized oxygen anions along with electrolyte species and Li reinsertion could occur by displacing already present protons in the material with a concurrent … 9 18 16 147 #/texts/125 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 bottom_margin column_2_of_2 2 2 p9:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [494.77, 741.91, 67.86, 7.64] (9 of 12) 1300998 (9 of 12) 1300998 9 16 17 148 #/texts/123 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:0 bottom_margin column_2_of_2 2 2 p9:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [185.77, 742.91, 169.97, 6.29] © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 9 17 18 149 #/texts/124 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 bottom_margin column_2_of_2 2 2 p9:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [388.05, 743.22, 64.38, 5.93] wileyonlinelibrary.com wileyonlinelibrary.com 10 1 1 150 #/texts/121#prov1 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 top_margin column_1_of_2 1 2 p10:top_margin:column_1_of_2:white [255, 255, 255] white False True [46.91, 45.16, 73.33, 6.78] www.advenergymat.de 10 3 2 151 #/texts/126 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_1_of_2 1 2 p10:page_body:column_1_of_2:gray [164, 165, 168] gray True True [10.31, 70.11, 11.89, 80.75] FULL PAPER FULL PAPER 10 2 3 152 #/texts/121#prov2 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 page_body column_1_of_2 1 2 p10:page_body:column_1_of_2:white [255, 255, 255] white False False [46.9, 71.38, 243.2, 206.52] subsequent cycle could lead to the loss of crystallinity of the material and consequently to the loss of its intercalation ability during cycling. The observed cleavage in Li 2 MnO 3 particles along the (001) plane [ 35… subsequent cycle could lead to the loss of crystallinity of the material and consequently to the loss of its intercalation ability during cycling. The observed cleavage in Li 2 MnO 3 particles along the (001) plane [ 35… 10 5 4 153 #/texts/128 section_header unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 page_body column_1_of_2 1 2 p10:page_body:column_1_of_2:white [255, 255, 255] white False False [46.9, 305.37, 72.99, 9.74] 4 . Conclusions 4 . Conclusions 10 6 5 154 #/texts/129 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 page_body column_1_of_2 1 2 p10:page_body:column_1_of_2:white [255, 255, 255] white False False [46.9, 323.38, 243.2, 272.52] Both XANES and EXAFS provide complementary information that helps to understand structural changes in Li 2 MnO 3 . The total charge capacity during activation can be attributed to the oxidation of oxygen anions and that… Both XANES and EXAFS provide complementary information that helps to understand structural changes in Li 2 MnO 3 . The total charge capacity during activation can be attributed to the oxidation of oxygen anions and that… 10 7 6 155 #/texts/131 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 page_body column_1_of_2 1 2 p10:page_body:column_1_of_2:white [255, 255, 255] white False False [46.9, 647.88, 243.2, 66.54] The proposed Li + -H + exchange during each subsequent charge and discharge could involve a structural fl ip-over between O3-type ( C2 / m ) and P3-type ( R 3 m ) by repeated shearing of oxygen layers. This could deteri… The proposed Li + -H + exchange during each subsequent charge and discharge could involve a structural fl ip-over between O3-type ( C2 / m ) and P3-type ( R 3 m ) by repeated shearing of oxygen layers. This could deteri… 10 14 7 156 #/texts/138 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 bottom_margin column_1_of_2 1 2 p10:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [32.48, 741.91, 72.35, 7.64] 1300998 (10 of 12) 1300998 (10 of 12) 10 15 8 157 #/texts/139 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 bottom_margin column_1_of_2 1 2 p10:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [137.77, 743.22, 64.38, 5.93] wileyonlinelibrary.com wileyonlinelibrary.com 10 4 9 158 #/texts/127 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p10:top_margin:column_2_of_2:white [253, 253, 253] white False False [577.94, 15.66, 4.29, 743.12] 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… 10 13 10 159 #/texts/137 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 top_margin column_2_of_2 2 2 p10:top_margin:column_2_of_2:white [255, 255, 255] white False False [457.98, 53.43, 83.44, 6.78] www.MaterialsViews.com 10 8 11 160 #/texts/132 section_header unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 page_body column_2_of_2 2 2 p10:page_body:column_2_of_2:white [255, 255, 255] white False False [302.01, 72.16, 115.78, 9.74] 5 . Experimental Section 5 . Experimental Section 10 9 12 161 #/texts/133 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 page_body column_2_of_2 2 2 p10:page_body:column_2_of_2:white [255, 255, 255] white False False [302.01, 89.94, 242.99, 130.29] Li 2 MnO 3 was synthesized by a modifi ed Pechini method from acetate precursors. [ 49 ] The precursor powders, Mn(OCOCH 3 ) 2 ·4H 2 O and Li(OCOCH 3 )·H 2 O were dissolved in an aqueous mixture of ethylene glycol and c… Li 2 MnO 3 was synthesized by a modifi ed Pechini method from acetate precursors. [ 49 ] The precursor powders, Mn(OCOCH 3 ) 2 ·4H 2 O and Li(OCOCH 3 )·H 2 O were dissolved in an aqueous mixture of ethylene glycol and c… 10 10 13 162 #/texts/134 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 page_body column_2_of_2 2 2 p10:page_body:column_2_of_2:white [255, 255, 255] white False False [302.01, 222.94, 242.95, 196.79] The cathodes for electrochemical characterization were prepared by mixing 80 wt% active material, 10 wt% carbon black, and 10 wt% of a solution of polyvinylidene di-fl uoride in N -methyl-2-pyrrolidone acting as a binde… The cathodes for electrochemical characterization were prepared by mixing 80 wt% active material, 10 wt% carbon black, and 10 wt% of a solution of polyvinylidene di-fl uoride in N -methyl-2-pyrrolidone acting as a binde… 10 11 14 163 #/texts/135 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 page_body column_2_of_2 2 2 p10:page_body:column_2_of_2:white [255, 255, 255] white False False [302.01, 422.44, 242.95, 215.79] XAS measurements were carried out in the transmission mode at the Mn K-edge of various Li 2 MnO 3 samples. The samples charged and discharged during the fi rst cycle were measured at beamline A1 of the Hamburger Synchro… XAS measurements were carried out in the transmission mode at the Mn K-edge of various Li 2 MnO 3 samples. The samples charged and discharged during the fi rst cycle were measured at beamline A1 of the Hamburger Synchro… 10 12 15 164 #/texts/136#prov0 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 page_body column_2_of_2 2 2 p10:page_body:column_2_of_2:white [255, 255, 255] white False False [302.01, 640.94, 242.95, 74.07] Various data pre-processing operations such as deglitching, averaging the scans, energy calibration, normalization, background subtraction etc., [ 50 ] were performed using the software ATHENA of the package IFEFFIT . [… Various data pre-processing operations such as deglitching, averaging the scans, energy calibration, normalization, background subtraction etc., [ 50 ] were performed using the software ATHENA of the package IFEFFIT . [… 10 16 16 165 #/texts/140 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 bottom_margin column_2_of_2 2 2 p10:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [236.51, 742.89, 169.97, 6.29] © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 10 17 17 166 #/texts/141 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 bottom_margin column_2_of_2 2 2 p10:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [440.0, 743.21, 103.42, 5.94] Adv. Energy Mater. 2014 , 4 , 1300998 Adv. Energy Mater. 2014 , 4 , 1300998 11 2 1 167 #/texts/136#prov2 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left_crossing None None p11:page_body:left_crossing:white [255, 255, 255] white False False [50.63, 70.67, 243.36, 302.53] using the code FEFF8.2. [ 52 ] The model function was least-square fi tted to the data using the software ARTEMIS of the package IFEFFIT which uses the algorithm FEFFIT. [ 51 ] The fi tting parameters involved a single … using the code FEFF8.2. [ 52 ] The model function was least-square fi tted to the data using the software ARTEMIS of the package IFEFFIT which uses the algorithm FEFFIT. [ 51 ] The fi tting parameters involved a single … 11 1 2 168 #/texts/136#prov1 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 top_margin left None None p11:top_margin:left:white [255, 255, 255] white False False [51.01, 53.34, 83.44, 6.78] www.MaterialsViews.com 11 13 3 169 #/texts/152 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left None None p11:page_body:left:white [255, 255, 255] white False False [51.04, 651.9, 172.03, 6.79] C. S. Johnson , J. Power Sources 2007 , 165 , 559 . C. S. Johnson , J. Power Sources 2007 , 165 , 559 . 11 5 4 170 #/texts/144 section_header back_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left None None p11:page_body:left:white [255, 255, 255] white False False [51.04, 401.12, 115.6, 9.74] Supporting Information Supporting Information 11 6 5 171 #/texts/145 text back_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left_crossing None None p11:page_body:left_crossing:white [255, 255, 255] white False False [51.04, 418.9, 242.95, 16.29] Supporting Information is available from the Wiley Online Library or from the author. Supporting Information is available from the Wiley Online Library or from the author. 11 7 6 172 #/texts/146 section_header back_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left None None p11:page_body:left:white [255, 255, 255] white False False [51.04, 463.12, 95.82, 9.74] Acknowledgements Acknowledgements 11 8 7 173 #/texts/147 text back_matter_text False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left_crossing None None p11:page_body:left_crossing:white [255, 255, 255] white False False [51.04, 480.9, 242.95, 54.79] The authors acknowledge fi nancial support from the Europäischer Fonds für regionale Entwicklung (EFRE) under the project BATMAT (No. 200720132/35). R.K. acknowledges fi nancial support from the Hans-L. Merkle Stiftung … The authors acknowledge fi nancial support from the Europäischer Fonds für regionale Entwicklung (EFRE) under the project BATMAT (No. 200720132/35). R.K. acknowledges fi nancial support from the Hans-L. Merkle Stiftung … 11 57 8 174 #/texts/196 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 bottom_margin left None None p11:bottom_margin:left:white [255, 255, 255] white False False [51.06, 743.21, 104.16, 5.94] Adv. Energy Mater . 2014 , 4 , 1300998 Adv. Energy Mater . 2014 , 4 , 1300998 11 11 9 175 #/texts/150 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left_crossing None None p11:page_body:left_crossing:white [255, 255, 255] white False False [55.34, 611.9, 238.65, 16.79] C. S. Johnson , N. Li , J. T . Vaughey , S. A. Hackney , M. M. Thackeray , Electrochem. Commun. 2005 , 7 , 528 . C. S. Johnson , N. Li , J. T . Vaughey , S. A. Hackney , M. M. Thackeray , Electrochem. Commun. 2005 , 7 , 528 . 11 12 10 176 #/texts/151 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left_crossing None None p11:page_body:left_crossing:white [255, 255, 255] white False False [55.34, 631.9, 238.65, 16.79] M. M. Thackeray , S.-H. Kang , C. S. Johnson , J. T . Vaughey , S. A. Hackney , Electrochem. Commun. 2006 , 8 , 1531 . M. M. Thackeray , S.-H. Kang , C. S. Johnson , J. T . Vaughey , S. A. Hackney , Electrochem. Commun. 2006 , 8 , 1531 . 11 14 11 177 #/texts/153 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left_crossing None None p11:page_body:left_crossing:white [255, 255, 255] white False False [55.34, 661.9, 238.65, 16.79] C. S. Johnson , N. Li , C. Lefi ef , M. M. Thackeray , Electrochem. Commun. 2007 , 9 , 787 . C. S. Johnson , N. Li , C. Lefi ef , M. M. Thackeray , Electrochem. Commun. 2007 , 9 , 787 . 11 15 12 178 #/texts/154 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left_crossing None None p11:page_body:left_crossing:white [255, 255, 255] white False False [55.34, 681.9, 238.65, 16.79] M. M. Thackeray , S.-H. Kang , C. S. Johnson , J. T. Vaughey , R. Benedek , S. A. Hackney , J. Mater. Chem. 2007 , 17 , 3112 . M. M. Thackeray , S.-H. Kang , C. S. Johnson , J. T. Vaughey , R. Benedek , S. A. Hackney , J. Mater. Chem. 2007 , 17 , 3112 . 11 16 13 179 #/texts/155 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left_crossing None None p11:page_body:left_crossing:white [255, 255, 255] white False False [55.34, 701.9, 238.65, 16.79] J. Li , R. Klöpsch , M. C. Stan , S. Nowak , M. Kunze , M. Winter , S. Passerini , J. Power Sources 2011 , 196 , 4821 . J. Li , R. Klöpsch , M. C. Stan , S. Nowak , M. Kunze , M. Winter , S. Passerini , J. Power Sources 2011 , 196 , 4821 . 11 10 14 180 #/texts/149 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left_crossing None None p11:page_body:left_crossing:white [255, 255, 255] white False False [55.35, 591.9, 238.63, 16.79] C. S. Johnson , J.-S. Kim , C. Lefi ef , N. Li , J. T . Vaughey , M. M. Thackeray , Electrochem. Commun. 2004 , 6 , 1085 . C. S. Johnson , J.-S. Kim , C. Lefi ef , N. Li , J. T . Vaughey , M. M. Thackeray , Electrochem. Commun. 2004 , 6 , 1085 . 11 9 15 181 #/texts/148 text reference False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 page_body left_crossing None None p11:page_body:left_crossing:white [255, 255, 255] white False False [167.56, 547.9, 126.43, 26.79] Received: August 7, 2013 Revised: October 17, 2013 Published online: December 27, 2013 Received: August 7, 2013 Revised: October 17, 2013 Published online: December 27, 2013 11 58 16 182 #/texts/197 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p11:body_region:0 bottom_margin left_crossing None None p11:bottom_margin:left_crossing:white [255, 255, 255] white False False [185.77, 742.91, 169.97, 6.29] © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 11 42 17 183 #/texts/181 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p11:page_body:right_crossing:white [255, 255, 255] white False False [306.14, 451.92, 242.95, 16.79] D. Marabello , R. Bianchi , G. Gervasio , F. Cargnoni , Acta Crystallogr., Sect. A: Found. Crystallogr. 2004 , A60 , 494 . D. Marabello , R. Bianchi , G. Gervasio , F. Cargnoni , Acta Crystallogr., Sect. A: Found. Crystallogr. 2004 , A60 , 494 . 11 43 18 184 #/texts/182 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop False None page_body right_crossing None None p11:page_body:right_crossing:white [255, 255, 255] white False False [306.14, 471.92, 242.94, 16.79] A. Ito , Y. Sato , T . Sanada , M. Hatano , H. Horie , Y . Ohsawa , J. Power Sources 2011 , 196 , 6828 . A. Ito , Y. Sato , T . Sanada , M. Hatano , H. Horie , Y . Ohsawa , J. 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