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Summary

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Page Overlays

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Visual Assets

这里对齐真实图表资产提取链路。caption_source=embedded_table_cell 表示表注来自 Docling table cell,不会出现在 text block 审计差集里;caption_continuation_used_by_asset 表示某个 text block 已被图表 caption 吸收,不应按普通 metadata 解读。

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1figureFig. 12direct_caption_ref0.82[107.21, 75.21, 380.04, 625.13]Fig. 1. Powder XRD patterns (a) and the (003) peaks (b) of LLNCMO and LTO@LLNCMO. SEM images of LLNCMO (c) and LTO@LLNCMO (d). TEM images of LLNCMO (e) and LTO@LLNCMO (f). HRTEM images of LLNCMO (g) and LTO@LLNCMO (h)
2figureFig. 23direct_caption_ref0.82[39.22, 58.99, 247.87, 331.03]Fig. 2. HADDF-STEM images of LLNCMO (a) and LTO@LLNCMO (f) particles and the corresponding element mapping: (b, g) Ni, (c, h) Co, (d, i) Mn, (e, j) O, (k) Ti.
3figureFig. 33direct_caption_ref0.82[146.34, 435.6, 301.87, 276.16]Fig. 3. (a) Atomic scale HAADF-STEM images of LLNCMO particles and the corresponding FFT pattern (the inset image). (b) Atomic scale HAADF-STEM image of LTO@LLNCMO sample; (c,d) the enlarged view of red region from (b) and the corresponding FFT pattern, which show the layered structure of LLNCMO; (e,f) the enlarged view of the coating layer (blue region from (b)) and the corresponding FFT pattern, which show the spinel structure of LTO. (g) The scheme of lithium ions through ultrathin LTO coating.
4figureFig. 44direct_caption_ref0.82[308.03, 56.76, 243.7, 583.81]Fig. 4. XPS peaks of (a) Mn3s; (b) O1s; (c) Ti2p in LLNCMO and LTO@LLNCMO.
5figureFig. 55direct_caption_ref0.82[51.68, 57.56, 490.53, 376.52]Fig. 5. The electrochemical performances of LLNCMO and LTO@LLNCMO cathodes: (a) the charge and discharge curves in the first three cycles at 0.1 C (1 C = 200 mA g -1 ); (b) the cycle life at 0.1 C; (c) the long term cycling at 2 C and the voltage fading, each point represents the average value of ten cycles; (d) the rate capability at different current densities.

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False[242.54, 37.5, 110.26, 6.03]Scripta Materialia 204 (2021) 114133Scripta Materialia 204 (2021) 114133
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False[37.6, 168.82, 414.99, 47.21]Stabilizing voltage and prolonge d cycling life of Li-rich Mn-base d oxides through spinel 'lithium ion pump' heteroepitaxial coating strategyStabilizing voltage and prolonge d cycling life of Li-rich Mn-base d oxides through spinel 'lithium ion pump' heteroepitaxial coating strategy
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False[37.6, 226.09, 411.98, 24.77]Jili Li a , ∗ , Tiekun Jia a , ∗ , Chunjuan Tang a , Dongsheng Yu a , ∗ , Jie Sun a , Wanzhen Zhang a , Yujiang Wang a , Joong Hee Lee b , Nam Hoon Kim bJili Li a , ∗ , Tiekun Jia a , ∗ , Chunjuan Tang a , Dongsheng Yu a , ∗ , Jie Sun a , Wanzhen Zhang a , Yujiang Wang a , Joong Hee Lee b , Nam Hoon Kim b
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False[37.6, 258.41, 434.75, 24.05]a Material Science and Engineering School, Henan Province International Joint Laboratory of Materials for Solar Energy Conversion and Lithium Sodium based Battery & Henan Key Laboratory of Special Protective Materials, …a Material Science and Engineering School, Henan Province International Joint Laboratory of Materials for Solar Energy Conversion and Lithium Sodium based Battery & Henan Key Laboratory of Special Protective Materials, …
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False[37.6, 378.69, 82.25, 31.74]Keywords: Heteroepitaxial coating Lithium-rich layered oxides Voltage fadingKeywords: Heteroepitaxial coating Lithium-rich layered oxides Voltage fading
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False[37.6, 328.62, 70.32, 40.31]Article history: Received 8 April 2021 Revised 15 June 2021 Accepted 30 June 2021 Available online 17 JulyArticle history: Received 8 April 2021 Revised 15 June 2021 Accepted 30 June 2021 Available online 17 July
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False[202.01, 329.43, 356.22, 102.43]The practical application of Li-rich layered oxides is impeded by its cycle instability, poor rate capability and serious voltage decay. Here, nano-sized spinel Li 4 Ti 5 O 12 (LTO) is constructed on Li 1.2 Ni 0.13 Co 0…The practical application of Li-rich layered oxides is impeded by its cycle instability, poor rate capability and serious voltage decay. Here, nano-sized spinel Li 4 Ti 5 O 12 (LTO) is constructed on Li 1.2 Ni 0.13 Co 0…
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False[309.72, 438.62, 248.3, 6.79]© 2021 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.© 2021 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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False[37.6, 476.5, 251.41, 164.46]With the rapid expansion of portable electronics, electric vehicles and power grid, the existing lithium-ion batteries (LIBs) as an important power source urgently need to be ameliorated. [ 1 , 2 ] Especially, the insuf…With the rapid expansion of portable electronics, electric vehicles and power grid, the existing lithium-ion batteries (LIBs) as an important power source urgently need to be ameliorated. [ 1 , 2 ] Especially, the insuf…
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False[37.6, 643.88, 251.34, 18.0]It has been proved that surface coating is a simple and efficient remedy to reform the interfacial stability. [18-27] Although inertIt has been proved that surface coating is a simple and efficient remedy to reform the interfacial stability. [18-27] Although inert
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False[43.74, 684.84, 75.35, 7.81]∗ Corresponding authors.∗ Corresponding authors.
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False[37.61, 695.14, 251.24, 14.6]E-mail addresses: lijili328@126.com (J. Li), tiekunjia@126.com (T. Jia), dongsh_yu@163.com (D. Yu).E-mail addresses: lijili328@126.com (J. Li), tiekunjia@126.com (T. Jia), dongsh_yu@163.com (D. Yu).
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False[37.6, 738.23, 254.47, 6.03]1359-6462/© 2021 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.1359-6462/© 2021 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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False[306.6, 476.5, 251.4, 227.21]surface coatings, including some oxides, [18] fluorides [19] and phosphates [ 20 , 21 ] etc. can enhance the cyclic stability and power performance of LLOs partly, the lattice structures mismatch with the host LLO mater…surface coatings, including some oxides, [18] fluorides [19] and phosphates [ 20 , 21 ] etc. can enhance the cyclic stability and power performance of LLOs partly, the lattice structures mismatch with the host LLO mater…
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False[37.6, 710.33, 520.77, 14.6]Fig. 1. Powder XRD patterns (a) and the (003) peaks (b) of LLNCMO and LTO@LLNCMO. SEM images of LLNCMO (c) and LTO@LLNCMO (d). TEM images of LLNCMO (e) and LTO@LLNCMO (f). HRTEM images of LLNCMO (g) and LTO@LLNCMO (h)Fig. 1. Powder XRD patterns (a) and the (003) peaks (b) of LLNCMO and LTO@LLNCMO. SEM images of LLNCMO (c) and LTO@LLNCMO (d). TEM images of LLNCMO (e) and LTO@LLNCMO (f). HRTEM images of LLNCMO (g) and LTO@LLNCMO (h)
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False[451.4, 37.29, 106.57, 6.03]Scripta Materialia 204 (2021) 114133Scripta Materialia 204 (2021) 114133
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False[306.6, 57.94, 251.38, 112.15]In animals and plants, there are some special carrier proteins called 'Ion pump' which can drive specific ions such as Na + , K + , Ca 2 + and H + across plasmolemma. Spinel Li 4 Ti 5 O 12 (LTO) with high Li + diffusion…In animals and plants, there are some special carrier proteins called 'Ion pump' which can drive specific ions such as Na + , K + , Ca 2 + and H + across plasmolemma. Spinel Li 4 Ti 5 O 12 (LTO) with high Li + diffusion…
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False[306.6, 173.01, 251.38, 143.53]In this paper, a heteroepitaxial composite of 'lithium ion pump' LTO coated on Li 1.2 Ni 0.13 Co 0.13 Mn 0.54 O 2 (LLNCMO) was designed and synthesized. It is demonstrated that the nanoscale LTO coating with the integra…In this paper, a heteroepitaxial composite of 'lithium ion pump' LTO coated on Li 1.2 Ni 0.13 Co 0.13 Mn 0.54 O 2 (LLNCMO) was designed and synthesized. It is demonstrated that the nanoscale LTO coating with the integra…
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False[37.6, 399.35, 251.36, 14.6]Fig. 2. HADDF-STEM images of LLNCMO (a) and LTO@LLNCMO (f) particles and the corresponding element mapping: (b, g) Ni, (c, h) Co, (d, i) Mn, (e, j) O, (k) Ti.Fig. 2. HADDF-STEM images of LLNCMO (a) and LTO@LLNCMO (f) particles and the corresponding element mapping: (b, g) Ni, (c, h) Co, (d, i) Mn, (e, j) O, (k) Ti.
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False[306.6, 319.45, 251.42, 91.23]X-ray diffraction (XRD) was carried out to investigate the structure of bare LLNCMO and LTO-coated LLNCMO materials, results are shown in Fig. 1 a and b. All sharp reflections in the XRD patterns can be assigned to the …X-ray diffraction (XRD) was carried out to investigate the structure of bare LLNCMO and LTO-coated LLNCMO materials, results are shown in Fig. 1 a and b. All sharp reflections in the XRD patterns can be assigned to the …
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False[37.6, 721.09, 520.77, 23.17]Fig. 3. (a) Atomic scale HAADF-STEM images of LLNCMO particles and the corresponding FFT pattern (the inset image). (b) Atomic scale HAADF-STEM image of LTO@LLNCMO sample; (c,d) the enlarged view of red region from (b) …Fig. 3. (a) Atomic scale HAADF-STEM images of LLNCMO particles and the corresponding FFT pattern (the inset image). (b) Atomic scale HAADF-STEM image of LTO@LLNCMO sample; (c,d) the enlarged view of red region from (b) …
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False[37.6, 37.29, 69.91, 6.03]J. Li, T. Jia, C. Tang et al.J. Li, T. Jia, C. Tang et al.
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False[37.6, 57.94, 251.34, 38.92]LLNCMO material. In the enlarged display of the (003) peaks ( Fig. 1 b), the peaks of the coated LTO@LLNCMO material obviously shifts to lower values illustrating the increase of c axis, which is beneficial for the Li-i…LLNCMO material. In the enlarged display of the (003) peaks ( Fig. 1 b), the peaks of the coated LTO@LLNCMO material obviously shifts to lower values illustrating the increase of c axis, which is beneficial for the Li-i…
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False[37.6, 99.78, 251.42, 206.3]The morphologies and microstructures of as-prepared materials were observed in SEM and TEM images to confirm the influence of LTO surface modification on the morphology, they are shown in Fig. 1 c-h. SEM images demonstr…The morphologies and microstructures of as-prepared materials were observed in SEM and TEM images to confirm the influence of LTO surface modification on the morphology, they are shown in Fig. 1 c-h. SEM images demonstr…
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False[37.6, 309.0, 251.46, 258.6]Atomic scale HAADF-STEM was used to clarify the surface and interface structures before and after LTO-coating LLNCMO materials, results are shown in Fig. 3 . For bare LLNCMO material ( Fig. 3 a), it is demonstrated that…Atomic scale HAADF-STEM was used to clarify the surface and interface structures before and after LTO-coating LLNCMO materials, results are shown in Fig. 3 . For bare LLNCMO material ( Fig. 3 a), it is demonstrated that…
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False[37.6, 570.52, 251.46, 180.93]XPS measurements were applied to characterize the surface compositions and chemical states of the transition metal ions and oxygen on the bare LLNCMO and LTO-coated LTO@LLNCMO materials, as shown in Figs. S1 and 4. Comp…XPS measurements were applied to characterize the surface compositions and chemical states of the transition metal ions and oxygen on the bare LLNCMO and LTO-coated LTO@LLNCMO materials, as shown in Figs. S1 and 4. Comp…
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False[306.6, 684.38, 251.49, 61.54]Mn 4 + ions or oxygen vacancies are engendered in the synthetic process. [27] After LTO-modification, the average oxidation states of Mn ions in LTO@LLNCMO material still maintain about + 3.77 with the same level in LLN…Mn 4 + ions or oxygen vacancies are engendered in the synthetic process. [27] After LTO-modification, the average oxidation states of Mn ions in LTO@LLNCMO material still maintain about + 3.77 with the same level in LLN…
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False[312.58, 650.0, 239.45, 6.03]Fig. 4. XPS peaks of (a) Mn3s; (b) O1s; (c) Ti2p in LLNCMO and LTO@LLNCMO.Fig. 4. XPS peaks of (a) Mn3s; (b) O1s; (c) Ti2p in LLNCMO and LTO@LLNCMO.
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False[37.6, 37.29, 69.91, 6.03]J. Li, T. Jia, C. Tang et al.J. Li, T. Jia, C. Tang et al.
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False[451.4, 37.29, 106.57, 6.03]Scripta Materialia 204 (2021) 114133Scripta Materialia 204 (2021) 114133
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False[37.6, 444.89, 520.91, 24.27]Fig. 5. The electrochemical performances of LLNCMO and LTO@LLNCMO cathodes: (a) the charge and discharge curves in the first three cycles at 0.1 C (1 C = 200 mA g -1 ); (b) the cycle life at 0.1 C; (c) the long term cyc…Fig. 5. The electrochemical performances of LLNCMO and LTO@LLNCMO cathodes: (a) the charge and discharge curves in the first three cycles at 0.1 C (1 C = 200 mA g -1 ); (b) the cycle life at 0.1 C; (c) the long term cyc…
547textabstract_candidateFalsemediuminside_abstractinside_abstract
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False[37.6, 494.63, 251.42, 71.87]crystal lattice and impurity lithium oxides on the surface of the layered cathode materials, respectively. [ 27 , 32 ] Compared to the O1s spectra in LLNCMO material, the peak at 533.97 eV disappears indicating more exc…crystal lattice and impurity lithium oxides on the surface of the layered cathode materials, respectively. [ 27 , 32 ] Compared to the O1s spectra in LLNCMO material, the peak at 533.97 eV disappears indicating more exc…
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False[37.6, 567.85, 251.46, 174.92]Fig. 5 displays the electrochemical performance of LLNCMO materials before and after LTO heteroepitaxial coating. The first three charge and discharge curves at 0.1 C (1 C = 200 mA g -1 ) are shown in Fig. 5 a. For bare…Fig. 5 displays the electrochemical performance of LLNCMO materials before and after LTO heteroepitaxial coating. The first three charge and discharge curves at 0.1 C (1 C = 200 mA g -1 ) are shown in Fig. 5 a. For bare…
549textabstract_candidateFalsemediuminside_abstractinside_abstract
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False[306.6, 494.63, 251.45, 248.14]To examine the variation of cycling stability and the voltage decay of LLNCMO modified by ultrathin LTO heteroepitaxial coating layer at high current density, the charge and discharge of LLNCMO and LTO@LLNCMO cathodes a…To examine the variation of cycling stability and the voltage decay of LLNCMO modified by ultrathin LTO heteroepitaxial coating layer at high current density, the charge and discharge of LLNCMO and LTO@LLNCMO cathodes a…
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False[295.78, 760.5, 3.69, 6.03]55
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False[37.6, 37.29, 69.91, 6.03]J. Li, T. Jia, C. Tang et al.J. Li, T. Jia, C. Tang et al.
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False[37.6, 57.94, 251.37, 143.53]respectively. Except for at 0.1 C, the average discharge capacities of the LTO-coated cathode are all enhanced at every current density. Specifically, the average discharge capacity of LTO@LLNCMO cathode is 104.7 mAh g …respectively. Except for at 0.1 C, the average discharge capacities of the LTO-coated cathode are all enhanced at every current density. Specifically, the average discharge capacity of LTO@LLNCMO cathode is 104.7 mAh g …
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False[37.6, 204.39, 251.41, 143.53]To further understand the redox process, cyclic voltammetry (CV) was done between 2.0 and 4.8 V with 0.1 mV s -1 (Fig. S3). The redox peaks of LLNCMO and LTO@LLNCMO cathodes both are consistent with the reported Li 1.2 …To further understand the redox process, cyclic voltammetry (CV) was done between 2.0 and 4.8 V with 0.1 mV s -1 (Fig. S3). The redox peaks of LLNCMO and LTO@LLNCMO cathodes both are consistent with the reported Li 1.2 …
654textabstract_candidateFalsemediuminside_abstractinside_abstract
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False[37.6, 350.84, 251.4, 174.92]The kinetics of electrochemical reaction in LLNCMO and LTO@LLNCMO cathodes can be surveyed by electrochemical impedance spectroscopy. The Nyquist plots before and after 50 cycles at 0.1 C fitted with equivalent circuit …The kinetics of electrochemical reaction in LLNCMO and LTO@LLNCMO cathodes can be surveyed by electrochemical impedance spectroscopy. The Nyquist plots before and after 50 cycles at 0.1 C fitted with equivalent circuit …
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False[37.6, 528.67, 251.38, 206.3]In summary, we designed a spinel Li 4 Ti 5 O 12 nano-sized coating on the surface of Li 1.2 Ni 0.13 Co 0.13 Mn 0.54 O 2 material to alleviate the inferior electrochemical performances, especially serious voltage loss. T…In summary, we designed a spinel Li 4 Ti 5 O 12 nano-sized coating on the surface of Li 1.2 Ni 0.13 Co 0.13 Mn 0.54 O 2 material to alleviate the inferior electrochemical performances, especially serious voltage loss. T…
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False[451.4, 37.29, 106.57, 6.03]Scripta Materialia 204 (2021) 114133Scripta Materialia 204 (2021) 114133
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False[306.6, 57.94, 133.49, 7.54]Declaration of Competing InterestDeclaration of Competing Interest
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False[306.6, 78.86, 251.29, 28.47]The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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False[306.6, 121.03, 71.83, 7.54]AcknowledgementAcknowledgement
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False[306.6, 141.96, 251.35, 49.38]This work was supported by the National Natural Science Foundation of China ( 51702148 , 51802139 ), Henan Science and Technology Research Program ( 182102410074 , 172102410047 ) and the Training Plan of Young Backbone …This work was supported by the National Natural Science Foundation of China ( 51702148 , 51802139 ), Henan Science and Technology Research Program ( 182102410074 , 172102410047 ) and the Training Plan of Young Backbone …
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False[306.6, 205.05, 98.28, 7.54]Supplementary materialsSupplementary materials
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False[306.6, 225.97, 251.28, 28.47]Supplementary material associated with this article can be found, in the online version, at doi: 10.1016/j.scriptamat.2021. 114133 .Supplementary material associated with this article can be found, in the online version, at
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