Docling layout block audit

original.pdf docling.json layout_blocks.json layout_blocks.tsv layout_blocks.jsonl excluded_blocks.html excluded_blocks.tsv final_body_blocks.tsv visual_assets.tsv visual_assets.json

Summary

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Diff Summary

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Truncation

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Page Overlays

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Visual Assets

这里对齐真实图表资产提取链路。caption_source=embedded_table_cell 表示表注来自 Docling table cell,不会出现在 text block 审计差集里;caption_continuation_used_by_asset 表示某个 text block 已被图表 caption 吸收,不应按普通 metadata 解读。

#typelabelpagecaption sourcesuppressedduplicate reasonrescue reasongroupconfidencebboxcaption
1figureFig. 13nearby_text_caption0.82[117.71, 75.75, 360.94, 259.86]Figure 1. a) HAADF-STEM image of the LMRO@7CuPc electrode. b) Atomic-resolution HAADF-STEM image of the site A in (a). c) Atomic-resolution HAADF-STEM image of the site B in (a). d) STEM-EDS mapping of the LMRO@7CuPc electrode.
2figureFig. 24nearby_text_caption0.82[115.2, 77.58, 362.43, 586.3]Figure 2. Electrochemical performance of LMRO and CuPc-enhanced electrodes. a) Initial charge-discharge profiles at 20 mA g -1 . b) Cycling performance at 20 mA g -1 . c) Cycling performance at 200 mA g -1 . d,e) Voltage-capacity profiles of LMRO and LMRO@7CuPc electrodes at different cycles. f) Energy density curves during cycling at 200 mA g -1 .
3figureFig. 36nearby_text_caption0.82[49.71, 76.06, 492.37, 550.82]Figure 3. The XPS spectra for LMRO@7CuPc electrode during the first cycle of a) N 1s spectra, b) Cu 2p Spectra. c) Relative atomic ratio of N re and N ox during the first cycle of LMRO@7CuPc electrode. d) Relative atomic ratio of Cu 2 + and Cu + during the first cycle of LMRO@7CuPc electrode. e) DEMS curves for LMRO and LMRO@7CuPc electrode during the first cycle. The O 1s after Ar etching 20 min during the first cycle for f) LMRO electrode and g) LMRO@7CuPc electrode.
4figureFig. 47nearby_text_caption0.82[119.14, 75.98, 359.56, 349.22]Figure 4. a) HAADF-STEM image of LMRO electrode after 500 cycles. b) Atomic-resolution HAADF-STEM image of site A in (a). Inset: FFT image of Figure b. c) Atomic-resolution HAADF-STEM image of site B in (a). d). HAADF-STEM image of LMRO@7CuPc electrode after 500 cycles. e) Atomicresolution HAADF-STEM image of site C in (d). f) Atomic-resolution HAADF-STEM image of site D in (d). g) FFT pattern of the purple rectangle region in (f). h) Atomic-resolution HAADF-STEM image of site E in (d). i) iDPC-STEM image of the red rectangle region in (h).
5figureFig. 59nearby_text_caption0.82[71.11, 76.88, 453.36, 587.72]Figure 5. a-c) EELS line scanning from the surface into the bulk of the LMRO electrode after 500 cycles. d-f) EELS line scanning from the surface into the bulk of LMRO@7CuPc electrode after 500 cycles. The corresponding EELS scanning pathway is shown in Figure S14 (Supporting Information). g) EELS mapping for Mn 4 + and Mn 3 + of LMRO electrode after 500 cycles. h) EELS mapping for Mn 4 + and Mn 3 + of LMRO@7CuPc electrode after 500 cycles.
6figureFig. 610nearby_text_caption0.82[55.12, 77.14, 480.22, 493.23]Figure 6. a) C 1s, O 1s, P 2p, and F 1s high-resolution XPS spectra of LMRO (top) and LMRO@7CuPc (bottom) after 500 cycles. b) TOF-SIMS investigations CEI structure after 500 cycles. The mapping for LiF -, C2 HO -, C2 H 3O -, PO3 -, PF 6 -and MnF 3 -secondary ions for LMRO electrode (top) and LMRO@7CuPc electrode (bottom). The secondary ion maps were acquired in a 200 µ m × 200 µ m region. STEM-EDS line scanning for c) LMRO electrode and d) LMRO@7CuPc electrode after 500 cycles. e) The dissolubilities of TM elements from the LMRO and LMRO@7CuPc electrodes after 500 cycles.

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True[50.81, 28.94, 126.19, 12.11]RESEARCH ARTICLERESEARCH ARTICLE
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False[50.81, 77.5, 490.56, 63.65]Cu-N Synergism Regulation to Enhance Anionic Redox Reversibility and Activity of Li- and Mn-Rich Layered Oxides CathodeCu-N Synergism Regulation to Enhance Anionic Redox Reversibility and Activity of Li- and Mn-Rich Layered Oxides Cathode
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False[50.81, 160.21, 457.88, 48.46]Zhijun Wu, Chenhui Yan, Panyu Gao, Liaona She,* Xin Zhang, Yue Lin, Xuebin Yu, Yongfeng Liu, Wenping Sun, Yinzhu Jiang, Yaxiong Yang,* Mingxia Gao,* and Hongge Pan*Zhijun Wu, Chenhui Yan, Panyu Gao, Liaona She,* Xin Zhang, Yue Lin, Xuebin Yu, Yongfeng Liu, Wenping Sun, Yinzhu Jiang, Yaxiong Yang,* Mingxia Gao,* and Hongge Pan*
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False[50.81, 245.62, 312.82, 228.87]Anionic redox chemistry enables extraordinary capacity for Li- and Mn-rich layered oxides (LMROs) cathodes. Unfortunately, irreversible surface oxygen evolution evokes the pernicious phase transition, structural deterio…Anionic redox chemistry enables extraordinary capacity for Li- and Mn-rich layered oxides (LMROs) cathodes. Unfortunately, irreversible surface oxygen evolution evokes the pernicious phase transition, structural deterio…
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False[50.81, 511.91, 70.4, 10.25]1. Introduction1. Introduction
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False[50.81, 531.27, 240.95, 19.41]Lithium-ion batteries (LIBs) have been worldwide applied in 3C products, electric vehicles (EVs), and grid energy storage in pastLithium-ion batteries (LIBs) have been worldwide applied in 3C products, electric vehicles (EVs), and grid energy storage in past
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False[50.81, 570.08, 169.38, 34.09]Z. Wu, C. Yan, L. She, Y. Yang, H. Pan Institute of Science and Technology for New Energy Xi'an Technological University Xi'an 710021, ChinaZ. Wu, C. Yan, L. She, Y. Yang, H. Pan Institute of Science and Technology for New Energy Xi'an Technological University Xi'an 710021, China
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False[50.81, 605.94, 193.95, 16.17]E-mail: sheliaona@xatu.edu.cn; yangyaxiong@xatu.edu.cn; honggepan@zju.edu.cnE-mail: sheliaona@xatu.edu.cn; yangyaxiong@xatu.edu.cn; honggepan@zju.edu.cn
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False[50.81, 625.87, 227.91, 43.07]C. Yan, X. Zhang, Y . Liu, W. Sun, Y . Jiang, M. Gao, H. Pan State Key Laboratory of Silicon and Advanced Semiconductor Materials andSchoolofMaterialsScienceandEngineering Zhejiang University Hangzhou310027,ChinaC. Yan, X. Zhang, Y . Liu, W. Sun, Y . Jiang, M. Gao, H. Pan State Key Laboratory of Silicon and Advanced Semiconductor Materials andSchoolofMaterialsScienceandEngineering Zhejiang University Hangzhou310027,China
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False[50.81, 670.7, 89.07, 7.2]E-mail: gaomx@zju.edu.cnE-mail: gaomx@zju.edu.cn
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False[68.79, 690.25, 222.97, 16.17]The ORCID identification number(s) for the author(s) of this article can be found under https://doi.org/10.1002/smll.202401645The ORCID identification number(s) for the author(s) of this article can be found under
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True[50.81, 712.5, 111.55, 8.02]DOI: 10.1002/smll.202401645DOI: 10.1002/smll.202401645
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False[384.63, 236.89, 162.26, 271.46]decades. However, current commercialized LIBs cannot fulfill the demand for high energy density and power density with the rapid development of modern industrial society. [ 1-4] As the critical component determining the…decades. However, current commercialized LIBs cannot fulfill the demand for high energy density and power density with the rapid development of modern industrial society. [ 1-4] As the critical component determining the…
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False[305.92, 509.8, 240.95, 20.47]the bulk (O 2 -→ O2 2 -) and irreversible oxygen gas release on the surface (O 2 -→ O2). [ 15-18]the bulk (O 2 -→ O2 2 -) and irreversible oxygen gas release on the surface (O 2 -→ O2). [ 15-18]
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False[305.93, 532.79, 240.95, 19.4]Although LMROs have advantages in capacity and cost, several inherent drawbacks still hinder the road to commercialization.Although LMROs have advantages in capacity and cost, several inherent drawbacks still hinder the road to commercialization.
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False[305.93, 570.99, 108.48, 34.1]P. Gao, X. Yu Department of Materials Science Fudan University Shanghai 200433, ChinaP. Gao, X. Yu Department of Materials Science Fudan University Shanghai 200433, China
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False[305.93, 617.82, 214.9, 25.13]Hefei National Laboratory for Physical Sciences at the Microscale University of Science and Technology of China Hefei 230026, ChinaHefei National Laboratory for Physical Sciences at the Microscale University of Science and Technology of China Hefei 230026, China
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False[469.66, 745.82, 77.21, 6.3]©2024 Wiley-VCH GmbH©2024 Wiley-VCH GmbH
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False[47.98, 76.43, 240.97, 216.67]First, irreversible oxygen release substantially damages the lattice crystal and facilitates transition metal migration to neighboring Li slabs, engendering layered-spinel phase transition, resulting in cathode degradat…First, irreversible oxygen release substantially damages the lattice crystal and facilitates transition metal migration to neighboring Li slabs, engendering layered-spinel phase transition, resulting in cathode degradat…
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False[47.98, 295.6, 240.94, 63.24]Various strategies have been employed to solve the drawbacks of LMROs, including surface modification, [28,29] element doping, [30,31] structure design, [32,33] binder readjustment, [34,35] and electrolyte optimization.…Various strategies have been employed to solve the drawbacks of LMROs, including surface modification, [28,29] element doping, [30,31] structure design, [32,33] binder readjustment, [34,35] and electrolyte optimization.…
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False[47.97, 361.36, 240.96, 271.46]The redox couple strategy has been proven to be a facile and efficacious approach to inhibit oxygen release and achieve outstanding electrochemical stability via chemically reducing the peroxide ion O2 2 -back to stable…The redox couple strategy has been proven to be a facile and efficacious approach to inhibit oxygen release and achieve outstanding electrochemical stability via chemically reducing the peroxide ion O2 2 -back to stable…
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False[47.98, 649.05, 122.45, 10.25]2. Results and Discussion2. Results and Discussion
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False[47.98, 668.41, 240.96, 52.28]The X-ray diffraction (XRD) patterns shown in Figure S1 (Supporting Information) show that a new diffraction peak appears when the amount of CuPc added increases ( ≥ 5 wt%), but the LMRO and CuPc-enhanced electrodes dis…The X-ray diffraction (XRD) patterns shown in Figure S1 (Supporting Information) show that a new diffraction peak appears when the amount of CuPc added increases ( ≥ 5 wt%), but the LMRO and CuPc-enhanced electrodes dis…
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False[303.09, 76.43, 240.96, 129.0]Supporting Information) further confirm that the lattice parameters of LMRO and LMRO@7CuPc electrodes keep well, indicating preparation process does not damage the bulk structure. Figure 1 a-c shows the high-angle annul…Supporting Information) further confirm that the lattice parameters of LMRO and LMRO@7CuPc electrodes keep well, indicating preparation process does not damage the bulk structure. Figure 1 a-c shows the high-angle annul…
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False[303.09, 207.94, 240.96, 512.55]The electrochemical performances of CuPc-enhanced electrodes in the voltage window of 2.0-4.8 V at 0.1 C and 1 C (1C = 200 mA g -1 ) are shown in Figure 2 , and corresponding data are summarized in Table S2 (Supporting …The electrochemical performances of CuPc-enhanced electrodes in the voltage window of 2.0-4.8 V at 0.1 C and 1 C (1C = 200 mA g -1 ) are shown in Figure 2 , and corresponding data are summarized in Table S2 (Supporting …
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False[50.81, 344.36, 496.04, 16.67]Figure 1. a) HAADF-STEM image of the LMRO@7CuPc electrode. b) Atomic-resolution HAADF-STEM image of the site A in (a). c) Atomic-resolution HAADF-STEM image of the site B in (a). d) STEM-EDS mapping of the LMRO@7CuPc el…Figure 1. a) HAADF-STEM image of the LMRO@7CuPc electrode. b) Atomic-resolution HAADF-STEM image of the site A in (a). c) Atomic-resolution HAADF-STEM image of the site B in (a). d) STEM-EDS mapping of the LMRO@7CuPc el…
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False[50.81, 383.18, 240.96, 293.38]vious that LMRO electrode shows extremely fast capacity fading from 214.2 to 119.6 mAh g -1 , with a poor retention of only 55.8% after 500 cycles, and the discharge curves (Figure 2d) show severe voltage decay with a v…vious that LMRO electrode shows extremely fast capacity fading from 214.2 to 119.6 mAh g -1 , with a poor retention of only 55.8% after 500 cycles, and the discharge curves (Figure 2d) show severe voltage decay with a v…
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False[50.81, 679.07, 240.97, 41.32]Furthermore, other metal phthalocyanine derivatives are investigated using as redox couple in LMRO as well, including phthalocyanine (Pc), nickel phthalocyanine (NiPc), cooper phthalocyanine (CoPc), manganese phthalocya…Furthermore, other metal phthalocyanine derivatives are investigated using as redox couple in LMRO as well, including phthalocyanine (Pc), nickel phthalocyanine (NiPc), cooper phthalocyanine (CoPc), manganese phthalocya…
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False[305.92, 383.18, 240.97, 315.29]phthalocyanine (FePc) and zinc phthalocyanine (ZnPc). All the additives are added into LMRO and the electrode preparation are same as CuPc enhanced electrodes, and the corresponding electrochemical performance data are …phthalocyanine (FePc) and zinc phthalocyanine (ZnPc). All the additives are added into LMRO and the electrode preparation are same as CuPc enhanced electrodes, and the corresponding electrochemical performance data are …
343textunknown_textFalsehighinside_back_matterinside_back_matter
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False[305.92, 700.99, 240.94, 19.4]According to the above discussion of electrochemical performance, we speculate that there is a synergetic effect on Cu andAccording to the above discussion of electrochemical performance, we speculate that there is a synergetic effect on Cu and
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False[469.66, 745.82, 77.21, 6.3]©2024 Wiley-VCH GmbH©2024 Wiley-VCH GmbH
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False[47.98, 669.89, 496.06, 27.59]Figure 2. Electrochemical performance of LMRO and CuPc-enhanced electrodes. a) Initial charge-discharge profiles at 20 mA g -1 . b) Cycling performance at 20 mA g -1 . c) Cycling performance at 200 mA g -1 . d,e) Voltag…Figure 2. Electrochemical performance of LMRO and CuPc-enhanced electrodes. a) Initial charge-discharge profiles at 20 mA g -1 . b) Cycling performance at 20 mA g -1 . c) Cycling performance at 200 mA g -1 . d,e) Voltag…
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False[466.82, 745.82, 77.21, 6.3]©2024 Wiley-VCH GmbH©2024 Wiley-VCH GmbH
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False[578.97, 15.65, 4.54, 751.19]16136829, 2024, 37, Downloaded from https://onlinelibrary.wiley.com/doi/10.1002/smll.202401645 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley.com/ter…
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False[50.81, 76.43, 240.97, 644.06]N elements of CuPc thus realizing the best cycling stability. To elucidate the mechanism of improved cycling stability and redox behavior of oxygen, X-ray photoelectron spectroscopy (XPS) measurement is conducted for LM…N elements of CuPc thus realizing the best cycling stability. To elucidate the mechanism of improved cycling stability and redox behavior of oxygen, X-ray photoelectron spectroscopy (XPS) measurement is conducted for LM…
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False[305.93, 76.42, 240.96, 41.32]and N ensures the high reaction activity of N element to reduce O2 2 -of LMRO in time, and the effect of Cu is also maintained in the next cycling (Figure S7, Supporting Information), thus realizing the high performance…and N ensures the high reaction activity of N element to reduce O2 2 -of LMRO in time, and the effect of Cu is also maintained in the next cycling (Figure S7, Supporting Information), thus realizing the high performance…
559textbody_candidate_excludedFalsehighinside_back_matterinside_back_matter
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False[305.92, 120.27, 240.96, 139.95]Operando differential electrochemical mass spectrometry (DEMS) was performed to evaluate the gas evolution during the initial cycle. As depicted in Figure 3e, the LMRO electrode displays an obvious O 2 and CO2 generatio…Operando differential electrochemical mass spectrometry (DEMS) was performed to evaluate the gas evolution during the initial cycle. As depicted in Figure 3e, the LMRO electrode displays an obvious O 2 and CO2 generatio…
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False[305.92, 262.73, 240.96, 271.46]Except for the effect on the LMRO surface, the CuPc strategy enhances the oxygen redox in bulk as well. LMRO and LMRO@7CuPc electrodes in different SOC were etched by Ar ion for 20 min to collect the bulk information of…Except for the effect on the LMRO surface, the CuPc strategy enhances the oxygen redox in bulk as well. LMRO and LMRO@7CuPc electrodes in different SOC were etched by Ar ion for 20 min to collect the bulk information of…
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False[305.92, 536.71, 240.97, 183.79]To investigate the structural degradation during cycling, XRD patterns of LMRO and LMRO@7CuPc at selected cycles are compared and shown in Figure S11 and Table S1 (Supporting Information). During the cycling, the diffra…To investigate the structural degradation during cycling, XRD patterns of LMRO and LMRO@7CuPc at selected cycles are compared and shown in Figure S11 and Table S1 (Supporting Information). During the cycling, the diffra…
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False[469.66, 745.82, 77.21, 6.3]©2024 Wiley-VCH GmbH©2024 Wiley-VCH GmbH
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False[47.98, 634.36, 496.06, 35.6]Figure 3. The XPS spectra for LMRO@7CuPc electrode during the first cycle of a) N 1s spectra, b) Cu 2p Spectra. c) Relative atomic ratio of N re and N ox during the first cycle of LMRO@7CuPc electrode. d) Relative atomi…Figure 3. The XPS spectra for LMRO@7CuPc electrode during the first cycle of a) N 1s spectra, b) Cu 2p Spectra. c) Relative atomic ratio of N re and N ox during the first cycle of LMRO@7CuPc electrode. d) Relative atomi…
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False[50.81, 431.36, 496.05, 35.6]Figure 4. a) HAADF-STEM image of LMRO electrode after 500 cycles. b) Atomic-resolution HAADF-STEM image of site A in (a). Inset: FFT image of Figure b. c) Atomic-resolution HAADF-STEM image of site B in (a). d). HAADF-S…Figure 4. a) HAADF-STEM image of LMRO electrode after 500 cycles. b) Atomic-resolution HAADF-STEM image of site A in (a). Inset: FFT image of Figure b. c) Atomic-resolution HAADF-STEM image of site B in (a). d). HAADF-S…
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False[50.81, 492.77, 240.95, 194.74]The better structure stability is also proven by surface-sensitive Raman spectrometry as shown in Figure S12 (Supporting Information). For the pristine LMRO electrode, the peak located at 415 cm -1 is ascribed to A 1g v…The better structure stability is also proven by surface-sensitive Raman spectrometry as shown in Figure S12 (Supporting Information). For the pristine LMRO electrode, the peak located at 415 cm -1 is ascribed to A 1g v…
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False[50.81, 690.03, 240.95, 30.36]Furthermore, Atomic-resolution HAADF-STEM is conducted to investigate the structure evolution on the nanoscale. As shown in Figure 4 a, the LMRO electrode shows a huge morphologyFurthermore, Atomic-resolution HAADF-STEM is conducted to investigate the structure evolution on the nanoscale. As shown in Figure 4 a, the LMRO electrode shows a huge morphology
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False[305.92, 492.77, 240.96, 227.62]change in that the whole particle becomes loose and the surface region becomes rough with jagged edges due to a side reaction with electrolyte. [ 20] It is worse that lots of nanovoids distribute throughout the particle…change in that the whole particle becomes loose and the surface region becomes rough with jagged edges due to a side reaction with electrolyte. [ 20] It is worse that lots of nanovoids distribute throughout the particle…
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False[469.66, 745.82, 77.21, 6.3]©2024 Wiley-VCH GmbH©2024 Wiley-VCH GmbH
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False[47.98, 339.45, 240.96, 337.21]Electron energy loss spectrometry (EELS) is conducted to evaluate the stability of oxygen lattice and valence states evolution of transition metal, and the line scanning spectra from surface to bulk is depicted in Figur…Electron energy loss spectrometry (EELS) is conducted to evaluate the stability of oxygen lattice and valence states evolution of transition metal, and the line scanning spectra from surface to bulk is depicted in Figur…
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False[47.98, 131.23, 240.95, 205.7]Further observation on the surface site C reveals that the CuPc coating layer remains yet and the surface region keeps a welllayered structure (Figure 4e). In the inner bulk (site D, Figure f), LMRO@7CuPc retains an int…Further observation on the surface site C reveals that the CuPc coating layer remains yet and the surface region keeps a welllayered structure (Figure 4e). In the inner bulk (site D, Figure f), LMRO@7CuPc retains an int…
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False[47.98, 75.38, 240.97, 53.33]release or eliminating the surface O 2 2 -will shut down the global oxygen migration and contribute to excellent cycling performance.According to the root origin of oxygen release, CuPc redox couple has been proven to b…release or eliminating the surface O 2 2 -will shut down the global oxygen migration and contribute to excellent cycling performance.According to the root origin of oxygen release, CuPc redox couple has been proven to b…
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False[47.98, 679.17, 240.95, 41.32]Another important effect of CuPc modification is that LMRO@7CuPc forms a more stable, uniform, and robust cathode-electrolyte interface shielding the cathode against electrolyte side reactions and suppressing the transi…Another important effect of CuPc modification is that LMRO@7CuPc forms a more stable, uniform, and robust cathode-electrolyte interface shielding the cathode against electrolyte side reactions and suppressing the transi…
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False[303.09, 76.43, 240.96, 644.06]solution. XPS is conducted to investigate surface compositions of the formed CEI layer for electrodes after 500 cycles as shown in Figure 6 a. The C 1s spectra of both electrodes have four peaks ascribed to C ─ C, C ─ O…solution. XPS is conducted to investigate surface compositions of the formed CEI layer for electrodes after 500 cycles as shown in Figure 6 a. The C 1s spectra of both electrodes have four peaks ascribed to C ─ C, C ─ O…
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False[578.97, 15.65, 4.54, 751.19]16136829, 2024, 37, Downloaded from https://onlinelibrary.wiley.com/doi/10.1002/smll.202401645 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley.com/ter…
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False[50.81, 671.35, 496.07, 35.6]Figure 5. a-c) EELS line scanning from the surface into the bulk of the LMRO electrode after 500 cycles. d-f) EELS line scanning from the surface into the bulk of LMRO@7CuPc electrode after 500 cycles. The corresponding…Figure 5. a-c) EELS line scanning from the surface into the bulk of the LMRO electrode after 500 cycles. d-f) EELS line scanning from the surface into the bulk of LMRO@7CuPc electrode after 500 cycles. The corresponding…
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False[47.98, 578.25, 496.07, 45.07]Figure 6. a) C 1s, O 1s, P 2p, and F 1s high-resolution XPS spectra of LMRO (top) and LMRO@7CuPc (bottom) after 500 cycles. b) TOF-SIMS investigations CEI structure after 500 cycles. The mapping for LiF -, C2 HO -, C2 H…Figure 6. a) C 1s, O 1s, P 2p, and F 1s high-resolution XPS spectra of LMRO (top) and LMRO@7CuPc (bottom) after 500 cycles. b) TOF-SIMS investigations CEI structure after 500 cycles. The mapping for LiF -, C2 HO -, C2 H…
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False[47.98, 646.19, 240.97, 74.2]metal dissolution quantificationally. The dissolution ratios of Ni, Co, and Mn for LMRO electrode are as high as 1.177, 0.831, and 1.937 wt%, respectively, while the corresponding dissolution ratios of TM elements for L…metal dissolution quantificationally. The dissolution ratios of Ni, Co, and Mn for LMRO electrode are as high as 1.177, 0.831, and 1.937 wt%, respectively, while the corresponding dissolution ratios of TM elements for L…
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False[303.09, 646.19, 240.95, 74.2]of cationic redox reaction thus maintaining electrode capacity. The above results demonstrate that the CuPc strategy can effectively restrain the decomposition of electrolytes and induce the formation of a more uniform …of cationic redox reaction thus maintaining electrode capacity. The above results demonstrate that the CuPc strategy can effectively restrain the decomposition of electrolytes and induce the formation of a more uniform …
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False[50.81, 76.58, 64.45, 10.25]3. Conclusion3. Conclusion
11110textbodyTruebodybody
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False[50.81, 95.93, 240.96, 282.43]In summary, we first develop CuPc as a redox couple to LMRO cathode by a facile and effective method and realize outstanding electrochemical performance with improved capacity and voltage stability. The LMRO@7CuPc maint…In summary, we first develop CuPc as a redox couple to LMRO cathode by a facile and effective method and realize outstanding electrochemical performance with improved capacity and voltage stability. The LMRO@7CuPc maint…
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False[50.81, 410.45, 111.91, 10.25]4. Experimental Section4. Experimental Section
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False[50.81, 429.0, 240.96, 111.54]Synthesis of Samples : The Li 1.2 Ni 0.13 Co 0.13 Mn0.54 O 2 material was synthesized by spray pyrolysis followed by high-temperature calcination. Lithium acetate dihydrate (LiAC · 2H2 O, AR), manganese acetate tetrahyd…Synthesis of Samples : The Li 1.2 Ni 0.13 Co 0.13 Mn0.54 O 2 material was synthesized by spray pyrolysis followed by high-temperature calcination. Lithium acetate dihydrate (LiAC · 2H2 O, AR), manganese acetate tetrahyd…
11113textbodyTruebodybody
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False[50.81, 542.57, 240.97, 158.86]Preparation of Electrodes : LMRO(1.6 g) and conductive additive Super P (TIMCAL) (0.2 g) were mixed via the ball-milling method in a stainlesssteel ball mill jar (120 mL) adding tungsten carbide balls (108 g) and ethano…Preparation of Electrodes : LMRO(1.6 g) and conductive additive Super P (TIMCAL) (0.2 g) were mixed via the ball-milling method in a stainlesssteel ball mill jar (120 mL) adding tungsten carbide balls (108 g) and ethano…
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False[50.81, 703.48, 240.95, 18.12]Material Structure Characterizations : XRD analysis was performed on a Mini Flex 600 X-ray diffractometer (Rigaku, Japan) with Cu-K /u1D6FC radiationMaterial Structure Characterizations : XRD analysis was performed on a Mini Flex 600 X-ray diffractometer (Rigaku, Japan) with Cu-K /u1D6FC radiation
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False[578.97, 15.65, 4.54, 751.19]16136829, 2024, 37, Downloaded from https://onlinelibrary.wiley.com/doi/10.1002/smll.202401645 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley.com/ter…
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False[459.64, 50.12, 87.21, 8.02]www.small-journal.com
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False[305.92, 77.35, 240.97, 205.96]operating at a voltage of 40 kV and current of 15 mA with 2 /u1D703 ranging from 10 ° to 60 ° at a scan rate of 1 ° min -1 . Rietveld refinements of the XRD data were carried out by a General Structure Analysis System (…operating at a voltage of 40 kV and current of 15 mA with 2 /u1D703 ranging from 10 ° to 60 ° at a scan rate of 1 ° min -1 . Rietveld refinements of the XRD data were carried out by a General Structure Analysis System (…
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False[305.92, 285.35, 240.97, 111.54]Electrochemical Measurements : The electrochemical performance was characterized by 2025 coin-type cells. These cells were assembled in an Arfilled glove box (water and oxygen content < 0.1 ppm) with lithium metal foil …Electrochemical Measurements : The electrochemical performance was characterized by 2025 coin-type cells. These cells were assembled in an Arfilled glove box (water and oxygen content < 0.1 ppm) with lithium metal foil …
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False[305.93, 412.38, 112.02, 10.25]Supporting InformationSupporting Information
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False[305.93, 431.16, 240.96, 16.67]Supporting Information is available from the Wiley Online Library or from the author.Supporting Information is available from the Wiley Online Library or from the author.
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False[305.93, 463.33, 92.58, 10.25]AcknowledgementsAcknowledgements
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False[305.93, 482.11, 240.97, 54.52]Z.J.W. and C.H.Y. contributed equally to this work. The authors gratefully acknowledge the financial support from the National Key Research and Development Program of China (2022YFB2502000), the National Natural Science…Z.J.W. and C.H.Y. contributed equally to this work. The authors gratefully acknowledge the financial support from the National Key Research and Development Program of China (2022YFB2502000), the National Natural Science…
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False[305.93, 552.14, 87.65, 10.25]Conflict of InterestConflict of Interest
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False[305.93, 570.91, 139.61, 7.2]The authors declare no conflict of interest.The authors declare no conflict of interest.
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False[305.93, 593.62, 128.2, 10.25]Data Availability StatementData Availability Statement
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False[305.93, 612.4, 240.92, 16.66]The data that support the findings of this study are available from the corresponding author upon reasonable request.The data that support the findings of this study are available from the corresponding author upon reasonable request.
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False[305.93, 644.57, 45.87, 10.25]KeywordsKeywords
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False[305.93, 663.35, 240.92, 16.66]copper phthalocyanine, Cu-N synergism, cycling stability, Li- and Mn-rich layered oxide, redox couplecopper phthalocyanine, Cu-N synergism, cycling stability, Li- and Mn-rich layered oxide, redox couple
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False[466.44, 694.23, 80.44, 7.2]Received: March 2, 2024Received: March 2, 2024
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False[471.82, 703.7, 75.05, 7.2]Revised: April 27, 2024Revised: April 27, 2024
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False[443.73, 713.17, 103.15, 7.2]Published online: May 19, 2024Published online: May 19, 2024
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False[469.66, 745.82, 77.21, 6.3]©2024 Wiley-VCH GmbH©2024 Wiley-VCH GmbH
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