Docling layout block audit

original.pdf docling.json layout_blocks.json layout_blocks.tsv layout_blocks.jsonl excluded_blocks.html excluded_blocks.tsv final_body_blocks.tsv visual_assets.tsv visual_assets.json

Summary

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Diff Summary

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Truncation

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Page Overlays

Green = final body chunks. Orange/purple asset boxes = actual figure/table assets used by ingestion. Cyan dashed text boxes = text blocks consumed by those assets as caption continuations. Red STOP = truncation trigger. Red boxes = blocks after truncation.

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Visual Assets

这里对齐真实图表资产提取链路。caption_source=embedded_table_cell 表示表注来自 Docling table cell,不会出现在 text block 审计差集里;caption_continuation_used_by_asset 表示某个 text block 已被图表 caption 吸收,不应按普通 metadata 解读。

#typelabelpagecaption sourcesuppressedduplicate reasonrescue reasongroupconfidencebboxcaption
1figureDocling Figure 11missing_caption0.55[388.25, 289.61, 174.92, 116.32]
2figureFig. 12direct_caption_ref0.82[104.17, 70.06, 415.26, 332.69]Figure 1. Structure and electrochemistry of Li2MnO3. (a) XRD pattern and (b) SEM image showing particles morphology of Li2MnO3 synthesized at 600 ◦ C. The fi rst cycle voltage pro fi les and subsequent cycling performance are shown in (c) and (d), respectively.
3figureFig. 23direct_caption_ref0.82[102.1, 67.98, 419.21, 280.81]Figure 2. Bulk O and Mn redox activity in Li2MnO3. O K-edge TFY XAS data (a), and RIXS maps of Li2MnO3 electrodes charged to 4.8 V (b) and 5.0 V (c). Operando Mn K-edge XANES (d) and EXAFS (e) data for charged and discharged states during the fi rst cycle.
4figureFig. 34direct_caption_ref0.82[93.48, 66.26, 437.02, 406.53]Figure 3. Gas evolution and surface studies of Li2MnO3. (a) DEMS for the fi rst charge and (b) XPS/HAXPES data and (c) Mn L3-edge TEY data for the pristine and electrolyte-soaked material.
5tableTable 15nearby_text_caption0.82[60.42, 658.7, 228.55, 63.77]Table 1. First Charge Capacity Contributions a

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False[60.49, 94.27, 102.61, 6.62]http://pubs.acs.org/journal/aelccp
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False[60.49, 122.84, 434.11, 50.16]Quantifying the Capacity Contributions during Activation of Li2MnO3Quantifying the Capacity Contributions during Activation of Li2MnO3
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False[60.49, 171.56, 467.35, 45.71]Jatinkumar Rana, ¶ Joseph K. Papp, ¶ Zachary Lebens-Higgins, Mateusz Zuba, Lori A. Kaufman, Anshika Goel, Richard Schmuch, Martin Winter, M. Stanley Whittingham, Wanli Yang, Bryan D. McCloskey, and Louis F. J. Piper *Jatinkumar Rana, ¶ Joseph K. Papp, ¶ Zachary Lebens-Higgins, Mateusz Zuba, Lori A. Kaufman, Anshika Goel, Richard Schmuch, Martin Winter, M. Stanley Whittingham, Wanli Yang, Bryan D. McCloskey, and Louis F. J. Piper *
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False[3.61, 201.0, 15.98, 370.5]Downloaded via JILIN UNIV on July 12, 2026 at 12:52:58 (UTC). See https://pubs.acs.org/sharingguidelines for options on how to legitimately share published articles.Downloaded via JILIN UNIV on July 12, 2026 at 12:52:58 (UTC). See for options on how to legitimately share published articles.
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False[84.19, 230.72, 151.99, 9.32]Cite This: ACS Energy Lett. 2020, 5, 634 -641Cite This: ACS Energy Lett. 2020, 5, 634 -641
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False[60.49, 291.3, 316.21, 130.86]ABSTRACT: Though Li2MnO3 was originally considered to be electrochemically inert, its observed activation has spawned a new class of Li-rich layered compounds that deliver capacities beyond the traditional transition-me…ABSTRACT: Though Li2MnO3 was originally considered to be electrochemically inert, its observed activation has spawned a new class of Li-rich layered compounds that deliver capacities beyond the traditional transition-me…
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False[60.49, 423.34, 504.01, 30.63]during activation with minor contributions from reduced Mn species on the surface. These studies reveal that, although Li2 MnO3 is considered critical for promoting bulk anionic redox in Li-rich layered oxides, Li2MnO3 …during activation with minor contributions from reduced Mn species on the surface. These studies reveal that, although Li2 MnO3 is considered critical for promoting bulk anionic redox in Li-rich layered oxides, Li2MnO3 …
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False[60.49, 477.74, 240.01, 279.62]O riginally considered electrochemically inactive, 1 Li2MnO3 can deliver substantial capacity during charge, as demonstrated by Kalyani et al. 2 Later, Robertson and Bruce 3 revealed how Li2MnO3 could be activated throu…O riginally considered electrochemically inactive, 1 Li2MnO3 can deliver substantial capacity during charge, as demonstrated by Kalyani et al. 2 Later, Robertson and Bruce 3 revealed how Li2MnO3 could be activated throu…
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False[324.45, 479.72, 240.07, 208.53]While Li2MnO3 is regarded as a model compound for describing bulk oxygen redox activity in LR-NMCs, recent RIXS studies did not detect similar spectroscopic signatures of oxidized lattice oxygen in Li2MnO3. 30 Additiona…While Li2MnO3 is regarded as a model compound for describing bulk oxygen redox activity in LR-NMCs, recent RIXS studies did not detect similar spectroscopic signatures of oxidized lattice oxygen in Li2MnO3. 30 Additiona…
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False[367.99, 705.59, 68.95, 7.92]December 23, 2019December 23, 2019
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False[324.45, 705.67, 35.03, 7.77]Received:Received:
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False[367.99, 716.59, 59.37, 7.92]January 27, 2020January 27, 2020
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False[324.45, 727.67, 38.36, 7.77]Published:Published:
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False[439.88, 771.53, 124.6, 12.72]https://dx.doi.org/10.1021/acsenergylett.9b02799 ACS Energy Lett. 2020, 5, 634 -641ACS Energy Lett. 2020, 5, 634 -641
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False[194.29, 772.66, 95.68, 5.88]© 2020 American Chemical Society© 2020 American Chemical Society
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False[60.49, 48.93, 84.37, 8.72]ACS Energy LettersACS Energy Letters
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False[278.65, 50.28, 118.38, 6.98]http://pubs.acs.org/journal/aelccp
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False[60.49, 412.0, 503.99, 17.75]Figure 1. Structure and electrochemistry of Li2MnO3. (a) XRD pattern and (b) SEM image showing particles morphology of Li2MnO3 synthesized at 600 ◦ C. The fi rst cycle voltage pro fi les and subsequent cycling performan…Figure 1. Structure and electrochemistry of Li2MnO3. (a) XRD pattern and (b) SEM image showing particles morphology of Li2MnO3 synthesized at 600 ◦ C. The fi rst cycle voltage pro fi les and subsequent cycling performan…
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False[60.49, 442.75, 239.96, 19.97]alternative charge compensation mechanisms that could explain the electrochemical activity of Li2MnO3?alternative charge compensation mechanisms that could explain the electrochemical activity of Li2MnO3?
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False[60.49, 464.98, 240.0, 220.33]To resolve these issues, we considered all possible charge compensation mechanisms including bulk oxygen redox, Mn 4+ /Mn 7+ redox, and surface degradation. Our investigation employed a combination of techniques sensiti…To resolve these issues, we considered all possible charge compensation mechanisms including bulk oxygen redox, Mn 4+ /Mn 7+ redox, and surface degradation. Our investigation employed a combination of techniques sensiti…
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False[60.49, 687.55, 240.01, 75.64]Figure 1a shows the XRD pattern of the as-synthesized material, where all re fl ections can be indexed in the monoclinic system with the space group C 2/ m . 33 In the layered structure of Li 2 MnO3, the interslab octah…Figure 1a shows the XRD pattern of the as-synthesized material, where all re fl ections can be indexed in the monoclinic system with the space group C 2/ m . 33 In the layered structure of Li 2 MnO3, the interslab octah…
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False[324.45, 439.45, 240.05, 301.52]20 to 34 ° . However, these superlattice re fl ections appear convoluted into a broad asymmetric peak as shown in Figure 1a. Previously, the intensity and asymmetry of these superlattice re fl ections are correlated wit…20 to 34 ° . However, these superlattice re fl ections appear convoluted into a broad asymmetric peak as shown in Figure 1a. Previously, the intensity and asymmetry of these superlattice re fl ections are correlated wit…
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False[324.45, 742.61, 240.0, 20.59]While the irreversible component of the fi rst cycle capacity could be attributed to gas evolution, 11 -15 other proposedWhile the irreversible component of the fi rst cycle capacity could be attributed to gas evolution, 11 -15 other proposed
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False[439.88, 774.81, 124.6, 12.72]https://dx.doi.org/10.1021/acsenergylett.9b02799 ACS Energy Lett. 2020, 5, 634 -641ACS Energy Lett. 2020, 5, 634 -641
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False[60.49, 48.93, 84.37, 8.72]ACS Energy LettersACS Energy Letters
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False[278.65, 50.28, 118.38, 6.98]http://pubs.acs.org/journal/aelccp
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False[60.49, 357.75, 503.97, 17.75]Figure 2. Bulk O and Mn redox activity in Li2MnO3. O K-edge TFY XAS data (a), and RIXS maps of Li2MnO3 electrodes charged to 4.8 V (b) and 5.0 V (c). Operando Mn K-edge XANES (d) and EXAFS (e) data for charged and disch…Figure 2. Bulk O and Mn redox activity in Li2MnO3. O K-edge TFY XAS data (a), and RIXS maps of Li2MnO3 electrodes charged to 4.8 V (b) and 5.0 V (c). Operando Mn K-edge XANES (d) and EXAFS (e) data for charged and disch…
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False[60.49, 386.73, 240.0, 233.52]charge compensation mechanisms, such as oxidation of Mn 4+ and/or lattice oxygen redox need to be considered to fully account for the observed total capacity. 23 We fi rst employed O K-edge XAS and RIXS studies to probe…charge compensation mechanisms, such as oxidation of Mn 4+ and/or lattice oxygen redox need to be considered to fully account for the observed total capacity. 23 We fi rst employed O K-edge XAS and RIXS studies to probe…
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False[60.49, 621.34, 240.0, 141.86]These results are further complemented by a quantitative measure of oxide oxidation using an acid titration of extracted Li2MnO3 cathodes. Previous studies on NMC cathode materials have found that O 2 evolves from parti…These results are further complemented by a quantitative measure of oxide oxidation using an acid titration of extracted Li2MnO3 cathodes. Previous studies on NMC cathode materials have found that O 2 evolves from parti…
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False[324.45, 387.94, 240.04, 53.76]fi rst charge and the bottom of the fi rst discharge. Here we have found that these titrations demonstrate minimal contributions from bulk oxygen redox (only 10 mAh g -1 ), which is in agreement with the lack of spectro…fi rst charge and the bottom of the fi rst discharge. Here we have found that these titrations demonstrate minimal contributions from bulk oxygen redox (only 10 mAh g -1 ), which is in agreement with the lack of spectro…
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False[324.45, 443.95, 240.05, 197.31]We then turn to operando Mn K-edge XAS to probe bulk Mn redox activity in Li2MnO3 involving Mn 4+ /Mn 7+ redox as proposed by Radin et al. 23 However, the experimental veri fi cation of the proposed Mn 4+ /Mn 7+ redox i…We then turn to operando Mn K-edge XAS to probe bulk Mn redox activity in Li2MnO3 involving Mn 4+ /Mn 7+ redox as proposed by Radin et al. 23 However, the experimental veri fi cation of the proposed Mn 4+ /Mn 7+ redox i…
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False[324.45, 643.51, 240.05, 119.7]Parts d and e of Figure 2 show operando Mn K-edge X-ray absorption near-edge structure (XANES) and extended X-ray absorption fi ne structure (EXAFS) data of Li2MnO3. At 5.0 V, no clear shift of the main edge beyond that…Parts d and e of Figure 2 show operando Mn K-edge X-ray absorption near-edge structure (XANES) and extended X-ray absorption fi ne structure (EXAFS) data of Li2MnO3. At 5.0 V, no clear shift of the main edge beyond that…
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False[439.88, 774.81, 124.57, 5.51]https://dx.doi.org/10.1021/acsenergylett.9b02799
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False[477.64, 779.76, 86.85, 7.78]ACS Energy Lett. 2020, 5, 634 -641ACS Energy Lett. 2020, 5, 634 -641
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False[60.49, 48.93, 84.37, 8.72]ACS Energy LettersACS Energy Letters
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False[278.65, 50.28, 118.38, 6.98]http://pubs.acs.org/journal/aelccp
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False[60.49, 481.34, 503.96, 17.81]Figure 3. Gas evolution and surface studies of Li2MnO3. (a) DEMS for the fi rst charge and (b) XPS/HAXPES data and (c) Mn L3-edge TEY data for the pristine and electrolyte-soaked material.Figure 3. Gas evolution and surface studies of Li2MnO3. (a) DEMS for the fi rst charge and (b) XPS/HAXPES data and (c) Mn L3-edge TEY data for the pristine and electrolyte-soaked material.
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False[60.49, 512.15, 240.0, 184.95]increase in the intensity of the pre-edge region can now be correlated to major restructuring during activation. This restructuring also likely accounts for the observed broadening of the O K-edge spectral features in F…increase in the intensity of the pre-edge region can now be correlated to major restructuring during activation. This restructuring also likely accounts for the observed broadening of the O K-edge spectral features in F…
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False[60.49, 697.52, 240.0, 66.84]Without oxidation of Mn 4+ and/or reversible participation of lattice oxygen in charge-compensation processes, a remaining possibility is the irreversible oxidation of lattice oxygen to oxygen gas. We employed DEMS to m…Without oxidation of Mn 4+ and/or reversible participation of lattice oxygen in charge-compensation processes, a remaining possibility is the irreversible oxidation of lattice oxygen to oxygen gas. We employed DEMS to m…
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False[324.45, 512.15, 240.05, 101.16]quickly rose to a sharp peak in evolution rate. As the voltage plateau region was reached, oxygen gas became the dominant evolution product, though CO2 continued to evolve at a lower rate. Total gas evolved across the f…quickly rose to a sharp peak in evolution rate. As the voltage plateau region was reached, oxygen gas became the dominant evolution product, though CO2 continued to evolve at a lower rate. Total gas evolved across the f…
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False[324.45, 615.78, 240.05, 147.42]The source of oxygen gas is the formation of oxidized lattice oxygen species followed by gas evolution, 15 as no O2 evolution results from electrolyte degradation or carbonate oxidation. 37 O2 evolution from the oxide l…The source of oxygen gas is the formation of oxidized lattice oxygen species followed by gas evolution, 15 as no O2 evolution results from electrolyte degradation or carbonate oxidation. 37 O2 evolution from the oxide l…
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False[439.88, 774.81, 124.6, 12.72]https://dx.doi.org/10.1021/acsenergylett.9b02799 ACS Energy Lett. 2020, 5, 634 -641ACS Energy Lett. 2020, 5, 634 -641
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False[60.49, 48.93, 84.37, 8.72]ACS Energy LettersACS Energy Letters
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False[60.49, 68.75, 239.99, 20.65]fi rst charge capacity. As this is not the case, we examined other capacity contributions.fi rst charge capacity. As this is not the case, we examined other capacity contributions.
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False[60.49, 91.71, 240.01, 435.42]We note that the CO2 evolution is remarkably high for a transition metal oxide material. The large quantity of CO2 evolved (Figure 3c) could originate from a variety of mechanisms, including electrolyte reaction with ge…We note that the CO2 evolution is remarkably high for a transition metal oxide material. The large quantity of CO2 evolved (Figure 3c) could originate from a variety of mechanisms, including electrolyte reaction with ge…
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False[60.49, 529.44, 240.0, 98.77]The fi rst charge capacity for Li2MnO3 as observed during the DEMS measurement can now be analyzed in terms of the contributions from the processes examined in this study (Table 1). O2 evolution originating from oxygen …The fi rst charge capacity for Li2MnO3 as observed during the DEMS measurement can now be analyzed in terms of the contributions from the processes examined in this study (Table 1). O2 evolution originating from oxygen …
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False[60.49, 638.64, 189.99, 12.35]Table 1. First Charge Capacity Contributions aTable 1. First Charge Capacity Contributions a
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False[60.49, 732.89, 239.98, 30.06]a Capacity contributions as determined using gas evolution and titration techniques compared to the total fi rst charge capacity of the cell run on the DEMS system.a Capacity contributions as determined using gas evolution and titration techniques compared to the total fi rst charge capacity of the cell run on the DEMS system.
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False[278.65, 50.28, 118.38, 6.98]http://pubs.acs.org/journal/aelccp
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False[324.45, 65.25, 240.04, 156.7](O 2 -/O -) revealed about 6% contribution to the total charge capacity. We suspect the remaining 14% of the fi rst charge capacity (Table 1) results from a combination of processes including electrolyte decomposition g…(O 2 -/O -) revealed about 6% contribution to the total charge capacity. We suspect the remaining 14% of the fi rst charge capacity (Table 1) results from a combination of processes including electrolyte decomposition g…
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False[324.45, 224.2, 240.05, 318.46]In summary, using the combination of operando Mn K-edge XAS, O K-edge RIXS, XPS/HAXPES, and DEMS, we interpret and quantify the capacity contributions observed during electrochemical activation of Li2MnO3. Taken togethe…In summary, using the combination of operando Mn K-edge XAS, O K-edge RIXS, XPS/HAXPES, and DEMS, we interpret and quantify the capacity contributions observed during electrochemical activation of Li2MnO3. Taken togethe…
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False[324.45, 547.02, 122.94, 23.97]■ ASSOCIATED CONTENT■ ASSOCIATED CONTENT
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False[324.45, 572.86, 114.41, 12.62]* s ı Supporting Information* s ı Supporting Information
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False[324.45, 587.6, 240.01, 19.86]The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsenergylett.9b02799.The Supporting Information is available free of charge at
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False[348.49, 616.69, 216.0, 52.8]Material synthesis and electrochemical details. Additional data includes XANES spectra of reference Mn 7+ (KMnO4) with Materials Project simulations, operando Mn K-edge XANES of Li2MnO3 pouch cells, and oxygen and carbo…Material synthesis and electrochemical details. Additional data includes XANES spectra of reference Mn 7+ (KMnO4) with Materials Project simulations, operando Mn K-edge XANES of Li2MnO3 pouch cells, and oxygen and carbo…
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False[324.45, 680.82, 126.36, 23.97]■ AUTHOR INFORMATION■ AUTHOR INFORMATION
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False[324.45, 708.78, 93.87, 8.29]Corresponding AuthorCorresponding Author
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False[324.45, 717.92, 240.03, 45.54]Louis F. J. Piper -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States; orcid.org/0000-0002-3421-3210; Email: lpiper@ binghamton.eduLouis F. J. Piper -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States; orcid.org/0000-0002-3421-3210; Email: lpiper@ binghamton.edu
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False[306.43, 774.02, 12.06, 6.54]638638
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False[439.88, 774.81, 124.6, 12.72]https://dx.doi.org/10.1021/acsenergylett.9b02799 ACS Energy Lett. 2020, 5, 634 -641ACS Energy Lett. 2020, 5, 634 -641
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False[60.49, 48.93, 84.37, 8.72]ACS Energy LettersACS Energy Letters
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False[60.49, 68.77, 32.92, 8.29]AuthorsAuthors
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False[60.49, 77.29, 239.97, 34.49]Jatinkumar Rana -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States; orcid.org/0000-0002-3552-2453Jatinkumar Rana -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States; orcid.org/0000-0002-3552-2453
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False[60.49, 110.29, 239.99, 56.48]Joseph K. Papp -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, Un…Joseph K. Papp -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, Un…
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False[60.49, 165.28, 238.2, 34.24]Zachary Lebens-Higgins -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United StatesZachary Lebens-Higgins -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States
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False[60.49, 198.27, 239.96, 23.3]Mateusz Zuba -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United StatesMateusz Zuba -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States
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False[60.49, 220.33, 240.01, 45.24]Lori A. Kaufman -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, U…Lori A. Kaufman -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, U…
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False[60.49, 264.32, 239.97, 34.24]Anshika Goel -NorthEast Center for Chemical Energy Storage (NECCES), Binghamton University, Binghamton, New York 13902, United StatesAnshika Goel -NorthEast Center for Chemical Energy Storage (NECCES), Binghamton University, Binghamton, New York 13902, United States
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False[60.49, 297.31, 239.97, 34.24]Richard Schmuch -MEET Battery Research Center, Institute of Physical Chemistry, University of Muenster, 48149 Muenster, GermanyRichard Schmuch -MEET Battery Research Center, Institute of Physical Chemistry, University of Muenster, 48149 Muenster, Germany
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False[60.49, 330.31, 239.98, 45.24]Martin Winter -Helmholtz-Institute Muenster, IEK-12, Forschungszentrum Juelich GmbH, 48149 Muenster, Germany M. Stanley Whittingham -NorthEast Center for Chemical Energy Storage (NECCES), Binghamton University, Binghamt…Martin Winter -Helmholtz-Institute Muenster, IEK-12, Forschungszentrum Juelich GmbH, 48149 Muenster, Germany M. Stanley Whittingham -NorthEast Center for Chemical Energy Storage (NECCES), Binghamton University, Binghamt…
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False[60.49, 377.79, 114.33, 8.76]New York 13902, United StatesNew York 13902, United States
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False[60.49, 385.3, 236.8, 34.49]Wanli Yang -The Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States; orcid.org/0000-0003-0666-8063Wanli Yang -The Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States; orcid.org/0000-0003-0666-8063
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False[60.49, 418.3, 228.4, 56.48]Bryan D. McCloskey -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720…Bryan D. McCloskey -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720…
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False[60.49, 480.74, 175.35, 8.8]Complete contact information is available at:Complete contact information is available at:
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False[60.49, 491.74, 201.73, 8.8]https://pubs.acs.org/10.1021/acsenergylett.9b02799
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False[60.49, 513.7, 89.1, 8.29]Author ContributionsAuthor Contributions
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False[60.49, 521.06, 157.05, 13.38]¶ J.R. and J.K.P. had equal contributions.¶ J.R. and J.K.P. had equal contributions.
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False[60.49, 539.55, 23.98, 8.29]NotesNotes
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False[60.49, 551.49, 203.31, 8.8]The authors declare no competing fi nancial interest.The authors declare no competing fi nancial interest.
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False[60.49, 562.67, 115.98, 23.97]■ ACKNOWLEDGMENTS■ ACKNOWLEDGMENTS
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False[60.49, 589.36, 240.03, 173.83]This work was supported as part of the NorthEast Center for Chemical Energy Storage (NECCES), an Energy Frontier Research Center funded by the U.S. Department of Energy, Offi ce of Science, Offi ce of Basic Energy Scien…This work was supported as part of the NorthEast Center for Chemical Energy Storage (NECCES), an Energy Frontier Research Center funded by the U.S. Department of Energy, Offi ce of Science, Offi ce of Basic Energy Scien…
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False[278.65, 50.28, 118.38, 6.98]http://pubs.acs.org/journal/aelccp
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False[324.46, 69.37, 240.05, 42.59]6BMM of NSLS-II. The authors also acknowledge Diamond Light Source for HAXPES beamtime (Beamline I09) under Proposals No. SI22250-1 and No. SI22148-1 and thank TienLin Lee for his assistance.6BMM of NSLS-II. The authors also acknowledge Diamond Light Source for HAXPES beamtime (Beamline I09) under Proposals No. SI22250-1 and No. SI22148-1 and thank TienLin Lee for his assistance.
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False[324.45, 116.32, 74.2, 23.97]■ REFERENCES■ REFERENCES
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False[324.45, 143.31, 240.02, 18.86]Thackeray, M. Manganese oxides for lithium batteries. Prog. Solid State Chem. 1997 , 25 , 1 -71.Thackeray, M. Manganese oxides for lithium batteries. Prog. Solid State Chem. 1997 , 25 , 1 -71.
6105list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
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False[324.45, 163.55, 240.04, 29.18]Kalyani, P.; Chitra, S.; Mohan, T.; Gopukumar, S. Lithium metal rechargeable cells using Li2MnO3 as the positive electrode. J. Power Sources 1999 , 80 , 103 -106.Kalyani, P.; Chitra, S.; Mohan, T.; Gopukumar, S. Lithium metal rechargeable cells using Li2MnO3 as the positive electrode. J. Power Sources 1999 , 80 , 103 -106.
6106list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
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False[324.45, 194.11, 240.02, 18.86]Robertson, A.; Bruce, P. Mechanism of Electrochemical Activity in Li2MnO3. Chem. Mater. 2003 , 15 , 1984 -1992.Robertson, A.; Bruce, P. Mechanism of Electrochemical Activity in Li2MnO3. Chem. Mater. 2003 , 15 , 1984 -1992.
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False[324.45, 214.35, 240.02, 18.86]Yu, D.; Yanagida, K.; Kato, Y.; Nakamura, H. Electrochemical Activities in Li2MnO3. J. Electrochem. Soc. 2009 , 156 , A417 -A424.Yu, D.; Yanagida, K.; Kato, Y.; Nakamura, H. Electrochemical Activities in Li2MnO3. J. Electrochem. Soc. 2009 , 156 , A417 -A424.
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False[324.45, 234.65, 240.01, 38.71]Rana, J.; Stan, M.; Kloepsch, R.; Li, J.; Schumacher, G.; Welter, E.; Zizak, I.; Banhart, J.; Winter, M. Structural Changes in Li2MnO3 Cathode Material for Li-Ion Batteries. Adv. Energy Mater. 2014 , 4 , 1300998.Rana, J.; Stan, M.; Kloepsch, R.; Li, J.; Schumacher, G.; Welter, E.; Zizak, I.; Banhart, J.; Winter, M. Structural Changes in Li2MnO3 Cathode Material for Li-Ion Batteries. Adv. Energy Mater. 2014 , 4 , 1300998.
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after_stopp6:page_body:column_2_of_2:white[255, 255, 255]
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False[324.45, 275.41, 240.04, 39.44]Amalraj, S. F.; Burlaka, L.; Julien, C. M.; Mauger, A.; Kovacheva, D.; Talianker, M.; Markovsky, B.; Aurbach, D. Phase transitions in Li2MnO3 electrodes at various states-of-charge. Electrochim. Acta 2014 , 123 , 395 -4…Amalraj, S. F.; Burlaka, L.; Julien, C. M.; Mauger, A.; Kovacheva, D.; Talianker, M.; Markovsky, B.; Aurbach, D. Phase transitions in Li2MnO3 electrodes at various states-of-charge. Electrochim. Acta 2014 , 123 , 395 -4…
6110list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.46, 316.23, 240.03, 48.97]Dogan, F.; Croy, J.; Balasubramanian, M.; Slater, M.; Iddir, H.; Johnson, C.; Vaughey, J.; Key, B. Solid state NMR studies of Li2MnO3 and li-rich cathode materials: Proton insertion, local structure, and voltage fade. J…Dogan, F.; Croy, J.; Balasubramanian, M.; Slater, M.; Iddir, H.; Johnson, C.; Vaughey, J.; Key, B. Solid state NMR studies of Li2MnO3 and li-rich cathode materials: Proton insertion, local structure, and voltage fade. J…
6111list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.46, 367.31, 240.01, 39.38]Kubota, K.; Kaneko, T.; Hirayama, M.; Yonemura, M.; Imanari, Y.; Nakane, K.; Kanno, R. Direct synthesis of oxygen-deficient Li2MnO3-x for high capacity lithium battery electrodes. J. Power Sources 2012 , 216 , 249 -255.Kubota, K.; Kaneko, T.; Hirayama, M.; Yonemura, M.; Imanari, Y.; Nakane, K.; Kanno, R. Direct synthesis of oxygen-deficient Li2MnO3-x for high capacity lithium battery electrodes. J. Power Sources 2012 , 216 , 249 -255.
6112list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 405.35, 240.03, 41.5]Phillips, P. J.; Baren ̃ o, J.; Li, Y.; Abraham, D. P.; Klie, R. F. On the Localized Nature of the Structural Transformations of Li2MnO3 Following Electrochemical Cycling. Adv. Energy Mater. 2015 , 5 , 1501252.Phillips, P. J.; Baren ̃ o, J.; Li, Y.; Abraham, D. P.; Klie, R. F. On the Localized Nature of the Structural Transformations of Li2MnO3 Following Electrochemical Cycling. Adv. Energy Mater. 2015 , 5 , 1501252.
6113list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 448.9, 240.04, 39.38]Croy, J.; Park, J.; Dogan, F.; Johnson, C.; Key, B.; Balasubramanian, M. First-Cycle Evolution of Local Structure in Electrochemically Activated Li2MnO3. Chem. Mater. 2014 , 26 , 7091 -7098.Croy, J.; Park, J.; Dogan, F.; Johnson, C.; Key, B.; Balasubramanian, M. First-Cycle Evolution of Local Structure in Electrochemically Activated Li2MnO3. Chem. Mater. 2014 , 26 , 7091 -7098.
6114list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.46, 489.72, 240.08, 38.7]Lu, Z.; Dahn, J. Understanding the Anomalous Capacity of Li/ Li[NixLi(1/32x/3)Mn(2/3x/3)O2 Cells Using In Situ X-Ray Diffraction and Electrochemical Studies. J. Electrochem. Soc. 2002 , 149 , A815.Lu, Z.; Dahn, J. Understanding the Anomalous Capacity of Li/ Li[NixLi(1/32x/3)Mn(2/3x/3)O2 Cells Using In Situ X-Ray Diffraction and Electrochemical Studies. J. Electrochem. Soc. 2002 , 149 , A815.
6115list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 530.47, 240.02, 39.38]Kim, J.-S.; Johnson, C.; Vaughey, J.; Thackeray, M.; Hackney, S.; Yoon, W.; Grey, C. Electrochemical and structural properties of xLi2MO 3 · (1-x)LiMn0.5Ni0.5O2 electrodes for lithium batteries (M = Ti, Mn, Zr; O x 0.3)…Kim, J.-S.; Johnson, C.; Vaughey, J.; Thackeray, M.; Hackney, S.; Yoon, W.; Grey, C. Electrochemical and structural properties of xLi2MO 3 · (1-x)LiMn0.5Ni0.5O2 electrodes for lithium batteries (M = Ti, Mn, Zr; O x 0.3)…
6116list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 571.29, 240.03, 39.38]Johnson, C.; Kim, J.-S.; Lefief, C.; Li, N.; Vaughey, J.; Thackeray, M. The significance of the Li2MnO3 component in ' composite ' xLi2MnO3 * (1-x)LiMn0.5Ni0.5O2 electrodes. Electrochem. Commun. 2004 , 6 , 1085 -1091.Johnson, C.; Kim, J.-S.; Lefief, C.; Li, N.; Vaughey, J.; Thackeray, M. The significance of the Li2MnO3 component in ' composite ' xLi2MnO3 * (1-x)LiMn0.5Ni0.5O2 electrodes. Electrochem. Commun. 2004 , 6 , 1085 -1091.
6117list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 609.09, 240.02, 42.39]Armstrong, A.; Holzapfel, M.; Nova ́ k, P.; Johnson, C.; Kang, S.H.; Thackeray, M.; Bruce, P. Demonstrating oxygen loss and associated structural reorganization in the lithium battery cathode Li[Ni0.2Li0.2Mn0.6]O2. J. A…Armstrong, A.; Holzapfel, M.; Nova ́ k, P.; Johnson, C.; Kang, S.H.; Thackeray, M.; Bruce, P. Demonstrating oxygen loss and associated structural reorganization in the lithium battery cathode Li[Ni0.2Li0.2Mn0.6]O2. J. A…
6118list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 652.87, 240.03, 29.12]Chen, H.; Islam, M. S. Lithium extraction mechanism in Li-rich Li2MnO3involving oxygen hole formation and dimerization. Chem. Mater. 2016 , 28 , 6656 -6663.Chen, H.; Islam, M. S. Lithium extraction mechanism in Li-rich Li2MnO3involving oxygen hole formation and dimerization. Chem. Mater. 2016 , 28 , 6656 -6663.
6119list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 683.43, 240.03, 39.38]Seo, D.-H.; Lee, J.; Urban, A.; Malik, R.; Kang, S.; Ceder, G. The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials. Nat. Chem. 2016 , 8 , 692 -697.Seo, D.-H.; Lee, J.; Urban, A.; Malik, R.; Kang, S.; Ceder, G. The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials. Nat. Chem. 2016 , 8 , 692 -697.
6120list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[324.45, 724.19, 240.03, 39.38]Yan, P.; Xiao, L.; Zheng, J.; Zhou, Y.; He, Y.; Zu, X.; Mao, S. X.; Xiao, J.; Gao, F.; Zhang, J.-G.; Wang, C.-M. Probing the Degradation Mechanism of Li2MnO3 Cathode for Li-Ion Batteries. Chem. Mater. 2015 , 27 , 975 -9…Yan, P.; Xiao, L.; Zheng, J.; Zhou, Y.; He, Y.; Zu, X.; Mao, S. X.; Xiao, J.; Gao, F.; Zhang, J.-G.; Wang, C.-M. Probing the Degradation Mechanism of Li2MnO3 Cathode for Li-Ion Batteries. Chem. Mater. 2015 , 27 , 975 -9…
6121page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:bottom_margin:column_2_of_2:white[252, 252, 252]
white
False[306.43, 774.02, 12.06, 6.54]639639
6122page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[439.88, 774.81, 124.6, 12.72]https://dx.doi.org/10.1021/acsenergylett.9b02799 ACS Energy Lett. 2020, 5, 634 -641ACS Energy Lett. 2020, 5, 634 -641
7123page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:top_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 48.93, 84.37, 8.72]ACS Energy LettersACS Energy Letters
7124list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 68.99, 239.99, 39.61]Johnson, C.; Li, N.; Lefief, C.; Thackeray, M. Anamolous capacity and cycling stability of xLi2MnO3 * (1-x)LiMO2 electrodes (M = Mn,Ni,Co) in lithium batteries at 50C. Electrochem. Commun. 2007 , 9 , 787 -795.Johnson, C.; Li, N.; Lefief, C.; Thackeray, M. Anamolous capacity and cycling stability of xLi2MnO3 * (1-x)LiMO2 electrodes (M = Mn,Ni,Co) in lithium batteries at 50C. Electrochem. Commun. 2007 , 9 , 787 -795.
7125list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 109.98, 239.99, 38.88]Thackeray, M.; Kang, S.-H.; Johnson, C.; Vaughey, J.; Benedek, R.; Hackney, S. Li2MnO3-stabilized LiMO2 (M= Mn, Ni, Co) electrodes for lithium-ion batteries. J. Mater. Chem. 2007 , 17 , 3112 -3125.Thackeray, M.; Kang, S.-H.; Johnson, C.; Vaughey, J.; Benedek, R.; Hackney, S. Li2MnO3-stabilized LiMO2 (M= Mn, Ni, Co) electrodes for lithium-ion batteries. J. Mater. Chem. 2007 , 17 , 3112 -3125.
7126list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 150.91, 239.97, 39.55]Rana, J.; Kloepsch, R.; Li, J.; Scherb, T.; Schumacher, G.; Winter, M.; Banhart, J. On the structural integrity and electrochemical activity of a 0.5Li2MnO3 * 0.5LiCoO2 cathode material for lithiumion batteries. J. Mate…Rana, J.; Kloepsch, R.; Li, J.; Scherb, T.; Schumacher, G.; Winter, M.; Banhart, J. On the structural integrity and electrochemical activity of a 0.5Li2MnO3 * 0.5LiCoO2 cathode material for lithiumion batteries. J. Mate…
7127list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 191.9, 240.0, 39.55]Rana, J.; Kloepsch, R.; Li, J.; Stan, M.; Schumacher, G.; Winter, M.; Banhart, J. Structural Changes in a Li-Rich 0.5Li2MnO3 * 0.5LiMn0.4Ni0.4Co0.2O2 Cathode Material for Li-Ion Batteries: A Local Perspective. J. Electr…Rana, J.; Kloepsch, R.; Li, J.; Stan, M.; Schumacher, G.; Winter, M.; Banhart, J. Structural Changes in a Li-Rich 0.5Li2MnO3 * 0.5LiMn0.4Ni0.4Co0.2O2 Cathode Material for Li-Ion Batteries: A Local Perspective. J. Electr…
7128list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 230.1, 240.01, 42.28]Teufl, T.; Strehle, B.; Mu ̈ ller, P.; Gasteiger, H.; Mendez, M. Oxygen Release and Surface Degradation of Li- and Mn-Rich Layered Oxides in Variation of the Li2MnO3 Content. J. Electrochem. Soc. 2018 , 165 , A2718 -A27…Teufl, T.; Strehle, B.; Mu ̈ ller, P.; Gasteiger, H.; Mendez, M. Oxygen Release and Surface Degradation of Li- and Mn-Rich Layered Oxides in Variation of the Li2MnO3 Content. J. Electrochem. Soc. 2018 , 165 , A2718 -A27…
7129list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 273.82, 239.99, 38.88]Radin, M.; Vinckeviciute, J.; Seshadri, R.; Van der Ven, A. Manganese oxidation as the origin of the anomalous capacity of Mncontaining Li-excess cathode materials. Nature Energy 2019 , 4 , 639 -646.Radin, M.; Vinckeviciute, J.; Seshadri, R.; Van der Ven, A. Manganese oxidation as the origin of the anomalous capacity of Mncontaining Li-excess cathode materials. Nature Energy 2019 , 4 , 639 -646.
7130list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 314.76, 240.01, 38.88]Qiu, B.; Zhang, M.; Wu, L.; Wang, J.; Xia, Y.; Qian, D.; Liu, H.; Hy, S.; Chen, Y.; An, K.; Zhu, Y.; Liu, Z.; Meng, Y. Gas -solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion bat…Qiu, B.; Zhang, M.; Wu, L.; Wang, J.; Xia, Y.; Qian, D.; Liu, H.; Hy, S.; Chen, Y.; An, K.; Zhu, Y.; Liu, Z.; Meng, Y. Gas -solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion bat…
7131list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 355.75, 240.01, 79.81]Pimenta, V.; Sathiya, M.; Batuk, D.; Abakumov, A. M.; Giaume, D.; Cassaignon, S.; Larcher, D.; Tarascon, J. M. Synthesis of Li-Rich NMC: A Comprehensive Study. Chem. Mater. 2017 , 29 , 9923 -9936. (26) Luo, K.; Roberts,…Pimenta, V.; Sathiya, M.; Batuk, D.; Abakumov, A. M.; Giaume, D.; Cassaignon, S.; Larcher, D.; Tarascon, J. M. Synthesis of Li-Rich NMC: A Comprehensive Study. Chem. Mater. 2017 , 29 , 9923 -9936. (26) Luo, K.; Roberts,…
7132list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 437.67, 239.99, 28.56]Gent, W.; et al. Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides. Nat. Commun. 2017 , 8 , 2091.Gent, W.; et al. Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides. Nat. Commun. 2017 , 8 , 2091.
7133list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 468.29, 239.97, 38.86]Xu, J.; Sun, M.; Qiao, R.; Renfrew, S. E.; Ma, L.; Wu, T.; Hwang, S.; Nordlund, D.; Su, D.; Amine, K.; Lu, J.; McCloskey, B. D.; Yang, W.; Tong, W. Elucidating anionic oxygen activity in lithium-rich layered oxides. Nat…Xu, J.; Sun, M.; Qiao, R.; Renfrew, S. E.; Ma, L.; Wu, T.; Hwang, S.; Nordlund, D.; Su, D.; Amine, K.; Lu, J.; McCloskey, B. D.; Yang, W.; Tong, W. Elucidating anionic oxygen activity in lithium-rich layered oxides. Nat…
7134list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 509.26, 240.01, 49.87]Lebens-Higgins, Z.; Vinckeviciute, J.; Wu, J.; Faenza, N.; Li, Y.; Sallis, S.; Pereira, N.; Meng, Y.; Amatucci, G.; Van Der Ven, A.; Yang, W.; Piper, L. Distinction between Intrinsic and X-ray-Induced Oxidized Oxygen St…Lebens-Higgins, Z.; Vinckeviciute, J.; Wu, J.; Faenza, N.; Li, Y.; Sallis, S.; Pereira, N.; Meng, Y.; Amatucci, G.; Van Der Ven, A.; Yang, W.; Piper, L. Distinction between Intrinsic and X-ray-Induced Oxidized Oxygen St…
7135list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 560.52, 240.0, 69.55]Massel, F.; Hikima, K.; Rensmo, H.; Suzuki, K.; Hirayama, M.; Xu, C.; Younesi, R.; Liu, Y.-S.; Guo, J.; Kanno, R.; Hahlin, M.; Duda, L.-C. Excess Lithium in Transition Metal Layers of Epitaxially Grown Thin Film Cathode…Massel, F.; Hikima, K.; Rensmo, H.; Suzuki, K.; Hirayama, M.; Xu, C.; Younesi, R.; Liu, Y.-S.; Guo, J.; Kanno, R.; Hahlin, M.; Duda, L.-C. Excess Lithium in Transition Metal Layers of Epitaxially Grown Thin Film Cathode…
7136list_itemaffiliationFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 622.14, 238.14, 18.91]mechanisms in LiNi 0.8 Co 0.2y Al y O 2 systems. Mater. Horiz. 2019 6 , 2112 -2123.mechanisms in LiNi 0.8 Co 0.2y Al y O 2 systems. Mater. Horiz. 2019 6 , 2112 -2123.
7137list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 642.44, 240.01, 39.55]Li, N.; Sallis, S.; Papp, J.; Wei, J.; McCloskey, B.; Yang, W.; Tong, W. Unraveling the Cationic and Anionic Redox Reactions in a Conventional Layered Oxide Cathode. ACS Energy Letters 2019 , 4 , 2836 -2842.Li, N.; Sallis, S.; Papp, J.; Wei, J.; McCloskey, B.; Yang, W.; Tong, W. Unraveling the Cationic and Anionic Redox Reactions in a Conventional Layered Oxide Cathode. ACS Energy Letters 2019 , 4 , 2836 -2842.
7138list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 683.43, 240.0, 18.91]Strobel, P.; Lambert-Andron, B. Crystallographic and magnetic structure of Li2MnO3. J. Solid State Chem. 1988 , 75 , 90 -98.Strobel, P.; Lambert-Andron, B. Crystallographic and magnetic structure of Li2MnO3. J. Solid State Chem. 1988 , 75 , 90 -98.
7139list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 703.73, 240.01, 29.23]Boulineau, A.; Croguennec, L.; Delmas, C.; Weill, F. Structure of Li2MnO3 with different degrees of defects. Solid State Ionics 2010 , 180 , 1652 -1659.Boulineau, A.; Croguennec, L.; Delmas, C.; Weill, F. Structure of Li2MnO3 with different degrees of defects. Solid State Ionics 2010 , 180 , 1652 -1659.
7140list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:bottom_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 734.34, 239.99, 28.62]Liang, Y.; Prendergast, D. Quantum many-body effects in x-ray spectra efficiently computed using a basic graph algorithm. Phys. Rev. B: Condens. Matter Mater. Phys. 2018 , 97 , 205127.Liang, Y.; Prendergast, D. Quantum many-body effects in x-ray spectra efficiently computed using a basic graph algorithm. Phys. Rev. B: Condens. Matter Mater. Phys. 2018 , 97 , 205127.
7141page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:top_margin:column_2_of_2:colored[159, 182, 177]
colored
True[537.79, 49.99, 19.7, 7.35]LetterLetter
7142page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:top_margin:column_2_of_2:white[255, 255, 255]
white
False[278.65, 50.28, 118.38, 6.98]http://pubs.acs.org/journal/aelccp
7143list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.46, 69.0, 240.04, 38.98]Yang, W.; Devereaux, T. Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering. J. Power Sources 2018 , 389 , 188 -197.Yang, W.; Devereaux, T. Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering. J. Power Sources 2018 , 389 , 188 -197.
7144list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.46, 109.36, 240.02, 38.98]Renfrew, S.; McCloskey, B. Quantification of Surface Oxygen Depletion and Solid Carbonate Evolution on the First Cycle of LiNi 0.6 Mn 0.2 Co 0.2 O 2 Electrodes. ACS Applied Energy Materials 2019 , 2 , 3762 -3772.Renfrew, S.; McCloskey, B. Quantification of Surface Oxygen Depletion and Solid Carbonate Evolution on the First Cycle of LiNi 0.6 Mn 0.2 Co 0.2 O 2 Electrodes. ACS Applied Energy Materials 2019 , 2 , 3762 -3772.
7145list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.46, 149.73, 240.02, 38.31]Jain, A.; Ong, S.; Hautier, G.; Chen, W.; Richards, W.; Dacek, S.; Cholia, S.; Gunter, D.; Skinner, D.; Ceder, G.; Persson, K. Commentary: The materials project: A materials genome approach to accelerating materials inn…Jain, A.; Ong, S.; Hautier, G.; Chen, W.; Richards, W.; Dacek, S.; Cholia, S.; Gunter, D.; Skinner, D.; Ceder, G.; Persson, K. Commentary: The materials project: A materials genome approach to accelerating materials inn…
7146list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 190.1, 240.0, 28.82]Christensen, A.; Hansen, P.; Lehmann, M. Isotope Effects in the Bonds of a-CrOOH and a-CrOOD. J. Solid State Chem. 1977 , 21 , 325 -329.Christensen, A.; Hansen, P.; Lehmann, M. Isotope Effects in the Bonds of a-CrOOH and a-CrOOD. J. Solid State Chem. 1977 , 21 , 325 -329.
7147list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 220.36, 240.04, 28.84]Yamamoto, T. Assignment of pre-edge peaks in K-edge x-ray absorption spectra of 3d transition metal compounds: electric dipole or quadrupole? X-Ray Spectrom. 2008 , 37 , 572 -584.Yamamoto, T. Assignment of pre-edge peaks in K-edge x-ray absorption spectra of 3d transition metal compounds: electric dipole or quadrupole? X-Ray Spectrom. 2008 , 37 , 572 -584.
7148list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 250.57, 240.04, 28.84]Wang, D.; Liu, L.; Sun, X.; Sham, T.-K. T.-K. Observation of lithiation-induced structural variations in TiO 2 nanotube arrays by Xray absorption fine structure. J. Mater. Chem. A 2015 , 3 , 412 -419.Wang, D.; Liu, L.; Sun, X.; Sham, T.-K. T.-K. Observation of lithiation-induced structural variations in TiO 2 nanotube arrays by Xray absorption fine structure. J. Mater. Chem. A 2015 , 3 , 412 -419.
7149list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 280.79, 240.03, 49.08]Gautam, S.; Das, A.; Ojha, S.; Shukla, D.; Phase, D.; Singh, F. Electronic structure modification and Fermi level shifting in niobiumdoped anatase titanium dioxide thin films: a comparative study of NEXAFS, work functio…Gautam, S.; Das, A.; Ojha, S.; Shukla, D.; Phase, D.; Singh, F. Electronic structure modification and Fermi level shifting in niobiumdoped anatase titanium dioxide thin films: a comparative study of NEXAFS, work functio…
7150list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 331.31, 240.03, 38.93]Wandt, J.; Freiberg, A. T.; Ogrodnik, A.; Gasteiger, H. Singlet oxygen evolution from layered transition metal oxide cathode materials and its implications for lithium-ion batteries. Mater. Today 2018 , 21 , 825 -833.Wandt, J.; Freiberg, A. T.; Ogrodnik, A.; Gasteiger, H. Singlet oxygen evolution from layered transition metal oxide cathode materials and its implications for lithium-ion batteries. Mater. Today 2018 , 21 , 825 -833.
7151list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 371.68, 240.02, 38.93]Grenier, A.; Liu, H.; Wiaderek, K.; Lebens-Higgins, Z.; Borkiewicz, O.; Piper, L.; Chupas, P.; Chapman, K. Reaction Heterogeneity in LiNi0.8Co0.15Al0.05O2 Induced by Surface Layer. Chem. Mater. 2017 , 29 , 7345 -7352.Grenier, A.; Liu, H.; Wiaderek, K.; Lebens-Higgins, Z.; Borkiewicz, O.; Piper, L.; Chupas, P.; Chapman, K. Reaction Heterogeneity in LiNi0.8Co0.15Al0.05O2 Induced by Surface Layer. Chem. Mater. 2017 , 29 , 7345 -7352.
7152list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 412.04, 240.03, 49.08]Lebens-Higgins, Z.; Sallis, S.; Faenza, N.; Badway, F.; Pereira, N.; Halat, D.; Wahila, M.; Schlueter, C.; Lee, T.-L.; Yang, W.; Grey, C.; Amatucci, G.; Piper, L. Evolution of the Electrode -Electrolyte Interface of LiN…Lebens-Higgins, Z.; Sallis, S.; Faenza, N.; Badway, F.; Pereira, N.; Halat, D.; Wahila, M.; Schlueter, C.; Lee, T.-L.; Yang, W.; Grey, C.; Amatucci, G.; Piper, L. Evolution of the Electrode -Electrolyte Interface of LiN…
7153list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 459.66, 240.04, 31.68]Edstro ̈ m, K.; Gustafsson, T.; Thomas, J. O. The cathodeelectrolyte interface in the Li-ion battery. Electrochim. Acta 2004 , 50 , 397 -403.Edstro ̈ m, K.; Gustafsson, T.; Thomas, J. O. The cathodeelectrolyte interface in the Li-ion battery. Electrochim. Acta 2004 , 50 , 397 -403.
7154list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.46, 492.72, 240.04, 38.31]El Ouatani, L.; Dedryvre, R.; Siret, C.; Biensan, P.; Reynaud, S.; Irat ̧ abal, P.; Gonbeau, D. The Effect of Vinylene Carbonate Additive on Surface Film Formation on Both Electrodes in Li-Ion Batteries. J. Electrochem.…El Ouatani, L.; Dedryvre, R.; Siret, C.; Biensan, P.; Reynaud, S.; Irat ̧ abal, P.; Gonbeau, D. The Effect of Vinylene Carbonate Additive on Surface Film Formation on Both Electrodes in Li-Ion Batteries. J. Electrochem.…
7155list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 530.12, 240.02, 41.94]Dahe ́ ron, L.; Dedryve ̀ re, R.; Martinez, H.; Me ́ ne ́ trier, M.; Denage, C.; Delmas, C.; Gonbeau, D. Electron Transfer Mechanisms upon Lithium Deintercalation from LiCoO 2 to CoO 2 Investigated by XPS. Chem. Mater. …Dahe ́ ron, L.; Dedryve ̀ re, R.; Martinez, H.; Me ́ ne ́ trier, M.; Denage, C.; Delmas, C.; Gonbeau, D. Electron Transfer Mechanisms upon Lithium Deintercalation from LiCoO 2 to CoO 2 Investigated by XPS. Chem. Mater. …
7156list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 573.44, 240.04, 38.98]Quesne-Turin, A.; Flahaut, D.; Croguennec, L.; Vallverdu, G.; Allouche, J.; Charles-Blin, Y.; Chotard, J.-N.; Me ́ ne ́ trier, M.; Baraille, I. Surface Reactivity of Li2MnO3: First-Principles and Experimental Study. ACS…Quesne-Turin, A.; Flahaut, D.; Croguennec, L.; Vallverdu, G.; Allouche, J.; Charles-Blin, Y.; Chotard, J.-N.; Me ́ ne ́ trier, M.; Baraille, I. Surface Reactivity of Li2MnO3: First-Principles and Experimental Study. ACS…
7157list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 613.81, 240.03, 18.74]Robertson, A.; Bruce, P. The origin of electrochemical activity in Li2MnO3. Chem. Commun. 2002 , 2790 -2791.Robertson, A.; Bruce, P. The origin of electrochemical activity in Li2MnO3. Chem. Commun. 2002 , 2790 -2791.
7158list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 633.93, 240.0, 28.84]Zhang, J.-N.; et al. Trace doping of multiple elements enables stable battery cycling of LiCoO2 at 4.6 V. Nature Energy 2019 , 4 , 594 -603.Zhang, J.-N.; et al. Trace doping of multiple elements enables stable battery cycling of LiCoO2 at 4.6 V. Nature Energy 2019 , 4 , 594 -603.
7159list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
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False[324.45, 661.2, 240.04, 52.03]McCalla, E.; Abakumov, A.; Saubane ̀ re, M.; Foix, D.; Berg, E.; Rousse, G.; Doublet, M.; Gonbeau, D.; Nova ́ k, P.; Van Tendeloo, G.; Dominko, R.; Tarascon, J.-M. Visualization of O-O peroxo-like dimers in high-capacit…McCalla, E.; Abakumov, A.; Saubane ̀ re, M.; Foix, D.; Berg, E.; Rousse, G.; Doublet, M.; Gonbeau, D.; Nova ́ k, P.; Van Tendeloo, G.; Dominko, R.; Tarascon, J.-M. Visualization of O-O peroxo-like dimers in high-capacit…
7160list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 711.65, 240.05, 31.85]Xie, Y.; Saubane ̀ re, M.; Doublet, M.-L. Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries. Energy Environ. Sci. 2017 , 10 , 266 -274.Xie, Y.; Saubane ̀ re, M.; Doublet, M.-L. Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries. Energy Environ. Sci. 2017 , 10 , 266 -274.
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after_stopp7:bottom_margin:column_2_of_2:white[255, 255, 255]
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False[324.45, 744.89, 240.03, 18.07]Zhao, E.; Zhang, M.; Wang, X.; Hu, E.; Liu, J.; Yu, X.; Olguin, M.; Wynn, T.; Meng, Y.; Page, K.; Wang, F.; Li, H.; Yang, X.-Q.;Zhao, E.; Zhang, M.; Wang, X.; Hu, E.; Liu, J.; Yu, X.; Olguin, M.; Wynn, T.; Meng, Y.; Page, K.; Wang, F.; Li, H.; Yang, X.-Q.;
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False[439.88, 774.81, 124.6, 12.72]https://dx.doi.org/10.1021/acsenergylett.9b02799 ACS Energy Lett. 2020, 5, 634 -641ACS Energy Lett. 2020, 5, 634 -641
8164page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
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False[60.49, 48.93, 84.37, 8.72]ACS Energy LettersACS Energy Letters
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after_stopp8:top_margin:right_crossing:white[255, 255, 255]
white
False[278.65, 50.28, 118.38, 6.98]http://pubs.acs.org/journal/aelccp
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8167textreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 68.99, 240.01, 28.61]Huang, X.; Chen, L. Local structure adaptability through multi cations for oxygen redox accommodation in Li-Rich layered oxides. Energy Storage Materials 2020 , 24 , 384 -393.Huang, X.; Chen, L. Local structure adaptability through multi cations for oxygen redox accommodation in Li-Rich layered oxides. Energy Storage Materials 2020 , 24 , 384 -393.
8168page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:bottom_margin:left_crossing:white[255, 255, 255]
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False[306.43, 774.02, 12.06, 6.54]641641
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False[439.88, 774.81, 124.6, 12.72]https://dx.doi.org/10.1021/acsenergylett.9b02799 ACS Energy Lett. 2020, 5, 634 -641ACS Energy Lett. 2020, 5, 634 -641