Docling layout block audit

original.pdf docling.json layout_blocks.json layout_blocks.tsv layout_blocks.jsonl excluded_blocks.html excluded_blocks.tsv final_body_blocks.tsv visual_assets.tsv visual_assets.json

Summary

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    "empty_after_cleaning": 9,
    "recovered_unbound_docling_caption": 3,
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Diff Summary

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Truncation

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    "text_preview": "speci fi c capacities of 2.0 wt% CoF2-coated sample (CF-2.0) and other four samples after 1st cycle and 100 th cycle, respectively. The initial discharge capacity of 236.0 mAh g \u0000 1 and operating potential of 3.444 V fo…"
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Page Overlays

Green = final body chunks. Orange/purple asset boxes = actual figure/table assets used by ingestion. Cyan dashed text boxes = text blocks consumed by those assets as caption continuations. Red STOP = truncation trigger. Red boxes = blocks after truncation.

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Visual Assets

这里对齐真实图表资产提取链路。caption_source=embedded_table_cell 表示表注来自 Docling table cell,不会出现在 text block 审计差集里;caption_continuation_used_by_asset 表示某个 text block 已被图表 caption 吸收,不应按普通 metadata 解读。

#typelabelpagecaption sourcesuppressedduplicate reasonrescue reasongroupconfidencebboxcaption
1figureDocling Figure 14missing_caption0.55[117.97, 66.61, 369.57, 434.98]
2figureDocling Figure 25missing_caption0.55[107.59, 65.57, 369.63, 541.34]
3figureDocling Figure 36missing_caption0.55[112.57, 67.04, 381.25, 300.21]
4figureDocling Figure 47missing_caption0.55[92.29, 65.57, 400.51, 442.12]
5figureDocling Figure 58missing_caption0.55[110.44, 69.66, 382.45, 279.34]
6figureDocling Figure 68missing_caption0.55[109.22, 395.25, 384.95, 143.13]

Blocks

pageorderlabelroleincludedriskreasonparser reasonproduction usage truncbody regionregionbgframebboxraw textcleaned text
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False[224.67, 47.78, 136.29, 6.37]Journal of Power Sources 332 (2016) 230 e 239Journal of Power Sources 332 (2016) 230 e 239
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False[216.51, 79.77, 156.17, 1.59]Contents lists available at ScienceDirectContents lists available at ScienceDirect
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False[210.56, 98.49, 167.92, 12.99]Journal of Power SourcesJournal of Power Sources
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False[165.09, 135.72, 258.93, 1.59]j o urnal homepage: www.elsevier.com/locate/jpowsourj o urnal homepage:
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False[32.82, 178.39, 414.73, 47.0]Suppressing capacity fading and voltage decay of Li-rich layered cathode material by a surface nano-protective layer of CoF2 for lithium-ion batteriesSuppressing capacity fading and voltage decay of Li-rich layered cathode material by a surface nano-protective layer of CoF2 for lithium-ion batteries
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False[32.83, 235.4, 399.71, 25.14]Shaokun Chong a , Yuanzhen Chen a , Wuwei Yan a , Shengwu Guo a , Qiang Tan a , Yifang Wu b , Tao Jiang a , Yongning Liu a, *Shaokun Chong a , Yuanzhen Chen a , Wuwei Yan a , Shengwu Guo a , Qiang Tan a , Yifang Wu b , Tao Jiang a , Yongning Liu a, *
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False[32.83, 267.32, 446.32, 7.46]a State Key Laboratory for Mechanical Behavior of Materials, School of Material Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049, PR Chinaa State Key Laboratory for Mechanical Behavior of Materials, School of Material Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049, PR China
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False[32.83, 275.88, 225.32, 7.46]b Northwest Institute for Nonferrous Metal Research, Xi'an, 710016, PR Chinab Northwest Institute for Nonferrous Metal Research, Xi'an, 710016, PR China
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False[32.83, 313.97, 86.34, 0.06]h i g h l i g h t sh i g h l i g h t s
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False[197.22, 313.97, 152.63, 0.06]g r a p h i c a l a b s t r a c tg r a p h i c a l a b s t r a c t
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False[32.83, 327.92, 133.2, 26.17] Nano-CoF2 is fi rstly coated on Li1.2Ni0.2Mn0.6O2 via a wet chemistry method. Nano-CoF2 is fi rstly coated on Li1.2Ni0.2Mn0.6O2 via a wet chemistry method.
111list_itembodyTruerecovered_body_outside_flowrecovered_body_outside_flow
p1:front_matter:column_1_of_2:white[255, 255, 255]
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False[32.83, 356.69, 133.16, 26.1] 0.5% CoF2-coated sample delivers the improved initial coulombic ef fi ciency of 86.2%. 0.5% CoF2-coated sample delivers the improved initial coulombic ef fi ciency of 86.2%.
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False[32.83, 385.37, 133.19, 26.1] Excellent stability of capacity and voltage are observed for 1.0% CoF2coating. Excellent stability of capacity and voltage are observed for 1.0% CoF2coating.
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False[32.83, 414.12, 133.22, 26.04] The mechanisms of serious fading of capacity and voltage are discussed in details. The mechanisms of serious fading of capacity and voltage are discussed in details.
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False[32.83, 442.8, 133.26, 26.04] Structure transition is suppressed by CoF2 nano-coating evidenced by TEM analysis. Structure transition is suppressed by CoF2 nano-coating evidenced by TEM analysis.
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False[32.83, 497.82, 95.61, 0.06]a r t i c l e i n f oa r t i c l e i n f o
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False[197.23, 497.82, 67.73, 0.06]a b s t r a c ta b s t r a c t
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False[32.83, 511.33, 85.09, 40.53]Article history: Received 8 July 2016 Received in revised form 2 September 2016 Accepted 6 September 2016Article history: Received 8 July 2016 Received in revised form 2 September 2016 Accepted 6 September 2016
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False[32.83, 554.53, 109.97, 5.94]Available online 29 September 2016Available online 29 September 2016
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False[32.83, 573.97, 59.83, 49.14]Keywords: Lithium-ion battery Cathode material CoF2 coating layer Capacity fading Voltage decayKeywords: Lithium-ion battery Cathode material CoF2 coating layer Capacity fading Voltage decay
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False[197.23, 512.05, 355.76, 102.32]Li-rich layered oxides have been regarded as valuable cathode materials for high energy density lithium-ion batteries. However, high initial irreversible capacity, bad rate capability, as well as serious capacity fading…Li-rich layered oxides have been regarded as valuable cathode materials for high energy density lithium-ion batteries. However, high initial irreversible capacity, bad rate capability, as well as serious capacity fading…
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False[416.24, 615.67, 136.59, 8.36]© 2016 Elsevier B.V. All rights reserved.© 2016 Elsevier B.V. All rights reserved.
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False[301.83, 675.65, 62.13, 7.42]1. Introduction1. Introduction
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False[37.87, 700.81, 3.32, 6.91]*
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False[44.56, 701.71, 141.56, 14.59]Corresponding author. E-mail address: ynliu@mail.xjtu.edu.cn (Y. Liu).Corresponding author. E-mail address: ynliu@mail.xjtu.edu.cn (Y. Liu).
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False[301.83, 696.57, 251.04, 17.91]To meet more demanding requirements for portable electronics, electric vehicles and hybrid electric vehicles, rechargeable lithium-To meet more demanding requirements for portable electronics, electric vehicles and hybrid electric vehicles, rechargeable lithium-
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False[32.83, 728.64, 156.13, 14.57]http://dx.doi.org/10.1016/j.jpowsour.2016.09.028 0378-7753/ © 2016 Elsevier B.V. All rights reserved.0378-7753/ © 2016 Elsevier B.V. All rights reserved.
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True[133.4, 378.9, 18.05, 5.94]Fig. 4.Fig. 4.
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True[154.66, 378.9, 316.99, 5.94]XPS spectra of LNMO, CF-0.1, CF-0.5 and CF-1.0 in the region of (a) Ni 2p, (b) Mn 2p, (c) Co 2p and (d) F 1s.XPS spectra of LNMO, CF-0.1, CF-0.5 and CF-1.0 in the region of (a) Ni 2p, (b) Mn 2p, (c) Co 2p and (d) F 1s.
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True[42.52, 411.97, 251.03, 7.42]ion vacancy in TM layers during initial discharge procedure resultingion vacancy in TM layers during initial discharge procedure resulting
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True[42.52, 422.4, 251.06, 7.42]in a large irreversible capacity loss [31,42,43], corresponding sche-in a large irreversible capacity loss [31,42,43], corresponding sche-
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False[42.52, 432.89, 20.86, 7.42]maticmatic
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False[68.26, 432.89, 17.91, 7.42]viewview
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False[91.05, 432.89, 7.2, 7.42]ofof
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p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
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True[103.24, 432.89, 73.15, 7.42]extraction/insertionextraction/insertion
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False[42.52, 443.32, 35.43, 7.42]dischargedischarge
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False[82.37, 443.32, 27.82, 7.42]processprocess
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False[114.57, 443.32, 7.42, 7.42]inin
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True[126.37, 443.32, 88.32, 7.42]LNMO active materialsLNMO active materials
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True[42.52, 453.81, 251.07, 7.42]Fig. 5(b) presents the CV pro fi les of all the samples for the initialFig. 5(b) presents the CV pro fi les of all the samples for the initial
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p4:body_region:0p4:page_body:column_1_of_2:unknownNone
unknown
True[161.18, 461.98, 4.79, 10.33]þ
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p4:body_region:0p4:page_body:column_1_of_2:unknownNone
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True[157.72, 462.19, 3.56, 5.57]22
442textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_1_of_2:unknownNone
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True[177.0, 462.19, 3.56, 5.57]33
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True[42.52, 464.24, 115.38, 7.42]cycle. The oxidation peaks of Nicycle. The oxidation peaks of Ni
444textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_1_of_2:unknownNone
unknown
True[166.0, 464.24, 11.18, 7.42]/Ni/Ni
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p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
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True[42.52, 474.73, 251.13, 7.42]well as the peaks of the release of O2 at about 4.75 V can be observedwell as the peaks of the release of O2 at about 4.75 V can be observed
446textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
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True[42.52, 485.16, 251.03, 7.42]clearly for all the samples during initial charge process, while theclearly for all the samples during initial charge process, while the
447textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
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True[42.52, 495.65, 251.04, 7.43]peak intensity of the release of O2 weakens gradually as the increasepeak intensity of the release of O2 weakens gradually as the increase
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p4:top_margin:column_2_of_2:white[255, 255, 255]
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False[213.68, 47.78, 177.75, 6.46]S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239
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False[551.68, 48.21, 10.94, 5.94]235235
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True[323.49, 411.97, 38.8, 7.42]Especially,Especially,
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True[366.58, 411.97, 12.33, 7.42]thethe
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p4:body_region:1p4:page_body:column_2_of_2:unknownNone
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True[383.24, 411.97, 21.9, 7.42]initialinitial
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True[409.49, 411.97, 36.11, 7.42]dischargedischarge
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True[449.97, 411.97, 31.04, 7.42]capacitycapacity
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True[485.17, 411.97, 77.41, 7.42]and coulombic ef fi -and coulombic ef fi -
456textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
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True[311.53, 422.4, 251.05, 7.42]ciency of CF-1.0 slightly decrease compared to CF-0.5, which isciency of CF-1.0 slightly decrease compared to CF-0.5, which is
457textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[199.79, 430.57, 4.79, 10.33]þ
458textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:unknownNone
unknown
True[311.53, 432.89, 43.25, 7.42]responsibleresponsible
459textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:unknownNone
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True[359.94, 432.89, 10.69, 7.42]forfor
460textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:unknownNone
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True[375.76, 432.89, 12.33, 7.42]thethe
461textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:colored[47, 97, 14]
colored
True[393.28, 432.89, 35.13, 7.42]relativelyrelatively
462textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:unknownNone
unknown
True[433.47, 432.89, 26.57, 7.42]thickerthicker
463textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
True[464.99, 432.89, 27.68, 7.42]coatingcoating
464textbodyTruebodybody
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[497.82, 432.89, 18.56, 7.42]layerlayer
465textbodyTruebodybody
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[521.51, 432.89, 41.07, 7.42]restrainingrestraining
466textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[181.3, 432.89, 7.33, 7.42]ofof
467textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[193.49, 432.89, 6.47, 7.42]LiLi
468textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[209.65, 432.89, 24.61, 7.42]duringduring
469textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[239.24, 432.89, 21.35, 7.42]initialinitial
470textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[265.55, 432.89, 28.08, 7.42]charge-charge-
471textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:unknownNone
unknown
True[311.53, 443.32, 93.23, 7.43]overmuch the loss of O2.overmuch the loss of O2.
472textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[219.11, 443.32, 53.83, 7.42]shown in Fig.shown in Fig.
473textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[277.4, 443.32, 16.19, 7.42]5(c).5(c).
474textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[180.45, 461.98, 4.79, 10.33]þ
475textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[199.79, 461.98, 4.79, 10.33]þ
476textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[196.27, 462.19, 3.56, 5.57]44
477textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[259.14, 463.71, 6.22, 7.96]ee
478textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:unknownNone
unknown
True[311.53, 463.81, 19.15, 7.97]3.2.2.3.2.2.
479textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:unknownNone
unknown
True[335.62, 463.81, 141.35, 7.97]Cyclic performance and rate capabilityCyclic performance and rate capability
480textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[185.27, 464.24, 11.09, 7.42]/Ni/Ni
481textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:colored[95, 99, 19]
colored
True[206.59, 464.24, 52.65, 7.42]at about 3.875at about 3.875
482textvisual_textFalselowvisual_textvisual_text
p4:body_region:0p4:page_body:column_2_of_2:unknownNone
unknown
True[265.38, 464.24, 28.32, 7.42]4.0 V as4.0 V as
483textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
True[323.49, 474.73, 239.06, 7.42]Fig. 6(a) shows the cycling stability of all the cathode materialsFig. 6(a) shows the cycling stability of all the cathode materials
484textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:unknownNone
unknown
True[480.98, 484.62, 6.22, 7.96]ee
485textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:unknownNone
unknown
True[311.53, 485.16, 169.49, 7.42]measured at 0.1C in the voltage range of 2.0measured at 0.1C in the voltage range of 2.0
486textbodyTruebodybody
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
True[487.28, 485.16, 75.28, 7.42]4.8 V. CF-0.1, CF-0.54.8 V. CF-0.1, CF-0.5
487textunknown_textFalsemediumempty_after_cleaningempty_after_cleaning
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[552.98, 493.33, 4.79, 10.33]
488textbodyTruebodybody
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[557.8, 493.54, 3.56, 5.57]11
489textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:gray[234, 231, 231]
gray
True[311.53, 495.65, 14.15, 7.42]andand
490textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:gray[233, 231, 231]
gray
True[331.03, 495.65, 23.14, 7.42]CF-1.0CF-1.0
491textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:gray[230, 230, 230]
gray
True[359.54, 495.65, 26.3, 7.42]exhibitexhibit
492textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:gray[230, 230, 230]
gray
True[391.24, 495.65, 12.33, 7.42]thethe
493textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:gray[231, 231, 230]
gray
True[408.98, 495.65, 36.11, 7.42]dischargedischarge
494textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:gray[231, 231, 230]
gray
True[450.53, 495.65, 31.04, 7.42]capacitycapacity
495textvisual_textFalselowvisual_textvisual_text
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
True[486.87, 495.65, 7.33, 7.42]ofof
496textbodyTruebodybody
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[499.63, 495.65, 53.35, 7.42]207.2 mAh g207.2 mAh g
497textunknown_textFalsemediumempty_after_cleaningempty_after_cleaning
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[560.69, 495.65, 1.9, 7.42],
498captionbodyTruerecovered_unbound_docling_captionrecovered_unbound_docling_caption
p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[42.52, 503.82, 520.07, 31.25]of CoF2 coating amount in consequence of effective suppression of the loss of O2 by nano-coating layer. And the reduction peaks of Ni 4 þ / Ni 3 þ /Ni 2 þ at approximately 3.75 V as well as the weak reduction 225.3 mAh …of CoF2 coating amount in consequence of effective suppression of the loss of O2 by nano-coating layer. And the reduction peaks of Ni 4 þ / Ni 3 þ /Ni 2 þ at approximately 3.75 V as well as the weak reduction 225.3 mAh …
499textunknown_textFalsemediumempty_after_cleaningempty_after_cleaning
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[149.27, 535.17, 4.79, 10.33]þ
4100textunknown_textFalsemediumempty_after_cleaningempty_after_cleaning
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[172.8, 535.17, 4.79, 10.33]þ
4101textbodyTruebodybody
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[42.52, 535.38, 106.85, 9.53]peaks corresponding to Mn 4peaks corresponding to Mn 4
4102textbodyTruebodybody
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[154.03, 535.38, 18.81, 9.53]/Mn 3/Mn 3
4103captionbodyTruerecovered_unbound_docling_captionrecovered_unbound_docling_caption
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[42.52, 547.92, 251.12, 29.31]initial discharge process are observed. Besides, the intensity of reduction peaks of Mn 4 þ /Mn 3 þ wanes with increasing the amount of CoF2 coating as a result of the reduction of MnO2 with electro-initial discharge process are observed. Besides, the intensity of reduction peaks of Mn 4 þ /Mn 3 þ wanes with increasing the amount of CoF2 coating as a result of the reduction of MnO2 with electro-
4104textunknown_textFalsemediumempty_after_cleaningempty_after_cleaning
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[107.21, 629.34, 4.79, 10.33]
4105textbodyTruebodybody
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[111.97, 629.55, 3.56, 5.57]11
4106textbodyTruebodybody
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[42.52, 631.6, 64.69, 7.42]and 259.1 mAh gand 259.1 mAh g
4107textbodyTruebodybody
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[118.15, 631.6, 175.42, 7.42]as well as larger fi rst coulombic ef fi ciencies ofas well as larger fi rst coulombic ef fi ciencies of
4108textbodyTruebodybody
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[42.52, 642.09, 22.5, 7.42]82.1%,82.1%,
4109textbodyTruebodybody
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[69.67, 642.09, 188.56, 7.42]86.2% and 84.4% than bare LNMO (244.0 mAh86.2% and 84.4% than bare LNMO (244.0 mAh
4110textbodyTruebodybody
p4:body_region:0p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[42.52, 652.57, 251.07, 38.78]75.5%), respectively, which mainly attributed to the suppression of side reaction between electrolyte and active material at high potential by CoF2 protective layer, less electrolyte oxidation resulting from less oxygen…75.5%), respectively, which mainly attributed to the suppression of side reaction between electrolyte and active material at high potential by CoF2 protective layer, less electrolyte oxidation resulting from less oxygen…
4111textbodyTruebodybody
p4:body_region:0p4:bottom_margin:column_1_of_2:white[255, 255, 255]
white
False[42.52, 694.41, 251.08, 55.33]additional capacity provided by reduction reaction of CoF2 during initial discharge process, the electrochemical conversion reactions of CoF2 shown as follows: CoF2 þ 2Li þ þ 2e / Co þ 2LiF [31].additional capacity provided by reduction reaction of CoF2 during initial discharge process, the electrochemical conversion reactions of CoF2 shown as follows: CoF2 þ 2Li þ þ 2e / Co þ 2LiF [31].
4112textbodyTruebodybody
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[365.39, 504.03, 3.56, 5.57]11
4113textbodyTruebodybody
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[441.52, 504.03, 3.56, 5.57]11
4114textbodyTruebodybody
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[311.53, 537.49, 251.03, 7.42]of 63.0% for bare LNMO is obtained at 0.1C. The reason for thisof 63.0% for bare LNMO is obtained at 0.1C. The reason for this
4115textbodyTruebodybody
p4:body_region:0p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[180.51, 537.49, 113.05, 7.42]couple at about 3.25 V duringcouple at about 3.25 V during
4116textbodyTruebodybody
p4:body_region:1p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[311.53, 547.92, 251.06, 59.75]superior cyclic stability, which generally enhances as the content of CoF2 nano-coating increases, involves two aspects. One reason can be the subdued interfacial reaction and the reduction of TM dissolution bene fi tin…superior cyclic stability, which generally enhances as the content of CoF2 nano-coating increases, involves two aspects. One reason can be the subdued interfacial reaction and the reduction of TM dissolution bene fi tin…
4117textbodyTruebodybody
p4:body_region:1p4:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[311.53, 610.68, 251.07, 133.0]phase transformation from layer to spinel structure upon cycling. Voltage decay resulting from the layer-spinel structure conversion, which gives rise to serious decrease in energy density upon cycling, is one of the ma…phase transformation from layer to spinel structure upon cycling. Voltage decay resulting from the layer-spinel structure conversion, which gives rise to serious decrease in energy density upon cycling, is one of the ma…
4118textunknown_textFalsemediumempty_after_cleaningempty_after_cleaning
p4:body_region:0p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[266.46, 639.83, 4.79, 10.33]
4119textbodyTruebodybody
p4:body_region:0p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[271.22, 640.03, 3.56, 5.57]11
4120textunknown_textFalsemediumempty_after_cleaningempty_after_cleaning
p4:body_region:0p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[258.24, 641.55, 3.71, 7.96]$
4121textbodyTruebodybody
p4:body_region:0p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[261.92, 642.09, 4.48, 7.42]gg
4122textbodyTruebodybody
p4:body_region:0p4:page_body:column_2_of_2:white[255, 255, 255]
white
False[279.44, 642.09, 14.15, 7.42]andand
5123page_headerpage_headerFalselowdocling_page_headerdocling_page_header
p5:body_region:0p5:top_margin:column_1_of_2:white[255, 255, 255]
white
False[32.82, 48.21, 10.94, 5.94]236236
5124page_headerpage_headerFalselowdocling_page_headerdocling_page_header
p5:top_margin:column_2_of_2:white[255, 255, 255]
white
False[203.98, 47.78, 177.75, 6.46]S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239
5125textvisual_textFalselowvisual_textvisual_text
p5:body_region:1p5:page_body:column_1_of_2:white[253, 253, 253]
white
True[53.46, 516.44, 499.38, 5.94](a) Initial charge-discharge curves of bare LNMO, CF-0.1, CF-0.5 and CF-1.0 from 2.0 V to 4.8 V at 0.1C and (b) corresponding cyclic voltammetry pro fi les; (c) schematic view of(a) Initial charge-discharge curves of bare LNMO, CF-0.1, CF-0.5 and CF-1.0 from 2.0 V to 4.8 V at 0.1C and (b) corresponding cyclic voltammetry pro fi les; (c) schematic view of
5126textbodyTruebodybody
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[32.83, 516.44, 17.49, 5.94]Fig. 5.Fig. 5.
5127textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[105.39, 523.41, 3.68, 7.71]þ
5128textbodyTruebodybody
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[32.83, 525.0, 72.55, 5.94]extraction/insertion of Liextraction/insertion of Li
5129textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_1_of_2:gray[185, 184, 184]
gray
True[111.17, 525.0, 194.81, 5.94]during initial charge-discharge process for LNMO active materials.during initial charge-discharge process for LNMO active materials.
5130textbodyTruebodybody
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[32.83, 558.41, 31.89, 7.42]stability.stability.
5131textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
True[44.79, 568.84, 239.09, 7.42]Fig. 6(c) presents energy density fading curves upon cycling,Fig. 6(c) presents energy density fading curves upon cycling,
5132textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
True[32.83, 579.33, 251.04, 7.42]which re fl ect the integration stability of capacity and voltage. CF-which re fl ect the integration stability of capacity and voltage. CF-
5133textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
True[32.83, 589.76, 251.04, 7.42]0.1, CF-0.5 and CF-1.0 reveal much higher initial energy densities0.1, CF-0.5 and CF-1.0 reveal much higher initial energy densities
5134textunknown_textFalsemediumempty_after_cleaningempty_after_cleaning
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[90.03, 597.93, 4.79, 10.33]
5135textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
True[149.73, 597.93, 4.79, 10.33]
5136textbodyTruebodybody
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[94.79, 598.14, 3.56, 5.57]11
5137textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_1_of_2:gray[82, 82, 82]
gray
True[154.49, 598.14, 3.56, 5.57]11
5138textbodyTruebodybody
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[32.83, 600.25, 57.19, 7.42]of 914.9 Wh kgof 914.9 Wh kg
5139textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
True[97.68, 600.25, 52.03, 7.42], 949.1 Wh kg, 949.1 Wh kg
5140textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
True[160.44, 600.25, 64.79, 7.42]and 926.7 Wh kgand 926.7 Wh kg
5141textunknown_textFalsemediumempty_after_cleaningempty_after_cleaning
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[142.58, 608.42, 4.79, 10.33]
5142textbodyTruebodybody
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[147.34, 608.63, 3.56, 5.57]11
5143textbodyTruebodybody
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[32.83, 610.68, 109.74, 7.42]compared with 872.9 Wh kgcompared with 872.9 Wh kg
5144textbodyTruebodybody
p5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[153.69, 610.68, 130.15, 7.42]for LNMO, as a result of improvedfor LNMO, as a result of improved
5145textvisual_textFalselowvisual_textvisual_text
p5:body_region:1p5:page_body:column_2_of_2:white[253, 253, 253]
white
False[301.83, 558.41, 251.01, 7.42]the one hand, the relatively thicker coating layer not only sup-the one hand, the relatively thicker coating layer not only sup-
5146textvisual_textFalselowvisual_textvisual_text
p5:body_region:1p5:page_body:column_2_of_2:white[253, 252, 252]
white
False[301.83, 568.84, 138.43, 8.39]presses excessively the release of O2presses excessively the release of O2
5147textbodyTruebodybody
p5:body_region:1p5:page_body:column_2_of_2:white[255, 255, 255]
white
False[442.94, 568.84, 109.91, 7.42]but also prevents the extrac-but also prevents the extrac-
5148textvisual_textFalselowvisual_textvisual_text
p5:body_region:1p5:page_body:column_2_of_2:white[252, 252, 252]
white
False[372.25, 577.01, 4.79, 10.33]þ
5149textvisual_textFalselowvisual_textvisual_text
p5:body_region:1p5:page_body:column_2_of_2:white[252, 252, 252]
white
False[301.83, 579.33, 70.41, 7.42]tion/insertion of Lition/insertion of Li
5150textvisual_textFalselowvisual_textvisual_text
p5:body_region:1p5:page_body:column_2_of_2:white[254, 254, 253]
white
False[379.5, 579.33, 173.33, 7.42]in layered structure, resulting in low capacity.in layered structure, resulting in low capacity.
5151textvisual_textFalselowvisual_textvisual_text
p5:body_region:1p5:page_body:column_2_of_2:white[253, 253, 253]
white
False[301.83, 589.76, 251.04, 7.42]On the other hand, the low reduction potential of 2.854 V for CoF2/On the other hand, the low reduction potential of 2.854 V for CoF2/
5152textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_2_of_2:white[255, 255, 255]
white
True[225.24, 597.93, 4.79, 10.33]
5153textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_2_of_2:unknownNone
unknown
True[230.0, 598.14, 3.56, 5.57]11
5154textvisual_textFalselowvisual_textvisual_text
p5:body_region:1p5:page_body:column_2_of_2:white[253, 253, 253]
white
False[301.83, 600.25, 251.02, 7.42]LiF can reduce the operating voltage of CF-2.0. Moreover, CF-2.0LiF can reduce the operating voltage of CF-2.0. Moreover, CF-2.0
5155textvisual_textFalselowvisual_textvisual_text
p5:body_region:0p5:page_body:column_2_of_2:white[255, 255, 255]
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True[232.89, 600.25, 50.99, 7.42], respectively,, respectively,
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False[301.83, 610.68, 29.93, 7.42]exhibitsexhibits
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False[336.58, 610.68, 12.33, 7.42]thethe
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False[353.82, 610.68, 36.38, 7.42]improvedimproved
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False[395.03, 610.68, 30.35, 7.42]stabilitystability
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False[430.24, 610.68, 17.51, 7.42]withwith
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False[452.63, 610.68, 12.33, 7.42]thethe
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False[469.81, 610.68, 31.04, 7.42]capacitycapacity
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False[505.75, 610.68, 34.9, 7.42]retentionretention
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False[545.55, 610.68, 7.33, 7.42]ofof
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False[32.82, 621.17, 520.06, 17.86]initial discharge capacities and similar operating voltage after CoF2 coating. Accordingly, the excellent stability of capacity and voltage 93.6% and the value of voltage drop of 0.299 V after 100 cycles as shown in Fig…initial discharge capacities and similar operating voltage after CoF2 coating. Accordingly, the excellent stability of capacity and voltage 93.6% and the value of voltage drop of 0.299 V after 100 cycles as shown in Fig…
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False[32.83, 642.09, 251.07, 7.42]for CF-1.0 delivers the highest retention value of 84.9% after 100for CF-1.0 delivers the highest retention value of 84.9% after 100
5167textbodyTruebodybody
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False[32.83, 652.57, 251.05, 7.42]cycles despite reducing on the fi rst discharge capacity than CF-0.5,cycles despite reducing on the fi rst discharge capacity than CF-0.5,
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False[32.83, 663.0, 215.53, 7.42]while LNMO exhibits the lowest retention value of 51.1%.while LNMO exhibits the lowest retention value of 51.1%.
5169section_headerbody_headingFalselowbody_headingbody_heading
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False[44.79, 673.49, 239.1, 7.42]In order to investigate the capacity and voltage stability for theIn order to investigate the capacity and voltage stability for the
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False[32.83, 683.92, 251.03, 7.43]sample whose CoF2 coating content is higher than 1.0 wt%, Fig. S1 insample whose CoF2 coating content is higher than 1.0 wt%, Fig. S1 in
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False[32.83, 694.41, 251.02, 7.42]supplementary materials presents the operation voltages versussupplementary materials presents the operation voltages versus
5172textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
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False[32.83, 704.84, 251.08, 38.83]speci fi c capacities of 2.0 wt% CoF2-coated sample (CF-2.0) and other four samples after 1st cycle and 100 th cycle, respectively. The initial discharge capacity of 236.0 mAh g 1 and operating potential of 3.444 V fo…speci fi c capacities of 2.0 wt% CoF2-coated sample (CF-2.0) and other four samples after 1st cycle and 100 th cycle, respectively. The initial discharge capacity of 236.0 mAh g 1 and operating potential of 3.444 V fo…
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False[301.83, 642.08, 251.04, 7.42]1.0. However, CF-2.0 delivers the much lower energy density of1.0. However, CF-2.0 delivers the much lower energy density of
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False[349.0, 650.26, 4.79, 10.33]
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False[353.76, 650.47, 3.56, 5.57]11
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False[301.83, 652.57, 47.16, 7.42]694.6 Wh kg694.6 Wh kg
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False[359.15, 652.57, 193.75, 7.42]than CF-0.5 and CF-1.0 owing to its low capacity andthan CF-0.5 and CF-1.0 owing to its low capacity and
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False[301.83, 663.01, 251.03, 7.42]voltage. Thus, CF-1.0 reaches the optimal integrated performancevoltage. Thus, CF-1.0 reaches the optimal integrated performance
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False[301.83, 673.49, 251.04, 70.18]between high capacity, high operating voltage and outstanding cycling stability. The excellence in rate capability, performed at various current densities from 0.1 C to 5 C between 2.0 and 4.8 V, further highlights the …between high capacity, high operating voltage and outstanding cycling stability. The excellence in rate capability, performed at various current densities from 0.1 C to 5 C between 2.0 and 4.8 V, further highlights the …
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False[213.68, 47.78, 177.75, 6.46]S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239
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False[551.79, 48.21, 10.79, 5.94]237237
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False[63.67, 359.17, 498.87, 5.94](a) Cycling performance, (b) discharge median voltage, (c) energy density and (d) rate discharge capability curves of all the samples at 0.1C between 2.0 V and 4.8 V upon(a) Cycling performance, (b) discharge median voltage, (c) energy density and (d) rate discharge capability curves of all the samples at 0.1C between 2.0 V and 4.8 V upon
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False[42.52, 359.17, 17.94, 5.94]Fig. 6.Fig. 6.
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False[42.52, 367.73, 21.75, 5.94]cycling.cycling.
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False[129.6, 547.84, 432.99, 70.26]fi tted with the equivalent circuits in the inset. Fig. 7(a) presents the EIS curves of the cells at open circuit potential before cycling. The intercept on the x-axis at the highest frequency is related to ohmic resist…fi tted with the equivalent circuits in the inset. Fig. 7(a) presents the EIS curves of the cells at open circuit potential before cycling. The intercept on the x-axis at the highest frequency is related to ohmic resist…
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False[42.52, 547.84, 251.06, 49.98]5 C, CF-1.0 exhibits the highest capacity of 167.5 mAh g 1 , yet that of LNMOis only 120.1 mAh g 1 . Moreover, when the current density is Fig. 7.5 C, CF-1.0 exhibits the highest capacity of 167.5 mAh g 1 , yet that of LNMOis only 120.1 mAh g 1 . Moreover, when the current density is Fig. 7.
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False[42.52, 600.25, 251.08, 122.51]back to 0.1 C, the discharge capacity returns to 98.7% of its initial value for CF-1.0, implying good reversibility and structural stability after high-rate measurements. The primary reason for the signi fi cantly impro…back to 0.1 C, the discharge capacity returns to 98.7% of its initial value for CF-1.0, implying good reversibility and structural stability after high-rate measurements. The primary reason for the signi fi cantly impro…
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False[42.52, 725.76, 251.05, 7.42]surements of all fi ve samples were performed respectively, whosesurements of all fi ve samples were performed respectively, whose
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False[311.53, 621.17, 251.07, 123.42]represents charge-transfer resistance (Rct), and the slope line at the low frequency is assigned to the Warburg impedance (Zw) exhibiting the diffusion of Li þ in the electrode material. It can be obviously seen that a …represents charge-transfer resistance (Rct), and the slope line at the low frequency is assigned to the Warburg impedance (Zw) exhibiting the diffusion of Li þ in the electrode material. It can be obviously seen that a …
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False[32.82, 48.21, 10.94, 5.94]238238
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False[203.98, 47.78, 177.75, 6.46]S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239
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False[53.69, 540.02, 499.18, 5.94](a) Schematic view of structural transformation from layered to spinel phase upon cycling for LNMO active materials; (b1) TEM image, (b2) corresponding SAED pattern and(a) Schematic view of structural transformation from layered to spinel phase upon cycling for LNMO active materials; (b1) TEM image, (b2) corresponding SAED pattern and
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False[32.83, 540.02, 17.66, 5.94]Fig. 8.Fig. 8.
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False[32.82, 548.58, 8.69, 6.64](b3(b3
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False[43.88, 548.58, 312.39, 6.64]and b4) dark fi eld images of LNMO after 50 cycles; TEM images and corresponding SAED patterns of: (c1and b4) dark fi eld images of LNMO after 50 cycles; TEM images and corresponding SAED patterns of: (c1
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False[358.64, 548.58, 100.87, 6.64]and c2) LNMO after 100cycles, (d1and c2) LNMO after 100cycles, (d1
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False[461.88, 548.58, 90.94, 5.94]and d2) CF-1.0 after 100 cyclesand d2) CF-1.0 after 100 cycles
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False[32.82, 557.14, 520.13, 134.85]growth of the unacceptable SEI fi lm as well as the interfacial reaction have been mitigated by CoF2 coating layer. Thus, the improvement of electrochemical kinetics, the suppression of the formation of SEI fi lm and si…growth of the unacceptable SEI fi lm as well as the interfacial reaction have been mitigated by CoF2 coating layer. Thus, the improvement of electrochemical kinetics, the suppression of the formation of SEI fi lm and si…
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False[32.82, 673.06, 251.09, 70.61]cycling To disclose the reasons for improving the capacity fading and voltage decay upon cycling of CoF2-coated samples, LNMO and CF1.0 after several cycles were observed using TEM. Fig. 8 (b1 and b2) presents TEM image…cycling To disclose the reasons for improving the capacity fading and voltage decay upon cycling of CoF2-coated samples, LNMO and CF1.0 after several cycles were observed using TEM. Fig. 8 (b1 and b2) presents TEM image…
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False[301.83, 694.41, 251.07, 49.26]serious capacity fading and voltage decay, as illustrated in Fig. 8(a). After 100 cycles for LNMO, a thick layer, namely, SEI fi lm formed on the surface of grain, indicative of the severe side reaction between electrol…serious capacity fading and voltage decay, as illustrated in Fig. 8(a). After 100 cycles for LNMO, a thick layer, namely, SEI fi lm formed on the surface of grain, indicative of the severe side reaction between electrol…
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False[42.52, 66.77, 251.12, 7.42]particle in Fig. 8(c2), indicating complete structure transition afterparticle in Fig. 8(c2), indicating complete structure transition after
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False[42.52, 77.2, 251.06, 7.42]100 cycles. However, the thin SEI fi lm mixed with CoF2 coating layer100 cycles. However, the thin SEI fi lm mixed with CoF2 coating layer
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False[42.52, 87.69, 251.06, 7.42]can be observed in Fig. 8(d1) for CF-1.0 after 100 cycles owing to thecan be observed in Fig. 8(d1) for CF-1.0 after 100 cycles owing to the
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False[42.52, 98.12, 37.08, 7.42]inhibitioninhibition
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False[83.56, 98.12, 7.33, 7.42]ofof
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False[94.9, 98.12, 42.72, 7.42]the releasethe release
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True[141.56, 98.12, 7.33, 7.42]ofof
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True[152.84, 98.12, 112.48, 7.42]oxygen during initial severaloxygen during initial several
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False[42.52, 108.6, 42.08, 7.42]meanwhilemeanwhile
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False[89.29, 108.6, 5.43, 7.42]itit
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False[99.38, 108.6, 13.88, 7.42]stillstill
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False[117.92, 108.6, 26.81, 7.42]remainremain
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False[149.44, 108.6, 7.42, 7.42]inin
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True[161.51, 108.6, 12.33, 7.42]thethe
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False[42.52, 119.04, 251.06, 7.42]which is in good agreement with the best stability of capacity andwhich is in good agreement with the best stability of capacity and
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False[42.52, 129.52, 251.04, 7.42]operating voltage. Therefore, the phase transition from layered tooperating voltage. Therefore, the phase transition from layered to
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False[42.52, 139.96, 251.08, 7.43]spinel can be delayed effectively by CoF2 nano-coating layer uponspinel can be delayed effectively by CoF2 nano-coating layer upon
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False[42.52, 150.44, 28.26, 7.42]cycling.cycling.
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False[42.52, 171.36, 6.81, 7.42]4.4.
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False[54.31, 171.36, 47.69, 7.42]ConclusionsConclusions
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False[54.48, 192.28, 239.1, 7.43]In this paper, a nano protective layer of CoF2, in situ synthesizedIn this paper, a nano protective layer of CoF2, in situ synthesized
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False[42.52, 202.72, 251.06, 7.42]by means of a common wet chemistry technology, was coated onby means of a common wet chemistry technology, was coated on
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False[42.52, 213.2, 251.05, 7.42]LNMO. The results of SEM, TEM, EDS and XPS demonstrate thatLNMO. The results of SEM, TEM, EDS and XPS demonstrate that
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False[42.52, 223.63, 251.03, 7.43]CoF2 coating, belong to cubic structure, distributes homogeneouslyCoF2 coating, belong to cubic structure, distributes homogeneously
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False[42.52, 234.12, 171.44, 7.42]on the surface of LNMO, and the cell testson the surface of LNMO, and the cell tests
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True[42.52, 244.55, 251.08, 7.43]chemical performances are enhanced obviously for CoF2-coatedchemical performances are enhanced obviously for CoF2-coated
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False[42.52, 255.04, 251.04, 7.42]samples. CF-0.5 delivers the highest initial discharge capacity ofsamples. CF-0.5 delivers the highest initial discharge capacity of
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False[91.11, 263.21, 4.79, 10.33]
8229textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
white
False[95.87, 263.42, 3.56, 5.57]11
8230textbody_headingFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
white
False[42.52, 265.47, 48.59, 7.42]264.4 mAh g264.4 mAh g
8231textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[254, 254, 254]
white
False[101.99, 265.47, 191.65, 7.42]and coulombic ef fi ciency of 86.2%, bene fi ting fromand coulombic ef fi ciency of 86.2%, bene fi ting from
8232textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[254, 254, 254]
white
False[42.52, 275.96, 251.04, 7.42]the electrochemical conversion reaction based on CoF2/LiF, as wellthe electrochemical conversion reaction based on CoF2/LiF, as well
8233textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[254, 254, 254]
white
False[42.52, 286.45, 246.27, 7.42]as the reduction in the amount of irreversible O2 release and the Lias the reduction in the amount of irreversible O2 release and the Li
8234textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[254, 254, 254]
white
False[42.52, 296.88, 251.07, 7.42]vacancies proved by the CV measurements. In addition, the highervacancies proved by the CV measurements. In addition, the higher
8235textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[254, 254, 254]
white
False[42.52, 307.0, 147.23, 7.79]fi rst discharge capacity of 259.1 mAh gfi rst discharge capacity of 259.1 mAh g
8236textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
white
False[101.37, 315.54, 4.79, 10.33]
8237textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
white
False[106.19, 315.75, 3.56, 5.57]11
8238textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
white
False[42.52, 317.8, 58.85, 7.42]of 244.0 mAh gof 244.0 mAh g
8239textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[254, 254, 254]
white
False[109.02, 317.8, 184.56, 7.42], the excellent cycling stability with the capacity, the excellent cycling stability with the capacity
8240textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[254, 254, 254]
white
False[42.52, 328.29, 251.03, 7.42]retention rate of 93.0% after 100 cycles at 0.1 C, the improved rateretention rate of 93.0% after 100 cycles at 0.1 C, the improved rate
8241textbody_headingFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[254, 254, 254]
white
False[42.52, 338.72, 177.84, 7.42]performance with the capacity of 167.5 mAh gperformance with the capacity of 167.5 mAh g
8242textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
white
False[42.52, 349.21, 251.08, 7.42]the restraining operating voltage decay with the drop of 0.312 Vthe restraining operating voltage decay with the drop of 0.312 V
8243page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:top_margin:column_2_of_2:white[255, 255, 255]
white
False[213.68, 47.78, 177.75, 6.46]S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239S. Chong et al. / Journal of Power Sources 332 (2016) 230 e 239
8244page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:top_margin:column_2_of_2:white[255, 255, 255]
white
False[551.62, 48.21, 10.94, 5.94]239239
8245textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[423.33, 66.32, 4.97, 6.37]ee
8246textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.4, 66.74, 95.96, 5.94]J. Mater. Chem. 17 (2007) 3112J. Mater. Chem. 17 (2007) 3112
8247textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[428.32, 66.74, 16.71, 5.94]3125.3125.
8248textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[252, 251, 251]
white
False[314.93, 74.74, 8.49, 5.94][4][4]
8249textaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.4, 74.74, 235.14, 5.94]X. Bian, Q. Fu, Q. Pang, Y. Gao, Y. Wei, B. Zou, F. Du, G. Chen, ACS Appl. Mater.X. Bian, Q. Fu, Q. Pang, Y. Gao, Y. Wei, B. Zou, F. Du, G. Chen, ACS Appl. Mater.
8250textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[402.58, 82.25, 4.97, 6.37]ee
8251textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.4, 82.67, 75.15, 5.94]Interfaces 8 (2016) 3308Interfaces 8 (2016) 3308
8252textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[407.57, 82.67, 16.66, 5.94]3318.3318.
8253textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[252, 252, 252]
white
False[314.93, 90.67, 8.49, 5.94][5][5]
8254textreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
True[327.4, 90.67, 235.14, 5.94]Q.Y. Wang, J. Liu, A.V. Murugan, A. Manthiram, J. Mater. Chem. 19 (2009)Q.Y. Wang, J. Liu, A.V. Murugan, A. Manthiram, J. Mater. Chem. 19 (2009)
8255textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:colored[217, 216, 247]
colored
True[269.23, 98.12, 24.34, 7.42]cycles,cycles,
8256textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[342.6, 98.18, 4.97, 6.37]ee
8257textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.4, 98.6, 15.17, 5.94]49654965
8258textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[347.53, 98.6, 16.71, 5.94]4972.4972.
8259textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[253, 253, 252]
white
True[314.93, 106.6, 8.49, 5.94][6][6]
8260textaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.4, 106.6, 235.14, 5.94]Z. Wang, E. Liu, L. Guo, C. Shi, C. He, J. Li, N. Zhao, Surf. Coat. Technol. 235Z. Wang, E. Liu, L. Guo, C. Shi, C. He, J. Li, N. Zhao, Surf. Coat. Technol. 235
8261textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
white
True[178.52, 108.6, 54.03, 7.42]rhombohedralrhombohedral
8262textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
white
True[237.25, 108.6, 27.65, 7.42]layeredlayered
8263textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
white
True[269.63, 108.6, 23.98, 7.42]phase,phase,
8264textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[361.02, 114.16, 4.97, 6.37]ee
8265textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.4, 114.59, 33.6, 5.94](2013) 570(2013) 570
8266textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[365.95, 114.59, 12.91, 5.94]576.576.
8267textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[460.74, 121.75, 3.32, 6.38]
8268textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[314.93, 122.53, 8.49, 5.94][7][7]
8269textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.4, 122.53, 11.46, 5.94]A.R.A.R.
8270textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[345.37, 122.53, 33.96, 5.94]Armstrong,Armstrong,
8271textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[385.85, 122.53, 7.67, 5.94]M.M.
8272textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[400.08, 122.53, 30.14, 5.94]Holzapfel,Holzapfel,
8273textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[436.76, 122.53, 5.24, 5.94]P.P.
8274textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[448.55, 122.53, 12.15, 5.94]NovNov
8275textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[460.69, 122.53, 8.56, 5.94]ak,ak,
8276textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[475.81, 122.53, 10.42, 5.94]C.S.C.S.
8277textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[492.76, 122.53, 25.89, 5.94]Johnson,Johnson,
8278textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[525.19, 122.53, 14.08, 5.94]S.-H.S.-H.
8279textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[545.77, 122.53, 16.77, 5.94]Kang,Kang,
8280textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[520.16, 130.09, 4.97, 6.37]ee
8281textaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.4, 130.52, 192.72, 5.94]M.M. Thackeray, P.G. Bruce, J. Am. Chem. Soc. 128 (2006) 8694M.M. Thackeray, P.G. Bruce, J. Am. Chem. Soc. 128 (2006) 8694
8282textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[525.09, 130.52, 16.71, 5.94]8698.8698.
8283textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[462.33, 138.03, 4.97, 6.37]ee
8284textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[314.93, 138.46, 8.49, 5.94][8][8]
8285textreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
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8286textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[467.32, 138.46, 20.51, 5.94]63284.63284.
8287textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[251, 251, 250]
white
True[314.93, 146.45, 8.49, 5.94][9][9]
8288textaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
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after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[357.22, 153.96, 4.97, 6.37]ee
8290textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.4, 154.39, 29.81, 5.94](2014) 83(2014) 83
8291textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[362.15, 154.39, 9.12, 5.94]87.87.
8292textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[253, 253, 253]
white
True[452.24, 161.96, 4.97, 6.37]ee
8293textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:gray[241, 242, 239]
gray
True[311.53, 162.38, 12.28, 5.94][10][10]
8294textaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 162.38, 124.41, 5.94]M. Xu, J. Mater. Chem. A 3 (2015) 13933M. Xu, J. Mater. Chem. A 3 (2015) 13933
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after_stopp8:page_body:column_2_of_2:white[252, 253, 252]
white
True[457.23, 162.38, 20.51, 5.94]13945.13945.
8296textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[446.85, 169.95, 4.97, 6.37]ee
8297textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[311.53, 170.38, 12.28, 5.94][11][11]
8298textaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
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False[327.8, 170.38, 119.02, 5.94]B. Li, J. Mater. Chem. A 3 (2015) 21290B. Li, J. Mater. Chem. A 3 (2015) 21290
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white
False[451.84, 170.38, 20.51, 5.94]21297.21297.
8300textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[311.53, 178.31, 12.28, 5.94][12][12]
8301textaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
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after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[357.62, 185.88, 4.97, 6.37]ee
8303textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 186.31, 29.81, 5.94](2015) 45(2015) 45
8304textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[362.55, 186.31, 9.12, 5.94]51.51.
8305textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[311.53, 194.24, 12.28, 5.94][13][13]
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after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[335.4, 201.81, 4.97, 6.37]ee
8308textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 202.24, 7.59, 5.94]2020
8309textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[340.33, 202.24, 9.12, 5.94]25.25.
8310textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:gray[232, 231, 231]
gray
True[311.53, 210.23, 12.28, 5.94][14][14]
8311textaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
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after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[361.42, 217.74, 4.97, 6.37]ee
8313textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 218.17, 33.6, 5.94](2013) 671(2013) 671
8314textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[366.35, 218.17, 12.91, 5.94]679.679.
8315textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[544.7, 225.73, 4.97, 6.37]ee
8316textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[311.53, 226.16, 12.28, 5.94][15][15]
8317textreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
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False[327.8, 226.16, 216.88, 5.94]Y. Liu, S. Liu, Y. Wang, L. Chen, X. Chen, J. Power Sources 222 (2013) 455Y. Liu, S. Liu, Y. Wang, L. Chen, X. Chen, J. Power Sources 222 (2013) 455
8318textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[549.64, 226.16, 12.91, 5.94]460.460.
8319textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[311.53, 234.1, 12.28, 5.94][16][16]
8320textaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 234.1, 234.74, 5.94]S. Shi, J. Tu, Y. Zhang, Y. Zhang, X. Zhao, X. Wang, C. Gu, Electrochim. Acta 108S. Shi, J. Tu, Y. Zhang, Y. Zhang, X. Zhao, X. Wang, C. Gu, Electrochim. Acta 108
8321textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
white
True[218.09, 234.12, 22.98, 7.42]revealreveal
8322textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
white
False[245.08, 234.12, 15.27, 7.42]thatthat
8323textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
white
False[264.35, 234.12, 29.23, 7.42]electro-electro-
8324textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[361.42, 241.66, 4.97, 6.37]ee
8325textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 242.09, 33.6, 5.94](2013) 441(2013) 441
8326textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
True[366.35, 242.09, 12.91, 5.94]448.448.
8327textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[540.9, 249.66, 4.97, 6.37]ee
8328textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:gray[228, 229, 229]
gray
True[311.53, 250.09, 12.28, 5.94][17][17]
8329textreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 250.09, 213.08, 5.94]J. Zheng, J. Li, Z. Zhang, X. Guo, Y. Yang, Solid State Ion. 179 (2008) 1794J. Zheng, J. Li, Z. Zhang, X. Guo, Y. Yang, Solid State Ion. 179 (2008) 1794
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after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[545.84, 250.09, 16.71, 5.94]1799.1799.
8331textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[516.87, 257.6, 4.97, 6.37]ee
8332textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[311.53, 258.02, 12.28, 5.94][18][18]
8333textreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 258.02, 189.05, 5.94]X. Liu, J. Liu, T. Huang, A. Yu, Electrochim. Acta 109 (2013) 52X. Liu, J. Liu, T. Huang, A. Yu, Electrochim. Acta 109 (2013) 52
8334textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[521.86, 258.02, 9.12, 5.95]58.58.
8335textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[498.33, 265.6, 4.97, 6.37]ee
8336textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:off_white[248, 249, 247]
off_white
True[311.53, 266.02, 12.28, 5.94][19][19]
8337textreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 266.02, 170.52, 5.94]X. Liu, T. Huang, A. Yu, Electrochim. Acta 163 (2015) 82X. Liu, T. Huang, A. Yu, Electrochim. Acta 163 (2015) 82
8338textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[503.26, 266.02, 9.12, 5.94]92.92.
8339textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
True[311.53, 273.96, 12.28, 5.94][20][20]
8340textaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 273.96, 234.74, 5.94]J.-H. Kim, M.-S. Park, J.-H. Song, D.-J. Byun, Y.-J. Kim, J.-S. Kim, J. Alloy. Compd.J.-H. Kim, M.-S. Park, J.-H. Song, D.-J. Byun, Y.-J. Kim, J.-S. Kim, J. Alloy. Compd.
8341textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[371.22, 281.53, 4.97, 6.37]ee
8342textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
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False[327.8, 281.95, 43.41, 5.94]517 (2012) 20517 (2012) 20
8343textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[376.16, 281.95, 9.12, 5.94]25.25.
8344textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
white
False[288.79, 284.13, 4.79, 10.33]þ
8345textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[251, 250, 251]
white
True[311.53, 289.89, 12.28, 5.94][21][21]
8346textaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 289.89, 234.76, 5.94]T. Zhao, L. Li, R. Chen, H. Wu, X. Zhang, S. Chen, M. Xie, F. Wu, J. Lu, K. Amine,T. Zhao, L. Li, R. Chen, H. Wu, X. Zhang, S. Chen, M. Xie, F. Wu, J. Lu, K. Amine,
8347textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[412.61, 297.46, 4.97, 6.37]ee
8348textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 297.88, 84.79, 5.94]Nano Energy 15 (2015) 164Nano Energy 15 (2015) 164
8349textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[417.6, 297.88, 12.91, 5.94]176.176.
8350textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
white
False[189.75, 305.05, 4.79, 10.33]
8351textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
white
False[194.51, 305.26, 3.56, 5.57]11
8352textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[253, 254, 253]
white
True[311.53, 305.88, 12.28, 5.94][22][22]
8353textreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 305.88, 234.74, 5.94]J. Ma, B. Li, L. An, H. Wei, X. Wang, P. Yu, D. Xia, J. Power Sources 277 (2015)J. Ma, B. Li, L. An, H. Wei, X. Wang, P. Yu, D. Xia, J. Power Sources 277 (2015)
8354textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
white
False[200.58, 307.37, 93.04, 7.42]compared to bare LNMOcompared to bare LNMO
8355textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[339.19, 313.39, 4.97, 6.37]ee
8356textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 313.81, 11.38, 5.94]393393
8357textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
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False[344.12, 313.81, 12.91, 5.94]402.402.
8358textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[311.53, 321.81, 12.28, 5.94][23][23]
8359textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
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False[327.8, 321.81, 12.56, 5.94]H.G.H.G.
8360textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
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False[345.09, 321.81, 16.29, 5.94]Song,Song,
8361textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[366.06, 321.81, 9.11, 5.94]J.Y.J.Y.
8362textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[379.89, 321.81, 13.8, 5.94]Kim,Kim,
8363textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[398.43, 321.81, 10.97, 5.94]K.T.K.T.
8364textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[414.14, 321.81, 13.8, 5.94]Kim,Kim,
8365textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[432.67, 321.81, 9.11, 5.94]Y.J.Y.J.
8366textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 253]
white
False[446.51, 321.81, 14.98, 5.94]Park,Park,
8367textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:gray[246, 245, 244]
gray
True[466.23, 321.81, 3.52, 5.94]J.J.
8368textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 253]
white
False[474.45, 321.81, 19.26, 5.94]PowerPower
8369textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[498.43, 321.81, 23.25, 5.94]SourcesSources
8370textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[526.44, 321.81, 11.38, 5.94]196196
8371textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
white
False[542.54, 321.81, 20.0, 5.94](2011)(2011)
8372textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[342.99, 329.32, 4.97, 6.37]ee
8373textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[327.8, 329.74, 15.17, 5.94]68476847
8374textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
white
False[347.92, 329.74, 16.71, 5.94]6855.6855.
8375textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[252, 252, 252]
white
False[220.37, 336.46, 4.79, 10.33]
8376textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
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False[225.18, 336.67, 3.56, 5.57]11
8377textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
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False[311.53, 337.74, 12.28, 5.94][24][24]
8378textreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[254, 254, 254]
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False[327.8, 337.74, 234.74, 5.94]J. Lu, Q. Peng, W. Wang, C. Nan, L. Li, Y. Li, J. Am. Chem. Soc. 135 (2013)J. Lu, Q. Peng, W. Wang, C. Nan, L. Li, Y. Li, J. Am. Chem. Soc. 135 (2013)
8379textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_2_of_2:white[254, 254, 254]
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False[231.48, 338.72, 62.11, 7.42]even at 5 C, andeven at 5 C, and
8380textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[342.99, 345.3, 4.97, 6.37]ee
8381textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:column_2_of_2:white[255, 255, 255]
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False[327.8, 345.73, 15.17, 5.94]16491649
8382textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[347.92, 345.73, 16.71, 5.94]1652.1652.
8383captioncaptionFalselowafter_back_matter_stopafter_back_matter_stop
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False[42.52, 353.67, 520.04, 24.8]after 100 cycles at 0.1 C are obtained for CF-1.0 sample. The outstanding electrochemical performances are ascribed to the CoF2 [25] L.-N. Cong, X.-G. Gao, S.-C. Ma, X. Guo, Y.-P. Zeng, L.-H. Tai, R.-S. Wang, H.M. Xie, …after 100 cycles at 0.1 C are obtained for CF-1.0 sample. The outstanding electrochemical performances are ascribed to the CoF2 [25] L.-N. Cong, X.-G. Gao, S.-C. Ma, X. Guo, Y.-P. Zeng, L.-H. Tai, R.-S. Wang, H.M. Xie, …
8384textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[42.52, 380.56, 251.08, 7.42]nano-coating in protection electrode material from deterioration innano-coating in protection electrode material from deterioration in
8385textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[42.52, 391.05, 12.33, 7.42]thethe
8386textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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False[61.0, 391.05, 41.88, 7.42]electrolyte,electrolyte,
8387textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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False[108.96, 391.05, 12.33, 7.42]thethe
8388textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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False[127.44, 391.05, 51.67, 7.42]enhancementenhancement
8389textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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False[42.52, 401.48, 154.03, 7.42]involving better electron transfer and Liinvolving better electron transfer and Li
8390textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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False[42.52, 411.97, 22.25, 7.42]bitionbition
8391textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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False[69.16, 411.97, 7.33, 7.42]ofof
8392textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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False[80.84, 411.97, 53.71, 7.42]layered-spinellayered-spinel
8393textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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True[138.95, 411.97, 63.1, 7.42]phase transitionphase transition
8394textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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False[42.52, 422.4, 17.92, 7.42]edgeedge
8395textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[64.97, 422.4, 43.9, 7.42]and spreadand spread
8396textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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False[113.38, 422.4, 14.98, 7.42]intointo
8397textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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False[132.89, 422.4, 20.1, 7.42]innerinner
8398textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
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False[157.49, 422.4, 16.64, 7.42]bulkbulk
8399textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[42.52, 432.89, 251.04, 7.42]migration of TM ions into Li layers. Therefore, the novel design ofmigration of TM ions into Li layers. Therefore, the novel design of
8400textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[42.52, 443.32, 251.03, 7.43]CoF2 nano-coating not only provides a tactic to surmount the de-CoF2 nano-coating not only provides a tactic to surmount the de-
8401textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[42.52, 453.81, 251.06, 7.42]fects of LNMO and displays the superior comprehensive effect onfects of LNMO and displays the superior comprehensive effect on
8402textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[42.52, 464.24, 39.18, 7.42]improvingimproving
8403textbody_headingFalselowafter_back_matter_stopafter_back_matter_stop
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False[86.12, 464.24, 59.58, 7.42]electrochemicalelectrochemical
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False[150.18, 464.24, 48.3, 7.42]performanceperformance
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False[42.52, 474.73, 251.04, 7.42]published data, but also illuminates in depth the mechanism ofpublished data, but also illuminates in depth the mechanism of
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False[42.52, 485.16, 180.7, 7.42]capacity fading and voltage decay upon cycling.capacity fading and voltage decay upon cycling.
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False[42.52, 506.08, 73.96, 7.42]AcknowledgementAcknowledgement
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False[54.48, 527.0, 239.17, 7.42]This work was supported by National Natural Science Founda-This work was supported by National Natural Science Founda-
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False[42.52, 537.49, 251.07, 7.42]tion of China (Grant no. E51504196), the China Postdoctoral Sciencetion of China (Grant no. E51504196), the China Postdoctoral Science
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False[90.03, 544.52, 413.34, 14.36](no. 2012M521760) and the Fundamental Research X.-Q. Yang, J.-G. Zhang, Nano Energy 16 (2015) 143 e 151. [39] M.E. Spahr, P. Nov (no. 2012M521760) and the Fundamental Research X.-Q. Yang, J.-G. Zhang, Nano Energy 16 (2015) 143 e 151. [39] M.E. Spahr, P. Nov 
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False[42.52, 547.92, 42.84, 7.42]FoundationFoundation
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False[42.52, 558.41, 193.56, 7.42]Funds for the Central Universities (no. xjj2014052).Funds for the Central Universities (no. xjj2014052).
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False[42.52, 579.32, 251.03, 93.4]Appendix A. Supplementary data Supplementary data related to this article can be found at http:// dx.doi.org/10.1016/j.jpowsour.2016.09.028. References [1] M.S. Whittingham, Chem. Rev. 104 (2004) 4271 e 4302. [2] J.B. G…Appendix A. Supplementary data Supplementary data related to this article can be found at http:// dx.doi.org/10.1016/j.jpowsour.2016.09.028. References [1] M.S. Whittingham, Chem. Rev. 104 (2004) 4271 e 4302. [2] J.B. G…
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False[450.31, 377.17, 4.97, 6.37]ee
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False[443.05, 385.1, 4.97, 6.37]ee
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False[185.15, 391.05, 7.33, 7.42]ofof
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False[198.59, 391.05, 29.23, 7.42]kineticskinetics
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False[233.97, 391.05, 59.58, 7.42]electrochemicalelectrochemical
8424textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[196.55, 399.22, 4.79, 10.33]þ
8427textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[342.99, 401.09, 4.97, 6.37]ee
8428textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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8429textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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8431textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[206.41, 411.97, 31.73, 7.42]initiatedinitiated
8434textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[242.47, 411.97, 51.1, 7.42]from particlefrom particle
8435textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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8436textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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8437textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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8439textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[281.25, 422.4, 12.33, 7.42]thethe
8440textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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8443textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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8445textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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8446textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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False[311.53, 537.01, 12.28, 5.94][38][38]
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False[382.85, 552.94, 179.7, 5.94]ak, B. Schnyder, O. Haas, R. Nesper, J. Electrochem. Soc. 145ak, B. Schnyder, O. Haas, R. Nesper, J. Electrochem. Soc. 145
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False[327.8, 560.88, 37.39, 5.94](1998) 1113(1998) 1113
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False[327.8, 568.88, 234.77, 5.94]C. Wagner, W. Riggs, L. Davis, Physical Electronics Division, Perking ElmerC. Wagner, W. Riggs, L. Davis, Physical Electronics Division, Perking Elmer
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False[311.52, 576.38, 251.05, 94.07]Corporation, 1979, pp. 74 e 80. [41] J. Liu, A. Manthiram, J. Mater. Chem. 19 (2010) 3961 e 3967. [42] X. He, J. Wang, R. Kloepsch, S. Krueger, H. Jia, H. Liu, B. Vortmann, J. Li, Nano Res. 7 (2014) 110 e 118. [43] S. C…Corporation, 1979, pp. 74 e 80. [41] J. Liu, A. Manthiram, J. Mater. Chem. 19 (2010) 3961 e 3967. [42] X. He, J. Wang, R. Kloepsch, S. Krueger, H. Jia, H. Liu, B. Vortmann, J. Li, Nano Res. 7 (2014) 110 e 118. [43] S. C…