Excluded Docling blocks

这里是差集：Docling 全量解析 text block 减去最终会进入正文的 block。优先人工检查 risk=high / medium。

layout_review.html excluded_blocks.json excluded_blocks.tsv final_body_blocks.tsv visual_assets.tsv original.pdf

Diff Summary

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Truncation

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Excluded Page Overlays

这些框显示被排除块，同时叠加真实图表资产框。青色虚线表示该 text block 被图表资产 caption 吸收；红色 STOP 是截断触发点，红色框是截断后被排除的块。

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Visual Assets

这是实际图表资产输出，不是审计层重新推断。

#	type	label	page	caption source	confidence	bbox	caption
1	figure	Fig. 1	3	direct_caption_ref	0.82	[146.03, 61.95, 249.17, 173.37]	Fig. 1. XRD patterns of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2.
2	figure	Fig. 2	4	direct_caption_ref	0.82	[57.05, 61.21, 433.75, 492.05]	Fig. 2. SEM images of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2. x = (a) 1.0, (b) 0.9, (c) 0.7, (d) 0.5, (e) 0.3 and (f) 0.1.
3	figure	Fig. 3	5	direct_caption_ref	0.82	[152.06, 60.67, 235.65, 365.55]	Fig. 3. First charge/discharge curves of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2.
4	figure	Fig. 4	6	direct_caption_ref	0.82	[153.24, 61.51, 242.42, 376.61]	Fig. 4. (a) Electrochemical properties of mixed compounds ofLi2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2: ( & ) charge capacity and ( * ) discharge capacity. (b) Electrochemical properties of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2: ( & ) capacity retention and ( * ) initial capacity loss.
5	figure	Fig. 5	7	nearby_text_caption	0.82	[149.33, 61.61, 239.86, 178.42]	Fig. 5. Cycle performance of the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound after fifty cycles.
6	figure	Fig. 6	7	direct_caption_ref	0.82	[150.56, 282.17, 238.63, 173.87]	Fig. 6. Cyclic voltammograms of the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound. Scan rate is 0.1 mV/s. The voltage range is 2.0 -4.8 V.
7	figure	Fig. 7	7	direct_caption_ref	0.82	[149.22, 492.89, 240.55, 174.41]	Fig. 7. Voltage profile of the cell during two cycles. Representative scans of XANES measurements are indicated.
8	figure	Fig. 8	8	direct_caption_ref	0.82	[151.76, 60.75, 244.92, 557.46]	Fig. 8. (a) Mn K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during the first charge process. (b) Co K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during the first charge process. (c) Ni K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during the first charge process.
9	figure	Fig. 9	9	direct_caption_ref	0.82	[149.93, 61.61, 240.7, 543.61]	Fig. 9. (a) Mn K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during 2 cycles. (b) Co K-edge XANES spectra for the Li[Li1/ 6Mn1/2Ni1/6Co1/6]O2 compound during 2 cycles. (c) Ni K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during 2 cycles.
10	table	Docling Table 10	2	missing_caption	0.55	[40.11, 83.95, 467.97, 62.92]

Excluded Blocks

risk	page	order	label	role	reason	parser reason	trunc	region	bg	bbox	raw text	cleaned text
medium	10	70	text	body_candidate_excluded	after_back_matter_stop	after_back_matter_stop	after_stop	p10:body_zone:left_crossing:white	[255, 255, 255] white	[53.07, 411.17, 240.66, 8.69]	Experiments at PLS were supported in part by POSTECH.	Experiments at PLS were supported in part by POSTECH.
low	1	0	text	body_heading	before_body_started	before_body_started		p1:front_matter:left_crossing:white	[255, 255, 255] white	[171.89, 99.61, 163.34, 6.95]	Materials Research Bulletin 43 (2008) 3543 -3552	Materials Research Bulletin 43 (2008) 3543 -3552
low	1	1	text	metadata	document_web_address	document_web_address		p1:front_matter:right:white	[255, 255, 255] white	[391.75, 109.07, 111.36, 6.95]	www.elsevier.com/locate/matresbu
low	1	2	section_header	body_heading	first_page_front_matter_heading	first_page_front_matter_heading		p1:front_matter:full:white	[255, 255, 255] white	[50.12, 143.16, 439.71, 54.63]	Electrochemical behaviors of Li[Li(1 x )/3Mn(2 x )/3Ni x /3Co x /3]O2 cathode series (0 < x < 1) synthesized by sucrose combustion process for high capacity lithium ion batteries	Electrochemical behaviors of Li[Li(1 x )/3Mn(2 x )/3Ni x /3Co x /3]O2 cathode series (0 < x < 1) synthesized by sucrose combustion process for high capacity lithium ion batteries
low	1	3	text	affiliation	first_page_author_or_affiliation	first_page_author_or_affiliation		p1:front_matter:left_crossing:white	[255, 255, 255] white	[91.16, 207.17, 357.6, 14.17]	Gu-Yeon Kim a, * , Seung-Beob Yi b , Yong Joon Park c , Ho-Gi Kim a	Gu-Yeon Kim a, * , Seung-Beob Yi b , Yong Joon Park c , Ho-Gi Kim a
low	1	4	text	affiliation	first_page_author_or_affiliation	first_page_author_or_affiliation		p1:front_matter:full:white	[255, 255, 255] white	[59.19, 227.9, 418.91, 18.57]	a Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701, Republic of Korea	a Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701, Republic of Korea
low	1	5	text	affiliation	first_page_author_or_affiliation	first_page_author_or_affiliation		p1:front_matter:left_crossing:white	[255, 255, 255] white	[115.03, 247.86, 307.31, 8.59]	b Energy Business Division Development Team, SAMSUNG SDI, 508 Sungsung-dong, Chenan,	b Energy Business Division Development Team, SAMSUNG SDI, 508 Sungsung-dong, Chenan,
low	1	6	text	affiliation	first_page_author_or_affiliation	first_page_author_or_affiliation		p1:front_matter:left_crossing:white	[255, 255, 255] white	[189.24, 259.66, 161.46, 6.77]	Chungcheongnam-do 330-300, Republic of Korea	Chungcheongnam-do 330-300, Republic of Korea
low	1	7	text	affiliation	first_page_author_or_affiliation	first_page_author_or_affiliation		p1:front_matter:left_crossing:white	[255, 255, 255] white	[95.64, 267.76, 346.04, 8.65]	c Division of Advanced Industrial Engineering, Kyonggi University, 94-6 Yiui-dong, Yeongtong-gu, Suwon,	c Division of Advanced Industrial Engineering, Kyonggi University, 94-6 Yiui-dong, Yeongtong-gu, Suwon,
low	1	8	text	affiliation	first_page_author_or_affiliation	first_page_author_or_affiliation		p1:front_matter:left_crossing:white	[255, 255, 255] white	[219.35, 279.56, 101.26, 6.77]	Kyonggi-do, Republic of Korea	Kyonggi-do, Republic of Korea
low	1	9	text	reference	first_page_metadata	first_page_metadata		p1:front_matter:left_crossing:white	[255, 255, 255] white	[105.45, 292.47, 329.04, 16.93]	Received 9 November 2007; received in revised form 21 December 2007; accepted 17 January 2008 Available online 29 January 2008	Received 9 November 2007; received in revised form 21 December 2007; accepted 17 January 2008 Available online 29 January 2008
low	1	10	section_header	abstract_heading	abstract_heading	abstract_heading		p1:front_matter:left:white	[255, 255, 255] white	[36.85, 329.56, 33.31, 7.9]	Abstract	Abstract
low	1	11	text	reference	first_page_summary	first_page_summary		p1:front_matter:full:white	[255, 255, 255] white	[36.85, 346.64, 466.27, 73.59]	A mixed cathode material between Li2MnO3 and Li[Mn1/3Ni1/3Co1/3]O2 for high capacity lithium secondary batteries was introduced in this study. It was prepared using the sucrose combustion process because this is a simple process. The oxidation states (1 x )/3Mn(2 x )/3Ni x /3Co x /3]O2 compounds were confirmed to be tetravalent, trivalent and divalent, respectively, via XANES measurements. Electrochemical charge/discharge studies showed that the highest first discharge capacity of 224 mAh/g was obtained in composition of x = 0.5 at a 0.2 C rate. The oxidation state of the Co and Ni ions in the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 changed to higher oxidation states, but that of the Mn ions did not change. # 2008 Elsevier Ltd. All rights reserved.	A mixed cathode material between Li2MnO3 and Li[Mn1/3Ni1/3Co1/3]O2 for high capacity lithium secondary batteries was introduced in this study. It was prepared using the sucrose combustion process because this is a simple process. The oxidation states (1 x )/3Mn(2 x )/3Ni x /3Co x /3]O2 compounds were confirmed to be tetravalent, trivalent and divalent, respectively, via XANES measurements. Electrochemical charge/discharge studies showed that the highest first discharge capacity of 224 mAh/g was obtained in composition of x = 0.5 at a 0.2 C rate. The oxidation state of the Co and Ni ions in the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 changed to higher oxidation states, but that of the Mn ions did not change. # 2008 Elsevier Ltd.
low	1	12	text	front_matter_heading	front_matter_heading	front_matter_heading		p1:front_matter:full:white	[255, 255, 255] white	[36.85, 431.43, 408.25, 6.95]	Keywords: A. Inorganic compounds; B. Chemical synthesis; C. XAFS (EXAFS and XANES); D. Electrochemical properties	Keywords: A. Inorganic compounds; B. Chemical synthesis; C. XAFS (EXAFS and XANES); D. Electrochemical properties
low	1	13	section_header	body_heading	body_heading	body_heading		p1:body_zone:left:white	[255, 255, 255] white	[36.85, 473.51, 66.61, 8.78]	1. Introduction	1. Introduction
low	1	16	footnote	footnote	first_page_metadata	first_page_metadata		p1:body_zone:left:white	[255, 255, 255] white	[41.39, 633.6, 172.87, 16.93]	* Corresponding author. Fax: +82 42 869 8650. E-mail address: antiserra@kaist.ac.kr (G.-Y. Kim).	* Corresponding author. Fax: +82 42 869 8650. E-mail address: antiserra@kaist.ac.kr (G.-Y. Kim).
low	1	17	page_footer	page_footer	first_page_metadata	first_page_metadata		p1:body_zone:left_crossing:white	[255, 255, 255] white	[36.85, 665.33, 240.11, 17.06]	0025-5408/$ -see front matter # 2008 Elsevier Ltd. All rights reserved. doi:10.1016/j.materresbull.2008.01.011	0025-5408/$ -see front matter # 2008 Elsevier Ltd. All rights reserved. doi:10.1016/j.materresbull.2008.01.011
low	2	18	page_header	page_header	docling_page_header	docling_page_header		p2:top_margin:left:white	[255, 255, 255] white	[41.16, 45.41, 15.94, 6.95]	3544	3544
low	2	19	page_header	page_header	docling_page_header	docling_page_header		p2:top_margin:right_crossing:white	[255, 255, 255] white	[164.3, 45.41, 219.98, 6.95]	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552
low	2	20	caption	caption	outside_body_flow_caption	outside_body_flow_caption		p2:front_matter:left_crossing:white	[255, 255, 255] white	[41.16, 63.78, 274.88, 16.93]	Table 1 c/a values, lattice parameters and theoretical capacity of layered oxide compositions	Table 1 c/a values, lattice parameters and theoretical capacity of layered oxide compositions
low	2	24	section_header	body_heading	body_heading	body_heading		p2:body_zone:left:white	[255, 255, 255] white	[41.16, 363.19, 70.77, 8.78]	2. Experimental	2. Experimental
low	2	26	section_header	body_heading	body_heading	body_heading		p2:body_zone:left:white	[255, 255, 255] white	[41.16, 638.15, 109.24, 8.78]	3. Results and discussion	3. Results and discussion
low	3	28	page_header	page_header	docling_page_header	docling_page_header		p3:top_margin:left_crossing:white	[255, 255, 255] white	[159.99, 45.41, 219.98, 6.95]	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552
low	3	29	page_header	page_header	docling_page_header	docling_page_header		p3:top_margin:right:white	[255, 255, 255] white	[487.22, 45.41, 15.94, 6.95]	3545	3545
low	3	30	caption	caption	outside_body_flow_caption	outside_body_flow_caption		p3:page_body:left_crossing:white	[255, 255, 255] white	[133.11, 243.89, 273.72, 7.7]	Fig. 1. XRD patterns of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2.	Fig. 1. XRD patterns of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2.
low	4	36	page_header	page_header	docling_page_header	docling_page_header		p4:top_margin:left:white	[255, 255, 255] white	[41.16, 45.41, 15.94, 6.95]	3546	3546
low	4	37	page_header	page_header	docling_page_header	docling_page_header		p4:top_margin:right_crossing:white	[255, 255, 255] white	[164.3, 45.41, 219.98, 6.95]	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552
low	4	38	caption	caption	outside_body_flow_caption	outside_body_flow_caption		p4:page_body:full:white	[255, 255, 255] white	[48.59, 562.05, 451.38, 7.7]	Fig. 2. SEM images of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2. x = (a) 1.0, (b) 0.9, (c) 0.7, (d) 0.5, (e) 0.3 and (f) 0.1.	Fig. 2. SEM images of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2. x = (a) 1.0, (b) 0.9, (c) 0.7, (d) 0.5, (e) 0.3 and (f) 0.1.
low	5	41	page_header	page_header	docling_page_header	docling_page_header		p5:top_margin:left_crossing:white	[255, 255, 255] white	[159.99, 45.41, 219.98, 6.95]	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552
low	5	42	page_header	page_header	docling_page_header	docling_page_header		p5:top_margin:right:white	[255, 255, 255] white	[487.22, 45.41, 15.94, 6.95]	3547	3547
low	5	43	caption	caption	outside_body_flow_caption	outside_body_flow_caption		p5:page_body:left_crossing:white	[255, 255, 255] white	[108.17, 434.43, 323.61, 7.75]	Fig. 3. First charge/discharge curves of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2.	Fig. 3. First charge/discharge curves of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2.
low	6	46	page_header	page_header	docling_page_header	docling_page_header		p6:top_margin:left:white	[255, 255, 255] white	[41.16, 45.41, 15.94, 6.95]	3548	3548
low	6	47	page_header	page_header	docling_page_header	docling_page_header		p6:top_margin:right_crossing:white	[255, 255, 255] white	[164.3, 45.41, 219.98, 6.95]	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552
low	6	48	caption	caption	outside_body_flow_caption	outside_body_flow_caption		p6:page_body:full:white	[255, 255, 255] white	[41.16, 446.26, 466.28, 27.33]	Fig. 4. (a) Electrochemical properties of mixed compounds ofLi2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2: ( & ) charge capacity and ( * ) discharge capacity. (b) Electrochemical properties of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2: ( & ) capacity retention and ( * ) initial capacity loss.	Fig. 4. (a) Electrochemical properties of mixed compounds ofLi2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2: ( & ) charge capacity and ( * ) discharge capacity. (b) Electrochemical properties of mixed compounds of Li2MnO3 and Li[Ni1/3Co1/3Mn1/3]O2: ( & ) capacity retention and ( * ) initial capacity loss.
low	7	51	page_header	page_header	docling_page_header	docling_page_header		p7:top_margin:left_crossing:white	[255, 255, 255] white	[159.99, 45.41, 219.98, 6.95]	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552
low	7	52	page_header	page_header	docling_page_header	docling_page_header		p7:top_margin:right:white	[255, 255, 255] white	[487.22, 45.41, 15.94, 6.95]	3549	3549
low	7	53	caption	caption	docling_caption	docling_caption		p7:page_body:left_crossing:white	[255, 255, 255] white	[123.87, 248.31, 292.28, 7.75]	Fig. 5. Cycle performance of the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound after fifty cycles.	Fig. 5. Cycle performance of the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound after fifty cycles.
low	7	54	caption	caption	outside_body_flow_caption	outside_body_flow_caption		p7:page_body:full:white	[255, 255, 255] white	[55.39, 464.42, 429.17, 7.7]	Fig. 6. Cyclic voltammograms of the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound. Scan rate is 0.1 mV/s. The voltage range is 2.0 -4.8 V.	Fig. 6. Cyclic voltammograms of the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound. Scan rate is 0.1 mV/s. The voltage range is 2.0 -4.8 V.
low	7	55	caption	caption	outside_body_flow_caption	outside_body_flow_caption		p7:page_body:left_crossing:white	[255, 255, 255] white	[82.94, 675.32, 374.11, 6.95]	Fig. 7. Voltage profile of the cell during two cycles. Representative scans of XANES measurements are indicated.	Fig. 7. Voltage profile of the cell during two cycles. Representative scans of XANES measurements are indicated.
low	8	56	page_header	page_header	docling_page_header	docling_page_header		p8:top_margin:left:white	[255, 255, 255] white	[41.16, 45.41, 15.94, 6.95]	3550	3550
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low	8	58	caption	caption	outside_body_flow_caption	outside_body_flow_caption		p8:page_body:full:white	[255, 255, 255] white	[41.16, 625.94, 466.25, 26.91]	Fig. 8. (a) Mn K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during the first charge process. (b) Co K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during the first charge process. (c) Ni K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during the first charge process.	Fig. 8. (a) Mn K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during the first charge process. (b) Co K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during the first charge process. (c) Ni K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during the first charge process.
low	9	59	page_header	page_header	docling_page_header	docling_page_header		p9:top_margin:left_crossing:white	[255, 255, 255] white	[159.99, 45.41, 219.98, 6.95]	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552
low	9	60	page_header	page_header	docling_page_header	docling_page_header		p9:top_margin:right:white	[255, 255, 255] white	[487.22, 45.41, 15.94, 6.95]	3551	3551
low	9	61	caption	caption	outside_body_flow_caption	outside_body_flow_caption		p9:page_body:full:white	[255, 255, 255] white	[36.85, 613.58, 466.26, 17.68]	Fig. 9. (a) Mn K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during 2 cycles. (b) Co K-edge XANES spectra for the Li[Li1/ 6Mn1/2Ni1/6Co1/6]O2 compound during 2 cycles. (c) Ni K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during 2 cycles.	Fig. 9. (a) Mn K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during 2 cycles. (b) Co K-edge XANES spectra for the Li[Li1/ 6Mn1/2Ni1/6Co1/6]O2 compound during 2 cycles. (c) Ni K-edge XANES spectra for the Li[Li1/6Mn1/2Ni1/6Co1/6]O2 compound during 2 cycles.
low	10	62	page_header	page_header	docling_page_header	docling_page_header		p10:top_margin:left:white	[255, 255, 255] white	[41.16, 45.4, 15.94, 6.95]	3552	3552
low	10	63	page_header	page_header	docling_page_header	docling_page_header		p10:top_margin:right_crossing:white	[255, 255, 255] white	[164.3, 45.4, 219.98, 6.95]	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552	G.-Y. Kim et al. / Materials Research Bulletin 43 (2008) 3543 -3552
low	10	66	section_header	body_heading	body_heading	body_heading		p10:body_zone:left:white	[255, 255, 255] white	[41.16, 243.68, 63.93, 8.78]	4. Conclusions	4. Conclusions
low	10	69	section_header	back_matter_heading	back_matter_heading	back_matter_heading	stop_trigger	p10:body_zone:left:white	[255, 255, 255] white	[41.16, 387.11, 78.62, 8.78]	Acknowledgement	Acknowledgement
low	10	71	section_header	back_matter_heading	after_back_matter_stop	after_back_matter_stop	after_stop	p10:body_zone:left:white	[255, 255, 255] white	[41.16, 434.96, 46.53, 8.78]	References	References
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