这里是差集：Docling 全量解析 text block 减去最终会进入正文的 block。优先人工检查 risk=high / medium。
layout_review.html excluded_blocks.json excluded_blocks.tsv final_body_blocks.tsv visual_assets.tsv original.pdf
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这些框显示被排除块，同时叠加真实图表资产框。青色虚线表示该 text block 被图表资产 caption 吸收；红色 STOP 是截断触发点，红色框是截断后被排除的块。
这是实际图表资产输出，不是审计层重新推断。
| # | type | label | page | caption source | suppressed | duplicate reason | rescue reason | group | confidence | bbox | caption |
|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | figure | Fig. 1 | 3 | direct_caption_ref | 0.82 | [71.63, 50.19, 401.32, 327.63] | Fig. 1 a Constitutional costs for manufacturing a typical LIB and SIB. Values are from ref. (Kim et al. 2014). b Abundances of metal elementals involved in standard cathode materials. Values are taken from ref. (Nitta et al. 2015). c Sustainable (naturally | ||||
| 2 | figure | Fig. 2 | 4 | sequence_or_inferred_caption | 0.82 | [46.13, 49.06, 455.09, 126.05] | Fig. 2 a Crystal structure of layered LiMO2. Reproduced from ref. (Chen et al. 2016) with permission. b Cycling profile of layered LiMnO2. Reproduced from ref. (Armstrong and Bruce 1996) with permission. c Structural illustration and voltage profiles of orthorhombic LiMnO2. Reproduced from ref. (Croguennec et al. 1997b) and ref. (He et al. 2010) with permissions | ||||
| 3 | figure | Fig. 3 | 5 | direct_caption_ref | 0.82 | [73.3, 51.24, 400.1, 219.97] | Fig. 3 a , b Charge/discharge curves of LiFeO2 ( a ) and oxygen-deficient LiFeO2-x ( b ). c XRD pattern of cycled O3-type LiFeO2. Reproduced from ref. (Hirayama et al. 2011) with permission | ||||
| 4 | figure | Docling Figure 4 | 6 | missing_caption | 0.55 | [79.6, 48.36, 382.72, 590.51] | |||||
| 5 | figure | Fig. 5 | 8 | direct_caption_ref | 0.82 | [71.07, 49.41, 400.28, 297.97] | Fig. 5 a Crystal structure of spinel LiMn2O4. Reproduced from ref. (Chen et al. 2016) with permission. b -e Schematic diagram of the composites and the corresponding electrochemical performance. Reproduced from ref. (Lee et al. 2017) with permission | ||||
| 6 | figure | Fig. 6 | 10 | sequence_or_inferred_caption | 0.82 | [48.04, 47.24, 452.62, 326.96] | Fig. 6 a Comparison of the two structural configurations in LNMO. Reproduced from ref. (Liu et al. 2012a) with permission. b Typical charge/discharge curves of LNMO with the two phases. Reproduced from ref. (Wang et al. 2011b) with permission. c , d Structural characteristics and electrochemical properties on the basis of our prepared samples. e , f Outstanding capacity retention achieved by using lithium phosphorus oxynitride solid electrolyte. Reproduced from ref. (Li et al. 2015b) with permission | ||||
| 7 | figure | Fig. 7 | 11 | direct_caption_ref | 0.82 | [253.86, 48.01, 243.63, 593.54] | Fig. 7 a Crystal structure of spinel LiMn2O4. Reproduced from ref. (Chen et al. 2016) with permission. b High-rate discharge capability of LiFe 0.9P0.95O4δ . Reproduced from ref. (Kang and Ceder 2009) with permission. c Structural and electrochemical properties of a core-shell LFP nanocomposites. Reproduced from ref. (Naoi et al. 2016) with permission. d Morphology and discharge curves of LMO nanoparticles. Reproduced with permission (Hong et al. 2015). e Phase transformation diagram of LiMn0.6Fe0.4PO4 over the extraction/insertion of Li ions. Reproduced from ref. (Ravnsbæk et al. 2014) with permission. f Phase transformation strain as a function of the Mn content in LFMP, and a special case of LiMn0.2Fe0.8PO4 with no misfit strain. Reproduced from ref. (Ravnsbæk et al. 2016) with permission. g LiMn0.5Fe0.5PO4 nanocrystals with different Fe-Li antisite defects showing distinct rate performance. Reproduced from ref. (Hu et al. 2017) with permission | ||||
| 8 | figure | Fig. 8 | 14 | sequence_or_inferred_caption | 0.82 | [45.97, 48.86, 456.28, 254.24] | Fig. 8 a , b Crystal structures of P 21/ n Li2FeSiO4 ( a ), which transforms into Pmn 21 Li2FeSiO4 ( b ). c Typical charge/discharge curves of Li2FeSiO4. Reproduced from ref. (Armstrong et al. 2011) with permission. d Structural transformation routes of LiFeBO3 during delithiation and degradation. Reproduced from ref. (Bo et al. 2014) with permission. e Charge/discharge profiles of mesoporous LiFeBO3/C hollow spheres. Reproduced from ref. (Chen et al. 2015) with permission | ||||
| 9 | figure | Fig. 9 | 15 | direct_caption_ref | 0.82 | [216.6, 48.7, 283.67, 313.54] | Fig. 9 a Structural comparison of P2-type and O3-type NaxMO2. Reproduced from ref. (Yabuuchi et al. 2012a) with permission. b Synthesis phase diagram of NaxCoO2 as a function of the Na/ Co ratio from precursors and heating temperature. Reproduced from ref. (Lei et al. 2014) with permission | ||||
| 10 | figure | Fig. 10 | 16 | sequence_or_inferred_caption | 0.82 | [46.31, 50.07, 454.85, 145.54] | Fig. 10 a Initial charge/discharge curves of NaFeO2 on the dependence of different cut-off potentials. Reprinted from ref. (Okada et al. 2006) with permission. b Voltage profiles along cycling. c A diagram illustrating the electrochemical active Fe 3+ / Fe 4+ redox couple. Reproduced from ref. (Lee et al. 2015) with permission | ||||
| 11 | figure | Fig. 11 | 16 | nearby_text_caption | 0.82 | [216.45, 275.4, 284.78, 387.31] | Fig. 11 a Stability domain of the different structural types observed for as-synthesized NaxMnO2 compounds. Reproduced from ref. (Clément et al. 2015) with permission. b Schematic representations of β -NaMnO2 and an intergrowth model between α - and β -NaMnO2. Reproduced from ref. (Billaud et al. 2014a) with permission. c , d Voltage profiles of α -NaMnO2 and the complex structure. Reproduced from ref. (Ma et al. 2011), (Billaud et al. 2014a) with permissions | ||||
| 12 | figure | Fig. 12 | 17 | nearby_text_caption | 0.82 | [285.05, 50.31, 216.58, 543.75] | Fig. 12 a , b Charge-discharge curves of o -NMO ( a ) and h -NMO ( b ). c , d Operando XRD patterns of o -NMO ( c ) and h -NMO ( d ) over initial charge/discharge curves. Reproduced from ref. (Kumakura et al. 2016) with permission | ||||
| 13 | figure | Fig. 13 | 18 | direct_caption_ref | 0.82 | [215.94, 49.21, 284.82, 231.46] | Fig. 13 a Schematic representation of the tunnel Na0.44MnO2. b Voltage profiles of the monocrystal Na0.44MnO2 nanoplates. c Cyclic voltammograms (CVs) of the Na0.44MnO2 electrode between 2.0 and 4.0 Vat a scanning rate of 0.1 mV s -1 . d Corresponding insitu XRD patterns over the voltage scanning. Reproduced from ref. (He et al. 2016) with permission | ||||
| 14 | figure | Fig. 14 | 19 | nearby_text_caption | 0.82 | [217.41, 540.48, 283.48, 120.53] | Fig. 14 Phase evolution in Na0.67Mn0.5Fe0.5O2 and Nisubstituted Na0.67Mn0.65Ni0.15Fe0.2O2 over the first cycle, and schematic illustration of Mn/Fe migration into tetrahedral sites in the Na space at high potential. Reproduced from ref. (Talaie et al. 2015) with permission | ||||
| 15 | figure | Fig. 15 | 21 | direct_caption_ref | 0.82 | [191.23, 48.89, 308.11, 592.98] | Fig. 15 a -e Crystal structures of olivine NFP, maricite NFP, NASICON-type Na3Fe2(PO4)3, layered Na3Fe3(PO4)4, alluauditetype Na2Fe3(PO4)3. Reproduced from ref. (Naoaki and Shinichi 2014) with permission. Their typical charge/discharge curves are shown on the right side. Reproduced from ref. (Ali et al. 2016), (Kim et al. 2015b), (Trad et al. 2010b), (Huang et al. 2015b), and (Liu et al. 2017b) with permissions | ||||
| 16 | figure | Fig. 16 | 22 | sequence_or_inferred_caption | 0.82 | [46.05, 395.76, 454.95, 224.11] | Fig. 16 a -c Triclinic structure ( P -1) of Na2FeP2O7 and corresponding electrochemical properties. Reproduced from ref. (Barpanda et al. 2012) with permission. d Voltage profiles of P -1 Na2MnP2O7. Reproduced from ref. (Park et al. 2013) with permission. e , f Crystal structure of β -Na2MnP2O7 (triclinic P 1) and its voltage profiles. Reproduced from ref. (Barpanda et al. 2013b) with permission | ||||
| 17 | figure | Fig. 17 | 23 | sequence_or_inferred_caption | 0.82 | [88.4, 48.39, 367.79, 575.2] | Fig. 17 Crystal structures of alluaudite-type Na2Fe2(SO4)3 ( a ), eldfellite NaFe(SO4)2 ( b ), Na2Fe2(C2O4)3·2H2O ( c ), and Na2Fe(C2O4)F2 with their voltage profiles are shown on the right side. Reproduced from ref. (Barpanda et al. 2014b), (Singh et al. 2015), (Yao et al. 2017b), and (Yao et al. 2017a) with permissions | ||||
| 18 | figure | Fig. 18 | 24 | direct_caption_ref | 0.82 | [240.07, 50.23, 258.44, 590.88] | Fig. 18 a -d Crystal structures of Na2FePO4F ( a ), Na2MnPO4F ( b ), Na4Fe3(PO4)2(P2O7) ( c ), and Na3MnPO4CO3 ( d ). Reproduced from ref. (Naoaki and Shinichi 2014) with permission. Their representative voltage profiles are shown on the right side. Reproduced from ref. (Law et al. 2015), (Lin et al. 2014), (Wu et al. 2016), and (Huang et al. 2014) with permissions. e Highperformance Na4Mn3(PO4)2(P2O7), which was ascribed to the cooperative JahnTeller effect of Mn 3+ . Reproduced from ref. (Kim et al. 2015a) with permission | ||||
| 19 | figure | Fig. 19 | 25 | sequence_or_inferred_caption | 0.82 | [46.6, 48.59, 454.1, 330.48] | Fig. 19 a Crystal structure of PBAs with a face-centered cubic phase. b Charge and discharge curves of Na2MnMn(CN)6. c , d The schematic illustrations of the step-wise structural evolution over the extraction/insertion of Na + ions. Reproduced from ref. (Lee et al. 2014) with permission. e , f Voltage profile and cycling performance of a Prussian blue@C composite. Reproduced from ref. (Jiang et al. 2016) with permission | ||||
| 20 | figure | Fig. 20 | 29 | direct_caption_ref | 0.82 | [74.14, 49.44, 399.05, 159.38] | Fig. 20 Illustration of the energy densities of those Fe- and Mn-based cathode materials for LIBs ( a ) and SIBs ( b ) | ||||
| 21 | table | Table 1 | 27 | direct_caption_ref | 0.82 | [293.62, 47.52, 205.35, 614.55] | Table 1 Electrochemical properties of representative Fe- and Mn-based cathode materials for LIBs | ||||
| 22 | table | Table 2 | 28 | nearby_text_caption | 0.82 | [160.73, 48.41, 234.47, 613.54] | Table 2 Electrochemical properties of representative Fe- and Mn-based cathode materials for SIBs |
| risk | page | order | label | role | reason | parser reason | production usage | trunc | body region | region | bg | bbox | raw text | cleaned text |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| medium | 1 | 5 | text | abstract_candidate | implicit_abstract | implicit_abstract | p1:body_region:0 | p1:front_matter:column_1_of_2:white | [255, 255, 255] white | [46.77, 262.24, 215.51, 195.45] | Abstract The ever-growing market of electrochemical energy storage impels the advances on cost-effective and environmentally friendly battery chemistries. Lithiumion batteries (LIBs) are currently the most critical energy storage devices for a variety of applications, while sodium-ion batteries (SIBs) are expected to complement LIBs in large-scale applications. In respect to their constituent components, the cathode part is the most significant sector regarding weight fraction and cost. Therefore, the development of cathode materials based on Earth ' s abundant elements (Fe and Mn) largely determines the prospects of the batteries. Herein, we offer a comprehensive review of the up-to-date advances on Fe- and Mnbased cathode materials for LIBs and SIBs, highlighting some promising candidates, such as Li- and Mn-rich layered oxides, LiNi0.5Mn1.5O4, LiFe1-xMnxPO4, | Abstract The ever-growing market of electrochemical energy storage impels the advances on cost-effective and environmentally friendly battery chemistries. Lithiumion batteries (LIBs) are currently the most critical energy storage devices for a variety of applications, while sodium-ion batteries (SIBs) are expected to complement LIBs in large-scale applications. In respect to their constituent components, the cathode part is the most significant sector regarding weight fraction and cost. Therefore, the development of cathode materials based on Earth ' s abundant elements (Fe and Mn) largely determines the prospects of the batteries. Herein, we offer a comprehensive review of the up-to-date advances on Fe- and Mnbased cathode materials for LIBs and SIBs, highlighting some promising candidates, such as Li- and Mn-rich layered oxides, LiNi0.5Mn1.5O4, LiFe1-xMnxPO4, | ||
| medium | 1 | 7 | text | abstract_candidate | implicit_abstract | implicit_abstract | p1:front_matter:column_2_of_2:white | [255, 255, 255] white | [284.88, 262.24, 215.53, 58.48] | NaxFeyMn1-yO2, Na4MnFe2(PO4)(P2O7), and Prussian blue analogs. Also, challenges and prospects are discussed to direct the possible development of costeffective and high-performance cathode materials for future rechargeable batteries. | NaxFeyMn1-yO2, Na4MnFe2(PO4)(P2O7), and Prussian blue analogs. Also, challenges and prospects are discussed to direct the possible development of costeffective and high-performance cathode materials for future rechargeable batteries. | |||
| medium | 1 | 9 | text | metadata | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:body_zone:column_1_of_2:white | [255, 255, 255] white | [46.76, 529.39, 214.35, 52.83] | X. Zhu : T. Lin : E. Manning : L. Wang ( * ) Nanomaterials Centre, School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, QLD, Brisbane 4072, Australia e-mail: l.wang@uq.edu.au | X. Zhu : T. Lin : E. Manning : L. Wang ( * ) Nanomaterials Centre, School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, QLD, Brisbane 4072, Australia e-mail: l.wang@uq.edu.au | ||
| medium | 1 | 14 | text | unknown_text | outside_body_flow | outside_body_flow | p1:body_region:0 | p1:body_zone:column_1_of_2:white | [255, 255, 255] white | [46.77, 495.95, 135.17, 7.35] | 20th Anniversary Issue: From the editors | 20th Anniversary Issue: From the editors | ||
| medium | 1 | 16 | text | unknown_text | empty_after_cleaning | empty_after_cleaning | p1:body_region:0 | p1:body_zone:column_1_of_2:white | [255, 255, 255] white | [80.84, 629.05, 32.89, 11.68] | : : | |||
| medium | 30 | 246 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p30:page_body:column_2_of_2:white | [255, 255, 255] white | [284.89, 415.51, 215.49, 47.37] | Banerjee A, Araujo RB, Ahuja R (2016) Unveiling the thermodynamic and kinetic properties of NaxFe(SO4)2 (x = 0-2): toward a high-capacity and low-cost cathode material. J Mater Chem A 4:17960 -17969. https://doi.org/10.1039/C6 TA05330K | Banerjee A, Araujo RB, Ahuja R (2016) Unveiling the thermodynamic and kinetic properties of NaxFe(SO4)2 (x = 0-2): toward a high-capacity and low-cost cathode material. J Mater Chem A 4:17960 -17969. | ||
| medium | 30 | 251 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p30:page_body:column_2_of_2:white | [255, 255, 255] white | [284.88, 625.67, 215.44, 37.34] | Barpanda P, Ye T, Avdeev M, Chung S-C, Yamada A (2013b) A new polymorph of Na2MnP2O7 as a 3.6 V cathode material for sodium-ion batteries. J Mater Chem A 1:4194 -4197. https://doi.org/10.1039/C3TA10210F | Barpanda P, Ye T, Avdeev M, Chung S-C, Yamada A (2013b) A new polymorph of Na2MnP2O7 as a 3.6 V cathode material for sodium-ion batteries. J Mater Chem A 1:4194 -4197. | ||
| medium | 31 | 266 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p31:page_body:column_1_of_2:white | [255, 255, 255] white | [46.81, 594.86, 215.4, 37.34] | Chen H, Dawson JA, Harding JH (2014) Effects of cationic substitution on structural defects in layered cathode materials LiNiO2. J Mater Chem A 2:7988 -7996. https://doi. org/10.1039/C4TA00637B | Chen H, Dawson JA, Harding JH (2014) Effects of cationic substitution on structural defects in layered cathode materials LiNiO2. J Mater Chem A 2:7988 -7996. org/10.1039/C4TA00637B | ||
| medium | 32 | 307 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p32:page_body:column_2_of_2:white | [255, 255, 255] white | [284.87, 195.46, 215.49, 47.37] | Guo H, Wu C, Xie J, Zhang S, Cao G, Zhao X (2014a) Controllable synthesis of high-performance LiMnPO4 nanocrystals by a facile one-spot solvothermal process. J Mater Chem A 2:10581 -10588. https://doi.org/10.1039/C4 TA01365D | Guo H, Wu C, Xie J, Zhang S, Cao G, Zhao X (2014a) Controllable synthesis of high-performance LiMnPO4 nanocrystals by a facile one-spot solvothermal process. J Mater Chem A 2:10581 -10588. | ||
| medium | 33 | 323 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p33:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 218.36, 215.51, 47.31] | Huang W et al (2015a) Self-assembled alluaudite Na2Fe3 -xMnx(PO4)3 micro/nanocompounds for sodium-ion battery electrodes: a new insight into their electronic and geometric structure. Chem Eur J 21:851 -860. https://doi. org/10.1002/chem.201403062 | Huang W et al (2015a) Self-assembled alluaudite Na2Fe3 -xMnx(PO4)3 micro/nanocompounds for sodium-ion battery electrodes: a new insight into their electronic and geometric structure. Chem Eur J 21:851 -860. org/10.1002/chem.201403062 | ||
| medium | 33 | 327 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p33:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 401.23, 215.42, 37.34] | Jang DH, Shin YJ, Oh SM (1996) Dissolution of Spinel Oxides and Capacity Losses in 4 V Li / Li x Mn2 O 4 Cells. J Electrochem Soc 143:2204 -2211. https://doi.org/10.1149 /1.1836981 | Jang DH, Shin YJ, Oh SM (1996) Dissolution of Spinel Oxides and Capacity Losses in 4 V Li / Li x Mn2 O 4 Cells. J Electrochem Soc 143:2204 -2211. | ||
| medium | 33 | 343 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p33:page_body:column_2_of_2:white | [255, 255, 255] white | [284.88, 355.54, 215.49, 37.44] | Kim H et al (2013a) Understanding the electrochemical mechanism of t h e new i r o n - b a s e d mixed-phosphate Na4Fe3(PO4)2(P2O7) in a Na rechargeable battery. Chem Mater 25:3614 -3622. https://doi.org/10.1021/cm4013816 | Kim H et al (2013a) Understanding the electrochemical mechanism of t h e new i r o n - b a s e d mixed-phosphate Na4Fe3(PO4)2(P2O7) in a Na rechargeable battery. Chem Mater 25:3614 -3622. | ||
| medium | 34 | 354 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p34:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 85.44, 215.5, 37.4] | Ko JS et al (2017) High-rate capability of Na2FePO4F nanoparticles by enhancing surface carbon functionality for Na-ion batteries. J Mater Chem A 5:18707 -18715. https://doi. org/10.1039/C7TA05680J | Ko JS et al (2017) High-rate capability of Na2FePO4F nanoparticles by enhancing surface carbon functionality for Na-ion batteries. J Mater Chem A 5:18707 -18715. org/10.1039/C7TA05680J | ||
| medium | 34 | 373 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p34:page_body:column_2_of_2:white | [255, 255, 255] white | [284.9, 228.86, 215.46, 37.34] | Li C, Miao X, Chu W, Wu P, Tong DG (2015a) Hollow amorphous NaFePO4 nanospheres as a high-capacity and high-rate cathode for sodium-ion batteries. J Mater Chem A 3:8265 -8271. https://doi.org/10.1039/C5TA01191D | Li C, Miao X, Chu W, Wu P, Tong DG (2015a) Hollow amorphous NaFePO4 nanospheres as a high-capacity and high-rate cathode for sodium-ion batteries. J Mater Chem A 3:8265 -8271. | ||
| medium | 34 | 376 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p34:page_body:column_2_of_2:white | [255, 255, 255] white | [284.9, 340.88, 215.5, 47.37] | Li D et al (2016) Soft-template construction of threedimensionally ordered inverse opal structure from Li2FeSiO4/C composite nanofibers for high-rate lithiumion batteries. Nanoscale 8:12202 -12214. https://doi. org/10.1039/C5NR07783D | Li D et al (2016) Soft-template construction of threedimensionally ordered inverse opal structure from Li2FeSiO4/C composite nanofibers for high-rate lithiumion batteries. Nanoscale 8:12202 -12214. org/10.1039/C5NR07783D | ||
| medium | 34 | 380 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p34:page_body:column_2_of_2:white | [255, 255, 255] white | [284.92, 523.6, 215.5, 37.34] | Liu Y et al (2012b) Porous amorphous FePO4 nanoparticles connected by single-wall carbon nanotubes for sodium ion battery cathodes. Nano Lett 12:5664 -5668. https://doi. org/10.1021/nl302819f | Liu Y et al (2012b) Porous amorphous FePO4 nanoparticles connected by single-wall carbon nanotubes for sodium ion battery cathodes. Nano Lett 12:5664 -5668. org/10.1021/nl302819f | ||
| medium | 35 | 387 | list_item | body_candidate_excluded | after_back_matter_stop | after_back_matter_stop | after_stop | p35:page_body:column_1_of_2:white | [255, 255, 255] white | [46.79, 115.48, 215.53, 47.37] | Liu H, Ji P, Han X (2016b) Rheological phase synthesis of nanosized α -LiFeO2 with higher crystallinity degree for cathode material of lithium-ion batteries. Mater Chem Phys 1 8 3 : 1 5 2 -1 5 7 . h t t p s : / / d o i . o r g / 1 0 . 1 0 1 6 / j . matchemphys.2016.08.013 | Liu H, Ji P, Han X (2016b) Rheological phase synthesis of nanosized α -LiFeO2 with higher crystallinity degree for cathode material of lithium-ion batteries. Mater Chem Phys 1 8 3 : 1 5 2 -1 5 7 . h t t p s : / / d o i . o r g / 1 0 . 1 0 1 6 / j . matchemphys.2016.08.013 | ||
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| low | 1 | 0 | page_header | page_header | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.19, 141.55, 18.69] | J Nanopart Res (2018) 20: 160 https://doi.org/10.1007/s11051-018-4235-1 | J Nanopart Res (2018) 20: 160 | ||
| low | 1 | 1 | section_header | title_candidate | first_page_front_matter_heading | first_page_front_matter_heading | p1:body_region:0 | p1:front_matter:front_panel:gray | [195, 196, 196] gray | [52.44, 65.76, 39.87, 9.08] | REVIEW | REVIEW | ||
| low | 1 | 2 | section_header | title_candidate | first_page_front_matter_heading | first_page_front_matter_heading | p1:body_region:0 | p1:front_matter:column_1_of_2:white | [255, 255, 255] white | [46.77, 107.14, 380.39, 30.94] | Recent advances on Fe- and Mn-based cathode materials for lithium and sodium ion batteries | Recent advances on Fe- and Mn-based cathode materials for lithium and sodium ion batteries | ||
| low | 1 | 3 | text | front_matter_candidate | before_body_started | before_body_started | p1:body_region:0 | p1:front_matter:column_1_of_2:white | [255, 255, 255] white | [46.77, 157.49, 192.35, 33.85] | Xiaobo Zhu & Tongen Lin & Eric Manning & Yuancheng Zhang & Mengmeng Yu & Bin Zuo & Lianzhou Wang | Xiaobo Zhu & Tongen Lin & Eric Manning & Yuancheng Zhang & Mengmeng Yu & Bin Zuo & Lianzhou Wang | ||
| low | 1 | 4 | text | metadata | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:front_matter:column_1_of_2:white | [255, 255, 255] white | [46.77, 225.19, 285.74, 17.6] | Received: 18 January 2018 /Accepted: 23 April 2018 /Published online: 11 June 2018 # Springer Science+Business Media B.V ., part of Springer Nature 2018 | Received: 18 January 2018 /Accepted: 23 April 2018 /Published online: 11 June 2018 # Springer Science+Business Media B.V ., part of Springer Nature 2018 | ||
| low | 1 | 6 | text | front_matter_heading | abstract_boundary_front_matter | abstract_boundary_front_matter | p1:front_matter:column_2_of_2:white | [255, 255, 255] white | [284.88, 346.38, 215.5, 33.53] | Keywords Cathodematerials . Iron-based . Manganesebased . Lithium ion batteries . Sodium ion batteries . Energy storage | Keywords Cathodematerials . Iron-based . Manganesebased . Lithium ion batteries . Sodium ion batteries . Energy storage | |||
| low | 1 | 8 | section_header | body_heading | body_heading | body_heading | p1:body_zone:column_2_of_2:white | [255, 255, 255] white | [284.89, 418.09, 52.55, 8.75] | Introduction | Introduction | |||
| low | 1 | 10 | text | affiliation | affiliation_block | affiliation_block | p1:body_region:0 | p1:body_zone:column_1_of_2:white | [255, 255, 255] white | [46.76, 594.77, 204.74, 17.33] | E. Manning Faculty of Engineering, University of Alberta, Edmonton, AB | E. Manning Faculty of Engineering, University of Alberta, Edmonton, AB | ||
| low | 2 | 18 | page_header | page_header | docling_page_header | docling_page_header | p2:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 63.0, 7.44] | 160 Page 2 of 40 | 160 Page 2 of 40 | |||
| low | 2 | 22 | page_header | page_header | docling_page_header | docling_page_header | p2:body_region:0 | p2:top_margin:column_2_of_2:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | ||
| low | 2 | 25 | section_header | body_heading | body_heading | body_heading | p2:body_region:0 | p2:page_body:column_2_of_2:white | [255, 255, 255] white | [284.89, 442.97, 174.19, 8.75] | Fe- and Mn-based oxides as LIB cathodes | Fe- and Mn-based oxides as LIB cathodes | ||
| low | 3 | 27 | page_header | page_header | docling_page_header | docling_page_header | p3:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 3 | 28 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p3:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 384.38, 215.5, 37.31] | Fig. 1 a Constitutional costs for manufacturing a typical LIB and SIB. Values are from ref. (Kim et al. 2014). b Abundances of metal elementals involved in standard cathode materials. Values are taken from ref. (Nitta et al. 2015). c Sustainable (naturally | Fig. 1 a Constitutional costs for manufacturing a typical LIB and SIB. Values are from ref. (Kim et al. 2014). b Abundances of metal elementals involved in standard cathode materials. Values are taken from ref. (Nitta et al. 2015). c Sustainable (naturally | |||
| low | 3 | 29 | section_header | body_heading | body_heading | body_heading | p3:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 442.98, 32.99, 9.61] | LiMnO2 | LiMnO2 | |||
| low | 3 | 31 | page_header | page_header | docling_page_header | docling_page_header | p3:top_margin:column_2_of_2:white | [255, 255, 255] white | [437.38, 34.25, 62.91, 7.44] | Page 3 of 40 160 | Page 3 of 40 160 | |||
| low | 4 | 35 | page_header | page_header | docling_page_header | docling_page_header | p4:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | |||
| low | 4 | 36 | page_header | page_header | docling_page_header | docling_page_header | p4:top_margin:column_1_of_2:white | [255, 255, 255] white | [67.64, 34.25, 42.14, 7.35] | Page 4 of 40 | Page 4 of 40 | |||
| low | 4 | 37 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p4:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 182.33, 215.42, 27.25] | Fig. 2 a Crystal structure of layered LiMO2. Reproduced from ref. (Chen et al. 2016) with permission. b Cycling profile of layered LiMnO2. Reproduced from ref. (Armstrong and Bruce | Fig. 2 a Crystal structure of layered LiMO2. Reproduced from ref. (Chen et al. 2016) with permission. b Cycling profile of layered LiMnO2. Reproduced from ref. (Armstrong and Bruce | |||
| low | 4 | 40 | section_header | body_heading | body_heading | body_heading | p4:page_body:column_1_of_2:white | [255, 255, 255] white | [46.78, 530.12, 29.02, 9.66] | LiFeO2 | LiFeO2 | |||
| low | 4 | 42 | page_header | page_header | docling_page_header | docling_page_header | p4:body_region:0 | p4:top_margin:column_2_of_2:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | ||
| low | 4 | 43 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p4:body_region:0 | p4:page_body:column_2_of_2:white | [255, 255, 255] white | [284.88, 182.33, 215.53, 27.25] | 1996) with permission. c Structural illustration and voltage profiles of orthorhombic LiMnO2. Reproduced from ref. (Croguennec et al. 1997b) and ref. (He et al. 2010) with permissions | 1996) with permission. c Structural illustration and voltage profiles of orthorhombic LiMnO2. Reproduced from ref. (Croguennec et al. 1997b) and ref. (He et al. 2010) with permissions | ||
| low | 5 | 47 | page_header | page_header | docling_page_header | docling_page_header | p5:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 5 | 48 | page_header | page_header | docling_page_header | docling_page_header | p5:top_margin:column_2_of_2:white | [255, 255, 255] white | [437.38, 34.25, 62.91, 7.44] | Page 5 of 40 160 | Page 5 of 40 160 | |||
| low | 5 | 49 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p5:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 277.12, 453.51, 17.33] | Fig. 3 a , b Charge/discharge curves of LiFeO2 ( a ) and oxygen-deficient LiFeO2-x ( b ). c XRD pattern of cycled O3-type LiFeO2. Reproduced from ref. (Hirayama et al. 2011) with permission | Fig. 3 a , b Charge/discharge curves of LiFeO2 ( a ) and oxygen-deficient LiFeO2-x ( b ). c XRD pattern of cycled O3-type LiFeO2. Reproduced from ref. (Hirayama et al. 2011) with permission | |||
| low | 5 | 51 | section_header | body_heading | body_heading | body_heading | p5:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 492.76, 89.77, 8.65] | Li2MnO3-based oxides | Li2MnO3-based oxides | |||
| low | 6 | 55 | page_header | page_header | docling_page_header | docling_page_header | p6:top_margin:left:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | |||
| low | 6 | 56 | page_header | page_header | docling_page_header | docling_page_header | p6:top_margin:left:white | [255, 255, 255] white | [67.64, 34.25, 42.14, 7.35] | Page 6 of 40 | Page 6 of 40 | |||
| low | 6 | 57 | page_header | page_header | docling_page_header | docling_page_header | p6:top_margin:right:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 7 | 58 | page_header | page_header | docling_page_header | docling_page_header | p7:body_region:0 | p7:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | ||
| low | 7 | 62 | section_header | body_heading | body_heading | body_heading | p7:body_region:0 | p7:page_body:column_1_of_2:white | [255, 255, 255] white | [46.78, 530.11, 36.61, 9.67] | LiMn2O4 | LiMn2O4 | ||
| low | 7 | 64 | page_header | page_header | docling_page_header | docling_page_header | p7:body_region:1 | p7:top_margin:column_2_of_2:white | [255, 255, 255] white | [437.38, 34.25, 62.91, 7.44] | Page 7 of 40 160 | Page 7 of 40 160 | ||
| low | 8 | 67 | page_header | page_header | docling_page_header | docling_page_header | p8:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | |||
| low | 8 | 68 | page_header | page_header | docling_page_header | docling_page_header | p8:top_margin:column_1_of_2:white | [255, 255, 255] white | [67.64, 34.25, 42.14, 7.35] | Page 8 of 40 | Page 8 of 40 | |||
| low | 8 | 69 | page_header | page_header | docling_page_header | docling_page_header | p8:top_margin:column_2_of_2:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 8 | 70 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p8:page_body:column_1_of_2:white | [255, 255, 255] white | [46.76, 351.44, 453.57, 18.81] | Fig. 5 a Crystal structure of spinel LiMn2O4. Reproduced from ref. (Chen et al. 2016) with permission. b -e Schematic diagram of the composites and the corresponding electrochemical performance. Reproduced from ref. (Lee et al. 2017) with permission | Fig. 5 a Crystal structure of spinel LiMn2O4. Reproduced from ref. (Chen et al. 2016) with permission. b -e Schematic diagram of the composites and the corresponding electrochemical performance. Reproduced from ref. (Lee et al. 2017) with permission | |||
| low | 8 | 72 | section_header | body_heading | body_heading | body_heading | p8:page_body:column_1_of_2:white | [255, 255, 255] white | [46.76, 442.98, 60.78, 9.61] | LiNi0.5Mn1.5O4 | LiNi0.5Mn1.5O4 | |||
| low | 9 | 76 | page_header | page_header | docling_page_header | docling_page_header | p9:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 9 | 79 | page_header | page_header | docling_page_header | docling_page_header | p9:top_margin:column_2_of_2:white | [255, 255, 255] white | [437.38, 34.25, 62.91, 7.44] | Page 9 of 40 160 | Page 9 of 40 160 | |||
| low | 9 | 81 | section_header | body_heading | body_heading | body_heading | p9:page_body:column_2_of_2:white | [255, 255, 255] white | [284.87, 380.67, 200.92, 21.22] | Fe- and Mn-based polyanion compounds as LIB cathodes | Fe- and Mn-based polyanion compounds as LIB cathodes | |||
| low | 9 | 83 | section_header | body_heading | body_heading | body_heading | p9:page_body:column_2_of_2:white | [255, 255, 255] white | [284.88, 592.42, 116.98, 8.65] | Fe- and Mn-based phosphates | Fe- and Mn-based phosphates | |||
| low | 10 | 85 | page_header | page_header | docling_page_header | docling_page_header | p10:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | |||
| low | 10 | 86 | page_header | page_header | docling_page_header | docling_page_header | p10:top_margin:column_1_of_2:white | [255, 255, 255] white | [67.64, 34.25, 46.28, 7.35] | Page 10 of 40 | Page 10 of 40 | |||
| low | 10 | 87 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p10:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 380.87, 215.56, 37.31] | Fig. 6 a Comparison of the two structural configurations in LNMO. Reproduced from ref. (Liu et al. 2012a) with permission. b Typical charge/discharge curves of LNMO with the two phases. Reproduced from ref. (Wang et al. 2011b) with permission. c , d | Fig. 6 a Comparison of the two structural configurations in LNMO. Reproduced from ref. (Liu et al. 2012a) with permission. b Typical charge/discharge curves of LNMO with the two phases. Reproduced from ref. (Wang et al. 2011b) with permission. c , d | |||
| low | 10 | 89 | page_header | page_header | docling_page_header | docling_page_header | p10:top_margin:column_2_of_2:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 10 | 90 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p10:page_body:column_2_of_2:white | [255, 255, 255] white | [284.9, 380.87, 215.49, 37.23] | Structural characteristics and electrochemical properties on the basis of our prepared samples. e , f Outstanding capacity retention achieved by using lithium phosphorus oxynitride solid electrolyte. Reproduced from ref. (Li et al. 2015b) with permission | Structural characteristics and electrochemical properties on the basis of our prepared samples. e , f Outstanding capacity retention achieved by using lithium phosphorus oxynitride solid electrolyte. Reproduced from ref. (Li et al. 2015b) with permission | |||
| low | 11 | 92 | page_header | page_header | docling_page_header | docling_page_header | p11:top_margin:left:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 11 | 93 | page_header | page_header | docling_page_header | docling_page_header | p11:top_margin:right:white | [255, 255, 255] white | [433.53, 34.25, 66.76, 7.44] | Page 11 of 40 160 | Page 11 of 40 160 | |||
| low | 11 | 94 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p11:top_margin:left:white | [255, 255, 255] white | [46.77, 54.43, 110.66, 316.15] | Fig. 7 a Crystal structure of spinel LiMn2O4. Reproduced from ref. (Chen et al. 2016) with permission. b High-rate discharge capability of LiFe 0.9P0.95O4δ . Reproduced from ref. (Kang and Ceder 2009) with permission. c Structural and electrochemical properties of a core-shell LFP nanocomposites. Reproduced from ref. (Naoi et al. 2016) with permission. d Morphology and discharge curves of LMO nanoparticles. Reproduced with permission (Hong et al. 2015). e Phase transformation diagram of LiMn0.6Fe0.4PO4 over the extraction/insertion of Li ions. Reproduced from ref. (Ravnsbæk et al. 2014) with permission. f Phase transformation strain as a function of the Mn content in LFMP, and a special case of LiMn0.2Fe0.8PO4 with no misfit strain. Reproduced from ref. (Ravnsbæk et al. 2016) with permission. g LiMn0.5Fe0.5PO4 nanocrystals with different Fe-Li antisite defects showing distinct rate performance. Reproduced from ref. (Hu et al. 2017) with permission | Fig. 7 a Crystal structure of spinel LiMn2O4. Reproduced from ref. (Chen et al. 2016) with permission. b High-rate discharge capability of LiFe 0.9P0.95O4δ . Reproduced from ref. (Kang and Ceder 2009) with permission. c Structural and electrochemical properties of a core-shell LFP nanocomposites. Reproduced from ref. (Naoi et al. 2016) with permission. d Morphology and discharge curves of LMO nanoparticles. Reproduced with permission (Hong et al. 2015). e Phase transformation diagram of LiMn0.6Fe0.4PO4 over the extraction/insertion of Li ions. Reproduced from ref. (Ravnsbæk et al. 2014) with permission. f Phase transformation strain as a function of the Mn content in LFMP, and a special case of LiMn0.2Fe0.8PO4 with no misfit strain. Reproduced from ref. (Ravnsbæk et al. 2016) with permission. g LiMn0.5Fe0.5PO4 nanocrystals with different Fe-Li antisite defects showing distinct rate performance. Reproduced from ref. (Hu et al. 2017) with permission | |||
| low | 12 | 95 | page_header | page_header | docling_page_header | docling_page_header | p12:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | |||
| low | 12 | 96 | page_header | page_header | docling_page_header | docling_page_header | p12:top_margin:column_1_of_2:white | [255, 255, 255] white | [67.64, 34.25, 46.28, 7.35] | Page 12 of 40 | Page 12 of 40 | |||
| low | 12 | 100 | page_header | page_header | docling_page_header | docling_page_header | p12:top_margin:column_2_of_2:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 12 | 103 | section_header | body_heading | body_heading | body_heading | p12:page_body:column_2_of_2:white | [255, 255, 255] white | [284.88, 604.83, 104.52, 8.65] | Fe- and Mn-based silicates | Fe- and Mn-based silicates | |||
| low | 13 | 105 | page_header | page_header | docling_page_header | docling_page_header | p13:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 13 | 108 | section_header | body_heading | body_heading | body_heading | p13:page_body:column_1_of_2:white | [255, 255, 255] white | [46.78, 604.84, 101.63, 8.65] | Fe- and Mn-based borates | Fe- and Mn-based borates | |||
| low | 13 | 110 | page_header | page_header | docling_page_header | docling_page_header | p13:top_margin:column_2_of_2:white | [255, 255, 255] white | [433.24, 34.25, 67.04, 7.44] | Page 13 of 40 160 | Page 13 of 40 160 | |||
| low | 13 | 112 | section_header | body_heading | body_heading | body_heading | p13:page_body:column_2_of_2:white | [255, 255, 255] white | [284.86, 442.98, 173.06, 8.75] | Fe- and Mn-based oxides as SIB cathodes | Fe- and Mn-based oxides as SIB cathodes | |||
| low | 14 | 114 | page_header | page_header | docling_page_header | docling_page_header | p14:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 67.14, 7.44] | 160 Page 14 of 40 | 160 Page 14 of 40 | |||
| low | 14 | 115 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p14:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 309.11, 215.54, 37.58] | Fig. 8 a , b Crystal structures of P 21/ n Li2FeSiO4 ( a ), which transforms into Pmn 21 Li2FeSiO4 ( b ). c Typical charge/discharge curves of Li2FeSiO4. Reproduced from ref. (Armstrong et al. 2011) with permission. d Structural transformation routes of | Fig. 8 a , b Crystal structures of P 21/ n Li2FeSiO4 ( a ), which transforms into Pmn 21 Li2FeSiO4 ( b ). c Typical charge/discharge curves of Li2FeSiO4. Reproduced from ref. (Armstrong et al. 2011) with permission. d Structural transformation routes of | |||
| low | 14 | 118 | section_header | body_heading | body_heading | body_heading | p14:page_body:column_1_of_2:white | [255, 255, 255] white | [46.76, 592.42, 31.87, 9.61] | NaFeO2 | NaFeO2 | |||
| low | 14 | 120 | page_header | page_header | docling_page_header | docling_page_header | p14:top_margin:column_2_of_2:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 14 | 121 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p14:page_body:column_2_of_2:white | [255, 255, 255] white | [284.88, 309.38, 215.56, 37.23] | LiFeBO3 during delithiation and degradation. Reproduced from ref. (Bo et al. 2014) with permission. e Charge/discharge profiles of mesoporous LiFeBO3/C hollow spheres. Reproduced from ref. (Chen et al. 2015) with permission | LiFeBO3 during delithiation and degradation. Reproduced from ref. (Bo et al. 2014) with permission. e Charge/discharge profiles of mesoporous LiFeBO3/C hollow spheres. Reproduced from ref. (Chen et al. 2015) with permission | |||
| low | 15 | 123 | page_header | page_header | docling_page_header | docling_page_header | p15:body_region:0 | p15:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | ||
| low | 15 | 124 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p15:body_region:0 | p15:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 54.43, 110.64, 96.98] | Fig. 9 a Structural comparison of P2-type and O3-type NaxMO2. Reproduced from ref. (Yabuuchi et al. 2012a) with permission. b Synthesis phase diagram of NaxCoO2 as a function of the Na/ Co ratio from precursors and heating temperature. Reproduced from ref. (Lei et al. 2014) with permission | Fig. 9 a Structural comparison of P2-type and O3-type NaxMO2. Reproduced from ref. (Yabuuchi et al. 2012a) with permission. b Synthesis phase diagram of NaxCoO2 as a function of the Na/ Co ratio from precursors and heating temperature. Reproduced from ref. (Lei et al. 2014) with permission | ||
| low | 15 | 128 | page_header | page_header | docling_page_header | docling_page_header | p15:top_margin:column_2_of_2:white | [255, 255, 255] white | [433.24, 34.25, 67.04, 7.44] | Page 15 of 40 160 | Page 15 of 40 160 | |||
| low | 16 | 131 | page_header | page_header | docling_page_header | docling_page_header | p16:top_margin:left:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | |||
| low | 16 | 132 | page_header | page_header | docling_page_header | docling_page_header | p16:top_margin:left:white | [255, 255, 255] white | [67.64, 34.25, 46.28, 7.35] | Page 16 of 40 | Page 16 of 40 | |||
| low | 16 | 133 | page_header | page_header | docling_page_header | docling_page_header | p16:top_margin:right:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 16 | 134 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p16:page_body:left:white | [255, 255, 255] white | [46.77, 202.0, 215.43, 27.39] | Fig. 10 a Initial charge/discharge curves of NaFeO2 on the dependence of different cut-off potentials. Reprinted from ref. (Okada et al. 2006) with permission. b Voltage profiles along | Fig. 10 a Initial charge/discharge curves of NaFeO2 on the dependence of different cut-off potentials. Reprinted from ref. (Okada et al. 2006) with permission. b Voltage profiles along | |||
| low | 16 | 136 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p16:page_body:left:white | [255, 255, 255] white | [46.77, 279.28, 110.59, 156.79] | Fig. 11 a Stability domain of the different structural types observed for as-synthesized NaxMnO2 compounds. Reproduced from ref. (Clément et al. 2015) with permission. b Schematic representations of β -NaMnO2 and an intergrowth model between α - and β -NaMnO2. Reproduced from ref. (Billaud et al. 2014a) with permission. c , d Voltage profiles of α -NaMnO2 and the complex structure. Reproduced from ref. (Ma et al. 2011), (Billaud et al. 2014a) with permissions | Fig. 11 a Stability domain of the different structural types observed for as-synthesized NaxMnO2 compounds. Reproduced from ref. (Clément et al. 2015) with permission. b Schematic representations of β -NaMnO2 and an intergrowth model between α - and β -NaMnO2. Reproduced from ref. (Billaud et al. 2014a) with permission. c , d Voltage profiles of α -NaMnO2 and the complex structure. Reproduced from ref. (Ma et al. 2011), (Billaud et al. 2014a) with permissions | |||
| low | 17 | 137 | page_header | page_header | docling_page_header | docling_page_header | p17:top_margin:left:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 17 | 138 | page_header | page_header | docling_page_header | docling_page_header | p17:top_margin:right:white | [255, 255, 255] white | [433.24, 34.25, 67.04, 7.44] | Page 17 of 40 160 | Page 17 of 40 160 | |||
| low | 17 | 141 | caption | caption | docling_caption | docling_caption | p17:page_body:right:white | [255, 255, 255] white | [284.88, 601.25, 215.47, 37.5] | Fig. 12 a , b Charge-discharge curves of o -NMO ( a ) and h -NMO ( b ). c , d Operando XRD patterns of o -NMO ( c ) and h -NMO ( d ) over initial charge/discharge curves. Reproduced from ref. (Kumakura et al. 2016) with permission | Fig. 12 a , b Charge-discharge curves of o -NMO ( a ) and h -NMO ( b ). c , d Operando XRD patterns of o -NMO ( c ) and h -NMO ( d ) over initial charge/discharge curves. Reproduced from ref. (Kumakura et al. 2016) with permission | |||
| low | 18 | 142 | page_header | page_header | docling_page_header | docling_page_header | p18:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | |||
| low | 18 | 143 | page_header | page_header | docling_page_header | docling_page_header | p18:top_margin:column_1_of_2:white | [255, 255, 255] white | [67.64, 34.25, 46.28, 7.35] | Page 18 of 40 | Page 18 of 40 | |||
| low | 18 | 144 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p18:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 54.43, 110.65, 126.91] | Fig. 13 a Schematic representation of the tunnel Na0.44MnO2. b Voltage profiles of the monocrystal Na0.44MnO2 nanoplates. c Cyclic voltammograms (CVs) of the Na0.44MnO2 electrode between 2.0 and 4.0 Vat a scanning rate of 0.1 mV s -1 . d Corresponding insitu XRD patterns over the voltage scanning. Reproduced from ref. (He et al. 2016) with permission | Fig. 13 a Schematic representation of the tunnel Na0.44MnO2. b Voltage profiles of the monocrystal Na0.44MnO2 nanoplates. c Cyclic voltammograms (CVs) of the Na0.44MnO2 electrode between 2.0 and 4.0 Vat a scanning rate of 0.1 mV s -1 . d Corresponding insitu XRD patterns over the voltage scanning. Reproduced from ref. (He et al. 2016) with permission | |||
| low | 18 | 147 | page_header | page_header | docling_page_header | docling_page_header | p18:top_margin:column_2_of_2:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 19 | 149 | page_header | page_header | docling_page_header | docling_page_header | p19:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 19 | 152 | section_header | body_heading | body_heading | body_heading | p19:page_body:column_1_of_2:white | [255, 255, 255] white | [46.78, 446.44, 199.79, 21.16] | Fe- and Mn-based polyanion compounds as SIB cathodes | Fe- and Mn-based polyanion compounds as SIB cathodes | |||
| low | 19 | 154 | caption | caption | docling_caption | docling_caption | p19:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 543.58, 110.57, 96.98] | Fig. 14 Phase evolution in Na0.67Mn0.5Fe0.5O2 and Nisubstituted Na0.67Mn0.65Ni0.15Fe0.2O2 over the first cycle, and schematic illustration of Mn/Fe migration into tetrahedral sites in the Na space at high potential. Reproduced from ref. (Talaie et al. 2015) with permission | Fig. 14 Phase evolution in Na0.67Mn0.5Fe0.5O2 and Nisubstituted Na0.67Mn0.65Ni0.15Fe0.2O2 over the first cycle, and schematic illustration of Mn/Fe migration into tetrahedral sites in the Na space at high potential. Reproduced from ref. (Talaie et al. 2015) with permission | |||
| low | 19 | 155 | page_header | page_header | docling_page_header | docling_page_header | p19:top_margin:column_2_of_2:white | [255, 255, 255] white | [433.24, 34.25, 67.04, 7.44] | Page 19 of 40 160 | Page 19 of 40 160 | |||
| low | 19 | 157 | section_header | body_heading | body_heading | body_heading | p19:page_body:column_2_of_2:white | [255, 255, 255] white | [284.88, 147.55, 114.29, 8.65] | Fe-and Mn-based phosphates | Fe-and Mn-based phosphates | |||
| low | 20 | 159 | page_header | page_header | docling_page_header | docling_page_header | p20:body_region:0 | p20:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | ||
| low | 20 | 160 | page_header | page_header | docling_page_header | docling_page_header | p20:body_region:0 | p20:top_margin:column_1_of_2:white | [255, 255, 255] white | [67.64, 34.25, 46.28, 7.35] | Page 20 of 40 | Page 20 of 40 | ||
| low | 20 | 164 | page_header | page_header | docling_page_header | docling_page_header | p20:top_margin:column_2_of_2:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 20 | 166 | section_header | body_heading | body_heading | body_heading | p20:page_body:column_2_of_2:white | [255, 255, 255] white | [284.88, 131.62, 134.79, 8.65] | Fe- and Mn-based pyrophosphates | Fe- and Mn-based pyrophosphates | |||
| low | 21 | 169 | page_header | page_header | docling_page_header | docling_page_header | p21:top_margin:left:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 21 | 170 | page_header | page_header | docling_page_header | docling_page_header | p21:top_margin:right:white | [255, 255, 255] white | [433.24, 34.25, 67.04, 7.44] | Page 21 of 40 160 | Page 21 of 40 160 | |||
| low | 21 | 171 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p21:top_margin:left:white | [255, 255, 255] white | [46.77, 52.9, 110.62, 138.37] | Fig. 15 a -e Crystal structures of olivine NFP, maricite NFP, NASICON-type Na3Fe2(PO4)3, layered Na3Fe3(PO4)4, alluauditetype Na2Fe3(PO4)3. Reproduced from ref. (Naoaki and Shinichi 2014) with permission. Their typical charge/discharge curves are shown on the right side. Reproduced from ref. (Ali et al. 2016), (Kim et al. 2015b), (Trad et al. 2010b), (Huang et al. 2015b), and (Liu et al. 2017b) with permissions | Fig. 15 a -e Crystal structures of olivine NFP, maricite NFP, NASICON-type Na3Fe2(PO4)3, layered Na3Fe3(PO4)4, alluauditetype Na2Fe3(PO4)3. Reproduced from ref. (Naoaki and Shinichi 2014) with permission. Their typical charge/discharge curves are shown on the right side. Reproduced from ref. (Ali et al. 2016), (Kim et al. 2015b), (Trad et al. 2010b), (Huang et al. 2015b), and (Liu et al. 2017b) with permissions | |||
| low | 22 | 172 | page_header | page_header | docling_page_header | docling_page_header | p22:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | |||
| low | 22 | 173 | page_header | page_header | docling_page_header | docling_page_header | p22:top_margin:column_1_of_2:white | [255, 255, 255] white | [67.64, 34.25, 46.28, 7.35] | Page 22 of 40 | Page 22 of 40 | |||
| low | 22 | 177 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p22:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 624.25, 215.51, 38.76] | Fig. 16 a -c Triclinic structure ( P -1) of Na2FeP2O7 and corresponding electrochemical properties. Reproduced from ref. (Barpanda et al. 2012) with permission. d Voltage profiles of P -1 Na2MnP2O7. Reproduced from ref. (Park et al. 2013) with | Fig. 16 a -c Triclinic structure ( P -1) of Na2FeP2O7 and corresponding electrochemical properties. Reproduced from ref. (Barpanda et al. 2012) with permission. d Voltage profiles of P -1 Na2MnP2O7. Reproduced from ref. (Park et al. 2013) with | |||
| low | 22 | 178 | page_header | page_header | docling_page_header | docling_page_header | p22:top_margin:column_2_of_2:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 22 | 182 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p22:page_body:column_2_of_2:white | [255, 255, 255] white | [284.88, 623.9, 215.53, 29.14] | permission. e , f Crystal structure of β -Na2MnP2O7 (triclinic P 1) and its voltage profiles. Reproduced from ref. (Barpanda et al. 2013b) with permission | permission. e , f Crystal structure of β -Na2MnP2O7 (triclinic P 1) and its voltage profiles. Reproduced from ref. (Barpanda et al. 2013b) with permission | |||
| low | 23 | 183 | page_header | page_header | docling_page_header | docling_page_header | p23:top_margin:left:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 23 | 184 | page_header | page_header | docling_page_header | docling_page_header | p23:top_margin:right:white | [255, 255, 255] white | [433.24, 34.25, 67.04, 7.44] | Page 23 of 40 160 | Page 23 of 40 160 | |||
| low | 23 | 185 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p23:page_body:left:white | [255, 255, 255] white | [46.77, 629.3, 215.52, 27.31] | Fig. 17 Crystal structures of alluaudite-type Na2Fe2(SO4)3 ( a ), eldfellite NaFe(SO4)2 ( b ), Na2Fe2(C2O4)3·2H2O ( c ), and Na2Fe(C2O4)F2 with their voltage profiles are shown on the right | Fig. 17 Crystal structures of alluaudite-type Na2Fe2(SO4)3 ( a ), eldfellite NaFe(SO4)2 ( b ), Na2Fe2(C2O4)3·2H2O ( c ), and Na2Fe(C2O4)F2 with their voltage profiles are shown on the right | |||
| low | 23 | 186 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p23:page_body:right:white | [255, 255, 255] white | [284.88, 629.29, 215.45, 17.33] | side. Reproduced from ref. (Barpanda et al. 2014b), (Singh et al. 2015), (Yao et al. 2017b), and (Yao et al. 2017a) with permissions | side. Reproduced from ref. (Barpanda et al. 2014b), (Singh et al. 2015), (Yao et al. 2017b), and (Yao et al. 2017a) with permissions | |||
| low | 24 | 187 | page_header | page_header | docling_page_header | docling_page_header | p24:top_margin:left:white | [255, 255, 255] white | [46.77, 34.25, 67.14, 7.44] | 160 Page 24 of 40 | 160 Page 24 of 40 | |||
| low | 24 | 188 | page_header | page_header | docling_page_header | docling_page_header | p24:top_margin:right:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 24 | 189 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p24:top_margin:left:white | [255, 255, 255] white | [46.77, 52.9, 110.66, 178.23] | Fig. 18 a -d Crystal structures of Na2FePO4F ( a ), Na2MnPO4F ( b ), Na4Fe3(PO4)2(P2O7) ( c ), and Na3MnPO4CO3 ( d ). Reproduced from ref. (Naoaki and Shinichi 2014) with permission. Their representative voltage profiles are shown on the right side. Reproduced from ref. (Law et al. 2015), (Lin et al. 2014), (Wu et al. 2016), and (Huang et al. 2014) with permissions. e Highperformance Na4Mn3(PO4)2(P2O7), which was ascribed to the cooperative JahnTeller effect of Mn 3+ . Reproduced from ref. (Kim et al. 2015a) with permission | Fig. 18 a -d Crystal structures of Na2FePO4F ( a ), Na2MnPO4F ( b ), Na4Fe3(PO4)2(P2O7) ( c ), and Na3MnPO4CO3 ( d ). Reproduced from ref. (Naoaki and Shinichi 2014) with permission. Their representative voltage profiles are shown on the right side. Reproduced from ref. (Law et al. 2015), (Lin et al. 2014), (Wu et al. 2016), and (Huang et al. 2014) with permissions. e Highperformance Na4Mn3(PO4)2(P2O7), which was ascribed to the cooperative JahnTeller effect of Mn 3+ . Reproduced from ref. (Kim et al. 2015a) with permission | |||
| low | 25 | 190 | page_header | page_header | docling_page_header | docling_page_header | p25:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 25 | 191 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p25:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 387.39, 215.52, 37.23] | Fig. 19 a Crystal structure of PBAs with a face-centered cubic phase. b Charge and discharge curves of Na2MnMn(CN)6. c , d The schematic illustrations of the step-wise structural evolution over the extraction/insertion of Na + ions. Reproduced from ref. | Fig. 19 a Crystal structure of PBAs with a face-centered cubic phase. b Charge and discharge curves of Na2MnMn(CN)6. c , d The schematic illustrations of the step-wise structural evolution over the extraction/insertion of Na + ions. Reproduced from ref. | |||
| low | 25 | 193 | page_header | page_header | docling_page_header | docling_page_header | p25:top_margin:column_2_of_2:white | [255, 255, 255] white | [433.24, 34.25, 67.04, 7.44] | Page 25 of 40 160 | Page 25 of 40 160 | |||
| low | 25 | 194 | caption | caption | docling_caption | docling_caption | p25:page_body:column_2_of_2:white | [255, 255, 255] white | [284.88, 387.39, 215.51, 27.25] | (Lee et al. 2014) with permission. e , f Voltage profile and cycling performance of a Prussian blue@C composite. Reproduced from ref. (Jiang et al. 2016) with permission | (Lee et al. 2014) with permission. e , f Voltage profile and cycling performance of a Prussian blue@C composite. Reproduced from ref. (Jiang et al. 2016) with permission | |||
| low | 26 | 198 | page_header | page_header | docling_page_header | docling_page_header | p26:body_region:0 | p26:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | ||
| low | 26 | 199 | page_header | page_header | docling_page_header | docling_page_header | p26:body_region:0 | p26:top_margin:column_1_of_2:white | [255, 255, 255] white | [67.64, 34.25, 46.28, 7.35] | Page 26 of 40 | Page 26 of 40 | ||
| low | 26 | 203 | page_header | page_header | docling_page_header | docling_page_header | p26:top_margin:column_2_of_2:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 26 | 206 | section_header | body_heading | body_heading | body_heading | p26:page_body:column_2_of_2:white | [255, 255, 255] white | [284.88, 579.95, 161.55, 8.75] | Fe- and Mn-based hexacyanometalates | Fe- and Mn-based hexacyanometalates | |||
| low | 27 | 208 | page_header | page_header | docling_page_header | docling_page_header | p27:top_margin:left:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 27 | 209 | page_header | page_header | docling_page_header | docling_page_header | p27:top_margin:right:white | [255, 255, 255] white | [433.24, 34.25, 67.04, 7.44] | Page 27 of 40 160 | Page 27 of 40 160 | |||
| low | 27 | 211 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p27:page_body:right:white | [255, 255, 255] white | [287.89, 333.72, 7.44, 327.83] | Table 1 Electrochemical properties of representative Fe- and Mn-based cathode materials for LIBs | Table 1 Electrochemical properties of representative Fe- and Mn-based cathode materials for LIBs | |||
| low | 28 | 212 | page_header | page_header | docling_page_header | docling_page_header | p28:top_margin:left:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | |||
| low | 28 | 213 | page_header | page_header | docling_page_header | docling_page_header | p28:top_margin:left:white | [255, 255, 255] white | [67.64, 34.25, 46.28, 7.35] | Page 28 of 40 | Page 28 of 40 | |||
| low | 28 | 214 | page_header | page_header | docling_page_header | docling_page_header | p28:top_margin:right:white | [255, 255, 255] white | [398.16, 34.25, 102.12, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | |||
| low | 28 | 215 | caption | caption | docling_caption | docling_caption | p28:page_body:left:white | [255, 255, 255] white | [152.79, 333.85, 7.44, 327.41] | Table 2 Electrochemical properties of representative Fe- and Mn-based cathode materials for SIBs | Table 2 Electrochemical properties of representative Fe- and Mn-based cathode materials for SIBs | |||
| low | 29 | 216 | page_header | page_header | docling_page_header | docling_page_header | p29:body_region:0 | p29:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 102.17, 7.35] | J Nanopart Res (2018) 20: 160 | J Nanopart Res (2018) 20: 160 | ||
| low | 29 | 217 | caption | caption | outside_body_flow_caption | outside_body_flow_caption | p29:body_region:0 | p29:front_matter:column_1_of_2:white | [255, 255, 255] white | [46.77, 213.91, 378.27, 7.44] | Fig. 20 Illustration of the energy densities of those Fe- and Mn-based cathode materials for LIBs ( a ) and SIBs ( b ) | Fig. 20 Illustration of the energy densities of those Fe- and Mn-based cathode materials for LIBs ( a ) and SIBs ( b ) | ||
| low | 29 | 219 | section_header | body_heading | body_heading | body_heading | p29:body_region:0 | p29:body_zone:column_1_of_2:white | [255, 255, 255] white | [46.77, 293.54, 93.5, 8.75] | Summary and outlook | Summary and outlook | ||
| low | 29 | 222 | page_header | page_header | docling_page_header | docling_page_header | p29:top_margin:column_2_of_2:white | [255, 255, 255] white | [433.24, 34.25, 67.04, 7.44] | Page 29 of 40 160 | Page 29 of 40 160 | |||
| low | 30 | 228 | page_header | page_header | docling_page_header | docling_page_header | p30:body_region:0 | p30:top_margin:column_1_of_2:white | [255, 255, 255] white | [46.77, 34.25, 12.51, 7.44] | 160 | 160 | ||
| low | 30 | 229 | page_header | page_header | docling_page_header | docling_page_header | p30:body_region:0 | p30:top_margin:column_1_of_2:white | [255, 255, 255] white | [67.64, 34.25, 46.28, 7.35] | Page 30 of 40 | Page 30 of 40 | ||
| low | 30 | 231 | text | back_matter_heading | back_matter_heading | back_matter_heading | stop_trigger | p30:body_region:0 | p30:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 468.74, 215.52, 17.28] | Acknowledgments Funding support from ARC through its LP and DP programs is acknowledged. | Acknowledgments Funding support from ARC through its LP and DP programs is acknowledged. | |
| low | 30 | 232 | section_header | unknown_text | after_back_matter_stop | after_back_matter_stop | after_stop | p30:body_region:0 | p30:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 501.12, 121.83, 7.44] | Compliance with ethical standards | Compliance with ethical standards | |
| low | 30 | 233 | text | back_matter_heading | after_back_matter_stop | after_back_matter_stop | after_stop | p30:body_region:0 | p30:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 523.51, 215.49, 17.33] | Conflict of interest The authors declare that they have no conflict of interest. | Conflict of interest The authors declare that they have no conflict of interest. | |
| low | 30 | 234 | section_header | back_matter_heading | after_back_matter_stop | after_back_matter_stop | after_stop | p30:body_region:0 | p30:page_body:column_1_of_2:white | [255, 255, 255] white | [46.77, 564.25, 44.94, 8.75] | References | References | |
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