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| 1 | figure | Fig. 1 | 1 | direct_caption_ref | 5227df2e-2213-5d9a-8d87-4b10066f4975 | 0.82 | [419.07, 246.14, 135.59, 138.63] | Figure 1. Voltage and capacity of the main cathode materials for lithium-ion batteries. | |||
| 2 | figure | Fig. 1 | 1 | nearby_text_caption | 5227df2e-2213-5d9a-8d87-4b10066f4975 | 0.82 | [323.58, 408.98, 240.99, 176.35] | Figure 1. Voltage and capacity of the main cathode materials for lithium-ion batteries. | |||
| 3 | figure | Fig. 2 | 2 | sequence_or_inferred_caption | 0.82 | [60.24, 304.41, 504.86, 383.48] | Figure 2. Crystal structure of the (a) rhombohedral LiMO2 structure (space group: R 3 ̅ m , M = Ni, Co, Mn, Fe, Cr, etc.) and (b) monoclinic Li2MnO3 structure (space group: C 2/ m ) viewed from the [100] crystallographic direction. (c) Synchrotron powder X-ray di ff raction pattern and Rietveld re fi nement pro fi le of the 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42Co0.16O2 material with rhombohedral and monoclinic structures. Reprinted with permission from ref 13. Copyright 2012 Royal Society of Chemistry. (d) Bragg fi ltered high-angle annular dark fi eld scanning transmission electron microscopy (STEM-HAADF) image of the Li1.2Mn0.61Ni0.18Mg0.01O2 material, containing Li 2 MnO3 parts (blue) and LiNi0.45 Mn0.525Mg0.025O2 ones (green). Reprinted with permission from ref 33. Copyright 2012 American Chemical Society. These LLOs were fi rst researched as cathode materials for rechargeable lithium batteries by Thackeray et al. when they were researching the LiMnO2 layered materials. 16,17 In 1991, inspired by Hunter ' s discovery that acid treatment of the spinel LiMn2O4 yielded λ -MnO2 with a Mn2O4 spinel framework, Thackeray et al. synthesized the layered lithium -manganese oxide compound Li2 -x MnO3 -x /2 (0 < x < 2) with a cubic-closepacked oxygen anion array by chemical leaching of Li2O from the rock salt phase Li2MnO3 (Li2O · MnO2) with acid at 25 ° C, a n d g o t t h e c o m p o u n d L i 1 . 0 9 Mn0.91 O 2 o r 0.2Li2MnO3 · 0.8LiMnO2 after relithiation in an electrochemical cell. 16,17 The structure stability of this compound is much better than that of the pure layered LiMnO 2 cathode material during electrochemical cycling, and then the x Li2MnO3 · (1 -x )LiMnO2 material concept is fi rst introduced. When Kalyani et al. fi rst found that the monoclinic Li2MnO3 material could be activated electrochemically by charging the Li/Li2MnO3 cell to 4.5 V, the x Li2MnO3 · (1 -x )LiMO2 (M = Mn, Ni, Co, Fe, Cr, etc.) materials became more and more attractive. 18 This notation can not only describe the electrochemical processes of these LLOs combining with the single LiMO2 (M = Mn, Ni, Co, Fe, Cr, etc.) and Li2MnO3 component electrochemical process, but also indicates that the cathode materials for lithium | ||||
| 4 | figure | Fig. 3 | 3 | direct_caption_ref | 0.82 | [81.47, 67.2, 458.89, 380.39] | Figure 3. (a) XRD patterns and (b) hexagonal lattice parameters of the x Li2MnO3 · (1 -x )LiNi1/2Mn1/2O2 ( x = 0, 1/3, 1/2, and 1) materials. Reprinted with permission from ref 40. Copyright 2012 Royal Society of Chemistry. (c) Homogeneous solid solution structure with partial ordered C 2/ m monoclinic phase viewed from the [100] crystallographic direction. (d) Aberration-corrected scanning transmission electron microscopy (STEM) image of the Li[Li0.2Ni0.2Mn0.6]O2 crystal. Reprinted with permission from ref 37. Copyright 2011 American Chemical Society. | ||||
| 5 | figure | Fig. 4 | 4 | direct_caption_ref | 0.82 | [136.66, 66.61, 350.28, 133.02] | Figure 4. The expected morphology evolution of the TM plane in x Li2MnO3 · (1 -x )LiCoO2, showing the coexistence of Co and LiMn2 domains: (a) x = 0.15; (b) x = 0.45; (c) x = 0.75; and (d) x = 0.90. The rhombohedral ( R ) and monoclinic ( M ) unit cells are indicated in the fi gure. Reprinted with permission from ref 29. Copyright 2011 American Chemical Society. | ||||
| 6 | figure | Fig. 5 | 5 | direct_caption_ref | 0.82 | [143.56, 66.6, 338.35, 430.02] | Figure 5. (a) Reaction pathways diagram through controlling the activation of the Li2MnO3 phase inside the 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42Co0.16O2 material based on the three-dimensional compositional phase diagram. (b) The charge and (c) discharge curves with three di ff erent current densities. (a -c) Reprinted with permission from ref 13. Copyright 2012 Royal Society of Chemistry. | ||||
| 7 | figure | Fig. 6 | 6 | direct_caption_ref | 0.82 | [64.88, 185.08, 230.18, 451.95] | Figure 6. (a) Mass spectrometry analysis of O2 evolved on the 1st charging process of the Li/Li[Ni 0.2 Li 0.2Mn0.6]O2 cell. Reprinted with permission from ref 52. Copyright 2006 American Chemical Society. (b) First-principle calculation sketch of partial oxygen layer in Li x /14Ni1/4Mn7/12O2 (pink balls: oxygen ions; colored polyhedrons: adjacent TM slab) and its calculated spin density at (c) x = 14, (d) x = 8, and (e) x = 0. Reprinted with permission from ref 34. Copyright 2011 Royal Society of Chemistry. (f) Schemes of the proposed surface reaction mechanisms in the Li 1.2 Ni0.13Co0.13Mn0.54O2 material. Reprinted with permission from ref 50. Copyright 2011 American Chemical Society. | ||||
| 8 | figure | Fig. 7 | 7 | direct_caption_ref | 0.82 | [75.04, 67.49, 472.75, 180.4] | Figure 7. Charge and discharge curves of the Li/Li[Li 1/5Ni1/5Mn3/5]O2 cell at (a) 55 ° C and (b) 85 ° C. Reprinted with permission from ref 40. Copyright 2011 Royal Society of Chemistry. | ||||
| 9 | figure | Fig. 8 | 8 | direct_caption_ref | 0.82 | [57.98, 66.58, 243.46, 193.55] | Figure 8. The initial Coulombic e ffi ciency and the charge/discharge capacity of the Li 1.2 Mn0.567 -x Ru x Ni0.166 Co0.067O2 ( x = 0.00, 0.03, 0.05, and 0.07) materials. Adapted from ref 14. Copyright 2012 Royal Society of Chemistry. | ||||
| 10 | figure | Fig. 9 | 8 | direct_caption_ref | 0.82 | [58.49, 443.96, 506.09, 244.43] | Figure 9. Charge/discharge and d Q /d V pro fi les at di ff erent cycling stages ((a,b), Stage I: from the 2nd cycle to the 25th cycle; (c,d), Stage II: from the 26th cycle to the 151st cycle) of the Li/0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42 Co0.16 O2 cell. Raman pro fi les of the 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42Co0.16O2 materials with di ff erent testing conditions: (e) pristine material; (f,g,h) electrode materials after 51 electrochemical cycles with 50 mA/g, 20 mA/g and 5 mA/g initial charge/discharge current density and 2.0 -4.8 V cuto ff voltage: (i) electrode material after 151 electrochemical cycles with 20 mA/g initial charge/discharge current density and 2.0 -4.6 V cuto ff voltage. (a -i) Reprinted with permission from ref 13. Copyright 2012 Royal Society of Chemistry. | ||||
| 11 | figure | Fig. 10 | 9 | direct_caption_ref | 0.82 | [58.86, 68.13, 505.66, 267.38] | Figure 10. Galvanostatic intermittent titration technique (GITT) in the fi rst, second, and third (a) charge and (b) discharge processes, Li + di ff usion coe ffi cients during the fi rst three (c) charge and (d) discharge processes, and interface activation energy of di ff erent states during the fi rst charge (e), discharge (f), and the second charge (g) processes of the 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42 Co0.16 O2 electrode material. The inset fi gures in panels e, f, and g are the d Q /d V curves during the fi rst charging, discharging, and second charging processes, respectively. (a) Reprinted with permission from ref 15. Copyright 2012 Royal Society of Chemistry. | ||||
| 12 | figure | Fig. 11 | 9 | direct_caption_ref | 0.82 | [160.68, 404.69, 304.99, 266.99] | Figure 11. (a) TEM image and (b) rate capabilities of Li[Ni 0.25 Li 0.15Mn0.6]O2 nanowires. Reprinted with permission from ref 77. Copyright 2009 Royal Society of Chemistry. (c) SEM image and (d) discharge curves with di ff erent rates (6, 3, 1, 0.5, and 0.1C) of the Li[Li 1/3 -2 x /3Ni x Mn2/3 -x /3]O2 habit-tuned nanoplate material. Reprinted with permission from ref 78. Copyright 2010 Wiley-VCH. | ||||
| 13 | figure | Fig. 12 | 10 | direct_caption_ref | 0.82 | [158.88, 67.65, 307.16, 305.28] | Figure 12. Current debates on structure and reaction mechanism, problems on electrochemical properties, and keys to the study in the future of Li 2 MnO3-based lithium-rich layered cathode materials. |
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| 1 | 7 | text | abstract_candidate | False | medium | inline_abstract | inline_abstract | p1:body_region:0 | p1:page_body:column_1_of_2:colored | [255, 242, 208] colored | False | [69.45, 247.25, 341.67, 111.16] | ABSTRACT: Lithium-rich layered oxide materials x Li2MnO3 · (1 -x )LiMO2 (M = Mn, Ni, Co, Fe, Cr, etc.) have attracted much attention for the use of cathode materials in lithiumion batteries in recent years. However, the… | ABSTRACT: Lithium-rich layered oxide materials x Li2MnO3 · (1 -x )LiMO2 (M = Mn, Ni, Co, Fe, Cr, etc.) have attracted much attention for the use of cathode materials in lithiumion batteries in recent years. However, the… | ||
| 1 | 8 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p1:body_region:0 | p1:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 409.33, 240.06, 123.08] | A s the problems of fossil energy exhaustion, global warming, and environment pollution plague modern society, sustainable energies have gradually become a worldwide topic. There have also been increasing demands for wi… | A s the problems of fossil energy exhaustion, global warming, and environment pollution plague modern society, sustainable energies have gradually become a worldwide topic. There have also been increasing demands for wi… | ||
| 1 | 9 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p1:body_region:0 | p1:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 534.71, 239.99, 132.68] | Owing to the key roles of cathode materials on energy density and the cost of current lithium-ion batteries, several alternative cathode materials, such as LiCoO2, LiNi0.8 Co0.15 Al0.05O2, LiNi0.33 Co0.33Mn0.33O2, spine… | Owing to the key roles of cathode materials on energy density and the cost of current lithium-ion batteries, several alternative cathode materials, such as LiCoO2, LiNi0.8 Co0.15 Al0.05O2, LiNi0.33 Co0.33Mn0.33O2, spine… | ||
| 1 | 10 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p1:body_region:0 | p1:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 669.75, 239.98, 89.31] | Among the reported cathode materials so far, the lithium-rich layered oxide materials (LLOs) have attracted much attention in recent years because their capacities can be larger than 280 mAhg -1 with 3.6 V or larger ope… | Among the reported cathode materials so far, the lithium-rich layered oxide materials (LLOs) have attracted much attention in recent years because their capacities can be larger than 280 mAhg -1 with 3.6 V or larger ope… | ||
| 1 | 11 | page_footer | page_footer | False | low | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [168.49, 771.47, 95.03, 5.58] | © 2013 American Chemical Society | © 2013 American Chemical Society | ||
| 1 | 12 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 595.55, 239.98, 17.9] | Figure 1. Voltage and capacity of the main cathode materials for lithium-ion batteries. | Figure 1. Voltage and capacity of the main cathode materials for lithium-ion batteries. | |||
| 1 | 13 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 635.06, 240.04, 74.79] | notations are equal to the same material and have been used extensively in the published literature. For example, the 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42Co0.16O2 material can also be described as Li[Li 0.2 Mn0.567 Ni0.166 C… | notations are equal to the same material and have been used extensively in the published literature. For example, the 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42Co0.16O2 material can also be described as Li[Li 0.2 Mn0.567 Ni0.166 C… | |||
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| 2 | 23 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p2:body_region:0 | p2:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 69.37, 239.98, 52.8] | local structures are discussed. The second section discusses the reaction mechanisms, especially the fi rst charge and discharge processes. The third section describes the electrochemical performance, current main probl… | local structures are discussed. The second section discusses the reaction mechanisms, especially the fi rst charge and discharge processes. The third section describes the electrochemical performance, current main probl… | ||
| 2 | 24 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p2:body_region:0 | p2:page_body:column_1_of_2:colored | [255, 242, 208] colored | False | [88.5, 135.92, 183.96, 109.37] | The rechargeable capacity and energy density of LLO materials at room temperature can be close to 280 mAhg -1 and 1000 Whkg -1 , respectively, which are about twice that of current commercial cathode materials for lithi… | The rechargeable capacity and energy density of LLO materials at room temperature can be close to 280 mAhg -1 and 1000 Whkg -1 , respectively, which are about twice that of current commercial cathode materials for lithi… | ||
| 2 | 25 | caption | caption | False | low | docling_caption | docling_caption | p2:body_region:0 | p2:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 262.87, 239.98, 32.52] | These LLOs were fi rst researched as cathode materials for rechargeable lithium batteries by Thackeray et al. when they were researching the LiMnO2 layered materials. 16,17 In 1991, | These LLOs were fi rst researched as cathode materials for rechargeable lithium batteries by Thackeray et al. when they were researching the LiMnO2 layered materials. 16,17 In 1991, | ||
| 2 | 26 | page_header | page_header | False | low | docling_page_header | docling_page_header | p2:body_region:1 | p2:top_margin:column_2_of_2:colored | [125, 168, 209] colored | True | [519.14, 50.28, 38.3, 6.98] | Perspective | Perspective | ||
| 2 | 27 | text | caption_continuation | False | low | caption_continuation_used_by_asset | inside_front_matter | caption_continuation_used_by_asset Fig. 2 | p2:body_region:1 | p2:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 67.46, 240.03, 226.77] | inspired by Hunter ' s discovery that acid treatment of the spinel LiMn2O4 yielded λ -MnO2 with a Mn2O4 spinel framework, Thackeray et al. synthesized the layered lithium -manganese oxide compound Li2 -x MnO3 -x /2 (0 <… | inspired by Hunter ' s discovery that acid treatment of the spinel LiMn2O4 yielded λ -MnO2 with a Mn2O4 spinel framework, Thackeray et al. synthesized the layered lithium -manganese oxide compound Li2 -x MnO3 -x /2 (0 <… | |
| 2 | 28 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p2:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 702.98, 503.98, 59.97] | Figure 2. Crystal structure of the (a) rhombohedral LiMO2 structure (space group: R 3 ̅ m , M = Ni, Co, Mn, Fe, Cr, etc.) and (b) monoclinic Li2MnO3 structure (space group: C 2/ m ) viewed from the [100] crystallographi… | Figure 2. Crystal structure of the (a) rhombohedral LiMO2 structure (space group: R 3 ̅ m , M = Ni, Co, Mn, Fe, Cr, etc.) and (b) monoclinic Li2MnO3 structure (space group: C 2/ m ) viewed from the [100] crystallographi… | |||
| 2 | 29 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p2:body_region:1 | p2:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [387.33, 773.27, 177.16, 7.74] | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | ||
| 2 | 30 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p2:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [304.5, 774.02, 15.93, 6.54] | 1269 | 1269 | |||
| 3 | 31 | page_header | page_header | False | low | docling_page_header | docling_page_header | p3:body_region:0 | p3:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 181.19, 8.72] | The Journal of Physical Chemistry Letters | The Journal of Physical Chemistry Letters | ||
| 3 | 32 | page_header | page_header | False | low | docling_page_header | docling_page_header | p3:body_region:1 | p3:top_margin:column_2_of_2:colored | [125, 168, 209] colored | True | [519.14, 50.28, 38.3, 6.98] | Perspective | Perspective | ||
| 3 | 33 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p3:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 455.66, 503.95, 42.02] | Figure 3. (a) XRD patterns and (b) hexagonal lattice parameters of the x Li2MnO3 · (1 -x )LiNi1/2Mn1/2O2 ( x = 0, 1/3, 1/2, and 1) materials. Reprinted with permission from ref 40. Copyright 2012 Royal Society of Chemis… | Figure 3. (a) XRD patterns and (b) hexagonal lattice parameters of the x Li2MnO3 · (1 -x )LiNi1/2Mn1/2O2 ( x = 0, 1/3, 1/2, and 1) materials. Reprinted with permission from ref 40. | |||
| 3 | 34 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p3:body_region:0 | p3:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 509.59, 240.0, 120.09] | ion batteries can be designed with di ff erent contents of LiMO 2 (M = Mn, Ni, Co, Fe, Cr, etc.) and Li2MnO3 components, realizing the variational electrochemical performances (rechargeable capacity, rate performance, a… | ion batteries can be designed with di ff erent contents of LiMO 2 (M = Mn, Ni, Co, Fe, Cr, etc.) and Li2MnO3 components, realizing the variational electrochemical performances (rechargeable capacity, rate performance, a… | ||
| 3 | 35 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p3:body_region:0 | p3:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 632.0, 240.0, 108.98] | Owing to the importance of the relationship between the structure and electrochemical performance of electrode materials for lithium-ion batteries, it is necessary to reveal the actual structure of these LLOs to deeply … | Owing to the importance of the relationship between the structure and electrochemical performance of electrode materials for lithium-ion batteries, it is necessary to reveal the actual structure of these LLOs to deeply … | ||
| 3 | 36 | text | unknown_text | False | high | inside_front_matter | inside_front_matter | p3:body_region:0 | p3:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 743.23, 239.97, 21.8] | Figure 2a,b shows the rhombohedral LiMO2 structure (space group: R 3 ̅ m , M = Co, Ni, Mn, Fe, Cr, etc.) and monoclinic | Figure 2a,b shows the rhombohedral LiMO2 structure (space group: R 3 ̅ m , M = Co, Ni, Mn, Fe, Cr, etc.) and monoclinic | ||
| 3 | 37 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p3:body_region:1 | p3:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 509.59, 240.03, 255.43] | Li2MnO3 structure (space group: C 2/ m ) viewed from their [100] crystallographic direction, respectively. As the Li2MnO3 structure can be reformulated with Li[Li 1/3Mn2/3]O2, the monoclinic Li2MnO3 structure is very si… | Li2MnO3 structure (space group: C 2/ m ) viewed from their [100] crystallographic direction, respectively. As the Li2MnO3 structure can be reformulated with Li[Li 1/3Mn2/3]O2, the monoclinic Li2MnO3 structure is very si… | ||
| 3 | 38 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p3:body_region:1 | p3:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [387.33, 773.27, 177.16, 7.74] | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | ||
| 3 | 39 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p3:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [304.5, 774.02, 15.93, 6.54] | 1270 | 1270 | |||
| 4 | 40 | page_header | page_header | False | low | docling_page_header | docling_page_header | p4:body_region:0 | p4:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 181.19, 8.72] | The Journal of Physical Chemistry Letters | The Journal of Physical Chemistry Letters | ||
| 4 | 41 | page_header | page_header | False | low | docling_page_header | docling_page_header | p4:body_region:1 | p4:top_margin:column_2_of_2:colored | [125, 168, 209] colored | True | [519.14, 50.28, 38.3, 6.98] | Perspective | Perspective | ||
| 4 | 42 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p4:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 206.55, 503.96, 30.97] | Figure 4. The expected morphology evolution of the TM plane in x Li2MnO3 · (1 -x )LiCoO2, showing the coexistence of Co and LiMn2 domains: (a) x = 0.15; (b) x = 0.45; (c) x = 0.75; and (d) x = 0.90. The rhombohedral ( R… | Figure 4. The expected morphology evolution of the TM plane in x Li2MnO3 · (1 -x )LiCoO2, showing the coexistence of Co and LiMn2 domains: (a) x = 0.15; (b) x = 0.45; (c) x = 0.75; and (d) x = 0.90. The rhombohedral ( R… | |||
| 4 | 43 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p4:body_region:0 | p4:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 250.45, 240.03, 54.81] | monoclinic Li2MnO3 (space group C 2/ m ) structures are chosen. The phase fractions of the rhombohedral and monoclinic components are 43% and 57%, respectively, and very close t o t h e composition of t h e studied 0.5L… | monoclinic Li2MnO3 (space group C 2/ m ) structures are chosen. The phase fractions of the rhombohedral and monoclinic components are 43% and 57%, respectively, and very close t o t h e composition of t h e studied 0.5L… | ||
| 4 | 44 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p4:body_region:0 | p4:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 306.35, 239.99, 278.86] | By the high-resolution transmission electron microscopy (HRTEM) technique combined with electron energy-loss spectroscopy (EELS) technique, Wen, Abraham, Tabuchi et al. fi nd that the locally monoclinic (Li 2 MnO3-like)… | By the high-resolution transmission electron microscopy (HRTEM) technique combined with electron energy-loss spectroscopy (EELS) technique, Wen, Abraham, Tabuchi et al. fi nd that the locally monoclinic (Li 2 MnO3-like)… | ||
| 4 | 45 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p4:body_region:0 | p4:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 586.36, 240.0, 176.84] | Although there is much two-phase evidence of these LLOs by average and local structure studies, on the other hand, some researchers think that these LLOs are homogeneous solid solutions between the two components Li2MnO… | Although there is much two-phase evidence of these LLOs by average and local structure studies, on the other hand, some researchers think that these LLOs are homogeneous solid solutions between the two components Li2MnO… | ||
| 4 | 46 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p4:body_region:1 | p4:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 250.45, 240.03, 109.6] | worth noting that the X-ray di ff raction techniques (XRD or SXRD) can only provide key information on the average crystal structure. As a matter of fact, the large di ff erence between the atomic number, size, and tend… | worth noting that the X-ray di ff raction techniques (XRD or SXRD) can only provide key information on the average crystal structure. As a matter of fact, the large di ff erence between the atomic number, size, and tend… | ||
| 4 | 47 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p4:body_region:1 | p4:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 362.36, 240.03, 400.84] | Thus, the local structure studies on these LLOs are very important to investigate their actual structure. Jarvis et al. carefully investigated the Li[Li 0.2 Ni0.2Mn0.6]O2 material with a di ff raction scanning transmiss… | Thus, the local structure studies on these LLOs are very important to investigate their actual structure. Jarvis et al. carefully investigated the Li[Li 0.2 Ni0.2Mn0.6]O2 material with a di ff raction scanning transmiss… | ||
| 4 | 48 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p4:body_region:1 | p4:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [387.33, 773.27, 177.16, 7.74] | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | ||
| 4 | 49 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p4:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [304.5, 774.02, 15.93, 6.54] | 1271 | 1271 | |||
| 5 | 50 | page_header | page_header | False | low | docling_page_header | docling_page_header | p5:body_region:0 | p5:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 181.19, 8.72] | The Journal of Physical Chemistry Letters | The Journal of Physical Chemistry Letters | ||
| 5 | 51 | page_header | page_header | False | low | docling_page_header | docling_page_header | p5:body_region:1 | p5:top_margin:column_2_of_2:colored | [125, 168, 209] colored | True | [519.14, 50.28, 38.3, 6.98] | Perspective | Perspective | ||
| 5 | 52 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p5:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 503.26, 503.99, 31.53] | Figure 5. (a) Reaction pathways diagram through controlling the activation of the Li2MnO3 phase inside the 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42Co0.16O2 material based on the three-dimensional compositional phase diagram. (b)… | Figure 5. (a) Reaction pathways diagram through controlling the activation of the Li2MnO3 phase inside the 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42Co0.16O2 material based on the three-dimensional compositional phase diagram. (b)… | |||
| 5 | 53 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:0 | p5:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 547.13, 240.0, 54.95] | domains with Li2MnO3-like components most probably exist inside these LLOs, increased with the lithium and manganese content (in proportion to x in the x Li2MnO3 · (1 -x )LiCoO2 equation) increasing, which is described … | domains with Li2MnO3-like components most probably exist inside these LLOs, increased with the lithium and manganese content (in proportion to x in the x Li2MnO3 · (1 -x )LiCoO2 equation) increasing, which is described … | ||
| 5 | 54 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:0 | p5:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 604.56, 239.98, 66.52] | The reaction mechanisms of these LLOs are very complicated, and have been extensively researched and discussed in the past decade. 6,11,12,25,35,40,42,48 -55 However, these reaction mechanisms proposed are still being d… | The reaction mechanisms of these LLOs are very complicated, and have been extensively researched and discussed in the past decade. 6,11,12,25,35,40,42,48 -55 However, these reaction mechanisms proposed are still being d… | ||
| 5 | 55 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:0 | p5:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 673.55, 239.99, 89.65] | In order to understand the complex electrochemical or chemical reaction processes during the fi rst and following cycles of these LLOs, one of the reaction mechanisms associated with an integrated three-dimensional comp… | In order to understand the complex electrochemical or chemical reaction processes during the fi rst and following cycles of these LLOs, one of the reaction mechanisms associated with an integrated three-dimensional comp… | ||
| 5 | 56 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:1 | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 547.12, 239.94, 20.31] | these LLOs during lithium extraction and insertion processes can be well explained. | these LLOs during lithium extraction and insertion processes can be well explained. | ||
| 5 | 57 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:1 | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 566.65, 240.04, 162.2] | For the 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42Co0.16O2 electrode material, the reaction pathways and phase composition changes during the fi rst charge region below 4.4 V with di ff erent current densities vary along the green… | For the 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42Co0.16O2 electrode material, the reaction pathways and phase composition changes during the fi rst charge region below 4.4 V with di ff erent current densities vary along the green… | ||
| 5 | 58 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p5:body_region:1 | p5:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 731.26, 240.03, 31.93] | When the electrochemical potential of the Li/ 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42Co0.16O2 cell increases from 4.4 to 4.8 V during the fi rst charge process, presented with the blue | When the electrochemical potential of the Li/ 0.5Li2MnO3 · 0.5LiMn0.42 Ni0.42Co0.16O2 cell increases from 4.4 to 4.8 V during the fi rst charge process, presented with the blue | ||
| 5 | 59 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p5:body_region:1 | p5:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [387.33, 773.27, 177.16, 7.74] | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | ||
| 5 | 60 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p5:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [304.5, 774.02, 15.93, 6.54] | 1272 | 1272 | |||
| 6 | 61 | page_header | page_header | False | low | docling_page_header | docling_page_header | p6:body_region:0 | p6:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 181.19, 8.72] | The Journal of Physical Chemistry Letters | The Journal of Physical Chemistry Letters | ||
| 6 | 62 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p6:body_region:0 | p6:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 69.37, 239.98, 106.2] | long voltage plateaus in Figure 5 b, more lithium ions can be extracted from the Li2MnO3 component together with the loss of oxygen and structure rearrangement, and there is probably a new phase (MnO2) formed. The oxyge… | long voltage plateaus in Figure 5 b, more lithium ions can be extracted from the Li2MnO3 component together with the loss of oxygen and structure rearrangement, and there is probably a new phase (MnO2) formed. The oxyge… | ||
| 6 | 63 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p6:body_region:0 | p6:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 655.02, 239.98, 107.93] | Figure 6. (a) Mass spectrometry analysis of O2 evolved on the 1st charging process of the Li/Li[Ni 0.2 Li 0.2Mn0.6]O2 cell. Reprinted with permission from ref 52. Copyright 2006 American Chemical Society. (b) First-prin… | Figure 6. (a) Mass spectrometry analysis of O2 evolved on the 1st charging process of the Li/Li[Ni 0.2 Li 0.2Mn0.6]O2 cell. Reprinted with permission from ref 52. | ||
| 6 | 64 | page_header | page_header | False | low | docling_page_header | docling_page_header | p6:body_region:1 | p6:top_margin:column_2_of_2:colored | [125, 168, 209] colored | True | [519.14, 50.28, 38.3, 6.98] | Perspective | Perspective | ||
| 6 | 65 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p6:body_region:1 | p6:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 69.37, 240.04, 371.81] | gas quantity in Figure 6a is associated with the voltage increasing, and the large amount of oxygen gas is emitted above 4.5 V, corresponding to the charge plateau of these LLOs. Through fi rst-principles calculations, … | gas quantity in Figure 6a is associated with the voltage increasing, and the large amount of oxygen gas is emitted above 4.5 V, corresponding to the charge plateau of these LLOs. Through fi rst-principles calculations, … | ||
| 6 | 66 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p6:body_region:1 | p6:page_body:column_2_of_2:colored | [255, 242, 208] colored | False | [352.46, 454.93, 183.98, 81.36] | The reaction mechanisms associated with the mysterious anomalous capacity of these LLOs at high temperature may be di ff erent compared with those at room temperature, and are still unclear. | The reaction mechanisms associated with the mysterious anomalous capacity of these LLOs at high temperature may be di ff erent compared with those at room temperature, and are still unclear. | ||
| 6 | 67 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p6:body_region:1 | p6:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 555.81, 240.03, 207.39] | During the fi rst discharge process, lithium ions will insert into the Mn0.42Ni0.42Co0.16O2 and newly formed MnO2 components, respectively, while the unactivated Li2MnO3 component still exist in these ' composite ' laye… | During the fi rst discharge process, lithium ions will insert into the Mn0.42Ni0.42Co0.16O2 and newly formed MnO2 components, respectively, while the unactivated Li2MnO3 component still exist in these ' composite ' laye… | ||
| 6 | 68 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p6:body_region:1 | p6:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [387.33, 773.27, 177.16, 7.74] | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | ||
| 6 | 69 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p6:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [304.5, 774.02, 15.93, 6.54] | 1273 | 1273 | |||
| 7 | 70 | page_header | page_header | False | low | docling_page_header | docling_page_header | p7:body_region:0 | p7:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 181.19, 8.72] | The Journal of Physical Chemistry Letters | The Journal of Physical Chemistry Letters | ||
| 7 | 71 | page_header | page_header | False | low | docling_page_header | docling_page_header | p7:body_region:1 | p7:top_margin:column_2_of_2:colored | [125, 168, 209] colored | True | [519.14, 50.28, 38.3, 6.98] | Perspective | Perspective | ||
| 7 | 72 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p7:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 255.34, 503.93, 20.9] | Figure 7. Charge and discharge curves of the Li/Li[Li 1/5Ni1/5Mn3/5]O2 cell at (a) 55 ° C and (b) 85 ° C. Reprinted with permission from ref 40. Copyright 2011 Royal Society of Chemistry. | Figure 7. Charge and discharge curves of the Li/Li[Li 1/5Ni1/5Mn3/5]O2 cell at (a) 55 ° C and (b) 85 ° C. Reprinted with permission from ref 40. | |||
| 7 | 73 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p7:body_region:0 | p7:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 289.17, 239.99, 76.04] | charge/discharge currents, is 272, 224, and 184 mAh/g, respectively (Figure 5c). It is obvious that all of the discharge capacity except for the value with small current density ( ≤ 5 mA/g) can be explained by the propo… | charge/discharge currents, is 272, 224, and 184 mAh/g, respectively (Figure 5c). It is obvious that all of the discharge capacity except for the value with small current density ( ≤ 5 mA/g) can be explained by the propo… | ||
| 7 | 74 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p7:body_region:0 | p7:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 367.54, 239.96, 48.47] | the oxygen molecules at the electrode surface ( ⎯ ⎯⎯⎯⎯⎯⎯⎯→ -O O 2 reduction 2 ), but these contribution are suppressed by the accumulated lithium carbonate formation at the electrode surface (Figure 6f). 50 | the oxygen molecules at the electrode surface ( ⎯ ⎯⎯⎯⎯⎯⎯⎯→ -O O 2 reduction 2 ), but these contribution are suppressed by the accumulated lithium carbonate formation at the electrode surface (Figure 6f). 50 | ||
| 7 | 75 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p7:body_region:0 | p7:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 418.32, 240.01, 176.95] | Nevertheless, with the temperature increased to 55 and 85 ° C, the rechargeable charge/discharge capacity of the Li/ Li[Li1/5Ni1/5Mn3/5]O2 can reach 300 mAh/g (Figure 7a), and even 350 mAh/g (Figure 7b), which are much … | Nevertheless, with the temperature increased to 55 and 85 ° C, the rechargeable charge/discharge capacity of the Li/ Li[Li1/5Ni1/5Mn3/5]O2 can reach 300 mAh/g (Figure 7a), and even 350 mAh/g (Figure 7b), which are much … | ||
| 7 | 76 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p7:body_region:0 | p7:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 597.58, 240.0, 120.89] | Although there are many debates on these LLOs currently, their large electrochemical capacities are still very attractive for utilization as cathode materials in lithium ion batteries. In the past, di ff erent compositi… | Although there are many debates on these LLOs currently, their large electrochemical capacities are still very attractive for utilization as cathode materials in lithium ion batteries. In the past, di ff erent compositi… | ||
| 7 | 77 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p7:body_region:0 | p7:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 720.72, 239.99, 42.48] | Low initial Coulombic e ffi ciency associated with large irreversible capacity can result in mass ionized lithium, and the formation of a solid electrolyte interface (SEI) layer, thus reducing the energy density of the … | Low initial Coulombic e ffi ciency associated with large irreversible capacity can result in mass ionized lithium, and the formation of a solid electrolyte interface (SEI) layer, thus reducing the energy density of the … | ||
| 7 | 78 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p7:body_region:1 | p7:page_body:column_2_of_2:colored | [255, 242, 208] colored | False | [353.82, 295.45, 181.27, 95.31] | Currently, the low initial coulombic e ffi ciency, unsatis fi ed rate performance, and cycle stability of these LLOs are still the main problems preventing their utilization in practical lithium ion batteries. | Currently, the low initial coulombic e ffi ciency, unsatis fi ed rate performance, and cycle stability of these LLOs are still the main problems preventing their utilization in practical lithium ion batteries. | ||
| 7 | 79 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p7:body_region:1 | p7:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 412.83, 240.04, 207.34] | presenting a serious trade-o ff in lithium-ion battery design. At present, most of the initial Coulombic e ffi ciencies of these LLOs in the published literature are smaller than 80% at room temperature, and the main re… | presenting a serious trade-o ff in lithium-ion battery design. At present, most of the initial Coulombic e ffi ciencies of these LLOs in the published literature are smaller than 80% at room temperature, and the main re… | ||
| 7 | 80 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p7:body_region:1 | p7:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 622.36, 240.04, 140.84] | Although most of the published literature shows that the cycle performance based on the charge and discharge capacity of these LLOs is good, their voltage degradation after long cycling is extremely serious, which can l… | Although most of the published literature shows that the cycle performance based on the charge and discharge capacity of these LLOs is good, their voltage degradation after long cycling is extremely serious, which can l… | ||
| 7 | 81 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p7:body_region:1 | p7:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [387.33, 773.27, 177.16, 7.74] | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | ||
| 7 | 82 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p7:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [304.5, 774.02, 15.93, 6.54] | 1274 | 1274 | |||
| 8 | 83 | page_header | page_header | False | low | docling_page_header | docling_page_header | p8:body_region:0 | p8:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 181.19, 8.72] | The Journal of Physical Chemistry Letters | The Journal of Physical Chemistry Letters | ||
| 8 | 84 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p8:body_region:0 | p8:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 269.11, 239.95, 37.92] | Figure 8. The initial Coulombic e ffi ciency and the charge/discharge capacity of the Li 1.2 Mn0.567 -x Ru x Ni0.166 Co0.067O2 ( x = 0.00, 0.03, 0.05, and 0.07) materials. Adapted from ref 14. Copyright 2012 Royal Socie… | Figure 8. The initial Coulombic e ffi ciency and the charge/discharge capacity of the Li 1.2 Mn0.567 -x Ru x Ni0.166 Co0.067O2 ( x = 0.00, 0.03, 0.05, and 0.07) materials. Adapted from ref 14. | ||
| 8 | 85 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p8:body_region:0 | p8:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 324.66, 239.99, 107.85] | 151st cycle). The increased capacity in Stage I is obvious and corresponds to the new redox peaks (Ox3 /Re3 ) increasing after the fi rst cycle (Figure 9b). This indicates that the content of activated manganese increas… | 151st cycle). The increased capacity in Stage I is obvious and corresponds to the new redox peaks (Ox3 /Re3 ) increasing after the fi rst cycle (Figure 9b). This indicates that the content of activated manganese increas… | ||
| 8 | 86 | page_header | page_header | False | low | docling_page_header | docling_page_header | p8:body_region:1 | p8:top_margin:column_2_of_2:colored | [125, 168, 209] colored | True | [519.14, 50.28, 38.3, 6.98] | Perspective | Perspective | ||
| 8 | 87 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p8:body_region:1 | p8:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 69.37, 240.01, 30.97] | reduction peaks shifting to the lower voltage region (Figure 9d), indicating that the structures of these LLOs are not stable during long cycling. | reduction peaks shifting to the lower voltage region (Figure 9d), indicating that the structures of these LLOs are not stable during long cycling. | ||
| 8 | 88 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p8:body_region:1 | p8:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 102.54, 240.03, 186.03] | Observing Figure 9b,d, we found that there are obvious swellings on the oxidation curves of d Q /d V between 3.0 and 3.2 V during Stage I, and this swelling become more and more obvious during Stage II. These phenomena … | Observing Figure 9b,d, we found that there are obvious swellings on the oxidation curves of d Q /d V between 3.0 and 3.2 V during Stage I, and this swelling become more and more obvious during Stage II. These phenomena … | ||
| 8 | 89 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p8:body_region:1 | p8:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 290.76, 240.02, 141.69] | Surface coating with Al2O3, CeO2, ZrO2, SiO2, ZnO, AlPO4, and Li -Ni -PO4 and mildly acidic treatment on these LLOs can enhance the cycling stability, but these coatings cannot adequately overcome the voltage decay. 53,… | Surface coating with Al2O3, CeO2, ZrO2, SiO2, ZnO, AlPO4, and Li -Ni -PO4 and mildly acidic treatment on these LLOs can enhance the cycling stability, but these coatings cannot adequately overcome the voltage decay. 53,… | ||
| 8 | 90 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p8:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 705.02, 503.99, 57.93] | Figure 9. Charge/discharge and d Q /d V pro fi les at di ff erent cycling stages ((a,b), Stage I: from the 2nd cycle to the 25th cycle; (c,d), Stage II: from the 26th cycle to the 151st cycle) of the Li/0.5Li2MnO3 · 0.5… | Figure 9. Charge/discharge and d Q /d V pro fi les at di ff erent cycling stages ((a,b), Stage I: from the 2nd cycle to the 25th cycle; (c,d), Stage II: from the 26th cycle to the 151st cycle) of the Li/0.5Li2MnO3 · 0.5… | |||
| 8 | 91 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p8:body_region:1 | p8:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [387.33, 773.27, 177.16, 7.74] | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | ||
| 8 | 92 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p8:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [304.5, 774.02, 15.93, 6.54] | 1275 | 1275 | |||
| 9 | 93 | page_header | page_header | False | low | docling_page_header | docling_page_header | p9:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 181.19, 8.72] | The Journal of Physical Chemistry Letters | The Journal of Physical Chemistry Letters | |||
| 9 | 94 | page_header | page_header | False | low | docling_page_header | docling_page_header | p9:top_margin:column_2_of_2:colored | [125, 168, 209] colored | True | [519.14, 50.28, 38.3, 6.98] | Perspective | Perspective | |||
| 9 | 95 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p9:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 344.29, 503.99, 49.53] | Figure 10. Galvanostatic intermittent titration technique (GITT) in the fi rst, second, and third (a) charge and (b) discharge processes, Li + di ff usion coe ffi cients during the fi rst three (c) charge and (d) discha… | Figure 10. Galvanostatic intermittent titration technique (GITT) in the fi rst, second, and third (a) charge and (b) discharge processes, Li + di ff usion coe ffi cients during the fi rst three (c) charge and (d) discha… | |||
| 9 | 96 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p9:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 683.42, 503.99, 27.94] | Figure 11. (a) TEM image and (b) rate capabilities of Li[Ni 0.25 Li 0.15Mn0.6]O2 nanowires. Reprinted with permission from ref 77. Copyright 2009 Royal Society of Chemistry. (c) SEM image and (d) discharge curves with d… | Figure 11. (a) TEM image and (b) rate capabilities of Li[Ni 0.25 Li 0.15Mn0.6]O2 nanowires. Reprinted with permission from ref 77. | |||
| 9 | 97 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p9:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 730.02, 239.97, 33.18] | oxygen arrays. 75 Thus, the voltage degradations of these LLOs during cycling are also believed to be associated with both internal and surface phase transition to a cubic spinel-like phase | oxygen arrays. 75 Thus, the voltage degradations of these LLOs during cycling are also believed to be associated with both internal and surface phase transition to a cubic spinel-like phase | |||
| 9 | 98 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p9:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 732.4, 240.02, 30.8] | by the migration of transition metal ions. At present, the stepwise precycling treatment on these LLOs is used and can improve their cyclic durability. 76 The reason may be | by the migration of transition metal ions. At present, the stepwise precycling treatment on these LLOs is used and can improve their cyclic durability. 76 The reason may be | |||
| 9 | 99 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p9:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [387.33, 773.27, 177.16, 7.74] | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | |||
| 9 | 100 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p9:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [304.5, 774.02, 15.93, 6.54] | 1276 | 1276 | |||
| 10 | 101 | page_header | page_header | False | low | docling_page_header | docling_page_header | p10:body_region:0 | p10:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 181.19, 8.72] | The Journal of Physical Chemistry Letters | The Journal of Physical Chemistry Letters | ||
| 10 | 102 | page_header | page_header | False | low | docling_page_header | docling_page_header | p10:body_region:1 | p10:top_margin:column_2_of_2:colored | [125, 168, 209] colored | True | [519.14, 50.28, 38.3, 6.98] | Perspective | Perspective | ||
| 10 | 103 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p10:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 384.09, 503.99, 18.97] | Figure 12. Current debates on structure and reaction mechanism, problems on electrochemical properties, and keys to the study in the future of Li 2 MnO3-based lithium-rich layered cathode materials. | Figure 12. Current debates on structure and reaction mechanism, problems on electrochemical properties, and keys to the study in the future of Li 2 MnO3-based lithium-rich layered cathode materials. | |||
| 10 | 104 | text | unknown_text | False | high | inside_front_matter | inside_front_matter | p10:body_region:0 | p10:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 414.92, 239.98, 31.48] | contributed by the weakened structure damage and little structure arrangement after electrochemical cycling of these materials with this pretreatment method. | contributed by the weakened structure damage and little structure arrangement after electrochemical cycling of these materials with this pretreatment method. | ||
| 10 | 105 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p10:body_region:0 | p10:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 448.76, 240.0, 314.44] | In order to reveal the kinetically controlled charge and discharge processes of these cathode materials, the lithium ion di ff usion in active material and lithium ion transfer at the e l e c t r o d e / e l e c t r o l… | In order to reveal the kinetically controlled charge and discharge processes of these cathode materials, the lithium ion di ff usion in active material and lithium ion transfer at the e l e c t r o d e / e l e c t r o l… | ||
| 10 | 106 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p10:body_region:1 | p10:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 414.92, 240.01, 110.74] | components and interfaces (between electrode and electrolyte) are very consistent with the two-phase models proposed and con fi rmed in Figure 2. Therefore, the electrochemical kinetics of the lithium ion extraction and… | components and interfaces (between electrode and electrolyte) are very consistent with the two-phase models proposed and con fi rmed in Figure 2. Therefore, the electrochemical kinetics of the lithium ion extraction and… | ||
| 10 | 107 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p10:body_region:1 | p10:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 528.02, 240.03, 201.33] | Thus, in order to improve the rate performance of these LLOs, the materials with low Li2MnO3 component proportion, short lithium ion di ff usion pathway, and small interface reaction barrier should be introduced to thes… | Thus, in order to improve the rate performance of these LLOs, the materials with low Li2MnO3 component proportion, short lithium ion di ff usion pathway, and small interface reaction barrier should be introduced to thes… | ||
| 10 | 108 | text | body_candidate_excluded | False | high | inside_front_matter | inside_front_matter | p10:body_region:1 | p10:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 731.72, 239.97, 31.48] | The LLOs are very attractive for utilization as cathode materials for lithium ion batteries. Although researchers have put forth much e ff ort in studying these materials in the past, | The LLOs are very attractive for utilization as cathode materials for lithium ion batteries. Although researchers have put forth much e ff ort in studying these materials in the past, | ||
| 10 | 109 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p10:body_region:1 | p10:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [387.33, 773.27, 177.16, 7.74] | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | ||
| 10 | 110 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p10:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [304.5, 774.02, 15.93, 6.54] | 1277 | 1277 | |||
| 11 | 111 | page_header | page_header | False | low | docling_page_header | docling_page_header | p11:body_region:0 | p11:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 181.19, 8.72] | The Journal of Physical Chemistry Letters | The Journal of Physical Chemistry Letters | ||
| 11 | 112 | text | unknown_text | False | high | inside_front_matter | inside_front_matter | p11:body_region:0 | p11:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 69.37, 239.99, 20.2] | many debates and issues over these materials still exist, and need to be clari fi ed and solved in the future (Figure 12). | many debates and issues over these materials still exist, and need to be clari fi ed and solved in the future (Figure 12). | ||
| 11 | 113 | list_item | body | True | recovered_body_same_page_outside_flow | recovered_body_same_page_outside_flow | p11:body_region:0 | p11:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 92.0, 239.99, 225.77] | The structures of these LLOs are still currently being debated (yellow region in Figure 12). The local structures are very important to the electrochemical performance, especially the rate performance of these LLOs. Aft… | The structures of these LLOs are still currently being debated (yellow region in Figure 12). The local structures are very important to the electrochemical performance, especially the rate performance of these LLOs. Aft… | |||
| 11 | 114 | list_item | body | True | recovered_body_outside_flow | recovered_body_outside_flow | p11:body_region:0 | p11:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 320.13, 240.0, 122.98] | It is very useful to understand the reaction mechanism (blue region in Figure 12) of these materials at room temperature by the three-dimensional phase diagram. However, it is still di ffi cult to understand the large m… | It is very useful to understand the reaction mechanism (blue region in Figure 12) of these materials at room temperature by the three-dimensional phase diagram. However, it is still di ffi cult to understand the large m… | |||
| 11 | 115 | text | body | True | body | body | p11:body_region:0 | p11:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 445.53, 239.98, 168.68] | (3) The electrochemical properties associated with low initial columbic e ffi ciency, slow Li + di ff usion speed, and voltage degradation during cycling of these LLOs are the main problems (green region in Figure 12) p… | (3) The electrochemical properties associated with low initial columbic e ffi ciency, slow Li + di ff usion speed, and voltage degradation during cycling of these LLOs are the main problems (green region in Figure 12) p… | |||
| 11 | 116 | text | body | True | body | body | p11:body_region:0 | p11:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 616.57, 239.96, 54.5] | In general, although there are many debates on these LLOs, they are still attractive for utilization as cathode materials in lithium ion batteries because of their large rechargeable capacities, thus, much e ff ort with… | In general, although there are many debates on these LLOs, they are still attractive for utilization as cathode materials in lithium ion batteries because of their large rechargeable capacities, thus, much e ff ort with… | |||
| 11 | 117 | section_header | body_heading | False | low | body_heading | body_heading | p11:body_region:0 | p11:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 675.56, 125.07, 23.65] | ■ AUTHOR INFORMATION | ■ AUTHOR INFORMATION | ||
| 11 | 118 | section_header | body_heading | False | low | body_heading | body_heading | p11:body_region:0 | p11:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 703.39, 93.07, 8.29] | Corresponding Author | Corresponding Author | ||
| 11 | 119 | text | metadata | False | low | metadata_line | metadata_line | p11:body_region:0 | p11:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 712.69, 239.94, 23.07] | * Fax: +81-29-861-3489; Tel: 81-29-861-5795; E-mail: hs. zhou@aist.go.jp. | * Fax: +81-29-861-3489; Tel: 81-29-861-5795; E-mail: hs. zhou@aist.go.jp. | ||
| 11 | 120 | section_header | body_heading | False | low | body_heading | body_heading | p11:body_region:0 | p11:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 741.55, 23.72, 8.29] | Notes | Notes | ||
| 11 | 121 | text | body | True | body | body | p11:body_region:0 | p11:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 754.4, 201.38, 8.8] | The authors declare no competing fi nancial interest. | The authors declare no competing fi nancial interest. | |||
| 11 | 122 | page_header | page_header | False | low | docling_page_header | docling_page_header | p11:top_margin:column_2_of_2:colored | [125, 168, 209] colored | True | [519.14, 50.28, 38.3, 6.98] | Perspective | Perspective | |||
| 11 | 123 | section_header | body_heading | False | low | body_heading | body_heading | p11:page_body:column_2_of_2:white | [253, 253, 253] white | False | [324.45, 68.77, 48.74, 8.29] | Biographies | Biographies | |||
| 11 | 124 | text | body | True | body | body | p11:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 82.59, 240.02, 84.91] | Haijun Yu received his Ph.D. (2007) in Metallurgy Science and Engineering from the Northeastern University. In 2007-10, he worked as senior engineer at the General Research Institute for Nonferrous Metals (GRINM) in Chi… | Haijun Yu received his Ph.D. (2007) in Metallurgy Science and Engineering from the Northeastern University. In 2007-10, he worked as senior engineer at the General Research Institute for Nonferrous Metals (GRINM) in Chi… | ||||
| 11 | 125 | text | body | True | body | body | p11:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 174.55, 240.02, 95.97] | Haoshen Zhou is now a prime senior researcher of the Energy Technology Research Institute (ETRI), National Institute of Advanced Industrial Science and Technology (AIST), and leading the Energy Interface Technology Grou… | Haoshen Zhou is now a prime senior researcher of the Energy Technology Research Institute (ETRI), National Institute of Advanced Industrial Science and Technology (AIST), and leading the Energy Interface Technology Grou… | ||||
| 11 | 126 | section_header | back_matter_heading | False | low | back_matter_heading | back_matter_heading | stop_trigger | p11:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 272.93, 114.79, 23.65] | ■ ACKNOWLEDGMENTS | ■ ACKNOWLEDGMENTS | ||
| 11 | 127 | text | back_matter_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 298.08, 240.0, 31.36] | This work was partially supported fi nancially by the Funding Program for World-Leading Innovative R&D on Science and Technology (FIRST Program). | This work was partially supported fi nancially by the Funding Program for World-Leading Innovative R&D on Science and Technology (FIRST Program). | ||
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| 12 | 144 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 181.19, 8.72] | The Journal of Physical Chemistry Letters | The Journal of Physical Chemistry Letters | ||
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| 12 | 159 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 640.34, 239.94, 40.16] | Park, S. H.; Kang, S. H.; Johnson, C. S.; Amine, K.; Thackeray, M. M. Lithium-Manganese-Nickel-Oxide Electrodes with Integrated Layered-Spinel Structures for Lithium Batteries. Electrochem. Commun. 2007 , 9 , 262 -268. | Park, S. H.; Kang, S. H.; Johnson, C. S.; Amine, K.; Thackeray, M. M. Lithium-Manganese-Nickel-Oxide Electrodes with Integrated Layered-Spinel Structures for Lithium Batteries. Electrochem. Commun. 2007 , 9 , 262 -268. | ||
| 12 | 160 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 681.9, 240.0, 40.15] | Bareno, J.; Balasubramanian, M.; Kang, S. H.; Wen, J. G.; Lei, C. H.; Pol, S. V.; Petrov, I.; Abraham, D. P. Long-Range and Local Structure in the Layered Oxide Li 1.2 Co0.4Mn0.4O2. Chem. Mater. 2011 , 23 , 2039 -2050. | Bareno, J.; Balasubramanian, M.; Kang, S. H.; Wen, J. G.; Lei, C. H.; Pol, S. V.; Petrov, I.; Abraham, D. P. Long-Range and Local Structure in the Layered Oxide Li 1.2 Co0.4Mn0.4O2. Chem. Mater. 2011 , 23 , 2039 -2050. | ||
| 12 | 161 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 723.45, 240.0, 40.16] | Lei, C. H.; Bareno, J.; Wen, J. G.; Petrov, I.; Kang, S. H.; Abraham, D. P. Local Structure and Composition Studies of Li 1.2 Ni0.2Mn0.6O2 by Analytical Electron Microscopy. J. Power Sources 2008 , 178 , 422 -433. | Lei, C. H.; Bareno, J.; Wen, J. G.; Petrov, I.; Kang, S. H.; Abraham, D. P. Local Structure and Composition Studies of Li 1.2 Ni0.2Mn0.6O2 by Analytical Electron Microscopy. J. Power Sources 2008 , 178 , 422 -433. | ||
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| 12 | 165 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 139.63, 240.0, 38.91] | Boulineau, A.; Simonin, L.; Colin, J. F.; Canevet, E.; Daniel, L.; Patoux, S. Evolutions of Li 1.2 Mn0.61 Ni0.18Mg0.01O2 during the Initial Charge/Discharge Cycle Studied by Advanced Electron Microscopy. Chem. Mater. 20… | Boulineau, A.; Simonin, L.; Colin, J. F.; Canevet, E.; Daniel, L.; Patoux, S. Evolutions of Li 1.2 Mn0.61 Ni0.18Mg0.01O2 during the Initial Charge/Discharge Cycle Studied by Advanced Electron Microscopy. Chem. Mater. 20… | ||
| 12 | 166 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 179.93, 240.02, 38.97] | Xu, B.; Fell, C. R.; Chi, M. F.; Meng, Y. S. Identifying Surface Structural Changes in Layered Li-Excess Nickel Manganese Oxides in High Voltage Lithium Ion Batteries: A Joint Experimental and Theoretical Study. Energ. … | Xu, B.; Fell, C. R.; Chi, M. F.; Meng, Y. S. Identifying Surface Structural Changes in Layered Li-Excess Nickel Manganese Oxides in High Voltage Lithium Ion Batteries: A Joint Experimental and Theoretical Study. Energ. … | ||
| 12 | 167 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 220.3, 240.01, 49.05] | Koga, H.; Croguennec, L.; Mannessiez, P.; Menetrier, M.; Weill, F.; Bourgeois, L.; Duttine, M.; Suard, E.; Delmas, C. Li 1.20 Mn0.54 Co0.13 Ni0.13O2 with Different Particle Sizes as Attractive Positive Electrode Materia… | Koga, H.; Croguennec, L.; Mannessiez, P.; Menetrier, M.; Weill, F.; Bourgeois, L.; Duttine, M.; Suard, E.; Delmas, C. Li 1.20 Mn0.54 Co0.13 Ni0.13O2 with Different Particle Sizes as Attractive Positive Electrode Materia… | ||
| 12 | 168 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 270.76, 240.03, 38.96] | Wen, J. G.; Bareno, J.; Lei, C. H.; Kang, S. H.; Balasubramanian, M.; Petrov, I.; Abraham, D. P. Analytical Electron Microscopy of Li 1.2Co0.4Mn0.4O2 for Lithium-Ion Batteries. Solid State Ionics 2011 , 182 , 98 -107. | Wen, J. G.; Bareno, J.; Lei, C. H.; Kang, S. H.; Balasubramanian, M.; Petrov, I.; Abraham, D. P. Analytical Electron Microscopy of Li 1.2Co0.4Mn0.4O2 for Lithium-Ion Batteries. Solid State Ionics 2011 , 182 , 98 -107. | ||
| 12 | 169 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 311.12, 240.0, 38.91] | Jarvis, K. A.; Deng, Z. Q.; Allard, L. F.; Manthiram, A.; Ferreira, P. J. Atomic Structure of a Lithium-Rich Layered Oxide Material for Lithium-Ion Batteries: Evidence of A Solid Solution. Chem. Mater. 2011 , 23 , 3614 … | Jarvis, K. A.; Deng, Z. Q.; Allard, L. F.; Manthiram, A.; Ferreira, P. J. Atomic Structure of a Lithium-Rich Layered Oxide Material for Lithium-Ion Batteries: Evidence of A Solid Solution. Chem. Mater. 2011 , 23 , 3614 … | ||
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| 12 | 173 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:page_body:column_2_of_2:white | [255, 255, 255] white | False | [324.45, 482.67, 240.0, 38.91] | Thackeray, M. M.; Kang, S. H.; Johnson, C. S.; Vaughey, J. T.; Hackney, S. A. Comments on the Structural Complexity of LithiumRich Li1+xM1 -x O2 Electrodes (M = Mn, Ni, Co) for Lithium Batteries. Electrochem. Commun. 20… | Thackeray, M. M.; Kang, S. H.; Johnson, C. S.; Vaughey, J. T.; Hackney, S. A. Comments on the Structural Complexity of LithiumRich Li1+xM1 -x O2 Electrodes (M = Mn, Ni, Co) for Lithium Batteries. Electrochem. Commun. 20… | ||
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| 12 | 181 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [387.33, 773.27, 177.16, 7.74] | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | dx.doi.org/10.1021/jz400032v | J. Phys. Chem. Lett. 2013, 4, 1268 -1280 | ||
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| 13 | 183 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p13:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 48.93, 181.19, 8.72] | The Journal of Physical Chemistry Letters | The Journal of Physical Chemistry Letters | ||
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| 13 | 188 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p13:page_body:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 240.48, 239.94, 38.96] | Kang, S. H.; Johnson, C. S.; Vaughey, J. T.; Amine, K.; Thackeray, M. M. The Effects of Acid Treatment on the Electrochemical Properties of 0.5Li2MnO3 · 0.5LiNi 0.44 Co0.25 Mn0.31 O2 Electrodes in Lithium Cells. J. Elec… | Kang, S. H.; Johnson, C. S.; Vaughey, J. T.; Amine, K.; Thackeray, M. M. The Effects of Acid Treatment on the Electrochemical Properties of 0.5Li2MnO3 · 0.5LiNi 0.44 Co0.25 Mn0.31 O2 Electrodes in Lithium Cells. J. Elec… | ||
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| 13 | 200 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p13:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [60.49, 724.64, 240.0, 38.96] | Park, C. W.; Kim, S. H.; Mangani, I. R.; Lee, J. H.; Boo, S.; Kim, J. Synthesis and Materials Characterization of Li2MnO3-LiCrO2 System Nanocomposite Electrode Materials. Mater. Res. Bull. 2007 , 42 , 1374 -1383. | Park, C. W.; Kim, S. H.; Mangani, I. R.; Lee, J. H.; Boo, S.; Kim, J. Synthesis and Materials Characterization of Li2MnO3-LiCrO2 System Nanocomposite Electrode Materials. Mater. Res. Bull. 2007 , 42 , 1374 -1383. | ||
| 13 | 201 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p13:top_margin:column_2_of_2:colored | [125, 168, 209] colored | True | [519.14, 50.28, 38.3, 6.98] | Perspective | Perspective | ||
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