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这里对齐真实图表资产提取链路。caption_source=embedded_table_cell 表示表注来自 Docling table cell，不会出现在 text block 审计差集里；caption_continuation_used_by_asset 表示某个 text block 已被图表 caption 吸收，不应按普通 metadata 解读。
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| 1 | figure | Fig. 1 | 4 | direct_caption_ref | 0.82 | [63.24, 67.99, 464.49, 611.84] | Fig. 1. (a) The synthetic procedure of Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO. XRD patterns of (b) (Ov-)BDC-LMO, (e) (Ov-)BTC-LMO, and (h) (Ov-)PTC-LMO. Rietveld refinements of (c) Ov-BDC-LMO, (d) BDC-LMO, (f) Ov-BTC-LMO, (g) BTC-LMO, (i) Ov-PTC-LMO, and (j) PTC-LMO. | ||||
| 2 | figure | Fig. 2 | 5 | direct_caption_ref | 0.82 | [64.74, 67.28, 458.61, 497.73] | Fig. 2. (a-c) The panoramic Raman spectra and the high-resolution XPS spectra of (d-f) Li 1 s , (g-i) O 1 s , and (j-l) Mn 2 p for (Ov-)BDC-LMO, (Ov-)BTC-LMO, and (Ov-)PTC-LMO, respectively. | ||||
| 3 | figure | Fig. 3 | 7 | direct_caption_ref | 0.82 | [91.16, 67.23, 411.67, 365.11] | Fig. 3. The SEM images of (a) Mn-BDC, (b) BDC-LMO, (c) Ov-BDC-LMO, (d) Mn-BTC, (e) BTC-LMO, (f) Ov-BTC-LMO, (g) Mn-PTC, (h) PTC-LMO, and (i) Ov-PTC-LMO. | ||||
| 4 | figure | Fig. 4 | 8 | direct_caption_ref | 0.82 | [75.92, 67.43, 441.0, 526.81] | Fig. 4. (a-f) TEM images, (g-l) HRTEM images, (m-r) SAED patterns, and (s-x) HAADF-STEM images and corresponding element mappings of BDC-LMO, BTC-LMO, PTC-LMO, Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO, respectively. | ||||
| 5 | figure | Fig. 5 | 9 | direct_caption_ref | 0.82 | [81.59, 67.07, 427.64, 552.57] | Fig. 5. (a-f) Spherical aberration-corrected HAADF-STEM and (g-l) spherical aberration-corrected ABF-STEM images for BDC-LMO, BTC-LMO, PTC-LMO, Ov-BDC-LMO, OvBTC-LMO, and Ov-PTC-LMO, respectively. | ||||
| 6 | figure | Fig. 6 | 10 | direct_caption_ref | 0.82 | [66.89, 66.56, 463.86, 455.48] | Fig. 6. The cycling performance at 20 mA g 1 for 200 loops of (a) (Ov-)BDC-LMO, (b) (Ov-)BTC-LMO, and (c) (Ov-)PTC-LMO. The rate performance at 0.1, 0.2, 0.4, 1, and 2 C (1 C = 200 mA g 1 ) of (d) (Ov-)BDC-LMO, (e) (Ov-)BTC-LMO, and (f) (Ov-)PTC-LMO. The GCD profiles at the 1st, 25th, 50th, and 100th cycle during the cycling test at 20 mA g 1 of (g) Ov-BDC-LMO, (h) Ov-BTC-LMO, and (i) Ov-PTC-LMO. Nyquist plots after 100 cycles at 20 mA g 1 for (j) (Ov-)BDC-LMO, (k) (Ov-)BTC-LMO, and (l) (Ov-)PTC-LMO. | ||||
| 7 | figure | Fig. 7 | 12 | direct_caption_ref | 0.82 | [52.12, 64.94, 489.3, 641.51] | Fig. 7. The CV curves for the first 3 cycles at 0.2 mV s 1 for (a) Ov-BDC-LMO, (b) Ov-BTC-LMO, (c) Ov-PTC-LMO, (d) BDC-LMO, (e) BTC-LMO, and (f) PTC-LMO. The schematic illustrations of the first cycle for (g) Ov-LMO and (h) LMO. The separation of the pseudocapacitive contribution at 0.4 mV s 1 for (i) Ov-BDC-LMO, (j) Ov-BTC-LMO, and (k) OvPTC-LMO. The pseudocapacitive contribution ratios at 0.2-1.0 mV s 1 for (l) Ov-BDC-LMO, (m) Ov-BTC-LMO, and (n) Ov-PTC-LMO. | ||||
| 8 | figure | Fig. 8 | 14 | direct_caption_ref | 0.82 | [59.85, 67.15, 477.24, 498.47] | Fig. 8. The single-step profiles of GITT titration during the charging process for (a) Ov-BDC-LMO, (b) Ov-BTC-LMO, and (c) Ov-PTC-LMO. The GITT curves of (d) Ov-BDC-LMO, (e) Ov-BTC-LMO, and (f) Ov-PTC-LMO. (g) The calculated Li + diffusion coefficients upon charging for all samples. (h) The schematic illustration of the mechanism of boosted lithium diffusion for Ov-LMO samples. (i) Ex situ XRD patterns at different cycling states (before cycling, after 50 cycles, and after 100 cycles) and (j) Ex situ high-resolution XPS spectra at different charge/discharge states (before charging, charge to 4.7 V, and discharge to 2.5 V) of Mn 2 p for Ov-BDC-LMO during the initial cycle. | ||||
| 9 | figure | Fig. 9 | 15 | direct_caption_ref | 0.82 | [94.16, 67.03, 402.91, 638.37] | Fig. 9. The optimized models of (a) LMO and (b) Ov-LMO. (c) The 3D differential charge density distribution of Ov-LMO. (d) The TDOS curves of LMO and Ov-LMO. The PDOS curves of (e) LMO and (f) Ov-LMO. The energy barriers during delithiation for (g) LMO and (h) Ov-LMO. The lithium vacancy migration paths and corresponding energy barrier curves for (i) LMO and (j) Ov-LMO. |
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| 1 | 12 | text | metadata | False | low | first_page_metadata | first_page_metadata | p1:front_matter:column_1_of_3:white | [255, 255, 255] white | False | [37.59, 395.91, 91.28, 5.93] | Available online 26 May 2023 | Available online 26 May 2023 | |||
| 1 | 13 | text | front_matter_heading | False | low | front_matter_heading | front_matter_heading | p1:front_matter:column_1_of_3:white | [255, 255, 255] white | False | [37.59, 415.97, 77.77, 48.79] | Keywords: Li2MnO3 Metal-organic framework Oxygen vacancy Lithium-ion battery Electrochemical activity | Keywords: Li2MnO3 Metal-organic framework Oxygen vacancy Lithium-ion battery Electrochemical activity | |||
| 1 | 14 | text | front_matter_candidate | False | low | first_page_summary | first_page_summary | p1:body_region:0 | p1:front_matter:column_2_of_3:white | [255, 255, 255] white | False | [202.17, 362.1, 355.49, 169.21] | Despite the dazzling theoretical capacity, the devasting electrochemical activity of Li2MnO3 (LMO) caused by the difficult oxidation of Mn 4+ impedes its practical application as the lithium-ion battery (LIB) cathode. T… | Despite the dazzling theoretical capacity, the devasting electrochemical activity of Li2MnO3 (LMO) caused by the difficult oxidation of Mn 4+ impedes its practical application as the lithium-ion battery (LIB) cathode. T… | ||
| 1 | 15 | text | metadata | False | low | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:front_matter:column_2_of_3:white | [255, 255, 255] white | False | [202.17, 532.25, 355.42, 18.23] | Ó 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved. | Ó 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. | ||
| 1 | 16 | section_header | body_heading | False | low | body_heading | body_heading | p1:body_zone:column_1_of_3:white | [255, 255, 255] white | False | [37.7, 605.71, 60.13, 7.96] | 1. Introduction | 1. Introduction | |||
| 1 | 17 | text | body | True | body | body | p1:body_zone:column_1_of_3:white | [255, 255, 255] white | False | [37.59, 627.06, 251.11, 49.26] | Lithium-ion batteries (LIBs) have become indispensable electrochemical energy storage and conversion devices due to their remarkable power density, satisfying cyclability, negligible memory effect, and environmental fri… | Lithium-ion batteries (LIBs) have become indispensable electrochemical energy storage and conversion devices due to their remarkable power density, satisfying cyclability, negligible memory effect, and environmental fri… | ||||
| 1 | 18 | footnote | footnote | False | low | first_page_metadata | first_page_metadata | p1:body_zone:column_1_of_3:white | [255, 255, 255] white | False | [42.07, 692.51, 78.23, 13.76] | ⇑ Corresponding authors. | ⇑ Corresponding authors. | |||
| 1 | 19 | footnote | footnote | False | low | first_page_metadata | first_page_metadata | p1:body_zone:column_1_of_3:off_white | [247, 250, 251] off_white | False | [48.81, 705.11, 220.95, 5.93] | E-mail addresses: linxm@scnu.edu.cn (X. Lin), caiyp@scnu.edu.cn (Y. Cai). | E-mail addresses: linxm@scnu.edu.cn (X. Lin), caiyp@scnu.edu.cn (Y. Cai). | |||
| 1 | 20 | footnote | footnote | False | low | docling_footnote | docling_footnote | p1:body_zone:column_1_of_3:white | [255, 255, 255] white | False | [43.09, 712.68, 148.31, 7.21] | 1 These authors contributed equally to this work. | 1 These authors contributed equally to this work. | |||
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| 1 | 23 | text | body | True | body | body | p1:body_region:0 | p1:front_matter:column_3_of_3:white | [255, 255, 255] white | False | [306.6, 597.64, 251.08, 91.09] | [1]. Nevertheless, the development of the next-generation LIBs is bottlenecked by the dissatisfying electrochemical properties of the prevailing electrode materials. Following this, the exploration of high-performance c… | [1]. Nevertheless, the development of the next-generation LIBs is bottlenecked by the dissatisfying electrochemical properties of the prevailing electrode materials. Following this, the exploration of high-performance c… | |||
| 1 | 24 | text | body | True | body | body | p1:body_region:0 | p1:body_zone:column_3_of_3:white | [255, 255, 255] white | False | [306.6, 691.8, 251.07, 29.12] | Owing to the enticing theoretical capacities that can better meet the future requirements of battery endurance, Li-rich layered materials have been extensively studied. Among them, Li2MnO3 | Owing to the enticing theoretical capacities that can better meet the future requirements of battery endurance, Li-rich layered materials have been extensively studied. Among them, Li2MnO3 | |||
| 1 | 25 | page_footer | page_footer | False | low | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:bottom_margin:column_1_of_3:white | [255, 255, 255] white | False | [37.59, 738.73, 520.05, 8.3] | 2095-4956/ Ó 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved. | 2095-4956/ Ó 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. | ||
| 2 | 26 | page_header | page_header | False | low | docling_page_header | docling_page_header | p2:body_region:0 | p2:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 2 | 27 | text | body | True | body | body | p2:body_region:0 | p2:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 67.96, 251.14, 237.53] | (LMO) has been regarded as a promising alternative for the mercantile LIB cathode materials such as LiCoO2 (LCO), Li[Ni x Co yMn1 x y ]O2 (NCM), and LiFePO4 (LFP) due to its superiority in theoretical capacity (460,… | (LMO) has been regarded as a promising alternative for the mercantile LIB cathode materials such as LiCoO2 (LCO), Li[Ni x Co yMn1 x y ]O2 (NCM), and LiFePO4 (LFP) due to its superiority in theoretical capacity (460,… | |||
| 2 | 28 | text | body | True | body | body | p2:body_region:0 | p2:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 308.56, 251.13, 279.37] | It is widely substantiated and acknowledged that morphological features are crucial metrics in LIB electrode design and can be facilely adjusted by synthetic routes. The morphologyperformance relationship has been exten… | It is widely substantiated and acknowledged that morphological features are crucial metrics in LIB electrode design and can be facilely adjusted by synthetic routes. The morphologyperformance relationship has been exten… | |||
| 2 | 29 | text | body | True | body | body | p2:body_region:0 | p2:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 591.0, 251.13, 164.29] | Apart from morphology control, the atomic structure and electronic configuration can significantly tune the electrochemical behaviors of LMO materials. Pristine LMO is confronted with the intrinsic undesirable electroch… | Apart from morphology control, the atomic structure and electronic configuration can significantly tune the electrochemical behaviors of LMO materials. Pristine LMO is confronted with the intrinsic undesirable electroch… | |||
| 2 | 30 | page_header | page_header | False | low | docling_page_header | docling_page_header | p2:body_region:1 | p2:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.77, 48.15, 139.86, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 2 | 31 | text | body | True | body | body | p2:body_region:1 | p2:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 67.95, 251.09, 70.18] | space, and suppressed oxygen shearing leading to detrimental structural change, the as-reported oxygen vacancy-enriched LMO materials display expected superiority in lithium storage with superior reversible capacity, pr… | space, and suppressed oxygen shearing leading to detrimental structural change, the as-reported oxygen vacancy-enriched LMO materials display expected superiority in lithium storage with superior reversible capacity, pr… | |||
| 2 | 32 | text | body | True | body | body | p2:body_region:1 | p2:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 141.14, 251.12, 258.51] | Inspired by these research advances, we systematically develop a multifunctional synthetic protocol to integrate the MOFtemplated method and oxygen-deficient strategy for optimizing morphological and atomic structure. T… | Inspired by these research advances, we systematically develop a multifunctional synthetic protocol to integrate the MOFtemplated method and oxygen-deficient strategy for optimizing morphological and atomic structure. T… | |||
| 2 | 33 | section_header | body_heading | False | low | body_heading | body_heading | p2:body_region:1 | p2:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.65, 433.65, 62.99, 7.96] | 2. Experimental | 2. Experimental | ||
| 2 | 34 | section_header | body_heading | False | low | body_heading | body_heading | p2:body_region:1 | p2:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.65, 455.0, 90.87, 7.42] | 2.1. Material preparation | 2.1. Material preparation | ||
| 2 | 35 | text | body | True | body | body | p2:body_region:1 | p2:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 475.92, 251.09, 174.78] | The Mn-MOFs with carboxyl-based ligands were prepared by solvothermal reactions according to the previous study [22,23]. Mn(CH3COO)2 4H2O (1 mmol) was dissolved in 6 mL of N,N -dimethylformamide (DMF)/methanol ( V D: … | The Mn-MOFs with carboxyl-based ligands were prepared by solvothermal reactions according to the previous study [22,23]. Mn(CH3COO)2 4H2O (1 mmol) was dissolved in 6 mL of N,N -dimethylformamide (DMF)/methanol ( V D: … | |||
| 2 | 36 | text | body | True | body | body | p2:body_region:1 | p2:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 653.76, 251.1, 102.29] | The LMO materials without oxygen vacancy were fabricated via pyrolysis of the Mn-MOF templates with Li2CO3 as the Li source with a molar ratio of Li: Mn = 2.05:1. The dried MOFs were mixed with Li2CO3 by ball-milling an… | The LMO materials without oxygen vacancy were fabricated via pyrolysis of the Mn-MOF templates with Li2CO3 as the Li source with a molar ratio of Li: Mn = 2.05:1. The dried MOFs were mixed with Li2CO3 by ball-milling an… | |||
| 2 | 37 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p2:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 165 | 165 | |||
| 3 | 38 | page_header | page_header | False | low | docling_page_header | docling_page_header | p3:body_region:0 | p3:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 3 | 39 | text | body | True | body | body | p3:body_region:0 | p3:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 67.96, 251.06, 17.85] | 8 h after mixing with stearic acid with a molar ratio of 20:1 in N2 according to the prior report [21]. | 8 h after mixing with stearic acid with a molar ratio of 20:1 in N2 according to the prior report [21]. | |||
| 3 | 40 | section_header | body_heading | False | low | body_heading | body_heading | p3:body_region:0 | p3:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [37.7, 99.31, 106.87, 7.42] | 2.2. Material characterization | 2.2. Material characterization | ||
| 3 | 41 | text | body | True | body | body | p3:body_region:0 | p3:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 120.23, 251.1, 227.1] | The crystallographic data and phase analyses of the Mn-MOFs and LMO materials were implemented with an X-ray diffraction spectrophotometer (XRD, Ultima IV, Japan) using Cu K a radiation with a scanning rate of 10 ° min … | The crystallographic data and phase analyses of the Mn-MOFs and LMO materials were implemented with an X-ray diffraction spectrophotometer (XRD, Ultima IV, Japan) using Cu K a radiation with a scanning rate of 10 ° min … | |||
| 3 | 42 | section_header | body_heading | False | low | body_heading | body_heading | p3:body_region:0 | p3:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [37.7, 360.83, 123.51, 7.42] | 2.3. Electrochemical measurement | 2.3. Electrochemical measurement | ||
| 3 | 43 | text | body | True | body | body | p3:body_region:0 | p3:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 381.75, 251.13, 310.78] | Electrochemical measurements of LMO were investigated using CR2032 coin cells. The cathode electrodes were prepared by using as-prepared LMO, acetylene black, and polyvinylidene fluoride (PVDF) with a weight ratio of 7:… | Electrochemical measurements of LMO were investigated using CR2032 coin cells. The cathode electrodes were prepared by using as-prepared LMO, acetylene black, and polyvinylidene fluoride (PVDF) with a weight ratio of 7:… | |||
| 3 | 44 | section_header | body_heading | False | low | body_heading | body_heading | p3:body_region:0 | p3:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [37.7, 706.04, 77.39, 7.42] | 2.4. Theoretical study | 2.4. Theoretical study | ||
| 3 | 45 | text | body | True | body | body | p3:body_region:0 | p3:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 726.95, 251.1, 28.34] | All the spin-polarized (AFM) density functional theoretical (DFT) calculations were conducted based on the Vienna Ab-inito Simulation Package (VASP) [24]. The electron-ion interactions were | All the spin-polarized (AFM) density functional theoretical (DFT) calculations were conducted based on the Vienna Ab-inito Simulation Package (VASP) [24]. The electron-ion interactions were | |||
| 3 | 46 | page_header | page_header | False | low | docling_page_header | docling_page_header | p3:body_region:1 | p3:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.71, 48.21, 139.91, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 3 | 47 | text | body | True | body | body | p3:body_region:1 | p3:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 67.95, 251.09, 132.94] | described by the Projected Augmented-Wave (PAW) potentials, while the exchange-correlation interactions were calculated by employing the Perdew-Burke-Enzerhof (PBE) pseudopotentials of Generalized Gradient Approximation… | described by the Projected Augmented-Wave (PAW) potentials, while the exchange-correlation interactions were calculated by employing the Perdew-Burke-Enzerhof (PBE) pseudopotentials of Generalized Gradient Approximation… | |||
| 3 | 48 | section_header | body_heading | False | low | body_heading | body_heading | p3:body_region:1 | p3:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.65, 213.96, 99.65, 7.96] | 3. Results and discussion | 3. Results and discussion | ||
| 3 | 49 | section_header | body_heading | False | low | body_heading | body_heading | p3:body_region:1 | p3:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.65, 235.31, 160.25, 7.42] | 3.1. Structural and morphological properties | 3.1. Structural and morphological properties | ||
| 3 | 50 | text | body | True | body | body | p3:body_region:1 | p3:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 256.23, 251.09, 133.7] | The synthetic procedure of Ov-LMO materials via solvothermal reaction, solid-state lithiation at high temperature, and lowtemperature reduction is schematically illustrated in Fig. 1(a). The high phase purity and crysta… | The synthetic procedure of Ov-LMO materials via solvothermal reaction, solid-state lithiation at high temperature, and lowtemperature reduction is schematically illustrated in Fig. 1(a). The high phase purity and crysta… | |||
| 3 | 51 | text | body | True | body | body | p3:body_region:1 | p3:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 392.24, 251.09, 331.7] | Powder XRD characterization was utilized to estimate the crystallographic configuration of LMO and Ov-LMO derived from MnBDC, Mn-BTC, and Mn-PTC. The XRD patterns of (Ov-)BDC-LMO (Fig. 1b), (Ov-)BTC-LMO (Fig. 1e), and (… | Powder XRD characterization was utilized to estimate the crystallographic configuration of LMO and Ov-LMO derived from MnBDC, Mn-BTC, and Mn-PTC. The XRD patterns of (Ov-)BDC-LMO (Fig. 1b), (Ov-)BTC-LMO (Fig. 1e), and (… | |||
| 3 | 52 | text | body | True | body | body | p3:body_region:1 | p3:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 726.95, 251.09, 28.34] | The Raman spectra were conducted to evaluate and compare the structural characteristics of LMO and Ov-LMO. As delivered in Fig. 2(a-c), the strong characteristic peaks at the high-frequency | The Raman spectra were conducted to evaluate and compare the structural characteristics of LMO and Ov-LMO. As delivered in Fig. 2(a-c), the strong characteristic peaks at the high-frequency | |||
| 3 | 53 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p3:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 166 | 166 | |||
| 4 | 54 | page_header | page_header | False | low | docling_page_header | docling_page_header | p4:top_margin:left:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | |||
| 4 | 55 | page_header | page_header | False | low | docling_page_header | docling_page_header | p4:top_margin:right:white | [255, 255, 255] white | False | [417.77, 48.15, 139.86, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | |||
| 4 | 56 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p4:page_body:full:white | [255, 255, 255] white | False | [37.59, 689.57, 520.05, 14.84] | Fig. 1. (a) The synthetic procedure of Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO. XRD patterns of (b) (Ov-)BDC-LMO, (e) (Ov-)BTC-LMO, and (h) (Ov-)PTC-LMO. Rietveld refinements of (c) Ov-BDC-LMO, (d) BDC-LMO, (f) Ov-BTC-LM… | Fig. 1. (a) The synthetic procedure of Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO. XRD patterns of (b) (Ov-)BDC-LMO, (e) (Ov-)BTC-LMO, and (h) (Ov-)PTC-LMO. Rietveld refinements of (c) Ov-BDC-LMO, (d) BDC-LMO, (f) Ov-BTC-LM… | |||
| 4 | 57 | text | body | True | body | body | p4:bottom_margin:left_crossing:white | [255, 255, 255] white | False | [37.59, 725.88, 251.09, 28.34] | region and the ones at the low-frequency region are related to the Mn A O and Li A O bonds, respectively, manifesting the high purity of all samples [20]. The Raman peak intensities of Ov-LMO are pro- | region and the ones at the low-frequency region are related to the Mn A O and Li A O bonds, respectively, manifesting the high purity of all samples [20]. The Raman peak intensities of Ov-LMO are pro- | ||||
| 4 | 58 | text | body | True | body | body | p4:bottom_margin:right_crossing:white | [255, 255, 255] white | False | [306.59, 725.88, 251.07, 28.34] | foundly lower than those of LMO, which can be ascribed to the enhanced conductivity caused by the oxygen vacancies [33]. Notably, the Raman peak intensity ratios of the characteristic peaks | foundly lower than those of LMO, which can be ascribed to the enhanced conductivity caused by the oxygen vacancies [33]. Notably, the Raman peak intensity ratios of the characteristic peaks | ||||
| 4 | 59 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p4:bottom_margin:left_crossing:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 167 | 167 | |||
| 5 | 60 | page_header | page_header | False | low | docling_page_header | docling_page_header | p5:body_region:0 | p5:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 5 | 61 | page_header | page_header | False | low | docling_page_header | docling_page_header | p5:body_region:1 | p5:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.71, 48.21, 139.91, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 5 | 62 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p5:page_body:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 576.81, 520.03, 14.84] | Fig. 2. (a-c) The panoramic Raman spectra and the high-resolution XPS spectra of (d-f) Li 1 s , (g-i) O 1 s , and (j-l) Mn 2 p for (Ov-)BDC-LMO, (Ov-)BTC-LMO, and (Ov-)PTC-LMO, respectively. | Fig. 2. (a-c) The panoramic Raman spectra and the high-resolution XPS spectra of (d-f) Li 1 s , (g-i) O 1 s , and (j-l) Mn 2 p for (Ov-)BDC-LMO, (Ov-)BTC-LMO, and (Ov-)PTC-LMO, respectively. | |||
| 5 | 63 | text | body | True | body | body | p5:body_region:0 | p5:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 611.37, 251.13, 134.68] | centered at 610 and 500 cm 1 increase with the existence of oxygen vacancies (1.34, 1.67, 1.35, 1.54, 1.29, and 1.52 for BDCLMO, Ov-BDC-LMO, BTC-LMO, Ov-BTC-LMO, PTC-LMO, and Ov-PTC-LMO, respectively), among which… | centered at 610 and 500 cm 1 increase with the existence of oxygen vacancies (1.34, 1.67, 1.35, 1.54, 1.29, and 1.52 for BDCLMO, Ov-BDC-LMO, BTC-LMO, Ov-BTC-LMO, PTC-LMO, and Ov-PTC-LMO, respectively), among which… | |||
| 5 | 64 | text | body | True | body | body | p5:body_region:1 | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 613.11, 251.09, 59.74] | and additional sharp ( g = 2.003) signals compared with their counterparts without oxygen vacancy, corresponding to the unpaired electrons of Mn 4+ and the typical feature of oxygen vacancies, respectively [21,34], whic… | and additional sharp ( g = 2.003) signals compared with their counterparts without oxygen vacancy, corresponding to the unpaired electrons of Mn 4+ and the typical feature of oxygen vacancies, respectively [21,34], whic… | |||
| 5 | 65 | text | body | True | body | body | p5:body_region:1 | p5:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 675.87, 251.09, 70.18] | XPS measurements were implemented to elucidate the compositional features and chemical states in LMO and Ov-LMO materials. The survey-scan XPS spectra reveal the coexistence of Li, Mn, and O in all samples, in which the… | XPS measurements were implemented to elucidate the compositional features and chemical states in LMO and Ov-LMO materials. The survey-scan XPS spectra reveal the coexistence of Li, Mn, and O in all samples, in which the… | |||
| 5 | 66 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p5:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 168 | 168 | |||
| 6 | 67 | page_header | page_header | False | low | docling_page_header | docling_page_header | p6:body_region:0 | p6:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 6 | 68 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 67.96, 251.13, 363.05] | strategy. The core-level O 1 s spectra can be deconvoluted into 2 sub-peaks located at 531.8 and 529.3 eV (Fig. 2g-i), correlating to the surficial absorbed and lattice oxygen, respectively, whose intensity ratios (0.73… | strategy. The core-level O 1 s spectra can be deconvoluted into 2 sub-peaks located at 531.8 and 529.3 eV (Fig. 2g-i), correlating to the surficial absorbed and lattice oxygen, respectively, whose intensity ratios (0.73… | |||
| 6 | 69 | text | body | True | body | body | p6:body_region:0 | p6:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 434.08, 251.13, 321.21] | The morphological features and architecture of the MOF precursors, LMO, and Ov-LMO were systematically analyzed by SEM and TEM characterizations. The SEM image of the Mn-BDC precursor (Fig. 3a) features a spongy lamella… | The morphological features and architecture of the MOF precursors, LMO, and Ov-LMO were systematically analyzed by SEM and TEM characterizations. The SEM image of the Mn-BDC precursor (Fig. 3a) features a spongy lamella… | |||
| 6 | 70 | page_header | page_header | False | low | docling_page_header | docling_page_header | p6:body_region:1 | p6:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.77, 48.15, 139.86, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 6 | 71 | text | body | True | body | body | p6:body_region:1 | p6:page_body:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 67.95, 251.1, 59.69] | tributed on the well-retained primary structure, in turn manifesting the negligible destruction of primary particles by the lowtemperature reduction [14,38], which ameliorates the surface property, provides abundant act… | tributed on the well-retained primary structure, in turn manifesting the negligible destruction of primary particles by the lowtemperature reduction [14,38], which ameliorates the surface property, provides abundant act… | |||
| 6 | 72 | text | body | True | body | body | p6:body_region:1 | p6:page_body:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 130.71, 251.12, 279.38] | Correspondingly, the N2 physisorption isotherms were acquired at 77 K to further demonstrate the porous traits, as elaborated in Fig. S5(a). The BET surface areas of Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO were found to … | Correspondingly, the N2 physisorption isotherms were acquired at 77 K to further demonstrate the porous traits, as elaborated in Fig. S5(a). The BET surface areas of Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO were found to … | |||
| 6 | 73 | text | body | True | body | body | p6:body_region:1 | p6:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 413.16, 251.11, 342.13] | To further unveil the internal architectures of the LMO and Ov-LMO products, the TEM technique was adopted. As disclosed by the TEM images, BDC-LMO (Fig. 4a) and Ov-BDC-LMO (Fig. 4d) feature a layered architecture compo… | To further unveil the internal architectures of the LMO and Ov-LMO products, the TEM technique was adopted. As disclosed by the TEM images, BDC-LMO (Fig. 4a) and Ov-BDC-LMO (Fig. 4d) feature a layered architecture compo… | |||
| 6 | 74 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p6:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 169 | 169 | |||
| 7 | 75 | page_header | page_header | False | low | docling_page_header | docling_page_header | p7:body_region:0 | p7:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 7 | 76 | page_header | page_header | False | low | docling_page_header | docling_page_header | p7:body_region:1 | p7:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.71, 48.21, 139.91, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 7 | 77 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p7:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [51.02, 441.88, 493.16, 6.37] | Fig. 3. The SEM images of (a) Mn-BDC, (b) BDC-LMO, (c) Ov-BDC-LMO, (d) Mn-BTC, (e) BTC-LMO, (f) Ov-BTC-LMO, (g) Mn-PTC, (h) PTC-LMO, and (i) Ov-PTC-LMO. | Fig. 3. The SEM images of (a) Mn-BDC, (b) BDC-LMO, (c) Ov-BDC-LMO, (d) Mn-BTC, (e) BTC-LMO, (f) Ov-BTC-LMO, (g) Mn-PTC, (h) PTC-LMO, and (i) Ov-PTC-LMO. | |||
| 7 | 78 | text | body | True | body | body | p7:body_region:0 | p7:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 475.92, 251.13, 227.1] | the predominant layered structure and minority spinel domain. To support this assumption from the atomic level, the spherical aberration-corrected HAADF-STEM and spherical aberrationcorrected annular bright-field STEM(A… | the predominant layered structure and minority spinel domain. To support this assumption from the atomic level, the spherical aberration-corrected HAADF-STEM and spherical aberrationcorrected annular bright-field STEM(A… | |||
| 7 | 79 | section_header | body_heading | False | low | body_heading | body_heading | p7:body_region:0 | p7:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [37.7, 716.52, 110.65, 7.42] | 3.2. Electrochemical properties | 3.2. Electrochemical properties | ||
| 7 | 80 | text | body | True | body | body | p7:body_region:0 | p7:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 737.44, 251.08, 17.85] | The electrochemical properties of LMO and Ov-LMO were comprehensively studied to illustrate the efficaciousness of the | The electrochemical properties of LMO and Ov-LMO were comprehensively studied to illustrate the efficaciousness of the | |||
| 7 | 81 | text | body | True | body | body | p7:body_region:1 | p7:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 475.92, 251.1, 216.61] | oxygen-deficient strategy for the activation and optimization of Li2MnO3 as an advanced LIB cathode. Ov-BDC-LMO (Fig. 6a), Ov-BTC-LMO (Fig. 6b), and Ov-PTC-LMO (Fig. 6c) samples exhibit reversible capacities of 179.2, 1… | oxygen-deficient strategy for the activation and optimization of Li2MnO3 as an advanced LIB cathode. Ov-BDC-LMO (Fig. 6a), Ov-BTC-LMO (Fig. 6b), and Ov-PTC-LMO (Fig. 6c) samples exhibit reversible capacities of 179.2, 1… | |||
| 7 | 82 | text | body | True | body | body | p7:body_region:1 | p7:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 695.6, 251.08, 59.7] | As expected, the Ov-LMO samples feature superiority in rate performance compared with their counterparts without oxygen vacancy (Fig. 6d-f). Superior reversible capacities are presented by Ov-BDC-LMO (199.5, 187.9, 167.… | As expected, the Ov-LMO samples feature superiority in rate performance compared with their counterparts without oxygen vacancy (Fig. 6d-f). Superior reversible capacities are presented by Ov-BDC-LMO (199.5, 187.9, 167.… | |||
| 7 | 83 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p7:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.38, 5.93] | 170 | 170 | |||
| 8 | 84 | page_header | page_header | False | low | docling_page_header | docling_page_header | p8:body_region:0 | p8:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 8 | 85 | page_header | page_header | False | low | docling_page_header | docling_page_header | p8:body_region:1 | p8:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.77, 48.15, 139.86, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 8 | 86 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p8:page_body:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 603.74, 520.03, 14.84] | Fig. 4. (a-f) TEM images, (g-l) HRTEM images, (m-r) SAED patterns, and (s-x) HAADF-STEM images and corresponding element mappings of BDC-LMO, BTC-LMO, PTC-LMO, Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO, respectively. | Fig. 4. (a-f) TEM images, (g-l) HRTEM images, (m-r) SAED patterns, and (s-x) HAADF-STEM images and corresponding element mappings of BDC-LMO, BTC-LMO, PTC-LMO, Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO, respectively. | |||
| 8 | 87 | text | body | True | body | body | p8:body_region:0 | p8:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 640.04, 251.12, 112.03] | respectively), and Ov-PTC-LMO (110.4, 97.6, 80.7, 57.8, and 39.5 mA h g 1 at 0.1, 0.2, 0.4, 1, and 2 C, respectively) at different current densities. In contrast, BDC-LMO (96.2, 76.3, 63.2, 43.4, and 37.9 mA h g 1 a… | respectively), and Ov-PTC-LMO (110.4, 97.6, 80.7, 57.8, and 39.5 mA h g 1 at 0.1, 0.2, 0.4, 1, and 2 C, respectively) at different current densities. In contrast, BDC-LMO (96.2, 76.3, 63.2, 43.4, and 37.9 mA h g 1 a… | |||
| 8 | 88 | text | body | True | body | body | p8:body_region:1 | p8:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 638.24, 251.1, 113.82] | ities of other samples (198.9, 124.3, 116.2, 53.9, and 45.5 mA h g 1 for Ov-BTC-LMO, Ov-PTC-LMO, BDC-LMO, BTC-LMO, and PTC-LMO, respectively) after the rate recovery. It is noteworthy that the MnBDC-derived samples ou… | ities of other samples (198.9, 124.3, 116.2, 53.9, and 45.5 mA h g 1 for Ov-BTC-LMO, Ov-PTC-LMO, BDC-LMO, BTC-LMO, and PTC-LMO, respectively) after the rate recovery. It is noteworthy that the MnBDC-derived samples ou… | |||
| 8 | 89 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p8:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 171 | 171 | |||
| 9 | 90 | page_header | page_header | False | low | docling_page_header | docling_page_header | p9:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | |||
| 9 | 91 | page_header | page_header | False | low | docling_page_header | docling_page_header | p9:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.71, 48.21, 139.91, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | |||
| 9 | 92 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p9:page_body:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 629.65, 520.04, 14.9] | Fig. 5. (a-f) Spherical aberration-corrected HAADF-STEM and (g-l) spherical aberration-corrected ABF-STEM images for BDC-LMO, BTC-LMO, PTC-LMO, Ov-BDC-LMO, OvBTC-LMO, and Ov-PTC-LMO, respectively. | Fig. 5. (a-f) Spherical aberration-corrected HAADF-STEM and (g-l) spherical aberration-corrected ABF-STEM images for BDC-LMO, BTC-LMO, PTC-LMO, Ov-BDC-LMO, OvBTC-LMO, and Ov-PTC-LMO, respectively. | |||
| 9 | 93 | text | body | True | body | body | p9:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 665.95, 251.13, 80.66] | cycling durability of Ov-BDC-LMO with a reversible capacity of 100.1 mA h g 1 outperforming those of Ov-BTC-LMO (95.5 mA h g 1 ) and Ov-PTC-LMO (58.9 mA h g 1 ). Moreover, the cross-sectional SEM images are disclo… | cycling durability of Ov-BDC-LMO with a reversible capacity of 100.1 mA h g 1 outperforming those of Ov-BTC-LMO (95.5 mA h g 1 ) and Ov-PTC-LMO (58.9 mA h g 1 ). Moreover, the cross-sectional SEM images are disclo… | ||||
| 9 | 94 | text | body | True | body | body | p9:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 665.95, 251.12, 80.67] | The galvanostatic charge/discharge (GCD) profiles of all samples performed at 20 mA g 1 were recorded to better demonstrate the working mechanism of the activation process of LMO and Ov-LMO electrodes. As depicted in … | The galvanostatic charge/discharge (GCD) profiles of all samples performed at 20 mA g 1 were recorded to better demonstrate the working mechanism of the activation process of LMO and Ov-LMO electrodes. As depicted in … | ||||
| 9 | 95 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p9:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 172 | 172 | |||
| 10 | 96 | page_header | page_header | False | low | docling_page_header | docling_page_header | p10:body_region:0 | p10:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 10 | 97 | page_header | page_header | False | low | docling_page_header | docling_page_header | p10:body_region:1 | p10:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.77, 48.15, 139.86, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 10 | 98 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p10:page_body:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 530.55, 520.08, 24.48] | Fig. 6. The cycling performance at 20 mA g 1 for 200 loops of (a) (Ov-)BDC-LMO, (b) (Ov-)BTC-LMO, and (c) (Ov-)PTC-LMO. The rate performance at 0.1, 0.2, 0.4, 1, and 2 C (1 C = 200 mA g 1 ) of (d) (Ov-)BDC-LMO, (e) … | Fig. 6. The cycling performance at 20 mA g 1 for 200 loops of (a) (Ov-)BDC-LMO, (b) (Ov-)BTC-LMO, and (c) (Ov-)PTC-LMO. The rate performance at 0.1, 0.2, 0.4, 1, and 2 C (1 C = 200 mA g 1 ) of (d) (Ov-)BDC-LMO, (e) … | |||
| 10 | 99 | text | body | True | body | body | p10:body_region:0 | p10:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 576.49, 251.1, 153.85] | 38.2%, respectively. Two successive charge plateaus can be observed at 3.9 and 4.4 V in the Ov-LMO samples during the first cycle, while merely a long voltage plateau appears above 4.4 V in the LMO samples, which ca… | 38.2%, respectively. Two successive charge plateaus can be observed at 3.9 and 4.4 V in the Ov-LMO samples during the first cycle, while merely a long voltage plateau appears above 4.4 V in the LMO samples, which ca… | |||
| 10 | 100 | text | body | True | body | body | p10:body_region:0 | p10:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 733.36, 251.1, 17.91] | Furthermore, to unravel the lithium storage behaviors of all samples during cycling from electronic conductivity and lithium | Furthermore, to unravel the lithium storage behaviors of all samples during cycling from electronic conductivity and lithium | |||
| 10 | 101 | text | body | True | body | body | p10:body_region:1 | p10:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 576.49, 251.09, 174.78] | diffusivity, EIS measurements were conducted for better comparison. As illustrated in Fig. S9(a-c) and Fig. 6(j-l), Nyquist plots of all samples before and after cycling can be divided into semicircles at high and middl… | diffusivity, EIS measurements were conducted for better comparison. As illustrated in Fig. S9(a-c) and Fig. 6(j-l), Nyquist plots of all samples before and after cycling can be divided into semicircles at high and middl… | |||
| 10 | 102 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p10:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 173 | 173 | |||
| 11 | 103 | page_header | page_header | False | low | docling_page_header | docling_page_header | p11:body_region:0 | p11:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 11 | 104 | text | body | True | body | body | p11:body_region:0 | p11:page_body:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 67.96, 251.1, 122.45] | induced by the oxygen vacancies. The resistance values after 100 cycles were also estimated and compared to further illustrate the enhanced electron/ion conductivity related to the activation process, as tabulated in Ta… | induced by the oxygen vacancies. The resistance values after 100 cycles were also estimated and compared to further illustrate the enhanced electron/ion conductivity related to the activation process, as tabulated in Ta… | |||
| 11 | 105 | text | body | True | body | body | p11:body_region:0 | p11:page_body:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 193.47, 251.14, 279.37] | To further investigate the lithium diffusion kinetics, the formula D Li+ = R 2 T 2 /(2 A 2 n 4 F 4 c 2 r 2 ) was applied, where D Li+ , R, T , A , n , F, c , and r symbolize the lithium-ion diffusion coefficient, gas co… | To further investigate the lithium diffusion kinetics, the formula D Li+ = R 2 T 2 /(2 A 2 n 4 F 4 c 2 r 2 ) was applied, where D Li+ , R, T , A , n , F, c , and r symbolize the lithium-ion diffusion coefficient, gas co… | |||
| 11 | 106 | text | body | True | body | body | p11:body_region:0 | p11:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 475.92, 251.13, 258.45] | The CV curves were further studied to unveil the working mechanisms of LMO and Ov-LMO in lithium storage. The CV curves for the initial three cycles of six samples are recorded in Fig. 7(a-f), which differentiate the wo… | The CV curves were further studied to unveil the working mechanisms of LMO and Ov-LMO in lithium storage. The CV curves for the initial three cycles of six samples are recorded in Fig. 7(a-f), which differentiate the wo… | |||
| 11 | 107 | text | body | True | body | body | p11:body_region:0 | p11:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 737.44, 251.08, 17.85] | The above observations expound the different working mechanisms of the Ov-LMO compared with the primitive materials with- | The above observations expound the different working mechanisms of the Ov-LMO compared with the primitive materials with- | |||
| 11 | 108 | page_header | page_header | False | low | docling_page_header | docling_page_header | p11:body_region:1 | p11:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.71, 48.21, 139.91, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 11 | 109 | text | body | True | body | body | p11:body_region:1 | p11:page_body:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 67.95, 251.08, 216.62] | out oxygen vacancy, particularly during the first cycle. For better understanding, the redox activities at the first (de)lithiation cycle are schematically illustrated. Fig. 7(g) portrays the reversible transformation o… | out oxygen vacancy, particularly during the first cycle. For better understanding, the redox activities at the first (de)lithiation cycle are schematically illustrated. Fig. 7(g) portrays the reversible transformation o… | |||
| 11 | 110 | text | body | True | body | body | p11:body_region:1 | p11:page_body:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 287.64, 251.1, 394.46] | The quantitation of pseudocapacitive behaviors can be utilized to interpret the electrochemical kinetics, reflect the Li + diffusion velocity, and further demonstrate the rate capability of electrode materials [5,52]. W… | The quantitation of pseudocapacitive behaviors can be utilized to interpret the electrochemical kinetics, reflect the Li + diffusion velocity, and further demonstrate the rate capability of electrode materials [5,52]. W… | |||
| 11 | 111 | text | body | True | body | body | p11:body_region:1 | p11:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 685.11, 251.08, 70.18] | Predictably, the Ov-LMO samples (89.8%, 86.6%, and 79.7% for Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO, respectively) hold superior pseudocapacitive contributions compared to their corresponding counterparts (51.9%, 45.2%,… | Predictably, the Ov-LMO samples (89.8%, 86.6%, and 79.7% for Ov-BDC-LMO, Ov-BTC-LMO, and Ov-PTC-LMO, respectively) hold superior pseudocapacitive contributions compared to their corresponding counterparts (51.9%, 45.2%,… | |||
| 11 | 112 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p11:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 174 | 174 | |||
| 12 | 113 | page_header | page_header | False | low | docling_page_header | docling_page_header | p12:top_margin:left:white | [255, 255, 255] white | False | [37.59, 48.2, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | |||
| 12 | 114 | page_header | page_header | False | low | docling_page_header | docling_page_header | p12:top_margin:right:white | [255, 255, 255] white | False | [417.77, 48.15, 139.86, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | |||
| 12 | 115 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p12:bottom_margin:full:white | [255, 255, 255] white | False | [37.59, 714.69, 520.07, 24.53] | Fig. 7. The CV curves for the first 3 cycles at 0.2 mV s 1 for (a) Ov-BDC-LMO, (b) Ov-BTC-LMO, (c) Ov-PTC-LMO, (d) BDC-LMO, (e) BTC-LMO, and (f) PTC-LMO. The schematic illustrations of the first cycle for (g) Ov-LMO a… | Fig. 7. The CV curves for the first 3 cycles at 0.2 mV s 1 for (a) Ov-BDC-LMO, (b) Ov-BTC-LMO, (c) Ov-PTC-LMO, (d) BDC-LMO, (e) BTC-LMO, and (f) PTC-LMO. The schematic illustrations of the first cycle for (g) Ov-LMO a… | |||
| 12 | 116 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p12:bottom_margin:right_crossing:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 175 | 175 | |||
| 13 | 117 | page_header | page_header | False | low | docling_page_header | docling_page_header | p13:body_region:0 | p13:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 13 | 118 | text | body | True | body | body | p13:body_region:0 | p13:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 67.96, 251.12, 185.26] | samples are also evaluated, as disclosed in Figs. S13-S18. All samples perform increasing pseudocapacitive-dominant behaviors as the sweep rate upgrades, among which the Ov-LMO samples (Fig. 7l-n) significantly outperfo… | samples are also evaluated, as disclosed in Figs. S13-S18. All samples perform increasing pseudocapacitive-dominant behaviors as the sweep rate upgrades, among which the Ov-LMO samples (Fig. 7l-n) significantly outperfo… | |||
| 13 | 119 | text | body | True | body | body | p13:body_region:0 | p13:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 256.23, 251.13, 242.64] | The galvanostatic intermittent titration technique (GITT) measurement was conducted to further support the effectiveness of the oxygen-deficient strategy for exalted lithium diffusivity of LMO materials. The whole-step … | The galvanostatic intermittent titration technique (GITT) measurement was conducted to further support the effectiveness of the oxygen-deficient strategy for exalted lithium diffusivity of LMO materials. The whole-step … | |||
| 13 | 120 | text | body | True | body | body | p13:body_region:0 | p13:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 501.88, 251.11, 248.02] | For a better understanding, the working mechanism of the advantageous Li + diffusion of the Ov-LMO samples is schematically illustrated in Fig. 8(h) to emphasize the optimized lithium storage behaviors brought by oxygen… | For a better understanding, the working mechanism of the advantageous Li + diffusion of the Ov-LMO samples is schematically illustrated in Fig. 8(h) to emphasize the optimized lithium storage behaviors brought by oxygen… | |||
| 13 | 121 | page_header | page_header | False | low | docling_page_header | docling_page_header | p13:body_region:1 | p13:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.71, 48.21, 139.91, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 13 | 122 | text | body | True | body | body | p13:body_region:1 | p13:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 67.95, 251.08, 38.77] | rating lithium diffusivity and intriguing pseudocapacitivedominant behaviors, which is in uniformity with the pseudocapacitive observations and constitutionally interprets the oxygen vacancy-intervened electrochemical p… | rating lithium diffusivity and intriguing pseudocapacitivedominant behaviors, which is in uniformity with the pseudocapacitive observations and constitutionally interprets the oxygen vacancy-intervened electrochemical p… | |||
| 13 | 123 | text | body | True | body | body | p13:body_region:1 | p13:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 109.79, 251.11, 227.11] | Additionally, a series of ex situ characterizations were conducted to further unearth the working mechanisms of the (Ov-)LMO during electrochemical measurements. It is widely substantiated that LMO materials undergo oxy… | Additionally, a series of ex situ characterizations were conducted to further unearth the working mechanisms of the (Ov-)LMO during electrochemical measurements. It is widely substantiated that LMO materials undergo oxy… | |||
| 13 | 124 | text | body | True | body | body | p13:body_region:1 | p13:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 339.91, 251.1, 321.27] | Ex situ XPS spectra were employed to decipher the reaction mechanism during charge/discharge processes of (Ov-)LMO materials during the initial cycle, by which the exalted structural stability of Ov-LMO can be investiga… | Ex situ XPS spectra were employed to decipher the reaction mechanism during charge/discharge processes of (Ov-)LMO materials during the initial cycle, by which the exalted structural stability of Ov-LMO can be investiga… | |||
| 13 | 125 | section_header | body_heading | False | low | body_heading | body_heading | p13:body_region:1 | p13:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.65, 680.01, 97.57, 7.42] | 3.3. DFT calculation results | 3.3. DFT calculation results | ||
| 13 | 126 | text | body | True | body | body | p13:body_region:1 | p13:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 700.93, 251.1, 49.26] | DFT calculation was implemented to theoretically verify the superiority of the Ov-LMO materials in lithium storage compared with the parent materials. Herein, the models of LMO (Fig. 9a and Fig. S30a) and Ov-LMO (Fig. 9… | DFT calculation was implemented to theoretically verify the superiority of the Ov-LMO materials in lithium storage compared with the parent materials. Herein, the models of LMO (Fig. 9a and Fig. S30a) and Ov-LMO (Fig. 9… | |||
| 13 | 127 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p13:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 176 | 176 | |||
| 14 | 128 | page_header | page_header | False | low | docling_page_header | docling_page_header | p14:body_region:0 | p14:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 14 | 129 | page_header | page_header | False | low | docling_page_header | docling_page_header | p14:body_region:1 | p14:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.77, 48.15, 139.86, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 14 | 130 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p14:page_body:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 575.68, 520.03, 31.96] | Fig. 8. The single-step profiles of GITT titration during the charging process for (a) Ov-BDC-LMO, (b) Ov-BTC-LMO, and (c) Ov-PTC-LMO. The GITT curves of (d) Ov-BDC-LMO, (e) Ov-BTC-LMO, and (f) Ov-PTC-LMO. (g) The calcu… | Fig. 8. The single-step profiles of GITT titration during the charging process for (a) Ov-BDC-LMO, (b) Ov-BTC-LMO, and (c) Ov-PTC-LMO. The GITT curves of (d) Ov-BDC-LMO, (e) Ov-BTC-LMO, and (f) Ov-PTC-LMO. (g) The calcu… | |||
| 14 | 131 | text | body | True | body | body | p14:body_region:0 | p14:page_body:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 620.6, 251.14, 59.74] | configuration induced by oxygen vacancies. The calculated lattice parameters of LMO and Ov-LMO after optimization are enumerated in Table S5, which elucidates the enlarged lattice parameters and cell volume of the Ov-LM… | configuration induced by oxygen vacancies. The calculated lattice parameters of LMO and Ov-LMO after optimization are enumerated in Table S5, which elucidates the enlarged lattice parameters and cell volume of the Ov-LM… | |||
| 14 | 132 | text | body | True | body | body | p14:body_region:0 | p14:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 683.36, 251.12, 70.18] | To further unearth the difference in electronic configuration, the three-dimensional (3D) differential charge density distributions of LMO and Ov-LMO were explored, as presented in Fig. S30 (c) and Fig. 9(c), respective… | To further unearth the difference in electronic configuration, the three-dimensional (3D) differential charge density distributions of LMO and Ov-LMO were explored, as presented in Fig. S30 (c) and Fig. 9(c), respective… | |||
| 14 | 133 | text | body | True | body | body | p14:body_region:1 | p14:page_body:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 620.6, 251.09, 70.18] | and plausibility of the local built-in electric field assumption, thereby verifying the exalted lithium diffusivity related to the adventitious Coulomb force generated by the self-adaptive electric field around the vaca… | and plausibility of the local built-in electric field assumption, thereby verifying the exalted lithium diffusivity related to the adventitious Coulomb force generated by the self-adaptive electric field around the vaca… | |||
| 14 | 134 | text | body | True | body | body | p14:body_region:1 | p14:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.59, 693.84, 251.07, 59.69] | Electronic conductivity is a crucial prerequisite condition for LIB electrodes, which was holistically investigated by calculating the total density of states (TDOS) profiles bound up with the Fermi level (denoted as E … | Electronic conductivity is a crucial prerequisite condition for LIB electrodes, which was holistically investigated by calculating the total density of states (TDOS) profiles bound up with the Fermi level (denoted as E … | |||
| 14 | 135 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p14:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 177 | 177 | |||
| 15 | 136 | page_header | page_header | False | low | docling_page_header | docling_page_header | p15:top_margin:left:white | [255, 255, 255] white | False | [37.59, 48.2, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | |||
| 15 | 137 | page_header | page_header | False | low | docling_page_header | docling_page_header | p15:top_margin:right:white | [255, 255, 255] white | False | [417.71, 48.2, 139.91, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | |||
| 15 | 138 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p15:bottom_margin:full:white | [255, 255, 255] white | False | [37.59, 715.76, 520.05, 23.46] | Fig. 9. The optimized models of (a) LMO and (b) Ov-LMO. (c) The 3D differential charge density distribution of Ov-LMO. (d) The TDOS curves of LMO and Ov-LMO. The PDOS curves of (e) LMO and (f) Ov-LMO. The energy barrier… | Fig. 9. The optimized models of (a) LMO and (b) Ov-LMO. (c) The 3D differential charge density distribution of Ov-LMO. (d) The TDOS curves of LMO and Ov-LMO. The PDOS curves of (e) LMO and (f) Ov-LMO. The energy barrier… | |||
| 15 | 139 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p15:bottom_margin:left_crossing:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 178 | 178 | |||
| 16 | 140 | page_header | page_header | False | low | docling_page_header | docling_page_header | p16:body_region:0 | p16:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 48.2, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 16 | 141 | text | body | True | body | body | p16:body_region:0 | p16:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 67.96, 251.12, 153.85] | and conduction bands. The reduced band gap and pronouncedly denser DOS adjacent to the Fermi energy level delivered by the Ov-LMO indicate enhanced metallicity and impressive electronic conductivity. To further unravel … | and conduction bands. The reduced band gap and pronouncedly denser DOS adjacent to the Fermi energy level delivered by the Ov-LMO indicate enhanced metallicity and impressive electronic conductivity. To further unravel … | |||
| 16 | 142 | text | body | True | body | body | p16:body_region:0 | p16:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 223.26, 251.14, 144.99] | As stated earlier, the ease of Li + extraction is vital to the reconstruction and activation of the LMO electrodes to sustain electrochemical activity, especially during the first cycle. To support this statement with m… | As stated earlier, the ease of Li + extraction is vital to the reconstruction and activation of the LMO electrodes to sustain electrochemical activity, especially during the first cycle. To support this statement with m… | |||
| 16 | 143 | text | body | True | body | body | p16:body_region:0 | p16:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 371.32, 251.11, 153.85] | The experimental observations extensively illuminate the significantly expedited Li + diffusion, which can be theoretically expounded by the calculated energy barriers of lithium vacancy migration. As displayed in Fig. … | The experimental observations extensively illuminate the significantly expedited Li + diffusion, which can be theoretically expounded by the calculated energy barriers of lithium vacancy migration. As displayed in Fig. … | |||
| 16 | 144 | text | body | True | body | body | p16:body_region:0 | p16:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 528.19, 251.12, 164.34] | Benefitting from the morphological and microstructural merits, the Ov-BDC-LMO reported in this study outperforms most of the counterparts mentioned in prior works in lithium storage capacity at various current densities… | Benefitting from the morphological and microstructural merits, the Ov-BDC-LMO reported in this study outperforms most of the counterparts mentioned in prior works in lithium storage capacity at various current densities… | |||
| 16 | 145 | section_header | body_heading | False | low | body_heading | body_heading | p16:body_region:0 | p16:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [37.7, 716.09, 57.15, 7.96] | 4. Conclusions | 4. Conclusions | ||
| 16 | 146 | text | body | True | body | body | p16:body_region:0 | p16:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [37.59, 737.44, 251.1, 17.85] | In conclusion, we have proposed a conceptual synthetic protocol with MOFs as self-sacrificial templates and stearic acid as the | In conclusion, we have proposed a conceptual synthetic protocol with MOFs as self-sacrificial templates and stearic acid as the | |||
| 16 | 147 | page_header | page_header | False | low | docling_page_header | docling_page_header | p16:body_region:1 | p16:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [417.77, 48.15, 139.86, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 16 | 148 | text | body | True | body | body | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 67.95, 251.12, 216.61] | reductant for the introduction of oxygen vacancies to ameliorate the electrochemical activity of LMO as an advanced cathode material for LIBs. The rational selection of MOF precursors efficaciously modulates the morphol… | reductant for the introduction of oxygen vacancies to ameliorate the electrochemical activity of LMO as an advanced cathode material for LIBs. The rational selection of MOF precursors efficaciously modulates the morphol… | |||
| 16 | 149 | section_header | back_matter_heading | False | low | back_matter_heading | back_matter_heading | stop_trigger | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 298.54, 134.88, 7.96] | Declaration of competing interest | Declaration of competing interest | |
| 16 | 150 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 319.9, 251.12, 28.34] | The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. | The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. | |
| 16 | 151 | section_header | back_matter_heading | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 362.22, 73.61, 7.96] | Acknowledgments | Acknowledgments | |
| 16 | 152 | text | back_matter_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 383.57, 251.08, 101.58] | We gratefully acknowledge the financial support from the Special Funds for the Cultivation of Guangdong College Students' Scientific and Technological Innovation (''Climbing Program' Special Funds, pdjh2023b0145), the R… | We gratefully acknowledge the financial support from the Special Funds for the Cultivation of Guangdong College Students' Scientific and Technological Innovation (''Climbing Program' Special Funds, pdjh2023b0145), the R… | |
| 16 | 153 | section_header | unknown_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.65, 500.83, 147.31, 7.96] | Appendix A. Supplementary material | Appendix A. Supplementary material | |
| 16 | 154 | text | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.6, 522.18, 251.04, 17.91] | Supplementary data to this article can be found online at https://doi.org/10.1016/j.jechem.2023.05.014. | Supplementary data to this article can be found online at | |
| 16 | 155 | section_header | back_matter_heading | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.65, 554.06, 43.1, 7.96] | References | References | |
| 16 | 156 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [309.83, 573.7, 247.83, 13.93] | R. Liu, N. Li, E. Zhao, J. Zhao, L. Yang, W. Wang, H. Liu, C. Zeng, Mater. Futures 1 (2022). | R. Liu, N. Li, E. Zhao, J. Zhao, L. Yang, W. Wang, H. Liu, C. Zeng, Mater. Futures 1 (2022). | |
| 16 | 157 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [309.83, 589.68, 247.79, 13.87] | Z.H. Zhang, X.Y. Xie, H.X. Xie, X.K. Ding, J.X. Cui, C.Y. Liu, D. Luo, Z. Lin, Chin. J. Struct. Chem. 41 (2022) 2204061-2204067. | Z.H. Zhang, X.Y. Xie, H.X. Xie, X.K. Ding, J.X. Cui, C.Y. Liu, D. Luo, Z. Lin, Chin. J. Struct. Chem. 41 (2022) 2204061-2204067. | |
| 16 | 158 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [309.83, 605.61, 247.78, 13.87] | C. Zheng, S. Tang, F. Wen, J. Peng, W. Yang, Z. Lv, Y. Wu, W. Tang, Z. Gong, Y. Yang, Mater. Futures 1 (2022). | C. Zheng, S. Tang, F. Wen, J. Peng, W. Yang, Z. Lv, Y. Wu, W. Tang, Z. Gong, Y. Yang, Mater. Futures 1 (2022). | |
| 16 | 159 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [309.83, 621.54, 208.72, 5.93] | S. Wang, J. Liu, Q. Sun, J. Mater. Chem. A 5 (2017) 16936-16943. | S. Wang, J. Liu, Q. Sun, J. Mater. Chem. A 5 (2017) 16936-16943. | |
| 16 | 160 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [309.83, 629.48, 155.32, 5.93] | J. Lin, Y.-H. Sun, X. Lin, Nano Energy 91 (2022). | J. Lin, Y.-H. Sun, X. Lin, Nano Energy 91 (2022). | |
| 16 | 161 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [309.83, 637.47, 247.83, 13.93] | F. Wang, Z. Chang, X. Wang, Y. Wang, B. Chen, Y. Zhu, Y. Wu, J. Mater. Chem. A 3 (2015) 4840-4845. | F. Wang, Z. Chang, X. Wang, Y. Wang, B. Chen, Y. Zhu, Y. Wu, J. Mater. Chem. A 3 (2015) 4840-4845. | |
| 16 | 162 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [309.83, 653.41, 247.82, 13.93] | M. Zhang, L. Qiu, Y. Sun, Y. Song, Z. Wu, Y. Liu, Z. Yang, Y. Liu, J. Zhang, B. Zhong, X. Guo, ACS. Appl. Mater. Interfaces 13 (2021) 40995-41003. | M. Zhang, L. Qiu, Y. Sun, Y. Song, Z. Wu, Y. Liu, Z. Yang, Y. Liu, J. Zhang, B. Zhong, X. Guo, ACS. Appl. Mater. Interfaces 13 (2021) 40995-41003. | |
| 16 | 163 | list_item | affiliation | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [309.83, 669.34, 247.8, 5.93] | B. Wu, Z. Lin, G. Zhang, D. Zhang, W. Zhang, G. Li, Y. Che, L. Chen, H. Wang, W. | B. Wu, Z. Lin, G. Zhang, D. Zhang, W. Zhang, G. Li, Y. Che, L. Chen, H. Wang, W. | |
| 16 | 164 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [321.56, 677.33, 190.24, 5.93] | Li, M. Chen, G. Cao, Energy Storage Mater. 53 (2022) 212-221. | Li, M. Chen, G. Cao, Energy Storage Mater. 53 (2022) 212-221. | |
| 16 | 165 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [309.83, 685.32, 247.83, 13.87] | F. Ning, H. Shang, B. Li, N. Jiang, R. Zou, D. Xia, Energy Storage Mater. 22 (2019) 113-119. | F. Ning, H. Shang, B. Li, N. Jiang, R. Zou, D. Xia, Energy Storage Mater. 22 (2019) 113-119. | |
| 16 | 166 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.65, 701.25, 240.53, 5.93] | W. Zhao, L. Xiong, Y. Xu, H. Li, Z. Ren, J. Power Sources 349 (2017) 11-17. | W. Zhao, L. Xiong, Y. Xu, H. Li, Z. Ren, J. Power Sources 349 (2017) 11-17. | |
| 16 | 167 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.65, 709.19, 251.0, 21.92] | S.F. Amalraj, D. Sharon, M. Talianker, C.M. Julien, L. Burlaka, R. Lavi, E. Zhecheva, B. Markovsky, E. Zinigrad, D. Kovacheva, R. Stoyanova, D. Aurbach, Electrochim. Acta 97 (2013) 259-270. | S.F. Amalraj, D. Sharon, M. Talianker, C.M. Julien, L. Burlaka, R. Lavi, E. Zhecheva, B. Markovsky, E. Zinigrad, D. Kovacheva, R. Stoyanova, D. Aurbach, Electrochim. Acta 97 (2013) 259-270. | |
| 16 | 168 | list_item | page_margin_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.65, 733.12, 238.99, 5.93] | Y. Shin, K.A. Persson, ACS. Appl. Mater. Interfaces 8 (2016) 25595-25602. | Y. Shin, K.A. Persson, ACS. Appl. Mater. Interfaces 8 (2016) 25595-25602. | |
| 16 | 169 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:body_region:1 | p16:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.65, 741.11, 250.98, 13.87] | A.S. Menon, D.O. Ojwang, T. Willhammar, V.K. Peterson, K. Edstrom, C.P. Gomez, W.R. Brant, ACS. Appl. Mater. Interfaces 12 (2020) 5939-5950. | A.S. Menon, D.O. Ojwang, T. Willhammar, V.K. Peterson, K. Edstrom, C.P. Gomez, W.R. Brant, ACS. Appl. Mater. Interfaces 12 (2020) 5939-5950. | |
| 16 | 170 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p16:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [291.91, 764.24, 11.45, 5.93] | 179 | 179 | ||
| 17 | 171 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:top_margin:left:white | [255, 255, 255] white | False | [37.59, 48.21, 93.88, 5.93] | J.-E. Zhou, Y. Peng, X. Sang et al. | J.-E. Zhou, Y. Peng, X. Sang et al. | ||
| 17 | 172 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:top_margin:right:white | [255, 255, 255] white | False | [417.71, 48.21, 139.91, 5.93] | Journal of Energy Chemistry 85 (2023) 164-180 | Journal of Energy Chemistry 85 (2023) 164-180 | ||
| 17 | 173 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.64, 67.94, 250.98, 13.93] | Y. Sun, M. Guo, S. Shu, D. Ding, C. Wang, Y. Zhang, J. Yan, Appl. Surf. Sci. 585 (2022). | Y. Sun, M. Guo, S. Shu, D. Ding, C. Wang, Y. Zhang, J. Yan, Appl. Surf. Sci. 585 (2022). | ||
| 17 | 174 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 67.94, 250.97, 13.93] | S. Cheng, Q. Ru, Y. Gao, M. Zhen, F. Chen, L. Wei, F.-C.-C. Ling, Chem. Eng. J. 406 (2021). | S. Cheng, Q. Ru, Y. Gao, M. Zhen, F. Chen, L. Wei, F.-C.-C. Ling, Chem. Eng. J. 406 (2021). | ||
| 17 | 175 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left:white | [255, 255, 255] white | False | [37.64, 83.87, 179.07, 5.93] | Y. Wu, Y. Li, J. Gao, Q. Zhang, SusMat 1 (2021) 66-87. | Y. Wu, Y. Li, J. Gao, Q. Zhang, SusMat 1 (2021) 66-87. | ||
| 17 | 176 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.65, 91.86, 251.01, 5.93] | R.C.K. Reddy, X. Lin, A. Zeb, C.Y. Su, Electrochem. Energ. Rev. 5 (2021) 312-347. | R.C.K. Reddy, X. Lin, A. Zeb, C.Y. Su, Electrochem. Energ. Rev. 5 (2021) 312-347. | ||
| 17 | 177 | list_item | affiliation | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 83.87, 163.65, 5.93] | A.P. Chernyshev, Mater. Chem. Phys. 282 (2022). | A.P. Chernyshev, Mater. Chem. Phys. 282 (2022). | ||
| 17 | 178 | list_item | affiliation | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 91.86, 143.64, 5.93] | M. Choi, W. Lee, Chem. Eng. J. 431 (2022). | M. Choi, W. Lee, Chem. Eng. J. 431 (2022). | ||
| 17 | 179 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.65, 99.8, 250.99, 13.93] | J. Rana, M. Stan, R. Kloepsch, J. Li, G. Schumacher, E. Welter, I. Zizak, J. Banhart, M. Winter, Adv. Energy Mater. 4 (2014) 1300998. | J. Rana, M. Stan, R. Kloepsch, J. Li, G. Schumacher, E. Welter, I. Zizak, J. Banhart, M. Winter, Adv. Energy Mater. 4 (2014) 1300998. | ||
| 17 | 180 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 99.8, 250.96, 13.93] | R. Jia, J. Yue, Q. Xia, J. Xu, X. Zhu, S. Sun, T. Zhai, H. Xia, Energy Storage Mater. 13 (2018) 303-311. | R. Jia, J. Yue, Q. Xia, J. Xu, X. Zhu, S. Sun, T. Zhai, H. Xia, Energy Storage Mater. 13 (2018) 303-311. | ||
| 17 | 181 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.64, 115.79, 251.01, 13.87] | K. Hikima, Y. Hinuma, K. Shimizu, K. Suzuki, S. Taminato, M. Hirayama, T. Masuda,K.Tamura,R.Kanno,ACS.Appl.Mater.Interfaces13(2021)7650-7663. | K. Hikima, Y. Hinuma, K. Shimizu, K. Suzuki, S. Taminato, M. Hirayama, T. Masuda,K.Tamura,R.Kanno,ACS.Appl.Mater.Interfaces13(2021)7650-7663. | ||
| 17 | 182 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 115.79, 250.96, 13.87] | C.R. Fell, D. Qian, K.J. Carroll, M. Chi, J.L. Jones, Y.S. Meng, Chem. Mater. 25 (2013) 1621-1629. | C.R. Fell, D. Qian, K.J. Carroll, M. Chi, J.L. Jones, Y.S. Meng, Chem. Mater. 25 (2013) 1621-1629. | ||
| 17 | 183 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.65, 131.72, 251.01, 13.87] | K. Kubota, T. Kaneko, M. Hirayama, M. Yonemura, Y. Imanari, K. Nakane, R. Kanno, J. Power Sources 216 (2012) 249-255. | K. Kubota, T. Kaneko, M. Hirayama, M. Yonemura, Y. Imanari, K. Nakane, R. Kanno, J. Power Sources 216 (2012) 249-255. | ||
| 17 | 184 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 131.72, 250.96, 13.87] | Y. Zhang, C. Yin, B. Qiu, G. Chen, Y. Shang, Z. Liu, Energy Storage Mater. 53 (2022) 763-773. | Y. Zhang, C. Yin, B. Qiu, G. Chen, Y. Shang, Z. Liu, Energy Storage Mater. 53 (2022) 763-773. | ||
| 17 | 185 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left:white | [255, 255, 255] white | False | [37.64, 147.65, 222.72, 5.93] | X. Tan, R. Liu, C. Xie, Q. Shen, J. Power Sources 374 (2018) 134-141. | X. Tan, R. Liu, C. Xie, Q. Shen, J. Power Sources 374 (2018) 134-141. | ||
| 17 | 186 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left:white | [255, 255, 255] white | False | [37.65, 155.64, 199.54, 5.93] | Y. Sun, L. Zan, Y. Zhang, Appl. Surf. Sci. 483 (2019) 270-277. | Y. Sun, L. Zan, Y. Zhang, Appl. Surf. Sci. 483 (2019) 270-277. | ||
| 17 | 187 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 147.65, 250.99, 13.93] | R. Wang, X. He, L. He, F. Wang, R. Xiao, L. Gu, H. Li, L. Chen, Adv. Energy Mater. 3 (2013) 1358-1367. | R. Wang, X. He, L. He, F. Wang, R. Xiao, L. Gu, H. Li, L. Chen, Adv. Energy Mater. 3 (2013) 1358-1367. | ||
| 17 | 188 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.64, 163.58, 251.0, 13.93] | S. Yadav, S. Sharma, S. Dutta, A. Sharma, A. Adholeya, R.K. Sharma, Inorg. Chem. 59 (2020) 8334-8344. | S. Yadav, S. Sharma, S. Dutta, A. Sharma, A. Adholeya, R.K. Sharma, Inorg. Chem. 59 (2020) 8334-8344. | ||
| 17 | 189 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 163.58, 251.01, 13.93] | P.J. Phillips, J. Bareño, Y. Li, D.P. Abraham, R.F. Klie, Adv. Energy Mater. 5 (2015) 1501252. | P.J. Phillips, J. Bareño, Y. Li, D.P. Abraham, R.F. Klie, Adv. Energy Mater. 5 (2015) 1501252. | ||
| 17 | 190 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.64, 179.51, 251.01, 5.93] | J.-E. Zhou, J. Chen, X. Zhang, A. Zeb, X. Lin, J. Energy Chem. 75 (2022) 216-228. | J.-E. Zhou, J. Chen, X. Zhang, A. Zeb, X. Lin, J. Energy Chem. 75 (2022) 216-228. | ||
| 17 | 191 | list_item | affiliation | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left:white | [251, 253, 253] white | False | [37.65, 187.5, 201.75, 5.93] | G. Kresse, J. Furthmüller, Comput. Mater. Sci 6 (1996) 15-50. | G. Kresse, J. Furthmüller, Comput. Mater. Sci 6 (1996) 15-50. | ||
| 17 | 192 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 179.51, 250.96, 13.93] | D. Ye, G. Zeng, K. Nogita, K. Ozawa, M. Hankel, D.J. Searles, L. Wang, Adv. Funct. Mater. 25 (2015) 7488-7496. | D. Ye, G. Zeng, K. Nogita, K. Ozawa, M. Hankel, D.J. Searles, L. Wang, Adv. Funct. Mater. 25 (2015) 7488-7496. | ||
| 17 | 193 | list_item | affiliation | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left:white | [255, 255, 255] white | False | [37.64, 203.43, 218.98, 5.93] | P.E. Blochl, Phys. Rev. B: Condens. Matter 50 (1994) 17953-17979. | P.E. Blochl, Phys. Rev. B: Condens. Matter 50 (1994) 17953-17979. | ||
| 17 | 194 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left:white | [255, 255, 255] white | False | [37.65, 195.44, 240.58, 5.93] | J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 77 (1996) 3865-3868. | J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 77 (1996) 3865-3868. | ||
| 17 | 195 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 195.44, 250.98, 13.93] | P. Yan, L. Xiao, J. Zheng, Y. Zhou, Y. He, X. Zu, S.X. Mao, J. Xiao, F. Gao, J.-G. Zhang, C.-M. Wang, Chem. Mater. 27 (2015) 975-982. | P. Yan, L. Xiao, J. Zheng, Y. Zhou, Y. He, X. Zu, S.X. Mao, J. Xiao, F. Gao, J.-G. Zhang, C.-M. Wang, Chem. Mater. 27 (2015) 975-982. | ||
| 17 | 196 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left:white | [255, 255, 255] white | False | [37.64, 211.43, 222.33, 5.93] | S. Grimme, J. Antony, S. Ehrlich, H. Krieg, J. Chem. Phys. 132 (2010). | S. Grimme, J. Antony, S. Ehrlich, H. Krieg, J. Chem. Phys. 132 (2010). | ||
| 17 | 197 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.65, 219.36, 251.01, 5.93] | J. Zheng, P. Yan, L. Estevez, C. Wang, J.G. Zhang, Nano Energy 49 (2018) 538-548. | J. Zheng, P. Yan, L. Estevez, C. Wang, J.G. Zhang, Nano Energy 49 (2018) 538-548. | ||
| 17 | 198 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left:white | [255, 255, 255] white | False | [37.65, 227.36, 229.87, 5.93] | C. Yin, Z. Bao, H. Tan, H. Zhou, J. Li, Chem. Eng. J. 372 (2019) 408-419. | C. Yin, Z. Bao, H. Tan, H. Zhou, J. Li, Chem. Eng. J. 372 (2019) 408-419. | ||
| 17 | 199 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 211.43, 250.96, 5.93] | C.O. Ehi-Eromosele, S.O. Ajayi, C.N. Onwucha, Mater. Chem. Phys. 259 (2021). | C.O. Ehi-Eromosele, S.O. Ajayi, C.N. Onwucha, Mater. Chem. Phys. 259 (2021). | ||
| 17 | 200 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 219.36, 251.01, 13.93] | M. Cheng, K. Zhu, L. Yang, L. Zhu, Y. Li, W. Tang, J. Alloys Compd. 686 (2016) 496-502. | M. Cheng, K. Zhu, L. Yang, L. Zhu, Y. Li, W. Tang, J. Alloys Compd. 686 (2016) 496-502. | ||
| 17 | 201 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.65, 235.29, 251.01, 13.93] | A. Quesne-Turin, D. Flahaut, G. Salvato Vallverdu, L. Croguennec, J. Allouche, F. Weill, M. Ménétrier, I. Baraille, Appl. Surf. Sci. 542 (2021). | A. Quesne-Turin, D. Flahaut, G. Salvato Vallverdu, L. Croguennec, J. Allouche, F. Weill, M. Ménétrier, I. Baraille, Appl. Surf. Sci. 542 (2021). | ||
| 17 | 202 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 235.29, 251.01, 13.93] | J. Lin, C. Zeng, Y. Chen, X. Lin, C. Xu, C. Su, J. Mater. Chem. A 8 (2020) 66076618. | J. Lin, C. Zeng, Y. Chen, X. Lin, C. Xu, C. Su, J. Mater. Chem. A 8 (2020) 66076618. | ||
| 17 | 203 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.64, 251.28, 251.02, 13.87] | M. Chen, D. Chen, Y. Liao, X. Zhong, W. Li, Y. Zhang, ACS. Appl. Mater. Interfaces 8 (2016) 4575-4584. | M. Chen, D. Chen, Y. Liao, X. Zhong, W. Li, Y. Zhang, ACS. Appl. Mater. Interfaces 8 (2016) 4575-4584. | ||
| 17 | 204 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 251.28, 251.01, 13.87] | F. Li, X. Zhang, J. Lin, J. Ma, S. Zhang, G. Yang, J. Phys. Chem. C 123 (2019) 23403-23409. | F. Li, X. Zhang, J. Lin, J. Ma, S. Zhang, G. Yang, J. Phys. Chem. C 123 (2019) 23403-23409. | ||
| 17 | 205 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.64, 267.21, 251.03, 13.87] | G. Zhang, M. Chen, C. Li, B. Wu, J. Chen, W. Xiang, X. Wen, D. Zhang, G. Cao, W. Li, Chem. Eng. J. 443 (2022). | G. Zhang, M. Chen, C. Li, B. Wu, J. Chen, W. Xiang, X. Wen, D. Zhang, G. Cao, W. Li, Chem. Eng. J. 443 (2022). | ||
| 17 | 206 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 267.21, 250.98, 13.87] | A. Klein, P. Axmann, C. Yada, M. Wohlfahrt-Mehrens, J. Power Sources 288 (2015) 302-307. | A. Klein, P. Axmann, C. Yada, M. Wohlfahrt-Mehrens, J. Power Sources 288 (2015) 302-307. | ||
| 17 | 207 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left:white | [255, 255, 255] white | False | [37.64, 283.14, 232.98, 5.93] | P. Lanz, C. Villevieille, P. Novák, Electrochim. Acta 109 (2013) 426-432. | P. Lanz, C. Villevieille, P. Novák, Electrochim. Acta 109 (2013) 426-432. | ||
| 17 | 208 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.65, 291.14, 251.01, 13.87] | Y. Liu, T. Zhou, Y. Zheng, Z. He, C. Xiao, W.K. Pang, W. Tong, Y. Zou, B. Pan, Z. Guo, Y. Xie, ACS Nano 11 (2017) 8519-8526. | Y. Liu, T. Zhou, Y. Zheng, Z. He, C. Xiao, W.K. Pang, W. Tong, Y. Zou, B. Pan, Z. Guo, Y. Xie, ACS Nano 11 (2017) 8519-8526. | ||
| 17 | 209 | list_item | unknown_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:off_white | [246, 249, 251] off_white | False | [306.65, 283.14, 155.49, 5.93] | J.-M. Savéant, ACS Catal. 8 (2018) 7608-7611. | J.-M. Savéant, ACS Catal. 8 (2018) 7608-7611. | ||
| 17 | 210 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 291.14, 250.98, 13.87] | X. Zhang, J. Li, J. Li, L. Han, T. Lu, X. Zhang, G. Zhu, L. Pan, Chem. Eng. J. 385 (2020). | X. Zhang, J. Li, J. Li, L. Han, T. Lu, X. Zhang, G. Zhu, L. Pan, Chem. Eng. J. 385 (2020). | ||
| 17 | 211 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.64, 307.07, 251.01, 13.87] | B. Qiu, M. Zhang, L. Wu, J. Wang, Y. Xia, D. Qian, H. Liu, S. Hy, Y. Chen, K. An, Y. Zhu, Z. Liu, Y.S. Meng, Nat. Commun. 7 (2016) 12108. | B. Qiu, M. Zhang, L. Wu, J. Wang, Y. Xia, D. Qian, H. Liu, S. Hy, Y. Chen, K. An, Y. Zhu, Z. Liu, Y.S. Meng, Nat. Commun. 7 (2016) 12108. | ||
| 17 | 212 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 307.07, 250.97, 13.87] | Y. Hao, W. Liu, Q. Zhang, X. Wang, H. Yang, L. Kou, Z. Tian, L. Shao, H. Maleki Kheimeh Sari, J. Wang, H. Shan, X. Li, Nano Energy 88 (2021). | Y. Hao, W. Liu, Q. Zhang, X. Wang, H. Yang, L. Kou, Z. Tian, L. Shao, H. Maleki Kheimeh Sari, J. Wang, H. Shan, X. Li, Nano Energy 88 (2021). | ||
| 17 | 213 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.65, 323.0, 251.01, 13.87] | A. Zhu, Q. Wang, Y. Zhang, Y. Zhang, X. He, K. Wu, H. Wu, Q. Wang, W. Cai, Y. Zhang, J. Energy Chem. 71 (2022) 384-391. | A. Zhu, Q. Wang, Y. Zhang, Y. Zhang, X. He, K. Wu, H. Wu, Q. Wang, W. Cai, Y. Zhang, J. Energy Chem. 71 (2022) 384-391. | ||
| 17 | 214 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 323.0, 250.98, 13.87] | X. Huang, J. Zhao, W. Zhu, M. Hou, T. Zhou, L. Bu, L. Gao, W. Zhang, J. Energy Chem. 63 (2021) 376-384. | X. Huang, J. Zhao, W. Zhu, M. Hou, T. Zhou, L. Bu, L. Gao, W. Zhang, J. Energy Chem. 63 (2021) 376-384. | ||
| 17 | 215 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.65, 338.93, 251.01, 13.93] | Y. Wang, L. Feng, W. Fan, K.Y. Wang, X. Wang, X. Wang, K. Zhang, X. Zhang, F. Dai, D. Sun, H.C. Zhou, J. Am. Chem. Soc. 141 (2019) 6967-6975. | Y. Wang, L. Feng, W. Fan, K.Y. Wang, X. Wang, X. Wang, K. Zhang, X. Zhang, F. Dai, D. Sun, H.C. Zhou, J. Am. Chem. Soc. 141 (2019) 6967-6975. | ||
| 17 | 216 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 338.93, 233.89, 5.93] | J. Yang, J. Xian, Q. Liu, Y. Sun, G. Li, J. Energy Chem. 69 (2022) 524-530. | J. Yang, J. Xian, Q. Liu, Y. Sun, G. Li, J. Energy Chem. 69 (2022) 524-530. | ||
| 17 | 217 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 346.92, 244.72, 5.93] | J. Lin, T. Huang, M. Lu, X. Lin, R.C.K. Reddy, X. Xu, Chem. Eng. J. 433 (2022). | J. Lin, T. Huang, M. Lu, X. Lin, R.C.K. Reddy, X. Xu, Chem. Eng. J. 433 (2022). | ||
| 17 | 218 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.64, 354.86, 251.04, 13.93] | L. Xiao, J. Xiao, X. Yu, P. Yan, J. Zheng, M. Engelhard, P. Bhattacharya, C. Wang, X.-Q. Yang, J.-G. Zhang, Nano Energy 16 (2015) 143-151. | L. Xiao, J. Xiao, X. Yu, P. Yan, J. Zheng, M. Engelhard, P. Bhattacharya, C. Wang, X.-Q. Yang, J.-G. Zhang, Nano Energy 16 (2015) 143-151. | ||
| 17 | 219 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 354.86, 250.96, 13.93] | Q. Li, Y. Zhao, H. Liu, P. Xu, L. Yang, K. Pei, Q. Zeng, Y. Feng, P. Wang, R. Che, ACS Nano 13 (2019) (1934) 11921-11931. | Q. Li, Y. Zhao, H. Liu, P. Xu, L. Yang, K. Pei, Q. Zeng, Y. Feng, P. Wang, R. Che, ACS Nano 13 (2019) (1934) 11921-11931. | ||
| 17 | 220 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:left_crossing:white | [255, 255, 255] white | False | [37.65, 370.79, 250.98, 13.93] | J.-E. Zhou, J. Chen, Y. Peng, Y. Zheng, A. Zeb, X. Lin, Coord. Chem. Rev. 472 (2022). | J.-E. Zhou, J. Chen, Y. Peng, Y. Zheng, A. Zeb, X. Lin, Coord. Chem. Rev. 472 (2022). | ||
| 17 | 221 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:page_body:right_crossing:white | [255, 255, 255] white | False | [306.65, 370.79, 250.97, 13.93] | M.A. Kebede, M.J. Phasha, N. Kunjuzwa, L.J. le Roux, D. Mkhonto, K.I. Ozoemena, M.K. Mathe, Sustain. Energy Technol. Assess. 5 (2014) 44-49. | M.A. Kebede, M.J. Phasha, N. Kunjuzwa, L.J. le Roux, D. Mkhonto, K.I. Ozoemena, M.K. Mathe, Sustain. Energy Technol. Assess. 5 (2014) 44-49. | ||
| 17 | 222 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p17:bottom_margin:left_crossing:white | [255, 255, 255] white | False | [291.91, 764.24, 11.38, 5.93] | 180 | 180 |