page source_page_order layout_page_order layout_order ref label role_guess included_in_body excluded_risk_level body_decision_reason parser_body_decision_reason production_usage visual_asset_type visual_asset_label visual_asset_caption_preview truncation_marker inside_body_region body_region_id zone column column_index column_count region_id background_rgb background_class is_gray_background has_frame_evidence bbox text_preview cleaned_text_preview 1 1 1 0 #/texts/0 page_header page_header False low document_ui document_ui True p1:body_region:0 top_margin column_1_of_2 1 2 p1:top_margin:column_1_of_2:white [255, 255, 255] white False True [50.81, 28.94, 126.19, 12.11] RESEARCH ARTICLE RESEARCH ARTICLE 1 2 2 1 #/texts/1 text page_margin_header False low document_web_address document_web_address True p1:body_region:1 top_margin column_2_of_2 2 2 p1:top_margin:column_2_of_2:white [255, 255, 255] white False False [472.46, 49.98, 74.39, 8.02] www.afm-journal.de 1 3 3 2 #/texts/2 section_header title_candidate False low first_page_front_matter_heading first_page_front_matter_heading True p1:body_region:0 front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [50.81, 77.5, 441.13, 63.65] Local Electronic Structure Modulation Enables Fast-Charging Capability for Li-Rich Mn-Based Oxides Cathodes With Reversible Anionic Redox Activity Local Electronic Structure Modulation Enables Fast-Charging Capability for Li-Rich Mn-Based Oxides Cathodes With Reversible Anionic Redox Activity 1 4 4 3 #/texts/3 text affiliation False low first_page_author_or_affiliation first_page_author_or_affiliation True p1:body_region:0 front_matter column_1_of_2 1 2 p1:front_matter:column_1_of_2:white [255, 255, 255] white False False [50.81, 160.21, 487.97, 30.54] Xianggang Gao, Haiyan Zhang, Shihao Li, Shuai Zhang, Chaohong Guan, Xiaoping Hu, Juanlang Guo, Yanqing Lai,* and Zhian Zhang* Xianggang Gao, Haiyan Zhang, Shihao Li, Shuai Zhang, Chaohong Guan, Xiaoping Hu, Juanlang Guo, Yanqing Lai,* and Zhian Zhang* 1 5 5 4 #/texts/4 text body True None recovered_body_before_first_heading recovered_body_before_first_heading True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:gray [203, 204, 203] gray True False [50.81, 227.68, 312.83, 241.82] Anionic and cationic redox chemistries boost ultrahigh specific capacities of Li-rich Mn-based oxides cathodes (LRMO). However, irreversible oxygen evolution and sluggish kinetics result in continuous capacity decay and… Anionic and cationic redox chemistries boost ultrahigh specific capacities of Li-rich Mn-based oxides cathodes (LRMO). However, irreversible oxygen evolution and sluggish kinetics result in continuous capacity decay and… 1 6 6 5 #/texts/5 text body True None body body True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 504.82, 188.74, 7.2] X. Gao, H. Zhang, S. Li, S. Zhang, J. Guo, Y. Lai, Z. Zhang X. Gao, H. Zhang, S. Li, S. Zhang, J. Guo, Y. Lai, Z. Zhang 1 7 7 6 #/texts/6 text affiliation False low affiliation_block affiliation_block True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 513.78, 127.19, 7.2] School of Metallurgy and Environment School of Metallurgy and Environment 1 8 8 7 #/texts/7 text affiliation False low affiliation_block affiliation_block True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 522.75, 234.43, 25.14] Hunan Province Key Laboratory of Nonferrous Value-Added Metallurgy Engineering Research Center of the Ministry of Education for Advanced Battery Materials Hunan Province Key Laboratory of Nonferrous Value-Added Metallurgy Engineering Research Center of the Ministry of Education for Advanced Battery Materials 1 9 9 8 #/texts/8 text affiliation False low affiliation_block affiliation_block True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 549.65, 80.2, 7.2] Central South University Central South University 1 10 10 9 #/texts/9 text body True None body body True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 558.61, 125.23, 7.2] Changsha, Hunan 410083, P. R. China Changsha, Hunan 410083, P. R. China 1 11 11 10 #/texts/10 text metadata False low first_page_metadata first_page_metadata True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 567.58, 191.32, 7.2] E-mail: laiyanqingcsu@163.com; zhangzhian@csu.edu.cn E-mail: laiyanqingcsu@163.com; zhangzhian@csu.edu.cn 1 12 12 11 #/texts/11 text metadata False low document_web_address document_web_address True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False True [50.81, 578.54, 30.54, 7.2] H.Zhang H.Zhang 1 13 13 12 #/texts/12 text body True None body body True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 587.51, 103.08, 7.2] HunanChangyuanLiCoCo.,Ltd HunanChangyuanLiCoCo.,Ltd 1 14 14 13 #/texts/13 text affiliation False low contextual_affiliation_fragment contextual_affiliation_fragment True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 596.47, 121.28, 7.2] Changsha,Hunan410205,P.R.China Changsha,Hunan410205,P.R.China 1 15 15 14 #/texts/14 text affiliation False low contextual_affiliation_fragment contextual_affiliation_fragment True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 607.44, 26.12, 7.2] C. Guan C. Guan 1 16 16 15 #/texts/15 text affiliation False low affiliation_block affiliation_block True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 616.4, 216.68, 7.2] University of Michigan-Shanghai Jiao Tong University Joint Institute University of Michigan-Shanghai Jiao Tong University Joint Institute 1 17 17 16 #/texts/16 text body True None body body True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 625.36, 96.01, 7.2] ShanghaiJiaoTongUniversity ShanghaiJiaoTongUniversity 1 18 18 17 #/texts/17 text affiliation False low contextual_affiliation_fragment contextual_affiliation_fragment True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 634.33, 166.08, 7.2] 800DongchuanRoad,Shanghai200240,P.R.China 800DongchuanRoad,Shanghai200240,P.R.China 1 19 19 18 #/texts/18 text affiliation False low contextual_affiliation_fragment contextual_affiliation_fragment True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 645.29, 18.22, 7.2] X. Hu X. Hu 1 20 20 19 #/texts/19 text body True None body body True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 654.25, 142.95, 7.2] SchoolofMaterialsScienceandEngineering SchoolofMaterialsScienceandEngineering 1 21 21 20 #/texts/20 text affiliation False low affiliation_block affiliation_block True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 663.23, 78.63, 7.2] Central South University Central South University 1 22 22 21 #/texts/21 text affiliation False low contextual_affiliation_fragment contextual_affiliation_fragment True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 672.19, 121.28, 7.2] Changsha,Hunan410083,P.R.China Changsha,Hunan410083,P.R.China 1 23 23 22 #/texts/22 text metadata False low first_page_metadata first_page_metadata True p1:body_region:0 body_zone column_1_of_2 1 2 p1:body_zone:column_1_of_2:white [255, 255, 255] white False False [68.79, 690.25, 222.97, 16.17] The ORCID identification number(s) for the author(s) of this article can be found under https://doi.org/10.1002/adfm.202304065 The ORCID identification number(s) for the author(s) of this article can be found under 1 24 24 23 #/texts/23 text page_margin_footer False low first_page_metadata first_page_metadata True p1:body_region:0 bottom_margin column_1_of_2 1 2 p1:bottom_margin:column_1_of_2:white [255, 255, 255] white False True [50.81, 712.5, 114.86, 8.02] DOI: 10.1002/adfm.202304065 DOI: 10.1002/adfm.202304065 1 25 25 24 #/texts/24 page_footer page_footer False low outside_body_flow_page_footer outside_body_flow_page_footer True p1:body_region:0 bottom_margin column_1_of_2 1 2 p1:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 745.71, 105.61, 6.3] Adv. Funct. Mater. 2023 , 33 , 2304065 Adv. Funct. Mater. 2023 , 33 , 2304065 1 26 26 25 #/texts/25 section_header body_heading False low body_heading body_heading True p1:body_region:1 body_zone column_2_of_2 2 2 p1:body_zone:column_2_of_2:white [255, 255, 255] white False False [384.63, 219.54, 70.41, 10.25] 1. Introduction 1. Introduction 1 27 27 26 #/texts/26 text body True None body body True p1:body_region:1 body_zone column_2_of_2 2 2 p1:body_zone:column_2_of_2:white [255, 255, 255] white False False [384.63, 238.89, 162.26, 249.54] Recently, Li-rich Mn-based oxides cathodes (LRMO) written as x Li2MnO3 · (1 -x )LiTMO2 (TM = Nickel, Cobalt and Manganese) have attracted extensive research due to its ultrahigh capacity ( > 250 mAh · g -1 ) and low cos… Recently, Li-rich Mn-based oxides cathodes (LRMO) written as x Li2MnO3 · (1 -x )LiTMO2 (TM = Nickel, Cobalt and Manganese) have attracted extensive research due to its ultrahigh capacity ( > 250 mAh · g -1 ) and low cos… 1 28 28 27 #/texts/27 text body True None body body True p1:body_region:1 body_zone column_2_of_2 2 2 p1:body_zone:column_2_of_2:white [255, 255, 255] white False False [305.92, 490.95, 240.96, 139.94] anionic redox such as oxygen loss has caused structural degradation, while contributing to ultrahigh capacity. For example, oxygen release can trigger irreversible migration of transition metal ions, severe side reactio… anionic redox such as oxygen loss has caused structural degradation, while contributing to ultrahigh capacity. For example, oxygen release can trigger irreversible migration of transition metal ions, severe side reactio… 1 29 29 28 #/texts/28#prov0 text body True None body body True p1:body_region:1 body_zone column_2_of_2 2 2 p1:body_zone:column_2_of_2:white [255, 255, 255] white False False [305.92, 633.41, 240.95, 85.16] In order to address the above issues, plenty of modification strategies including surface coating, elemental doping, and surface defect/heterostructure engineering have been raised to suppress oxygen loss, severe side r… In order to address the above issues, plenty of modification strategies including surface coating, elemental doping, and surface defect/heterostructure engineering have been raised to suppress oxygen loss, severe side r… 1 30 30 29 #/texts/29 page_footer page_footer False low docling_page_footer docling_page_footer True p1:body_region:0 bottom_margin column_2_of_2 2 2 p1:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [266.69, 744.38, 64.3, 8.02] 2304065 (1 of 11) 2304065 (1 of 11) 1 31 31 30 #/texts/30 page_footer page_footer False low first_page_metadata first_page_metadata True p1:body_region:1 bottom_margin column_2_of_2 2 2 p1:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [469.66, 745.82, 77.21, 6.3] ©2023 Wiley-VCH GmbH ©2023 Wiley-VCH GmbH 2 1 1 31 #/texts/28#prov1 text page_margin_header False low page_margin_header page_margin_header False None top_margin column_1_of_2 1 2 p2:top_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 50.12, 120.78, 8.02] www.advancedsciencenews.com 2 5 2 32 #/texts/32 caption caption False low outside_body_flow_caption outside_body_flow_caption False None page_body column_1_of_2 1 2 p2:page_body:column_1_of_2:white [255, 255, 255] white False False [47.98, 388.13, 405.37, 7.2] Figure 1. Schematic of surface defect engineering and the transformation of surface crystal structures for LRMO materials. Figure 1. Schematic of surface defect engineering and the transformation of surface crystal structures for LRMO materials. 2 3 3 33 #/texts/28#prov3 text body True None body body False None bottom_margin column_1_of_2 1 2 p2:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 416.06, 240.96, 304.33] inactive substances. Therefore, surface defect engineering has received wide attention in the past few years. Surface defects such as lithium and oxygen vacancies can be incorporated into the crystal structure during th… inactive substances. Therefore, surface defect engineering has received wide attention in the past few years. Surface defects such as lithium and oxygen vacancies can be incorporated into the crystal structure during th… 2 6 4 34 #/texts/33 page_footer page_footer False low outside_body_flow_page_footer outside_body_flow_page_footer False None bottom_margin column_1_of_2 1 2 p2:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 745.71, 105.61, 6.3] Adv. Funct. Mater. 2023 , 33 , 2304065 Adv. Funct. Mater. 2023 , 33 , 2304065 2 4 5 35 #/texts/31 page_header page_header False low docling_page_header docling_page_header False None top_margin column_2_of_2 2 2 p2:top_margin:column_2_of_2:off_white [246, 246, 246] off_white False False [579.16, 15.65, 4.41, 751.61] 16163028, 2023, 43, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202304065 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wile… 2 2 6 36 #/texts/28#prov2 text page_margin_header False low page_margin_header page_margin_header True p2:body_region:0 top_margin column_2_of_2 2 2 p2:top_margin:column_2_of_2:white [255, 255, 255] white False False [469.62, 50.12, 74.39, 8.02] www.afm-journal.de 2 7 7 37 #/texts/34 text body True None body body True p2:body_region:0 page_body column_2_of_2 2 2 p2:page_body:column_2_of_2:white [255, 255, 255] white False False [303.09, 416.06, 240.96, 107.07] constructed oxygen vacancy and Li4Mn5O12 on the surface of Lirich oxide layered cathodes by using a facile oxalic acid assisted delithiation process. [ 10] The irreversible release of oxygen and voltage decay were obvio… constructed oxygen vacancy and Li4Mn5O12 on the surface of Lirich oxide layered cathodes by using a facile oxalic acid assisted delithiation process. [ 10] The irreversible release of oxygen and voltage decay were obvio… 2 8 8 38 #/texts/35#prov0 text body True None body body True p2:body_region:0 bottom_margin column_2_of_2 2 2 p2:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [303.09, 525.65, 240.96, 194.74] Herein, as shown in Figure 1 , a moderate surface defects construction strategy with ammonium oxalate thermal treatment is successfully realized for manufacturing oxygen vacancies and spinel-like structure on the surfac… Herein, as shown in Figure 1 , a moderate surface defects construction strategy with ammonium oxalate thermal treatment is successfully realized for manufacturing oxygen vacancies and spinel-like structure on the surfac… 2 9 9 39 #/texts/36 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p2:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [263.85, 744.38, 64.3, 8.02] 2304065 (2 of 11) 2304065 (2 of 11) 2 10 10 40 #/texts/37 page_footer page_footer False low docling_page_footer docling_page_footer True p2:body_region:0 bottom_margin column_2_of_2 2 2 p2:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [466.82, 745.82, 77.21, 6.3] ©2023 Wiley-VCH GmbH ©2023 Wiley-VCH GmbH 3 2 1 41 #/texts/38 page_header page_header False low docling_page_header docling_page_header False None top_margin column_1_of_2 1 2 p3:top_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 50.12, 120.78, 8.02] www.advancedsciencenews.com 3 3 2 42 #/texts/39 page_header page_header False low docling_page_header docling_page_header False None top_margin column_2_of_2 2 2 p3:top_margin:column_2_of_2:off_white [246, 246, 246] off_white False False [579.16, 15.65, 4.41, 751.61] 16163028, 2023, 43, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202304065 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wile… 3 5 3 43 #/texts/41 section_header metadata False low outside_body_flow_metadata_line outside_body_flow_metadata_line True p3:body_region:0 top_margin column_2_of_2 2 2 p3:top_margin:column_2_of_2:white [255, 255, 255] white False False [472.46, 50.12, 74.39, 8.02] www.afm-journal.de 3 4 4 44 #/texts/40 caption caption False low outside_body_flow_caption outside_body_flow_caption False None front_matter column_1_of_2 1 2 p3:front_matter:column_1_of_2:white [255, 255, 255] white False False [50.81, 575.36, 496.07, 26.13] Figure 2. a) The XRD patterns of P0 and NHCO-5 samples with the enlarged images of (003), (101), and (104) peaks, respectively. Refined XRD data of b) P0 and c) NHCO-5. Raman spectra of d) P0 and e) NHCO-5. The TEM and … Figure 2. a) The XRD patterns of P0 and NHCO-5 samples with the enlarged images of (003), (101), and (104) peaks, respectively. Refined XRD data of b) P0 and c) NHCO-5. Raman spectra of d) P0 and e) NHCO-5. The TEM and … 3 1 5 45 #/texts/35#prov1 text body True None body body False None front_matter column_1_of_2 1 2 p3:front_matter:column_1_of_2:white [255, 255, 255] white False False [50.81, 624.27, 240.96, 41.32] cycling performance with excellent rate performance and fastcharging capability. The present work provides some references to enhance fast-charging capability of LRMO with reversible anionic redox via surface defect eng… cycling performance with excellent rate performance and fastcharging capability. The present work provides some references to enhance fast-charging capability of LRMO with reversible anionic redox via surface defect eng… 3 6 6 46 #/texts/42 section_header body_heading False low body_heading body_heading False None body_zone column_1_of_2 1 2 p3:body_zone:column_1_of_2:white [255, 255, 255] white False False [50.81, 681.93, 122.45, 10.25] 2. Results and Discussion 2. Results and Discussion 3 7 7 47 #/texts/43#prov0 text body True None body body False None bottom_margin column_1_of_2 1 2 p3:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 701.29, 240.94, 19.41] Li-rich Mn-based oxides cathodes treated with 3wt%, 5wt%, and 8wt% of ammonium oxalate are denoted as NHCO-3, NHCO-5, Li-rich Mn-based oxides cathodes treated with 3wt%, 5wt%, and 8wt% of ammonium oxalate are denoted as NHCO-3, NHCO-5, 3 9 8 48 #/texts/44 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_1_of_2 1 2 p3:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 745.71, 105.61, 6.3] Adv. Funct. Mater. 2023 , 33 , 2304065 Adv. Funct. Mater. 2023 , 33 , 2304065 3 8 9 49 #/texts/43#prov1 text body True None body body True p3:body_region:0 bottom_margin column_2_of_2 2 2 p3:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [305.92, 624.27, 240.97, 96.11] and NHCO-8 samples, respectively. The pristine LRMO without any modification is marked as P0 sample. Figure 2 a shows the XRDpatterns of P0 and NHCO-5 samples. The narrow and sharp peaks of both the samples demonstrate … and NHCO-8 samples, respectively. The pristine LRMO without any modification is marked as P0 sample. Figure 2 a shows the XRDpatterns of P0 and NHCO-5 samples. The narrow and sharp peaks of both the samples demonstrate … 3 10 10 50 #/texts/45 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p3:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [266.69, 744.38, 64.3, 8.02] 2304065 (3 of 11) 2304065 (3 of 11) 3 11 11 51 #/texts/46 page_footer page_footer False low docling_page_footer docling_page_footer True p3:body_region:0 bottom_margin column_2_of_2 2 2 p3:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [469.66, 745.82, 77.21, 6.3] ©2023 Wiley-VCH GmbH ©2023 Wiley-VCH GmbH 4 1 1 52 #/texts/43#prov2 text page_margin_header False low page_margin_header page_margin_header True p4:body_region:0 top_margin column_1_of_2 1 2 p4:top_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 50.12, 120.78, 8.02] www.advancedsciencenews.com 4 2 2 53 #/texts/43#prov3 text body True None body body True p4:body_region:0 page_body column_1_of_2 1 2 p4:page_body:column_1_of_2:white [255, 255, 255] white False False [47.98, 76.43, 240.96, 413.93] ammonium oxalate thermal treatment. What is more, the well splitting of (006)/(102) and (108)/(110) peaks for all the samples demonstrates the well-formed layered ordering structure without any destruction after surface… ammonium oxalate thermal treatment. What is more, the well splitting of (006)/(102) and (108)/(110) peaks for all the samples demonstrates the well-formed layered ordering structure without any destruction after surface… 4 3 3 54 #/texts/47 text body True None body body True p4:body_region:0 bottom_margin column_1_of_2 1 2 p4:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 492.87, 240.96, 227.62] Further, transmission electron microscopy (TEM) and highresolution TEM (HRTEM) characterizations were conducted to explore the surface crystal structure changes after surface modification. The relevant results are depic… Further, transmission electron microscopy (TEM) and highresolution TEM (HRTEM) characterizations were conducted to explore the surface crystal structure changes after surface modification. The relevant results are depic… 4 4 4 55 #/texts/48 page_footer page_footer False low outside_body_flow_page_footer outside_body_flow_page_footer True p4:body_region:0 bottom_margin column_1_of_2 1 2 p4:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 745.71, 105.61, 6.3] Adv. Funct. Mater. 2023 , 33 , 2304065 Adv. Funct. Mater. 2023 , 33 , 2304065 4 9 5 56 #/texts/53#prov0 text reference False low empty_after_cleaning empty_after_cleaning False None top_margin column_2_of_2 2 2 p4:top_margin:column_2_of_2:off_white [246, 246, 246] off_white False False [579.16, 15.65, 4.41, 751.61] 16163028, 2023, 43, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202304065 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wile… 4 5 6 57 #/texts/49 text page_margin_header False low page_margin_header page_margin_header True p4:body_region:1 top_margin column_2_of_2 2 2 p4:top_margin:column_2_of_2:white [255, 255, 255] white False False [469.62, 50.12, 74.39, 8.02] www.afm-journal.de 4 6 7 58 #/texts/50 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [303.09, 75.54, 240.95, 86.05] structure can boost the fast Li + diffusion, enhance the rate performance and fast-charging capability of LRMO. These results provide strong evidences of the existence of spinel phase, well consistent with the results f… structure can boost the fast Li + diffusion, enhance the rate performance and fast-charging capability of LRMO. These results provide strong evidences of the existence of spinel phase, well consistent with the results f… 4 7 8 59 #/texts/51 text body True None body body True p4:body_region:1 page_body column_2_of_2 2 2 p4:page_body:column_2_of_2:white [255, 255, 255] white False False [303.09, 164.11, 240.97, 479.67] Surface defect engineering usually can result in the obvious changes of elemental chemical compositions and metal valence, exerting a significant impact on the electrochemical properties of LRMO. Therefore, relevant cha… Surface defect engineering usually can result in the obvious changes of elemental chemical compositions and metal valence, exerting a significant impact on the electrochemical properties of LRMO. Therefore, relevant cha… 4 8 9 60 #/texts/52 text body True None body body True p4:body_region:1 bottom_margin column_2_of_2 2 2 p4:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [303.09, 646.29, 240.96, 74.2] With respect to electrochemical performance, to evaluate the cyclic stability, rate performance, and fast-charging properties of P0 and NHCO-5, all the assembled electrodes are initially activated at a low rate of 0.1 C… With respect to electrochemical performance, to evaluate the cyclic stability, rate performance, and fast-charging properties of P0 and NHCO-5, all the assembled electrodes are initially activated at a low rate of 0.1 C… 4 10 10 61 #/texts/54 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p4:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [263.85, 744.38, 64.3, 8.02] 2304065 (4 of 11) 2304065 (4 of 11) 4 11 11 62 #/texts/55 page_footer page_footer False low docling_page_footer docling_page_footer True p4:body_region:1 bottom_margin column_2_of_2 2 2 p4:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [466.82, 745.82, 77.21, 6.3] ©2023 Wiley-VCH GmbH ©2023 Wiley-VCH GmbH 5 1 1 63 #/texts/53#prov1 text page_margin_header False low page_margin_header page_margin_header True p5:body_region:0 top_margin column_1_of_2 1 2 p5:top_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 50.12, 120.78, 8.02] www.advancedsciencenews.com 5 2 2 64 #/texts/56 page_header page_header False low docling_page_header docling_page_header False None top_margin column_2_of_2 2 2 p5:top_margin:column_2_of_2:off_white [246, 246, 246] off_white False False [579.16, 15.65, 4.41, 751.61] 16163028, 2023, 43, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202304065 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wile… 5 4 3 65 #/texts/58 text page_margin_header False low page_margin_header page_margin_header True p5:body_region:1 top_margin column_2_of_2 2 2 p5:top_margin:column_2_of_2:white [255, 255, 255] white False False [472.46, 50.12, 74.39, 8.02] www.afm-journal.de 5 3 4 66 #/texts/57 caption caption False low outside_body_flow_caption outside_body_flow_caption False None page_body column_1_of_2 1 2 p5:page_body:column_1_of_2:white [255, 255, 255] white False False [50.81, 486.36, 496.05, 16.66] Figure 3. High-resolution XPS spectra of O 1s for a) P0 and b) NHCO-5. c) EPR spectra of P0 and NHCO-5. d) Normalized O K-edge sXAS spectra of P0 and NHCO-5. The XPS spectra of Mn 2p for e) P0 and f) NHCO-5. g) The XPS … Figure 3. High-resolution XPS spectra of O 1s for a) P0 and b) NHCO-5. c) EPR spectra of P0 and NHCO-5. d) Normalized O K-edge sXAS spectra of P0 and NHCO-5. The XPS spectra of Mn 2p for e) P0 and f) NHCO-5. g) The XPS … 5 5 5 67 #/texts/59#prov0 text body True None body body True p5:body_region:0 bottom_margin column_1_of_2 1 2 p5:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 525.64, 240.96, 194.75] ( < 4.5 V) and a long plateau ( ≈ 4.5 V) correspond to the oxidation process of transition metals and electrochemical activation of Li 2 MnO3, respectively. [22] In contrast, NHCO-5 electrode delivers increasing dischar… ( < 4.5 V) and a long plateau ( ≈ 4.5 V) correspond to the oxidation process of transition metals and electrochemical activation of Li 2 MnO3, respectively. [22] In contrast, NHCO-5 electrode delivers increasing dischar… 5 8 6 68 #/texts/61 page_footer page_footer False low docling_page_footer docling_page_footer True p5:body_region:0 bottom_margin column_1_of_2 1 2 p5:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 745.71, 105.61, 6.3] Adv. Funct. Mater. 2023 , 33 , 2304065 Adv. Funct. Mater. 2023 , 33 , 2304065 5 6 7 69 #/texts/59#prov1 text body True None body body True p5:body_region:1 page_body column_2_of_2 2 2 p5:page_body:column_2_of_2:white [255, 255, 255] white False False [305.92, 525.64, 240.96, 139.95] rates of 0.1, 0.2, 0.5, 1, 2, and 5 C, respectively. However, NHCO-5 electrode exhibits superior rate performance with low voltage polarization. The capacities of NHCO-5 electrode are 292.9, 278.1, 256.7, 240.7, 219.9, … rates of 0.1, 0.2, 0.5, 1, 2, and 5 C, respectively. However, NHCO-5 electrode exhibits superior rate performance with low voltage polarization. The capacities of NHCO-5 electrode are 292.9, 278.1, 256.7, 240.7, 219.9, … 5 7 8 70 #/texts/60#prov0 text body True None body body True p5:body_region:1 bottom_margin column_2_of_2 2 2 p5:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [305.92, 668.11, 240.96, 52.27] To further examine the fast-charging properties of modified material, both the electrodes were charged at 3 or 5 C and discharged at 1 C for the fast-charging performance assessment. Figure 4e-i; Figure S5c-f, Supportin… To further examine the fast-charging properties of modified material, both the electrodes were charged at 3 or 5 C and discharged at 1 C for the fast-charging performance assessment. Figure 4e-i; Figure S5c-f, Supportin… 5 9 9 71 #/texts/62 page_footer page_footer False low docling_page_footer docling_page_footer False None bottom_margin column_2_of_2 2 2 p5:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [266.69, 744.38, 64.3, 8.02] 2304065 (5 of 11) 2304065 (5 of 11) 5 10 10 72 #/texts/63 page_footer page_footer False low docling_page_footer docling_page_footer True p5:body_region:1 bottom_margin column_2_of_2 2 2 p5:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [469.66, 745.82, 77.21, 6.3] ©2023 Wiley-VCH GmbH ©2023 Wiley-VCH GmbH 6 3 1 73 #/texts/64 page_header page_header False low docling_page_header docling_page_header True p6:body_region:0 top_margin column_1_of_2 1 2 p6:top_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 50.12, 120.78, 8.02] www.advancedsciencenews.com 6 4 2 74 #/texts/65 page_header page_header False low docling_page_header docling_page_header False None top_margin column_2_of_2 2 2 p6:top_margin:column_2_of_2:off_white [246, 246, 246] off_white False False [579.16, 15.65, 4.41, 751.61] 16163028, 2023, 43, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202304065 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wile… 6 6 3 75 #/texts/67 section_header metadata False low outside_body_flow_metadata_line outside_body_flow_metadata_line True p6:body_region:1 top_margin column_2_of_2 2 2 p6:top_margin:column_2_of_2:white [255, 255, 255] white False False [469.62, 50.12, 74.39, 8.02] www.afm-journal.de 6 5 4 76 #/texts/66 caption caption False low outside_body_flow_caption outside_body_flow_caption False None page_body column_1_of_2 1 2 p6:page_body:column_1_of_2:white [255, 255, 255] white False False [47.98, 482.35, 496.08, 35.6] Figure 4. The electrochemical performance of P0 and NHCO-5 electrodes: charge-discharge curves of a) P0 electrode and b) NHCO-5 electrode. c) The rate performance. d) Cycling performance. The initial charge and discharg… Figure 4. The electrochemical performance of P0 and NHCO-5 electrodes: charge-discharge curves of a) P0 electrode and b) NHCO-5 electrode. c) The rate performance. d) Cycling performance. The initial charge and discharg… 6 1 5 77 #/texts/60#prov1 text back_matter_heading False low back_matter_heading back_matter_heading stop_trigger True p6:body_region:0 bottom_margin column_1_of_2 1 2 p6:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 536.6, 240.96, 183.79] Supporting Information, shows the first and last charge and discharge curves at 3 and 5 C charging rate, respectively. There is no obvious difference as charged at 3 C for the two electrodes. However, P0 electrode shows… Supporting Information, shows the first and last charge and discharge curves at 3 and 5 C charging rate, respectively. There is no obvious difference as charged at 3 C for the two electrodes. However, P0 electrode shows… 6 7 6 78 #/texts/68 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:0 bottom_margin column_1_of_2 1 2 p6:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 745.71, 105.61, 6.3] Adv. Funct. Mater. 2023 , 33 , 2304065 Adv. Funct. Mater. 2023 , 33 , 2304065 6 2 7 79 #/texts/60#prov2 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 bottom_margin column_2_of_2 2 2 p6:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [303.09, 536.61, 240.96, 183.78] and less than P0 ( ≈ 11 min), as seen in the Figure 4h. Figure S5f, Supporting Information; Figure 5 i show the comparison of the cycling performance of P0 and NHCO-5 electrodes at 3 and 5 C fast-charging rate. P0 and N… and less than P0 ( ≈ 11 min), as seen in the Figure 4h. Figure S5f, Supporting Information; Figure 5 i show the comparison of the cycling performance of P0 and NHCO-5 electrodes at 3 and 5 C fast-charging rate. P0 and N… 6 8 8 80 #/texts/69 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop False None bottom_margin column_2_of_2 2 2 p6:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [263.85, 744.38, 64.3, 8.02] 2304065 (6 of 11) 2304065 (6 of 11) 6 9 9 81 #/texts/70 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p6:body_region:1 bottom_margin column_2_of_2 2 2 p6:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [466.82, 745.82, 77.21, 6.3] ©2023 Wiley-VCH GmbH ©2023 Wiley-VCH GmbH 7 2 1 82 #/texts/72 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 top_margin column_1_of_2 1 2 p7:top_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 50.12, 120.78, 8.02] www.advancedsciencenews.com 7 1 2 83 #/texts/71 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p7:top_margin:column_2_of_2:off_white [246, 246, 246] off_white False False [579.16, 15.65, 4.41, 751.61] 16163028, 2023, 43, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202304065 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wile… 7 4 3 84 #/texts/74 section_header metadata False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:1 top_margin column_2_of_2 2 2 p7:top_margin:column_2_of_2:white [255, 255, 255] white False False [472.46, 50.12, 74.39, 8.02] www.afm-journal.de 7 3 4 85 #/texts/73 caption caption False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_1_of_2 1 2 p7:page_body:column_1_of_2:white [255, 255, 255] white False False [50.81, 561.36, 496.06, 35.6] Figure 5. The O 1s XPS spectra at different charging/discharging states of a) P0 electrode and b) NHCO-5 electrode. The normalized O pre K-edge and Mn pre L-edge XAS spectra for c,e) P0 electrode and d,f) NHCO-5 electro… Figure 5. The O 1s XPS spectra at different charging/discharging states of a) P0 electrode and b) NHCO-5 electrode. The normalized O pre K-edge and Mn pre L-edge XAS spectra for c,e) P0 electrode and d,f) NHCO-5 electro… 7 5 5 86 #/texts/75#prov0 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 bottom_margin column_1_of_2 1 2 p7:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 624.27, 240.97, 96.11] As far as mechanisms of the improved rate performance and fast-charging capability are concerned, previous reports have demonstrated that oxygen redox chemistry results in sluggish kinetics with low Li + diffusion rate … As far as mechanisms of the improved rate performance and fast-charging capability are concerned, previous reports have demonstrated that oxygen redox chemistry results in sluggish kinetics with low Li + diffusion rate … 7 7 6 87 #/texts/76 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:0 bottom_margin column_1_of_2 1 2 p7:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 745.71, 105.61, 6.3] Adv. Funct. Mater. 2023 , 33 , 2304065 Adv. Funct. Mater. 2023 , 33 , 2304065 7 6 7 88 #/texts/75#prov1 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:1 bottom_margin column_2_of_2 2 2 p7:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [305.92, 624.27, 240.96, 96.11] shows the EIS Nyquist plots of P0 and NHCO-5 electrodes before electrochemical cycles. All the curves include three regions. Asmall interrupt in the high frequency represents the Ohmic resistance ( R s ) of the cell. On… shows the EIS Nyquist plots of P0 and NHCO-5 electrodes before electrochemical cycles. All the curves include three regions. Asmall interrupt in the high frequency represents the Ohmic resistance ( R s ) of the cell. On… 7 8 8 89 #/texts/77 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop False None bottom_margin column_2_of_2 2 2 p7:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [266.69, 744.38, 64.3, 8.02] 2304065 (7 of 11) 2304065 (7 of 11) 7 9 9 90 #/texts/78 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p7:body_region:1 bottom_margin column_2_of_2 2 2 p7:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [469.66, 745.82, 77.21, 6.3] ©2023 Wiley-VCH GmbH ©2023 Wiley-VCH GmbH 8 1 1 91 #/texts/79 section_header metadata False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 top_margin column_1_of_2 1 2 p8:top_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 50.12, 120.78, 8.02] www.advancedsciencenews.com 8 2 2 92 #/texts/80 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 page_body column_1_of_2 1 2 p8:page_body:column_1_of_2:white [255, 255, 255] white False False [47.97, 76.43, 240.96, 172.83] impedance of NHCO-5 with surface defect construction. [17c] The GITT measurement is also conducted to compare the kinetic performance of P0 and NHCO-5 electrodes after five cycles at 0.04 C (Figure S6b, Supporting Infor… impedance of NHCO-5 with surface defect construction. [17c] The GITT measurement is also conducted to compare the kinetic performance of P0 and NHCO-5 electrodes after five cycles at 0.04 C (Figure S6b, Supporting Infor… 8 3 3 93 #/texts/81 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 bottom_margin column_1_of_2 1 2 p8:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [47.97, 251.77, 240.97, 468.71] The O 1s XPS spectra of P0 and NHCO-5 electrodes at charging and discharging state in the first cycle are conducted for exploring the mechanisms of oxygen redox (Figure 5a,b). Three obvious peaks appearing at ≈ 529.5, ≈… The O 1s XPS spectra of P0 and NHCO-5 electrodes at charging and discharging state in the first cycle are conducted for exploring the mechanisms of oxygen redox (Figure 5a,b). Three obvious peaks appearing at ≈ 529.5, ≈… 8 4 4 94 #/texts/82 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:0 bottom_margin column_1_of_2 1 2 p8:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 745.71, 105.61, 6.3] Adv. Funct. Mater. 2023 , 33 , 2304065 Adv. Funct. Mater. 2023 , 33 , 2304065 8 9 5 95 #/texts/87#prov0 text reference False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p8:top_margin:column_2_of_2:off_white [246, 246, 246] off_white False False [579.16, 15.65, 4.41, 751.61] 16163028, 2023, 43, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202304065 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wile… 8 5 6 96 #/texts/83 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 top_margin column_2_of_2 2 2 p8:top_margin:column_2_of_2:white [255, 255, 255] white False False [469.62, 50.12, 74.39, 8.02] www.afm-journal.de 8 6 7 97 #/texts/84 text body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [303.09, 76.42, 240.93, 30.37] results successfully demonstrate the surface oxygen vacancies, and spinel phase can enhance the reversible anionic redox and suppress irreversible oxygen release. results successfully demonstrate the surface oxygen vacancies, and spinel phase can enhance the reversible anionic redox and suppress irreversible oxygen release. 8 7 8 98 #/texts/85 text back_matter_text False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 page_body column_2_of_2 2 2 p8:page_body:column_2_of_2:white [255, 255, 255] white False False [303.09, 109.3, 240.96, 293.38] Ex situ XRD is applied to figure out the influence of the surface treatment on the crystal structural evolution of LRMO. The associated results are displayed in Figure 5g,h. The shift of (003) peak can directly reflect … Ex situ XRD is applied to figure out the influence of the surface treatment on the crystal structural evolution of LRMO. The associated results are displayed in Figure 5g,h. The shift of (003) peak can directly reflect … 8 8 9 99 #/texts/86 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 bottom_margin column_2_of_2 2 2 p8:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [303.09, 405.2, 240.96, 315.29] To further demonstrate and understand the influencing mechanisms of surface defect structure on the electrochemical performance, first principles calculations are conducted for studying the electronic structure of P0 an… To further demonstrate and understand the influencing mechanisms of surface defect structure on the electrochemical performance, first principles calculations are conducted for studying the electronic structure of P0 an… 8 10 10 100 #/texts/88 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop False None bottom_margin column_2_of_2 2 2 p8:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [263.85, 744.38, 64.3, 8.02] 2304065 (8 of 11) 2304065 (8 of 11) 8 11 11 101 #/texts/89 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p8:body_region:1 bottom_margin column_2_of_2 2 2 p8:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [466.82, 745.82, 77.21, 6.3] ©2023 Wiley-VCH GmbH ©2023 Wiley-VCH GmbH 9 1 1 102 #/texts/87#prov1 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:0 top_margin column_1_of_2 1 2 p9:top_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 50.12, 120.78, 8.02] www.advancedsciencenews.com 9 4 2 103 #/texts/90 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p9:top_margin:column_2_of_2:off_white [246, 246, 246] off_white False False [579.16, 15.65, 4.41, 751.61] 16163028, 2023, 43, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202304065 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wile… 9 2 3 104 #/texts/87#prov2 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 top_margin column_2_of_2 2 2 p9:top_margin:column_2_of_2:white [255, 255, 255] white False False [472.46, 50.12, 74.39, 8.02] www.afm-journal.de 9 5 4 105 #/texts/91 caption caption False low after_back_matter_stop after_back_matter_stop after_stop False None page_body column_1_of_2 1 2 p9:page_body:column_1_of_2:white [255, 255, 255] white False False [50.81, 473.35, 496.06, 16.67] Figure 6. The analysis of P0 and NHCO-5 electrodes after 200 cycles: a) The comparison of XRD pattern. b) Raman spectra. The SEM images of c) P0 and e) NHCO-5. HRTEM images of d) P0 and f) NHCO-5. g) The schematic of th… Figure 6. The analysis of P0 and NHCO-5 electrodes after 200 cycles: a) The comparison of XRD pattern. b) Raman spectra. The SEM images of c) P0 and e) NHCO-5. HRTEM images of d) P0 and f) NHCO-5. g) The schematic of th… 9 3 5 106 #/texts/87#prov3 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:0 page_body column_1_of_2 1 2 p9:page_body:column_1_of_2:white [255, 255, 255] white False False [50.81, 514.68, 240.95, 41.32] increasing electrical conductivity, facilitating lithium ion diffusion and fast charge transfer, but also suppressing oxygen release and promoting the charge compensation of both cationic and anionic redox. increasing electrical conductivity, facilitating lithium ion diffusion and fast charge transfer, but also suppressing oxygen release and promoting the charge compensation of both cationic and anionic redox. 9 6 6 107 #/texts/92 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:0 bottom_margin column_1_of_2 1 2 p9:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 558.52, 240.96, 161.87] To explore the structural evolution of P0 and NHCO-5 electrodes after 200 cycles, relevant characterizations were employed to study the changes of crystal structure and morphology. Figure 6 a shows the comparison of XRD… To explore the structural evolution of P0 and NHCO-5 electrodes after 200 cycles, relevant characterizations were employed to study the changes of crystal structure and morphology. Figure 6 a shows the comparison of XRD… 9 8 7 108 #/texts/94 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:0 bottom_margin column_1_of_2 1 2 p9:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [50.81, 745.71, 105.61, 6.3] Adv. Funct. Mater. 2023 , 33 , 2304065 Adv. Funct. Mater. 2023 , 33 , 2304065 9 7 8 109 #/texts/93#prov0 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 bottom_margin column_2_of_2 2 2 p9:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [305.92, 513.64, 240.97, 206.75] bonds. [5b] The smaller area ratio of spinel-like component for NHCO-5 suggests that minor structural transformation occurs from layer to spinel/rock-salt phase. It is mainly ascribed to be the fact that surface defect … bonds. [5b] The smaller area ratio of spinel-like component for NHCO-5 suggests that minor structural transformation occurs from layer to spinel/rock-salt phase. It is mainly ascribed to be the fact that surface defect … 9 9 9 110 #/texts/95 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop False None bottom_margin column_2_of_2 2 2 p9:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [266.69, 744.38, 64.3, 8.02] 2304065 (9 of 11) 2304065 (9 of 11) 9 10 10 111 #/texts/96 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p9:body_region:1 bottom_margin column_2_of_2 2 2 p9:bottom_margin:column_2_of_2:white [255, 255, 255] white False False [469.66, 745.82, 77.21, 6.3] ©2023 Wiley-VCH GmbH ©2023 Wiley-VCH GmbH 10 1 1 112 #/texts/93#prov1 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 top_margin column_1_of_2 1 2 p10:top_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 50.12, 120.78, 8.02] www.advancedsciencenews.com 10 2 2 113 #/texts/93#prov2 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 front_matter column_1_of_2 1 2 p10:front_matter:column_1_of_2:white [255, 255, 255] white False False [47.97, 76.43, 240.96, 337.21] S8b, Supporting Information. Both P0 and NHCO-5 show the high content of Mn in comparison with Co, which demonstrates that Mn dissolves in the electrolyte more easily. In addition, the dissolution content of Mn and Co f… S8b, Supporting Information. Both P0 and NHCO-5 show the high content of Mn in comparison with Co, which demonstrates that Mn dissolves in the electrolyte more easily. In addition, the dissolution content of Mn and Co f… 10 4 3 114 #/texts/98 section_header body_heading False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 body_zone column_1_of_2 1 2 p10:body_zone:column_1_of_2:white [255, 255, 255] white False False [47.98, 440.84, 64.45, 10.25] 3. Conclusion 3. Conclusion 10 5 4 115 #/texts/99 text body_candidate_excluded False medium after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 bottom_margin column_1_of_2 1 2 p10:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 460.19, 240.95, 260.51] In summary, a facile surface defect construction strategy is proved to address the issues of irreversible oxygen release and sluggish kinetic for Li-rich Mn-based oxides cathodes, resulting in the excellent rate perform… In summary, a facile surface defect construction strategy is proved to address the issues of irreversible oxygen release and sluggish kinetic for Li-rich Mn-based oxides cathodes, resulting in the excellent rate perform… 10 6 5 116 #/texts/100 page_footer page_footer False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:0 bottom_margin column_1_of_2 1 2 p10:bottom_margin:column_1_of_2:white [255, 255, 255] white False False [47.98, 745.71, 105.61, 6.3] Adv. Funct. Mater. 2023 , 33 , 2304065 Adv. Funct. Mater. 2023 , 33 , 2304065 10 3 6 117 #/texts/97 page_header page_header False low after_back_matter_stop after_back_matter_stop after_stop False None top_margin column_2_of_2 2 2 p10:top_margin:column_2_of_2:off_white [246, 246, 246] off_white False False [579.16, 15.65, 4.41, 751.61] 16163028, 2023, 43, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202304065 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wile… 10 24 7 118 #/texts/118 text page_margin_header False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 top_margin column_2_of_2 2 2 p10:top_margin:column_2_of_2:white [255, 255, 255] white False False [469.62, 50.12, 74.39, 8.02] www.afm-journal.de 10 7 8 119 #/texts/101 section_header back_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [303.09, 76.58, 112.02, 10.25] Supporting Information Supporting Information 10 8 9 120 #/texts/102 text back_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [303.09, 95.35, 240.96, 16.67] Supporting Information is available from the Wiley Online Library or from the author. Supporting Information is available from the Wiley Online Library or from the author. 10 9 10 121 #/texts/103 section_header back_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [303.09, 136.03, 92.58, 10.25] Acknowledgements Acknowledgements 10 10 11 122 #/texts/104 text back_matter_text False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [303.09, 154.8, 240.95, 35.6] The authors acknowledge the financial support of the National Natural Science Foundation of China (52274309). This work also was supported by the Beamlines MCD-A and MCD-B (Soochow Beamline for Energy Materials) at NSRL. The authors acknowledge the financial support of the National Natural Science Foundation of China (52274309). This work also was supported by the Beamlines MCD-A and MCD-B (Soochow Beamline for Energy Materials) at NSRL. 10 11 12 123 #/texts/105 section_header back_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [303.09, 214.4, 87.65, 10.25] Conflict of Interest Conflict of Interest 10 12 13 124 #/texts/106 text back_matter_text False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [303.09, 233.17, 139.61, 7.2] The authors declare no conflict of interest. The authors declare no conflict of interest. 10 13 14 125 #/texts/107 section_header back_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [303.09, 264.37, 128.2, 10.25] Data Availability Statement Data Availability Statement 10 14 15 126 #/texts/108 text metadata False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [303.09, 283.15, 240.92, 16.67] The data that support the findings of this study are available from the corresponding author upon reasonable request. The data that support the findings of this study are available from the corresponding author upon reasonable request. 10 15 16 127 #/texts/109 section_header front_matter_heading False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [303.09, 323.81, 45.87, 10.25] Keywords Keywords 10 16 17 128 #/texts/110 text unknown_text False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [303.09, 342.59, 240.96, 16.67] anionic redox, electronic structure modulation, fast-charging, Li-rich Mnbased oxides cathodes, oxygen vacancy anionic redox, electronic structure modulation, fast-charging, Li-rich Mnbased oxides cathodes, oxygen vacancy 10 17 18 129 #/texts/111 text metadata False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [465.28, 373.47, 78.77, 16.67] Received: April 12, 2023 Revised: May 22, 2023 Received: April 12, 2023 Revised: May 22, 2023 10 18 19 130 #/texts/112 text metadata False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [440.13, 392.41, 103.92, 7.2] Published online: June 21, 2023 Published online: June 21, 2023 10 19 20 131 #/texts/113 list_item reference False low after_back_matter_stop after_back_matter_stop after_stop True p10:body_region:1 front_matter column_2_of_2 2 2 p10:front_matter:column_2_of_2:white [255, 255, 255] white False False [307.08, 434.21, 236.97, 37.09] a) S. 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