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这里对齐真实图表资产提取链路。caption_source=embedded_table_cell 表示表注来自 Docling table cell,不会出现在 text block 审计差集里;caption_continuation_used_by_asset 表示某个 text block 已被图表 caption 吸收,不应按普通 metadata 解读。
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| 3 | figure | Fig. 2 | 3 | direct_caption_ref | 0.82 | [102.1, 67.98, 419.21, 280.81] | Figure 2. Bulk O and Mn redox activity in Li2MnO3. O K-edge TFY XAS data (a), and RIXS maps of Li2MnO3 electrodes charged to 4.8 V (b) and 5.0 V (c). Operando Mn K-edge XANES (d) and EXAFS (e) data for charged and discharged states during the fi rst cycle. | ||||
| 4 | figure | Fig. 3 | 4 | direct_caption_ref | 0.82 | [93.48, 66.26, 437.02, 406.53] | Figure 3. Gas evolution and surface studies of Li2MnO3. (a) DEMS for the fi rst charge and (b) XPS/HAXPES data and (c) Mn L3-edge TEY data for the pristine and electrolyte-soaked material. | ||||
| 5 | table | Table 1 | 5 | nearby_text_caption | 0.82 | [60.42, 658.7, 228.55, 63.77] | Table 1. First Charge Capacity Contributions a |
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| 1 | 8 | text | abstract_candidate | False | medium | inline_abstract | inline_abstract | p1:body_region:0 | p1:page_body:column_1_of_2:gray | [244, 244, 245] gray | False | [60.49, 291.3, 316.21, 130.86] | ABSTRACT: Though Li2MnO3 was originally considered to be electrochemically inert, its observed activation has spawned a new class of Li-rich layered compounds that deliver capacities beyond the traditional transition-me… | ABSTRACT: Though Li2MnO3 was originally considered to be electrochemically inert, its observed activation has spawned a new class of Li-rich layered compounds that deliver capacities beyond the traditional transition-me… | ||
| 1 | 9 | text | metadata | False | low | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [346.45, 232.1, 48.46, 7.85] | Read Online | Read Online | ||
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| 1 | 15 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p1:body_region:0 | p1:page_body:column_1_of_2:gray | [244, 244, 245] gray | False | [60.49, 423.34, 504.01, 30.63] | during activation with minor contributions from reduced Mn species on the surface. These studies reveal that, although Li2 MnO3 is considered critical for promoting bulk anionic redox in Li-rich layered oxides, Li2MnO3 … | during activation with minor contributions from reduced Mn species on the surface. These studies reveal that, although Li2 MnO3 is considered critical for promoting bulk anionic redox in Li-rich layered oxides, Li2MnO3 … | ||
| 1 | 16 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p1:body_region:0 | p1:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 477.74, 240.01, 279.62] | O riginally considered electrochemically inactive, 1 Li2MnO3 can deliver substantial capacity during charge, as demonstrated by Kalyani et al. 2 Later, Robertson and Bruce 3 revealed how Li2MnO3 could be activated throu… | O riginally considered electrochemically inactive, 1 Li2MnO3 can deliver substantial capacity during charge, as demonstrated by Kalyani et al. 2 Later, Robertson and Bruce 3 revealed how Li2MnO3 could be activated throu… | ||
| 1 | 17 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p1:body_region:1 | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 479.72, 240.07, 208.53] | While Li2MnO3 is regarded as a model compound for describing bulk oxygen redox activity in LR-NMCs, recent RIXS studies did not detect similar spectroscopic signatures of oxidized lattice oxygen in Li2MnO3. 30 Additiona… | While Li2MnO3 is regarded as a model compound for describing bulk oxygen redox activity in LR-NMCs, recent RIXS studies did not detect similar spectroscopic signatures of oxidized lattice oxygen in Li2MnO3. 30 Additiona… | ||
| 1 | 18 | text | metadata | False | low | first_page_metadata | first_page_metadata | p1:body_region:1 | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [367.99, 705.59, 68.95, 7.92] | December 23, 2019 | December 23, 2019 | ||
| 1 | 19 | text | metadata | False | low | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 705.67, 35.03, 7.77] | Received: | Received: | ||
| 1 | 20 | text | metadata | False | low | first_page_metadata | first_page_metadata | p1:body_region:1 | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [367.99, 716.59, 59.37, 7.92] | January 27, 2020 | January 27, 2020 | ||
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| 1 | 23 | text | metadata | False | low | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 727.67, 38.36, 7.77] | Published: | Published: | ||
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| 1 | 25 | page_footer | page_footer | False | low | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [194.29, 772.66, 95.68, 5.88] | © 2020 American Chemical Society | © 2020 American Chemical Society | ||
| 1 | 26 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p1:body_region:0 | p1:bottom_margin:column_2_of_2:white | [255, 255, 255] white | True | [306.43, 778.33, 12.06, 6.54] | 634 | 634 | ||
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| 2 | 29 | page_header | page_header | False | low | docling_page_header | docling_page_header | p2:body_region:1 | p2:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [278.65, 50.28, 118.38, 6.98] | http://pubs.acs.org/journal/aelccp | |||
| 2 | 30 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p2:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 412.0, 503.99, 17.75] | Figure 1. Structure and electrochemistry of Li2MnO3. (a) XRD pattern and (b) SEM image showing particles morphology of Li2MnO3 synthesized at 600 ◦ C. The fi rst cycle voltage pro fi les and subsequent cycling performan… | Figure 1. Structure and electrochemistry of Li2MnO3. (a) XRD pattern and (b) SEM image showing particles morphology of Li2MnO3 synthesized at 600 ◦ C. The fi rst cycle voltage pro fi les and subsequent cycling performan… | |||
| 2 | 31 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p2:body_region:0 | p2:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 442.75, 239.96, 19.97] | alternative charge compensation mechanisms that could explain the electrochemical activity of Li2MnO3? | alternative charge compensation mechanisms that could explain the electrochemical activity of Li2MnO3? | ||
| 2 | 32 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p2:body_region:0 | p2:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 464.98, 240.0, 220.33] | To resolve these issues, we considered all possible charge compensation mechanisms including bulk oxygen redox, Mn 4+ /Mn 7+ redox, and surface degradation. Our investigation employed a combination of techniques sensiti… | To resolve these issues, we considered all possible charge compensation mechanisms including bulk oxygen redox, Mn 4+ /Mn 7+ redox, and surface degradation. Our investigation employed a combination of techniques sensiti… | ||
| 2 | 33 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p2:body_region:0 | p2:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 687.55, 240.01, 75.64] | Figure 1a shows the XRD pattern of the as-synthesized material, where all re fl ections can be indexed in the monoclinic system with the space group C 2/ m . 33 In the layered structure of Li 2 MnO3, the interslab octah… | Figure 1a shows the XRD pattern of the as-synthesized material, where all re fl ections can be indexed in the monoclinic system with the space group C 2/ m . 33 In the layered structure of Li 2 MnO3, the interslab octah… | ||
| 2 | 34 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p2:body_region:1 | p2:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 439.45, 240.05, 301.52] | 20 to 34 ° . However, these superlattice re fl ections appear convoluted into a broad asymmetric peak as shown in Figure 1a. Previously, the intensity and asymmetry of these superlattice re fl ections are correlated wit… | 20 to 34 ° . However, these superlattice re fl ections appear convoluted into a broad asymmetric peak as shown in Figure 1a. Previously, the intensity and asymmetry of these superlattice re fl ections are correlated wit… | ||
| 2 | 35 | text | unknown_text | False | high | inside_front_matter | inside_front_matter | p2:body_region:1 | p2:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 742.61, 240.0, 20.59] | While the irreversible component of the fi rst cycle capacity could be attributed to gas evolution, 11 -15 other proposed | While the irreversible component of the fi rst cycle capacity could be attributed to gas evolution, 11 -15 other proposed | ||
| 2 | 36 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p2:bottom_margin:column_2_of_2:white | [254, 254, 254] white | False | [306.43, 774.02, 12.06, 6.54] | 635 | 635 | |||
| 2 | 37 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p2:body_region:1 | p2:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [439.88, 774.81, 124.6, 12.72] | https://dx.doi.org/10.1021/acsenergylett.9b02799 ACS Energy Lett. 2020, 5, 634 -641 | ACS Energy Lett. 2020, 5, 634 -641 | ||
| 3 | 38 | page_header | page_header | False | low | docling_page_header | docling_page_header | p3:body_region:0 | p3:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 84.37, 8.72] | ACS Energy Letters | ACS Energy Letters | ||
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| 3 | 40 | page_header | page_header | False | low | docling_page_header | docling_page_header | p3:body_region:1 | p3:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [278.65, 50.28, 118.38, 6.98] | http://pubs.acs.org/journal/aelccp | |||
| 3 | 41 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p3:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 357.75, 503.97, 17.75] | Figure 2. Bulk O and Mn redox activity in Li2MnO3. O K-edge TFY XAS data (a), and RIXS maps of Li2MnO3 electrodes charged to 4.8 V (b) and 5.0 V (c). Operando Mn K-edge XANES (d) and EXAFS (e) data for charged and disch… | Figure 2. Bulk O and Mn redox activity in Li2MnO3. O K-edge TFY XAS data (a), and RIXS maps of Li2MnO3 electrodes charged to 4.8 V (b) and 5.0 V (c). Operando Mn K-edge XANES (d) and EXAFS (e) data for charged and disch… | |||
| 3 | 42 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p3:body_region:0 | p3:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 386.73, 240.0, 233.52] | charge compensation mechanisms, such as oxidation of Mn 4+ and/or lattice oxygen redox need to be considered to fully account for the observed total capacity. 23 We fi rst employed O K-edge XAS and RIXS studies to probe… | charge compensation mechanisms, such as oxidation of Mn 4+ and/or lattice oxygen redox need to be considered to fully account for the observed total capacity. 23 We fi rst employed O K-edge XAS and RIXS studies to probe… | ||
| 3 | 43 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p3:body_region:0 | p3:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 621.34, 240.0, 141.86] | These results are further complemented by a quantitative measure of oxide oxidation using an acid titration of extracted Li2MnO3 cathodes. Previous studies on NMC cathode materials have found that O 2 evolves from parti… | These results are further complemented by a quantitative measure of oxide oxidation using an acid titration of extracted Li2MnO3 cathodes. Previous studies on NMC cathode materials have found that O 2 evolves from parti… | ||
| 3 | 44 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p3:body_region:1 | p3:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 387.94, 240.04, 53.76] | fi rst charge and the bottom of the fi rst discharge. Here we have found that these titrations demonstrate minimal contributions from bulk oxygen redox (only 10 mAh g -1 ), which is in agreement with the lack of spectro… | fi rst charge and the bottom of the fi rst discharge. Here we have found that these titrations demonstrate minimal contributions from bulk oxygen redox (only 10 mAh g -1 ), which is in agreement with the lack of spectro… | ||
| 3 | 45 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p3:body_region:1 | p3:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 443.95, 240.05, 197.31] | We then turn to operando Mn K-edge XAS to probe bulk Mn redox activity in Li2MnO3 involving Mn 4+ /Mn 7+ redox as proposed by Radin et al. 23 However, the experimental veri fi cation of the proposed Mn 4+ /Mn 7+ redox i… | We then turn to operando Mn K-edge XAS to probe bulk Mn redox activity in Li2MnO3 involving Mn 4+ /Mn 7+ redox as proposed by Radin et al. 23 However, the experimental veri fi cation of the proposed Mn 4+ /Mn 7+ redox i… | ||
| 3 | 46 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p3:body_region:1 | p3:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 643.51, 240.05, 119.7] | Parts d and e of Figure 2 show operando Mn K-edge X-ray absorption near-edge structure (XANES) and extended X-ray absorption fi ne structure (EXAFS) data of Li2MnO3. At 5.0 V, no clear shift of the main edge beyond that… | Parts d and e of Figure 2 show operando Mn K-edge X-ray absorption near-edge structure (XANES) and extended X-ray absorption fi ne structure (EXAFS) data of Li2MnO3. At 5.0 V, no clear shift of the main edge beyond that… | ||
| 3 | 47 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p3:bottom_margin:column_2_of_2:white | [253, 253, 253] white | False | [306.43, 774.02, 12.06, 6.54] | 636 | 636 | |||
| 3 | 48 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p3:body_region:1 | p3:bottom_margin:column_2_of_2:off_white | [245, 247, 250] off_white | False | [439.88, 774.81, 124.57, 5.51] | https://dx.doi.org/10.1021/acsenergylett.9b02799 | |||
| 3 | 49 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p3:body_region:1 | p3:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [477.64, 779.76, 86.85, 7.78] | ACS Energy Lett. 2020, 5, 634 -641 | ACS Energy Lett. 2020, 5, 634 -641 | ||
| 4 | 50 | page_header | page_header | False | low | docling_page_header | docling_page_header | p4:body_region:0 | p4:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 84.37, 8.72] | ACS Energy Letters | ACS Energy Letters | ||
| 4 | 51 | page_header | page_header | False | low | docling_page_header | docling_page_header | p4:body_region:1 | p4:top_margin:column_2_of_2:colored | [159, 182, 177] colored | True | [537.79, 49.99, 19.7, 7.35] | Letter | Letter | ||
| 4 | 52 | page_header | page_header | False | low | docling_page_header | docling_page_header | p4:body_region:1 | p4:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [278.65, 50.28, 118.38, 6.98] | http://pubs.acs.org/journal/aelccp | |||
| 4 | 53 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p4:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 481.34, 503.96, 17.81] | Figure 3. Gas evolution and surface studies of Li2MnO3. (a) DEMS for the fi rst charge and (b) XPS/HAXPES data and (c) Mn L3-edge TEY data for the pristine and electrolyte-soaked material. | Figure 3. Gas evolution and surface studies of Li2MnO3. (a) DEMS for the fi rst charge and (b) XPS/HAXPES data and (c) Mn L3-edge TEY data for the pristine and electrolyte-soaked material. | |||
| 4 | 54 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p4:body_region:0 | p4:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 512.15, 240.0, 184.95] | increase in the intensity of the pre-edge region can now be correlated to major restructuring during activation. This restructuring also likely accounts for the observed broadening of the O K-edge spectral features in F… | increase in the intensity of the pre-edge region can now be correlated to major restructuring during activation. This restructuring also likely accounts for the observed broadening of the O K-edge spectral features in F… | ||
| 4 | 55 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p4:body_region:0 | p4:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 697.52, 240.0, 66.84] | Without oxidation of Mn 4+ and/or reversible participation of lattice oxygen in charge-compensation processes, a remaining possibility is the irreversible oxidation of lattice oxygen to oxygen gas. We employed DEMS to m… | Without oxidation of Mn 4+ and/or reversible participation of lattice oxygen in charge-compensation processes, a remaining possibility is the irreversible oxidation of lattice oxygen to oxygen gas. We employed DEMS to m… | ||
| 4 | 56 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p4:body_region:1 | p4:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 512.15, 240.05, 101.16] | quickly rose to a sharp peak in evolution rate. As the voltage plateau region was reached, oxygen gas became the dominant evolution product, though CO2 continued to evolve at a lower rate. Total gas evolved across the f… | quickly rose to a sharp peak in evolution rate. As the voltage plateau region was reached, oxygen gas became the dominant evolution product, though CO2 continued to evolve at a lower rate. Total gas evolved across the f… | ||
| 4 | 57 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p4:body_region:1 | p4:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 615.78, 240.05, 147.42] | The source of oxygen gas is the formation of oxidized lattice oxygen species followed by gas evolution, 15 as no O2 evolution results from electrolyte degradation or carbonate oxidation. 37 O2 evolution from the oxide l… | The source of oxygen gas is the formation of oxidized lattice oxygen species followed by gas evolution, 15 as no O2 evolution results from electrolyte degradation or carbonate oxidation. 37 O2 evolution from the oxide l… | ||
| 4 | 58 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p4:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [306.43, 774.02, 12.06, 6.54] | 637 | 637 | |||
| 4 | 59 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p4:body_region:1 | p4:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [439.88, 774.81, 124.6, 12.72] | https://dx.doi.org/10.1021/acsenergylett.9b02799 ACS Energy Lett. 2020, 5, 634 -641 | ACS Energy Lett. 2020, 5, 634 -641 | ||
| 5 | 60 | page_header | page_header | False | low | docling_page_header | docling_page_header | p5:body_region:0 | p5:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 84.37, 8.72] | ACS Energy Letters | ACS Energy Letters | ||
| 5 | 61 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:0 | p5:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 68.75, 239.99, 20.65] | fi rst charge capacity. As this is not the case, we examined other capacity contributions. | fi rst charge capacity. As this is not the case, we examined other capacity contributions. | ||
| 5 | 62 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:0 | p5:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 91.71, 240.01, 435.42] | We note that the CO2 evolution is remarkably high for a transition metal oxide material. The large quantity of CO2 evolved (Figure 3c) could originate from a variety of mechanisms, including electrolyte reaction with ge… | We note that the CO2 evolution is remarkably high for a transition metal oxide material. The large quantity of CO2 evolved (Figure 3c) could originate from a variety of mechanisms, including electrolyte reaction with ge… | ||
| 5 | 63 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:0 | p5:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 529.44, 240.0, 98.77] | The fi rst charge capacity for Li2MnO3 as observed during the DEMS measurement can now be analyzed in terms of the contributions from the processes examined in this study (Table 1). O2 evolution originating from oxygen … | The fi rst charge capacity for Li2MnO3 as observed during the DEMS measurement can now be analyzed in terms of the contributions from the processes examined in this study (Table 1). O2 evolution originating from oxygen … | ||
| 5 | 64 | section_header | caption | False | low | visual_caption_heading | visual_caption_heading | p5:body_region:0 | p5:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 638.64, 189.99, 12.35] | Table 1. First Charge Capacity Contributions a | Table 1. First Charge Capacity Contributions a | ||
| 5 | 65 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:0 | p5:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 732.89, 239.98, 30.06] | a Capacity contributions as determined using gas evolution and titration techniques compared to the total fi rst charge capacity of the cell run on the DEMS system. | a Capacity contributions as determined using gas evolution and titration techniques compared to the total fi rst charge capacity of the cell run on the DEMS system. | ||
| 5 | 66 | page_header | page_header | False | low | docling_page_header | docling_page_header | p5:body_region:1 | p5:top_margin:column_2_of_2:colored | [159, 182, 177] colored | True | [537.79, 49.99, 19.7, 7.35] | Letter | Letter | ||
| 5 | 67 | page_header | page_header | False | low | docling_page_header | docling_page_header | p5:body_region:1 | p5:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [278.65, 50.28, 118.38, 6.98] | http://pubs.acs.org/journal/aelccp | |||
| 5 | 68 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:1 | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 65.25, 240.04, 156.7] | (O 2 -/O -) revealed about 6% contribution to the total charge capacity. We suspect the remaining 14% of the fi rst charge capacity (Table 1) results from a combination of processes including electrolyte decomposition g… | (O 2 -/O -) revealed about 6% contribution to the total charge capacity. We suspect the remaining 14% of the fi rst charge capacity (Table 1) results from a combination of processes including electrolyte decomposition g… | ||
| 5 | 69 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:1 | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 224.2, 240.05, 318.46] | In summary, using the combination of operando Mn K-edge XAS, O K-edge RIXS, XPS/HAXPES, and DEMS, we interpret and quantify the capacity contributions observed during electrochemical activation of Li2MnO3. Taken togethe… | In summary, using the combination of operando Mn K-edge XAS, O K-edge RIXS, XPS/HAXPES, and DEMS, we interpret and quantify the capacity contributions observed during electrochemical activation of Li2MnO3. Taken togethe… | ||
| 5 | 70 | section_header | body_heading | False | low | non_body_heading | non_body_heading | p5:body_region:1 | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 547.02, 122.94, 23.97] | ■ ASSOCIATED CONTENT | ■ ASSOCIATED CONTENT | ||
| 5 | 71 | section_header | body_heading | False | low | non_body_heading | non_body_heading | p5:body_region:1 | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 572.86, 114.41, 12.62] | * s ı Supporting Information | * s ı Supporting Information | ||
| 5 | 72 | text | body_candidate_excluded | False | medium | before_body_started | before_body_started | p5:body_region:1 | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 587.6, 240.01, 19.86] | The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsenergylett.9b02799. | The Supporting Information is available free of charge at | ||
| 5 | 73 | text | body | True | body_before_non_intro_heading | body_before_non_intro_heading | p5:body_region:1 | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [348.49, 616.69, 216.0, 52.8] | Material synthesis and electrochemical details. Additional data includes XANES spectra of reference Mn 7+ (KMnO4) with Materials Project simulations, operando Mn K-edge XANES of Li2MnO3 pouch cells, and oxygen and carbo… | Material synthesis and electrochemical details. Additional data includes XANES spectra of reference Mn 7+ (KMnO4) with Materials Project simulations, operando Mn K-edge XANES of Li2MnO3 pouch cells, and oxygen and carbo… | |||
| 5 | 74 | section_header | body_heading | False | low | body_heading | body_heading | p5:body_region:1 | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 680.82, 126.36, 23.97] | ■ AUTHOR INFORMATION | ■ AUTHOR INFORMATION | ||
| 5 | 75 | section_header | body_heading | False | low | body_heading | body_heading | p5:body_region:1 | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 708.78, 93.87, 8.29] | Corresponding Author | Corresponding Author | ||
| 5 | 76 | text | page_margin_footer | False | low | page_margin_footer | page_margin_footer | p5:body_region:1 | p5:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 717.92, 240.03, 45.54] | Louis F. J. Piper -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States; orcid.org/0000-0002-3421-3210; Email: lpiper@ binghamton.edu | Louis F. J. Piper -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States; orcid.org/0000-0002-3421-3210; Email: lpiper@ binghamton.edu | ||
| 5 | 77 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p5:bottom_margin:column_2_of_2:white | [250, 250, 250] white | False | [306.43, 774.02, 12.06, 6.54] | 638 | 638 | |||
| 5 | 78 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p5:body_region:1 | p5:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [439.88, 774.81, 124.6, 12.72] | https://dx.doi.org/10.1021/acsenergylett.9b02799 ACS Energy Lett. 2020, 5, 634 -641 | ACS Energy Lett. 2020, 5, 634 -641 | ||
| 6 | 79 | page_header | page_header | False | low | docling_page_header | docling_page_header | p6:body_region:0 | p6:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 84.37, 8.72] | ACS Energy Letters | ACS Energy Letters | ||
| 6 | 80 | section_header | body_heading | False | low | body_heading | body_heading | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 68.77, 32.92, 8.29] | Authors | Authors | ||
| 6 | 81 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 77.29, 239.97, 34.49] | Jatinkumar Rana -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States; orcid.org/0000-0002-3552-2453 | Jatinkumar Rana -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States; orcid.org/0000-0002-3552-2453 | |||
| 6 | 82 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 110.29, 239.99, 56.48] | Joseph K. Papp -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, Un… | Joseph K. Papp -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, Un… | |||
| 6 | 83 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 165.28, 238.2, 34.24] | Zachary Lebens-Higgins -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States | Zachary Lebens-Higgins -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States | |||
| 6 | 84 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 198.27, 239.96, 23.3] | Mateusz Zuba -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States | Mateusz Zuba -Department of Physics, Applied Physics, and Astronomy, Binghamton University, New York 13902, United States | |||
| 6 | 85 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 220.33, 240.01, 45.24] | Lori A. Kaufman -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, U… | Lori A. Kaufman -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, U… | |||
| 6 | 86 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 264.32, 239.97, 34.24] | Anshika Goel -NorthEast Center for Chemical Energy Storage (NECCES), Binghamton University, Binghamton, New York 13902, United States | Anshika Goel -NorthEast Center for Chemical Energy Storage (NECCES), Binghamton University, Binghamton, New York 13902, United States | |||
| 6 | 87 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 297.31, 239.97, 34.24] | Richard Schmuch -MEET Battery Research Center, Institute of Physical Chemistry, University of Muenster, 48149 Muenster, Germany | Richard Schmuch -MEET Battery Research Center, Institute of Physical Chemistry, University of Muenster, 48149 Muenster, Germany | |||
| 6 | 88 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 330.31, 239.98, 45.24] | Martin Winter -Helmholtz-Institute Muenster, IEK-12, Forschungszentrum Juelich GmbH, 48149 Muenster, Germany M. Stanley Whittingham -NorthEast Center for Chemical Energy Storage (NECCES), Binghamton University, Binghamt… | Martin Winter -Helmholtz-Institute Muenster, IEK-12, Forschungszentrum Juelich GmbH, 48149 Muenster, Germany M. Stanley Whittingham -NorthEast Center for Chemical Energy Storage (NECCES), Binghamton University, Binghamt… | |||
| 6 | 89 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 377.79, 114.33, 8.76] | New York 13902, United States | New York 13902, United States | |||
| 6 | 90 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 385.3, 236.8, 34.49] | Wanli Yang -The Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States; orcid.org/0000-0003-0666-8063 | Wanli Yang -The Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States; orcid.org/0000-0003-0666-8063 | |||
| 6 | 91 | text | body | True | body | body | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 418.3, 228.4, 56.48] | Bryan D. McCloskey -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720… | Bryan D. McCloskey -Department of Chemical and Biomolecular Engineering, University of California, and Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720… | |||
| 6 | 92 | text | metadata | False | low | document_ui | document_ui | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 480.74, 175.35, 8.8] | Complete contact information is available at: | Complete contact information is available at: | ||
| 6 | 93 | text | metadata | False | low | metadata_line | metadata_line | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 491.74, 201.73, 8.8] | https://pubs.acs.org/10.1021/acsenergylett.9b02799 | |||
| 6 | 94 | section_header | back_matter_heading | False | low | back_matter_heading | back_matter_heading | stop_trigger | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 513.7, 89.1, 8.29] | Author Contributions | Author Contributions | |
| 6 | 95 | text | unknown_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 521.06, 157.05, 13.38] | ¶ J.R. and J.K.P. had equal contributions. | ¶ J.R. and J.K.P. had equal contributions. | |
| 6 | 96 | section_header | unknown_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 539.55, 23.98, 8.29] | Notes | Notes | |
| 6 | 97 | text | unknown_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 551.49, 203.31, 8.8] | The authors declare no competing fi nancial interest. | The authors declare no competing fi nancial interest. | |
| 6 | 98 | section_header | back_matter_heading | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 562.67, 115.98, 23.97] | ■ ACKNOWLEDGMENTS | ■ ACKNOWLEDGMENTS | |
| 6 | 99 | text | back_matter_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 589.36, 240.03, 173.83] | This work was supported as part of the NorthEast Center for Chemical Energy Storage (NECCES), an Energy Frontier Research Center funded by the U.S. Department of Energy, Offi ce of Science, Offi ce of Basic Energy Scien… | This work was supported as part of the NorthEast Center for Chemical Energy Storage (NECCES), an Energy Frontier Research Center funded by the U.S. Department of Energy, Offi ce of Science, Offi ce of Basic Energy Scien… | |
| 6 | 100 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:top_margin:column_2_of_2:colored | [159, 182, 177] colored | True | [537.79, 49.99, 19.7, 7.35] | Letter | Letter | ||
| 6 | 101 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [278.65, 50.28, 118.38, 6.98] | http://pubs.acs.org/journal/aelccp | |||
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