Docling layout block audit

original.pdf docling.json layout_blocks.json layout_blocks.tsv layout_blocks.jsonl excluded_blocks.html excluded_blocks.tsv final_body_blocks.tsv visual_assets.tsv visual_assets.json

Summary

{
  "blocks": 154,
  "included_in_body": 14,
  "gray_background_blocks": 0,
  "framed_blocks": 9,
  "by_role_guess": {
    "page_header": 18,
    "metadata": 10,
    "title_candidate": 2,
    "body_candidate_excluded": 13,
    "footnote": 7,
    "affiliation": 1,
    "body": 14,
    "front_matter_heading": 1,
    "page_footer": 19,
    "caption": 5,
    "back_matter_heading": 3,
    "unknown_text": 7,
    "back_matter_text": 6,
    "reference": 48
  },
  "by_docling_label": {
    "page_header": 18,
    "text": 46,
    "section_header": 9,
    "footnote": 7,
    "page_footer": 19,
    "caption": 5,
    "list_item": 50
  },
  "by_body_decision_reason": {
    "docling_page_header": 8,
    "document_web_address": 1,
    "non_body_heading": 2,
    "before_body_started": 1,
    "docling_footnote": 7,
    "front_matter_author_line": 1,
    "body": 14,
    "front_matter_heading": 1,
    "first_page_metadata": 8,
    "docling_page_footer": 5,
    "outside_body_flow_caption": 2,
    "back_matter_heading": 1,
    "after_back_matter_stop": 103
  },
  "visual_assets": {
    "count": 6,
    "indexable_count": 6,
    "suppressed_count": 0,
    "by_type": {
      "figure": 6
    },
    "by_caption_source": {
      "direct_caption_ref": 5,
      "missing_caption": 1
    },
    "by_duplicate_reason": {
      "": 6
    },
    "missing_caption_count": 1
  }
}

Diff Summary

{
  "parsed_text_blocks": 154,
  "final_body_blocks": 14,
  "excluded_blocks": {
    "count": 140,
    "by_reason": {
      "after_back_matter_stop": 103,
      "docling_page_header": 8,
      "first_page_metadata": 8,
      "docling_footnote": 7,
      "docling_page_footer": 5,
      "non_body_heading": 2,
      "outside_body_flow_caption": 2,
      "back_matter_heading": 1,
      "before_body_started": 1,
      "document_web_address": 1,
      "front_matter_author_line": 1,
      "front_matter_heading": 1
    },
    "by_role_guess": {
      "reference": 48,
      "page_footer": 19,
      "page_header": 18,
      "body_candidate_excluded": 13,
      "metadata": 10,
      "footnote": 7,
      "unknown_text": 7,
      "back_matter_text": 6,
      "caption": 5,
      "back_matter_heading": 3,
      "title_candidate": 2,
      "affiliation": 1,
      "front_matter_heading": 1
    },
    "by_risk_level": {
      "low": 127,
      "medium": 13
    },
    "high_risk_count": 0,
    "medium_risk_count": 13
  },
  "char_counts": {
    "parsed_text_chars": 43999,
    "final_body_chars": 12156,
    "excluded_chars": 31843
  }
}

Truncation

{
  "truncated": true,
  "message": "Body extraction stopped at page 4 block #/texts/41#prov1: Supporting Information Figure S3. Figure 1 (c -f) and Supporting Information Figure S4 show elemental distribution captured by EDS mapping of a pristine particle. In Figure 1c, the particle was tilted to [010] zone axis…. 103 following text blocks were excluded as after_back_matter_stop.",
  "stop_trigger": {
    "ref": "#/texts/41#prov1",
    "page": 4,
    "layout_order": 50,
    "role_guess": "back_matter_heading",
    "body_decision_reason": "back_matter_heading",
    "text_preview": "Supporting Information Figure S3. Figure 1 (c -f) and Supporting Information Figure S4 show elemental distribution captured by EDS mapping of a pristine particle. In Figure 1c, the particle was tilted to [010] zone axis…"
  },
  "first_truncated_block": {
    "ref": "#/texts/47#prov0",
    "page": 4,
    "layout_order": 51,
    "role_guess": "body_candidate_excluded",
    "body_decision_reason": "after_back_matter_stop",
    "text_preview": "Cycling induced structural change. In this section, we discuss the structural evolution of the particle upon cyclic charge and discharge. Supporting Information Figure S5 shows the fi rst charge/discharge cycle and capa…"
  },
  "truncated_block_count": 103,
  "truncated_pages": [
    4,
    5,
    6,
    7,
    8,
    9
  ],
  "by_role_guess": {
    "reference": 48,
    "body_candidate_excluded": 12,
    "page_footer": 12,
    "page_header": 10,
    "unknown_text": 7,
    "back_matter_text": 6,
    "caption": 3,
    "metadata": 3,
    "back_matter_heading": 2
  }
}

Page Overlays

Green = final body chunks. Orange/purple asset boxes = actual figure/table assets used by ingestion. Cyan dashed text boxes = text blocks consumed by those assets as caption continuations. Red STOP = truncation trigger. Red boxes = blocks after truncation.

Page 1

Page 2

Page 3

Page 4

Page 5

Page 6

Page 7

Page 8

Page 9

Visual Assets

这里对齐真实图表资产提取链路。caption_source=embedded_table_cell 表示表注来自 Docling table cell,不会出现在 text block 审计差集里;caption_continuation_used_by_asset 表示某个 text block 已被图表 caption 吸收,不应按普通 metadata 解读。

#typelabelpagecaption sourcesuppressedduplicate reasonrescue reasongroupconfidencebboxcaption
1figureDocling Figure 11missing_caption0.55[314.57, 410.37, 242.33, 104.54]
2figureFig. 13direct_caption_ref0.82[161.38, 66.05, 301.22, 412.29]Figure 1. (a) low magni fi cation and (b) high resolution STEM-HAADF images of the PNS layer in a pristine particle. White arrows in (b) indicate ordered features along (20 -2) planes. Red arrows in (b) indicated Li-slabs being inserted heavy TM cations in the PNS layer. A [010] direction C 2/ m crystal structure is shown as inset map in (b). Green: Li; Blue: Ni; Purple: Mn; Red: O. (c) STEM-HAADF image of EDS mapping area. The particle was tilted to [010] zone and its surface facets were determined. (d) Corresponding Ni elemental mapping. (e) Line scan signal counts across the PNS layer, whose location is shown in the STEM-HAADF image; (f) Quantitative Ni/Mn atomic ratios along the line scan. The Ni/Mn ratios are around 0.35 in bulk region, which is close to the designed value 0.33.
3figureFig. 24direct_caption_ref0.82[160.9, 64.69, 301.7, 350.7]Figure 2. (a-d) Low magni fi cation STEM-HAADF images to show cycling induced corrosion. Cracks and pits are highlighted by red arrows. (002) surface planes show strong resistance to corrosion. e-h) [010] zone axis SAED patterns. Extra di ff raction spots appeared in cycled samples, which are highlighted by red and blue circles. Red circles indicated the formation of ordered structure. (10 -1) ordered plane is clearly seen after cycling. Blue circles come from double di ff raction. (i -l) High resolution STEM-HAADF images to show the cycling induced structure change on particle surfaces. Pristine samples (i) shows homogeneous structure from surface to bulk. Dashed lines in (j, k) highlight the thickness of the SRL. In (l), the whole areas were transformed. (m) [101] zone axis STEM-HAADF image and its fast Fourier transformation image. Blue arrows indicate the ordered features of (20 -2) planes and extra di ff raction spots. (n) [010] zone axis STEM-HAADF image to show spinel structure and I41 structure in a 45 cycled sample.
4figureFig. 35direct_caption_ref0.82[104.5, 67.51, 412.09, 458.65]Figure 3. (a-d) EDS mapping results from a 45 cycled LMR particle. The particle was tilted to the [010] zone axis and three surface facets were determined in (b). (e) Quantitative Ni/Mn ratios from surface and bulk positions as marked in (a); (f) line scan signal counts; (g) Quantitative Ni/ Mn atomic ratios along the line scan. The Ni/Mn ratios are around 0.26 in bulk region. (h)Low loss EELS spectra and (i) high low EELS spectra from di ff erent samples. 4.7 V bulk: spectrum collected from 4.7 V overcharged sample ' s bulk region; 100S: spectra collected from the surface of 100 cycled sample; 45S: spectra collected from the surface of 45 cycled sample; PNS: spectra collected from the Ni-rich surface of pristine sample; PS: spectra collected from pristine sample surface without Ni-rich layer; Li2O: spectrum collected from Li2O sample; Bulk: spectrum collected from pristine sample ' s bulk region. The degree of Li -K edge depression is 4.7 V bulk >100S > 45S ≈ PNS > PS. The order of Mn L3/L2 ratio is 100S > 45S > PNS ≈ PS ≈ Bulk.
5figureFig. 47direct_caption_ref0.82[99.49, 65.21, 426.88, 349.49]Figure 4. Comparison between experimental results and simulation results of di ff erent crystal models for the SRL from the [010] zone axis. I41 structure matches best in the four crystal models.
6figureFig. 57direct_caption_ref0.82[142.46, 454.0, 339.52, 205.34]Figure 5. Schematic diagram to show cycling induced surface layer evolution. At left side, the pristine particle has a C 2/ m structure and PNS layers are located at (20 -2) surface planes. After cycling, due to Ni 2+ migration from bulk to surface, Mn 2+ surface aggregation and Li + depletion in surface layer, SRL is developed on particle surface except the PNS. The structure of surface layer transforms from original C 2/ m into I41 and fi nally developed spinel structure due to progressive TM enrichment and Li depletion. I41 structure is the main phase in the SRL.

Blocks

pageorderlabelroleincludedriskreasonparser reasonproduction usage truncbody regionregionbgframebboxraw textcleaned text
10page_headerpage_headerFalselowdocling_page_headerdocling_page_header
p1:top_margin:column_2_of_2:colored[238, 164, 167]
colored
True[537.96, 60.48, 19.47, 7.35]LetterLetter
11textmetadataFalselowdocument_web_addressdocument_web_address
p1:page_body:column_2_of_2:white[255, 255, 255]
white
False[489.49, 76.75, 74.9, 7.35]pubs.acs.org/NanoLettpubs.acs.org/NanoLett
12section_headertitle_candidateFalselownon_body_headingnon_body_heading
p1:body_region:0p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 121.2, 503.96, 50.83]Evolution of Lattice Structure and Chemical Composition of the Surface Reconstruction Layer in Li1.2Ni0.2Mn0.6O2 Cathode Material for Lithium Ion BatteriesEvolution of Lattice Structure and Chemical Composition of the Surface Reconstruction Layer in Li1.2Ni0.2Mn0.6O2 Cathode Material for Lithium Ion Batteries
13textbody_candidate_excludedFalsemediumbefore_body_startedbefore_body_started
p1:body_region:0p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 174.05, 504.0, 46.22]Pengfei Yan, † Anmin Nie, ‡ Jianming Zheng, § Yungang Zhou, ∥ Dongping Lu, § Xiaofeng Zhang, ⊥ Rui Xu, ⊥ Ilias Belharouak, ⊥ , ¶ Xiaotao Zu, ∥ Jie Xiao, § Khalil Amine, ⊥ Jun Liu, § Fei Gao, ○ Reza Shahbazian-Yassar, ‡ …Pengfei Yan, † Anmin Nie, ‡ Jianming Zheng, § Yungang Zhou, ∥ Dongping Lu, § Xiaofeng Zhang, ⊥ Rui Xu, ⊥ Ilias Belharouak, ⊥ , ¶ Xiaotao Zu, ∥ Jie Xiao, § Khalil Amine, ⊥ Jun Liu, § Fei Gao, ○ Reza Shahbazian-Yassar, ‡ …
14page_headerpage_headerFalselowdocling_page_headerdocling_page_header
p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[3.61, 223.96, 15.98, 347.54]Downloaded via JILIN UNIV on July 12, 2026 at 04:41:59 (UTC). See https:/pubs.acs.org/sharingguidelines for options on how to legitimately share published articles.Downloaded via JILIN UNIV on July 12, 2026 at 04:41:59 (UTC). See https:/pubs.acs.org/sharingguidelines for options on how to legitimately share published articles.
15footnotefootnoteFalselowdocling_footnotedocling_footnote
p1:body_region:0p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 225.47, 468.18, 24.71]† Environmental Molecular Sciences Laboratory, Paci fi c Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99352, United States† Environmental Molecular Sciences Laboratory, Paci fi c Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99352, United States
16footnotefootnoteFalselowdocling_footnotedocling_footnote
p1:body_region:0p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 250.47, 471.42, 24.71]‡ Department of Mechanical Engineering-Engineering Mechanics, Michigan Technological University, 1400 Townsend Dr., Houghton, Michigan 49931, United States‡ Department of Mechanical Engineering-Engineering Mechanics, Michigan Technological University, 1400 Townsend Dr., Houghton, Michigan 49931, United States
17footnotefootnoteFalselowdocling_footnotedocling_footnote
p1:body_region:0p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 275.83, 488.88, 24.36]§ Energy and Environmental Directorate, Paci fi c Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99352, United States§ Energy and Environmental Directorate, Paci fi c Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99352, United States
18textaffiliationFalselowfront_matter_author_linefront_matter_author_line
p1:body_region:0p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 300.77, 503.95, 24.42]∥ Department of Applied Physics, University of Electronic Science and Technology of China, Chengdu 610054, People ' s Republic of China∥ Department of Applied Physics, University of Electronic Science and Technology of China, Chengdu 610054, People ' s Republic of China
19footnotefootnoteFalselowdocling_footnotedocling_footnote
p1:body_region:0p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 325.77, 495.31, 24.42]⊥ Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States⊥ Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States
110footnotefootnoteFalselowdocling_footnotedocling_footnote
p1:body_region:0p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 350.84, 387.04, 13.36]¶ Qatar Environment and Energy Research Institute, Qatar Foundation, P.O. Box 5825, Doha, Qatar¶ Qatar Environment and Energy Research Institute, Qatar Foundation, P.O. Box 5825, Doha, Qatar
111footnotefootnoteFalselowdocling_footnotedocling_footnote
p1:body_region:0p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 365.19, 6.25, 8.05]
112footnotefootnoteFalselowdocling_footnotedocling_footnote
p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[66.73, 369.39, 497.7, 8.8]Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, Michigan 48109, United StatesDepartment of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, Michigan 48109, United States
113section_headertitle_candidateFalselownon_body_headingnon_body_heading
p1:body_region:0p1:page_body:column_1_of_2:white[255, 255, 255]
white
False[69.45, 385.15, 101.14, 12.62]* S Supporting Information* S Supporting Information
114textbodyTruebodybody
p1:body_region:0p1:page_body:column_1_of_2:colored[255, 242, 208]
colored
False[69.45, 414.35, 237.05, 107.84]ABSTRACT: Voltage and capacity fading of layer structured lithium and manganese rich (LMR) transition metal oxide is directly related to the structural and composition evolution of the material during the cycling of the…ABSTRACT: Voltage and capacity fading of layer structured lithium and manganese rich (LMR) transition metal oxide is directly related to the structural and composition evolution of the material during the cycling of the…
115textbodyTruebodybody
p1:body_region:0p1:page_body:column_1_of_2:colored[255, 242, 208]
colored
False[69.45, 524.39, 486.04, 96.79]depletion of Ni in the bulk lattice and thickening of a Ni enriched surface reconstruction layer (SRL). Furthermore, Ni and Mn also exhibit concentration partitions within the thin layer of SRL in the cycled samples whe…depletion of Ni in the bulk lattice and thickening of a Ni enriched surface reconstruction layer (SRL). Furthermore, Ni and Mn also exhibit concentration partitions within the thin layer of SRL in the cycled samples whe…
116textfront_matter_headingFalselowfront_matter_headingfront_matter_heading
p1:body_region:0p1:page_body:column_1_of_2:colored[255, 242, 208]
colored
False[69.45, 625.84, 459.96, 9.53]KEYWORDS: lithium ion battery, LMR cathode, surface reconstruction, ion migration, voltage fading, Ni surface segregationKEYWORDS: lithium ion battery, LMR cathode, surface reconstruction, ion migration, voltage fading, Ni surface segregation
117textbodyTruebodybody
p1:body_region:0p1:bottom_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 660.42, 239.99, 96.94]L ithium-ion batteries (LIBs) have been commercialized for more than two decades. Nowadays, driven by the demand of portable electronic device market, the next generation LIBs, featured with high capacity, high operatin…L ithium-ion batteries (LIBs) have been commercialized for more than two decades. Nowadays, driven by the demand of portable electronic device market, the next generation LIBs, featured with high capacity, high operatin…
118page_footerpage_footerFalselowfirst_page_metadatafirst_page_metadata
p1:body_region:0p1:bottom_margin:column_1_of_2:white[255, 255, 255]
white
False[168.49, 771.24, 95.03, 5.88]© 2014 American Chemical Society© 2014 American Chemical Society
119textbodyTruebodybody
p1:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 656.8, 240.01, 53.05]world. 7 -9 To date, Mn-based LiNi x Mn1 -x -y Co y O2 (NCM), Nibased LiNi1 -x -y Co x Al y O2 (NCA), and Li -Mn-rich (LMR) cathode materials are among the most promising competitors in the cathode materials. 1,10 -16 H…world. 7 -9 To date, Mn-based LiNi x Mn1 -x -y Co y O2 (NCM), Nibased LiNi1 -x -y Co x Al y O2 (NCA), and Li -Mn-rich (LMR) cathode materials are among the most promising competitors in the cathode materials. 1,10 -16 H…
120textmetadataFalselowfirst_page_metadatafirst_page_metadata
p1:page_body:column_2_of_2:white[255, 255, 255]
white
False[367.99, 727.13, 57.04, 7.92]October 7, 2014October 7, 2014
121textmetadataFalselowfirst_page_metadatafirst_page_metadata
p1:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 727.21, 34.65, 7.77]Received:Received:
122textmetadataFalselowfirst_page_metadatafirst_page_metadata
p1:page_body:column_2_of_2:white[255, 255, 255]
white
False[367.99, 738.19, 69.23, 7.92]November 17, 2014November 17, 2014
123textmetadataFalselowfirst_page_metadatafirst_page_metadata
p1:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 738.27, 30.25, 7.77]Revised:Revised:
124textmetadataFalselowfirst_page_metadatafirst_page_metadata
p1:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[367.99, 749.19, 63.96, 7.92]December 8, 2014December 8, 2014
125textmetadataFalselowfirst_page_metadatafirst_page_metadata
p1:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[324.45, 749.27, 37.75, 7.77]Published:Published:
126page_footerpage_footerFalselowfirst_page_metadatafirst_page_metadata
p1:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[411.19, 769.98, 153.29, 7.74]dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522
127page_footerpage_footerFalselowdocling_page_footerdocling_page_footer
p1:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[306.48, 770.73, 11.95, 6.54]514514
228page_headerpage_headerFalselowdocling_page_headerdocling_page_header
p2:body_region:0p2:top_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 48.93, 55.9, 8.72]Nano LettersNano Letters
229textbodyTruebodybody
p2:body_region:0p2:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 69.37, 240.0, 229.79]these cathode materials faces many challenges. For example, LMR cathode still su ff ered from voltage fading, capacity decay, cycling instability, and poor rate capability. Structurally, these three groups of cathode ma…these cathode materials faces many challenges. For example, LMR cathode still su ff ered from voltage fading, capacity decay, cycling instability, and poor rate capability. Structurally, these three groups of cathode ma…
230textbodyTruebodybody
p2:body_region:0p2:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 301.36, 239.99, 251.9]Although the common features of SRL have been well recognized as mentioned above, it is still far from clear on the fundamental mechanism behind the formation and evolution SRL during the cycling process. It has been re…Although the common features of SRL have been well recognized as mentioned above, it is still far from clear on the fundamental mechanism behind the formation and evolution SRL during the cycling process. It has been re…
231textbodyTruebodybody
p2:body_region:0p2:bottom_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 555.52, 240.0, 207.68]In this work, using aberration-corrected scanning/transmission electron microscopes (S/TEM) equipped with high angle annular dark fi eld/annular bright fi eld (HAADF/ABF) detectors, advanced energy dispersive X-ray spec…In this work, using aberration-corrected scanning/transmission electron microscopes (S/TEM) equipped with high angle annular dark fi eld/annular bright fi eld (HAADF/ABF) detectors, advanced energy dispersive X-ray spec…
232page_headerpage_headerFalselowdocling_page_headerdocling_page_header
p2:body_region:1p2:top_margin:column_2_of_2:colored[238, 164, 167]
colored
True[537.96, 49.99, 19.47, 7.35]LetterLetter
233textbodyTruebodybody
p2:body_region:1p2:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 69.37, 240.04, 53.02]of Ni ions in the electrolyte. Meanwhile, structural evolution is observed and identi fi ed as a sequential phase transition of C 2/ m → I 41 → spinel. The present work provides new insights as how structural and chemic…of Ni ions in the electrolyte. Meanwhile, structural evolution is observed and identi fi ed as a sequential phase transition of C 2/ m → I 41 → spinel. The present work provides new insights as how structural and chemic…
234textbodyTruebodybody
p2:body_region:1p2:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 124.59, 240.02, 274.02]The LMR was synthesized by a coprecipitation process. Nickel sulfate hexahydrate (NiSO4 · 6H2O), manganese sulfate monohydrate (MnSO4 · H2O), sodium hydroxide (NaOH), and ammonium hydroxide (NH3 · H2O) were used as the …The LMR was synthesized by a coprecipitation process. Nickel sulfate hexahydrate (NiSO4 · 6H2O), manganese sulfate monohydrate (MnSO4 · H2O), sodium hydroxide (NaOH), and ammonium hydroxide (NH3 · H2O) were used as the …
235textbodyTruebodybody
p2:body_region:1p2:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 400.8, 240.03, 329.23]Following the cycling of the battery, the obtained electrode was fi rst immersed in DMC for 12 h and then washed by DMC for three times and dried in vacuum for 12h. The electrode were peeled o ff from the Al-foil and gr…Following the cycling of the battery, the obtained electrode was fi rst immersed in DMC for 12 h and then washed by DMC for three times and dried in vacuum for 12h. The electrode were peeled o ff from the Al-foil and gr…
236textbodyTruebodybody
p2:body_region:1p2:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[324.45, 732.28, 240.05, 30.91]Computer simulations of electron di ff ractions and HRTEM images were conducted by using JEMS software. For di ff ractions, sample thickness is 60 nm. For HRTEM images,Computer simulations of electron di ff ractions and HRTEM images were conducted by using JEMS software. For di ff ractions, sample thickness is 60 nm. For HRTEM images,
237page_footerpage_footerFalselowdocling_page_footerdocling_page_footer
p2:body_region:1p2:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[411.19, 773.27, 153.29, 7.74]dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522
238page_footerpage_footerFalselowdocling_page_footerdocling_page_footer
p2:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[306.48, 774.02, 11.95, 6.54]515515
339page_headerpage_headerFalselowdocling_page_headerdocling_page_header
p3:body_region:0p3:top_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 48.93, 55.9, 8.72]Nano LettersNano Letters
340page_headerpage_headerFalselowdocling_page_headerdocling_page_header
p3:body_region:1p3:top_margin:column_2_of_2:colored[238, 164, 167]
colored
True[537.96, 49.99, 19.47, 7.35]LetterLetter
341captioncaptionFalselowoutside_body_flow_captionoutside_body_flow_caption
p3:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 488.68, 503.97, 57.93]Figure 1. (a) low magni fi cation and (b) high resolution STEM-HAADF images of the PNS layer in a pristine particle. White arrows in (b) indicate ordered features along (20 -2) planes. Red arrows in (b) indicated Li-sla…Figure 1. (a) low magni fi cation and (b) high resolution STEM-HAADF images of the PNS layer in a pristine particle. White arrows in (b) indicate ordered features along (20 -2) planes. Red arrows in (b) indicated Li-sla…
342textbodyTruebodybody
p3:body_region:0p3:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 559.6, 240.01, 100.59]the microscope parameters Cc and Cs are 1.2 mm and 0.7 mm, respectively. The STEM-HAADF simulations were conducted by the multislice method implanted in the Kirkland code. 38,39 For all the structures calculated in this…the microscope parameters Cc and Cs are 1.2 mm and 0.7 mm, respectively. The STEM-HAADF simulations were conducted by the multislice method implanted in the Kirkland code. 38,39 For all the structures calculated in this…
343textbodyTruebodybody
p3:body_region:0p3:bottom_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 662.61, 240.01, 100.59]Li2MnO3 and LiNi0.5Mn0.5O2 are two well-studied cathode materials. The former adopts monoclinic C 2/ m structure and the latter has an R 3 ̅ m layered structure. Because Li 1.2 Ni0.2Mn0.6O2 can be expressed as (50%Li2Mn…Li2MnO3 and LiNi0.5Mn0.5O2 are two well-studied cathode materials. The former adopts monoclinic C 2/ m structure and the latter has an R 3 ̅ m layered structure. Because Li 1.2 Ni0.2Mn0.6O2 can be expressed as (50%Li2Mn…
344textbodyTruebodybody
p3:body_region:1p3:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[324.45, 559.06, 240.04, 204.14]cathode particles exhibit a C 2/ m symmetry (see Figure S1 and S2 in the Supporting Information). Compared with ideal C 2/ m Li 2 MnO3 structure, due to more transition metal (TM) cations being incorporated, disordered …cathode particles exhibit a C 2/ m symmetry (see Figure S1 and S2 in the Supporting Information). Compared with ideal C 2/ m Li 2 MnO3 structure, due to more transition metal (TM) cations being incorporated, disordered …
345page_footerpage_footerFalselowdocling_page_footerdocling_page_footer
p3:body_region:1p3:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[411.19, 773.27, 153.29, 7.74]dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522
346page_footerpage_footerFalselowdocling_page_footerdocling_page_footer
p3:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[306.48, 774.02, 11.95, 6.54]516516
447page_headerpage_headerFalselowdocling_page_headerdocling_page_header
p4:body_region:0p4:top_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 48.93, 55.9, 8.72]Nano LettersNano Letters
448page_headerpage_headerFalselowdocling_page_headerdocling_page_header
p4:body_region:1p4:top_margin:column_2_of_2:colored[238, 164, 167]
colored
True[537.96, 49.99, 19.47, 7.35]LetterLetter
449captioncaptionFalselowoutside_body_flow_captionoutside_body_flow_caption
p4:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 426.09, 503.98, 77.89]Figure 2. (a-d) Low magni fi cation STEM-HAADF images to show cycling induced corrosion. Cracks and pits are highlighted by red arrows. (002) surface planes show strong resistance to corrosion. e-h) [010] zone axis SAED…Figure 2. (a-d) Low magni fi cation STEM-HAADF images to show cycling induced corrosion. Cracks and pits are highlighted by red arrows. (002) surface planes show strong resistance to corrosion. e-h) [010] zone axis SAED…
450textback_matter_headingFalselowback_matter_headingback_matter_heading
stop_triggerp4:body_region:0p4:bottom_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 513.6, 239.99, 249.6]Supporting Information Figure S3. Figure 1 (c -f) and Supporting Information Figure S4 show elemental distribution captured by EDS mapping of a pristine particle. In Figure 1c, the particle was tilted to [010] zone axis…Supporting Information Figure S3. Figure 1 (c -f) and Supporting Information Figure S4 show elemental distribution captured by EDS mapping of a pristine particle. In Figure 1c, the particle was tilted to [010] zone axis…
451textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp4:body_region:1p4:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[324.45, 516.54, 240.03, 246.66]Cycling induced structural change. In this section, we discuss the structural evolution of the particle upon cyclic charge and discharge. Supporting Information Figure S5 shows the fi rst charge/discharge cycle and capa…Cycling induced structural change. In this section, we discuss the structural evolution of the particle upon cyclic charge and discharge. Supporting Information Figure S5 shows the fi rst charge/discharge cycle and capa…
452page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp4:body_region:1p4:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[411.19, 773.27, 153.29, 7.74]dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522
453page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp4:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[306.48, 774.02, 11.95, 6.54]517517
554page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp5:body_region:0p5:top_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 48.93, 55.9, 8.72]Nano LettersNano Letters
555page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp5:body_region:1p5:top_margin:column_2_of_2:colored[238, 164, 167]
colored
True[537.96, 49.99, 19.47, 7.35]LetterLetter
556captioncaptionFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp5:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 535.74, 503.99, 78.59]Figure 3. (a-d) EDS mapping results from a 45 cycled LMR particle. The particle was tilted to the [010] zone axis and three surface facets were determined in (b). (e) Quantitative Ni/Mn ratios from surface and bulk posi…Figure 3. (a-d) EDS mapping results from a 45 cycled LMR particle. The particle was tilted to the [010] zone axis and three surface facets were determined in (b). (e) Quantitative Ni/Mn ratios from surface and bulk posi…
557textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp5:body_region:0p5:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 624.7, 240.0, 22.39]surface layer ' s both structural and composition evolution upon cycling.surface layer ' s both structural and composition evolution upon cycling.
558textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp5:body_region:0p5:bottom_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 649.57, 240.0, 113.63]Upon cycling, the most discernible change of the LMR particle is the formation of a surface reconstruction layer (SRL), as representatively shown by the STEM-HAADF images in Figure 2j -n and HRTEM images in Supporting I…Upon cycling, the most discernible change of the LMR particle is the formation of a surface reconstruction layer (SRL), as representatively shown by the STEM-HAADF images in Figure 2j -n and HRTEM images in Supporting I…
559textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp5:body_region:1p5:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[324.45, 623.24, 240.03, 140.69]SAED patterns. As shown in Figure 2e -h, compared with pristine sample, cycled samples show extra spots (highlighted by red and blue circles). The blue circles indicate double di ff raction spots. The stronger double di…SAED patterns. As shown in Figure 2e -h, compared with pristine sample, cycled samples show extra spots (highlighted by red and blue circles). The blue circles indicate double di ff raction spots. The stronger double di…
560page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp5:body_region:1p5:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[411.19, 773.27, 153.29, 7.74]dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522
561page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp5:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[306.48, 774.02, 11.95, 6.54]518518
662page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:body_region:0p6:top_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 48.93, 55.9, 8.72]Nano LettersNano Letters
663textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp6:body_region:0p6:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 69.37, 240.0, 141.41](marked by blue arrows) due to the structural ordering. Thus, the SRL structure is actually an ordered structure, which means extra ordering was introduced during cycling as compared with pristine layered structure. It …(marked by blue arrows) due to the structural ordering. Thus, the SRL structure is actually an ordered structure, which means extra ordering was introduced during cycling as compared with pristine layered structure. It …
664textback_matter_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:body_region:0p6:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 212.55, 240.0, 528.54]Cycling induced chemical composition change. The chemical compositions of the LMR particles after cycling were mapped by using the high e ffi cient EDS spectrometer (Figure 3a -d). In order to compare the structural and…Cycling induced chemical composition change. The chemical compositions of the LMR particles after cycling were mapped by using the high e ffi cient EDS spectrometer (Figure 3a -d). In order to compare the structural and…
665textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:body_region:0p6:bottom_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 743.34, 239.95, 19.86]Compared with the PNS layer, the cycling induced SRL presents three clear di ff erences. First, the SRL occurred on allCompared with the PNS layer, the cycling induced SRL presents three clear di ff erences. First, the SRL occurred on all
666page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:body_region:1p6:top_margin:column_2_of_2:colored[238, 164, 167]
colored
True[537.96, 49.99, 19.47, 7.35]LetterLetter
667textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp6:body_region:1p6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 66.0, 240.04, 78.45]surface, while the PNS layer only formed on the (20 -2) surface. Second, the outside edge of the SRL is Ni-poor, while the outside edge of the PNS layer has the highest Ni content. The third di ff erence is that the thi…surface, while the PNS layer only formed on the (20 -2) surface. Second, the outside edge of the SRL is Ni-poor, while the outside edge of the PNS layer has the highest Ni content. The third di ff erence is that the thi…
668textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp6:body_region:1p6:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 146.7, 240.04, 329.24]In accordance with the quantitative measurement of the TM elements (Mn and Ni) in the SRL and the PNS layer of both pristine and cycled samples, the Li concentration of these samples was also measured using EELS. The EE…In accordance with the quantitative measurement of the TM elements (Mn and Ni) in the SRL and the PNS layer of both pristine and cycled samples, the Li concentration of these samples was also measured using EELS. The EE…
669textback_matter_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:body_region:1p6:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[324.45, 477.7, 240.04, 285.5]Structure modeling of the SRL. In the literature, the structure of the SRL has been assigned to rock salt, 5,20,35 disordered rock salt 2 and spinel (including disordered-spinel/ spinel-like). 10,21,23 However, as shown…Structure modeling of the SRL. In the literature, the structure of the SRL has been assigned to rock salt, 5,20,35 disordered rock salt 2 and spinel (including disordered-spinel/ spinel-like). 10,21,23 However, as shown…
670page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:body_region:1p6:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[411.19, 773.27, 153.29, 7.74]dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522
671page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp6:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[306.48, 774.02, 11.95, 6.54]519519
772page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:top_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 48.93, 55.9, 8.72]Nano LettersNano Letters
773page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:top_margin:column_2_of_2:colored[238, 164, 167]
colored
True[537.96, 49.99, 19.47, 7.35]LetterLetter
774captioncaptionFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 427.51, 503.95, 17.9]Figure 4. Comparison between experimental results and simulation results of di ff erent crystal models for the SRL from the [010] zone axis. I41 structure matches best in the four crystal models.Figure 4. Comparison between experimental results and simulation results of di ff erent crystal models for the SRL from the [010] zone axis. I41 structure matches best in the four crystal models.
775captioncaptionFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 668.71, 503.98, 38.4]Figure 5. Schematic diagram to show cycling induced surface layer evolution. At left side, the pristine particle has a C 2/ m structure and PNS layers are located at (20 -2) surface planes. After cycling, due to Ni 2+ m…Figure 5. Schematic diagram to show cycling induced surface layer evolution. At left side, the pristine particle has a C 2/ m structure and PNS layers are located at (20 -2) surface planes. After cycling, due to Ni 2+ m…
776textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp7:bottom_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 720.04, 239.95, 43.16]matching with experimental results. In Supporting Information Figure S11, we also compare the pristine and cycled samples (100s) from [100] zone axis, which also indicates the SRL has an I41 structure. It should be poin…matching with experimental results. In Supporting Information Figure S11, we also compare the pristine and cycled samples (100s) from [100] zone axis, which also indicates the SRL has an I41 structure. It should be poin…
777textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp7:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[324.45, 720.04, 240.01, 43.16]varies across the SRL from outer surface to inner layer, therefore, an average composition value was chosen to de fi ne the SRL composition.varies across the SRL from outer surface to inner layer, therefore, an average composition value was chosen to de fi ne the SRL composition.
778page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[411.19, 773.27, 153.29, 7.74]dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522
779page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp7:bottom_margin:column_2_of_2:white[254, 254, 254]
white
False[306.48, 774.02, 11.95, 6.54]520520
880page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:top_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 48.93, 55.9, 8.72]Nano LettersNano Letters
881textback_matter_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 69.37, 240.0, 153.63]Above experimental observation is also consistently supported by the density functional theory (DFT) calculation of the lattice energy, which indicates that the I41 has the lowest lattice energy. In order to understand …Above experimental observation is also consistently supported by the density functional theory (DFT) calculation of the lattice energy, which indicates that the I41 has the lowest lattice energy. In order to understand …
882textback_matter_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 224.03, 240.0, 240.85]Depending on the Li, TM and O composition, di ff erent phases can be formed. For example, Li2MnO3 adopts a monoclinic C 2/ m structure; LiMnO2 and Li(Ni0.5Mn0.5)O2 adopt the trigonal R 3 ̅ m structure; LiMn2O4 adopts a …Depending on the Li, TM and O composition, di ff erent phases can be formed. For example, Li2MnO3 adopts a monoclinic C 2/ m structure; LiMnO2 and Li(Ni0.5Mn0.5)O2 adopt the trigonal R 3 ̅ m structure; LiMn2O4 adopts a …
883textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:page_body:column_1_of_2:white[255, 255, 255]
white
False[60.49, 467.13, 239.98, 186.73]Overall, upon continuous cycling of the battery, a progressive TM enrichment and Li depletion process is undergoing at the surface of LMR particles, leading to the formation of SRL. Structurally, in accordance with the …Overall, upon continuous cycling of the battery, a progressive TM enrichment and Li depletion process is undergoing at the surface of LMR particles, leading to the formation of SRL. Structurally, in accordance with the …
884textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:0p8:bottom_margin:column_1_of_2:white[255, 255, 255]
white
False[60.49, 654.9, 239.99, 108.3]It has been generally accepted that the voltage fading and capacity decaying are in some degrees directly correlated with the formation of the SRL on the particle. On the other hand, it is also speculated that related t…It has been generally accepted that the voltage fading and capacity decaying are in some degrees directly correlated with the formation of the SRL on the particle. On the other hand, it is also speculated that related t…
885page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:1p8:top_margin:column_2_of_2:colored[238, 164, 167]
colored
True[537.96, 49.99, 19.47, 7.35]LetterLetter
886textback_matter_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:1p8:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 69.37, 240.04, 335.76]indeed correlated to the SRL on the surface of each particle. This conclusion is supported by the following points. (1) Gradual migration of Ni from bulk lattice to the surface will lead to gradual depletion of Ni from …indeed correlated to the SRL on the surface of each particle. This conclusion is supported by the following points. (1) Gradual migration of Ni from bulk lattice to the surface will lead to gradual depletion of Ni from …
887textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:1p8:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 407.44, 240.04, 268.06]In summary, pristine and cycled LMR cathode materials were investigated by advanced microscopes. For the pristine LMR particles, Ni-segregation surface layer are always found at (20 -2) facets. After cycling, LMR partic…In summary, pristine and cycled LMR cathode materials were investigated by advanced microscopes. For the pristine LMR particles, Ni-segregation surface layer are always found at (20 -2) facets. After cycling, LMR partic…
888section_headerunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:1p8:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 680.04, 121.77, 23.65]■ ASSOCIATED CONTENT■ ASSOCIATED CONTENT
889section_headerunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:1p8:page_body:column_2_of_2:white[255, 255, 255]
white
False[324.45, 705.69, 113.4, 12.62]* S Supporting Information* S Supporting Information
890textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:1p8:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[324.45, 720.55, 240.0, 42.65]Additional XRD pattern, electrochemical data, TEM images and fi gures are supplied in the Supporting Information. This material is available free of charge via the Internet at http:// pubs.acs.org.Additional XRD pattern, electrochemical data, TEM images and fi gures are supplied in the Supporting Information. This material is available free of charge via the Internet at http:// pubs.acs.org.
891page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:body_region:1p8:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[411.19, 773.27, 153.29, 7.74]dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522
892page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp8:bottom_margin:column_2_of_2:white[255, 255, 255]
white
False[306.48, 774.02, 11.95, 6.54]521521
993page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:top_margin:left:white[255, 255, 255]
white
False[60.49, 48.93, 55.9, 8.72]Nano LettersNano Letters
994page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:top_margin:right:colored[238, 164, 167]
colored
True[537.96, 49.99, 19.47, 7.35]LetterLetter
995section_headerunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:top_margin:left:white[255, 255, 255]
white
False[60.49, 58.18, 125.07, 23.65]■ AUTHOR INFORMATION■ AUTHOR INFORMATION
996list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 68.99, 239.97, 18.61]Li, H. H.; Yabuuchi, N.; Meng, Y. S.; Kumar, S.; Breger, J.; Grey, C. P.; Shao-Horn, Y. Chem. Mater. 2007 , 19 , 2551 -2565.Li, H. H.; Yabuuchi, N.; Meng, Y. S.; Kumar, S.; Breger, J.; Grey, C. P.; Shao-Horn, Y. Chem. Mater. 2007 , 19 , 2551 -2565.
997section_headermetadataFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left:white[255, 255, 255]
white
False[60.49, 84.08, 97.03, 8.29]Corresponding AuthorsCorresponding Authors
998list_itemmetadataFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left:white[255, 255, 255]
white
False[60.49, 92.47, 130.11, 12.07]E-mail: Jiguang.zhang@pnnl.gov.E-mail: Jiguang.zhang@pnnl.gov.
999list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 89.0, 239.98, 18.61]Jarvis, K. A.; Deng, Z. Q.; Allard, L. F.; Manthiram, A.; Ferreira, P. J. Chem. Mater. 2011 , 23 , 3614 -3621.Jarvis, K. A.; Deng, Z. Q.; Allard, L. F.; Manthiram, A.; Ferreira, P. J. Chem. Mater. 2011 , 23 , 3614 -3621.
9100list_itemmetadataFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left:white[255, 255, 255]
white
False[60.49, 103.47, 140.43, 12.07]E-mail: Chongmin.wang@pnnl.gov.E-mail: Chongmin.wang@pnnl.gov.
9101section_headerunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left:white[255, 255, 255]
white
False[60.49, 120.36, 23.72, 8.29]NotesNotes
9102list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 109.01, 239.98, 18.07]Lin, F.; Markus, I. M.; Nordlund, D.; Weng, T. C.; Asta, M. D.; Xin, H. L.; Doeff, M. M. Nat. Commun. 2014 , 5 , 3529.Lin, F.; Markus, I. M.; Nordlund, D.; Weng, T. C.; Asta, M. D.; Xin, H. L.; Doeff, M. M. Nat. Commun. 2014 , 5 , 3529.
9103textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left:white[255, 255, 255]
white
False[60.49, 132.02, 201.38, 8.8]The authors declare no competing fi nancial interest.The authors declare no competing fi nancial interest.
9104section_headerback_matter_headingFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left:white[255, 255, 255]
white
False[60.49, 142.48, 114.79, 23.65]■ ACKNOWLEDGMENTS■ ACKNOWLEDGMENTS
9105list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.46, 148.56, 240.04, 19.04]Xu, B.; Fell, C. R.; Chi, M. F.; Meng, Y. S. Energy Environ. Sci. 2011 , 4 , 2223 -2233.Xu, B.; Fell, C. R.; Chi, M. F.; Meng, Y. S. Energy Environ. Sci. 2011 , 4 , 2223 -2233.
9106list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.46, 129.03, 240.0, 18.56]Boulineau, A.; Simonin, L.; Colin, J. F.; Bourbon, C.; Patoux, S. Nano Lett. 2013 , 13 , 3857 -63.Boulineau, A.; Simonin, L.; Colin, J. F.; Bourbon, C.; Patoux, S. Nano Lett. 2013 , 13 , 3857 -63.
9107textback_matter_textFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 168.7, 239.99, 228.77]We appreciate the bene fi cial discussion of Dr. Ping Lu of Sandia National Laboratory during the course of this work. This work was supported by the Assistant Secretary for Energy E ffi ciency and Renewable Energy, Off…We appreciate the bene fi cial discussion of Dr. Ping Lu of Sandia National Laboratory during the course of this work. This work was supported by the Assistant Secretary for Energy E ffi ciency and Renewable Energy, Off…
9108list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 239.01, 240.0, 18.56]Fell, C. R.; Qian, D. N.; Carroll, K. J.; Chi, M. F.; Jones, J. L.; Meng, Y. S. Chem. Mater. 2013 , 25 , 1621 -1629.Fell, C. R.; Qian, D. N.; Carroll, K. J.; Chi, M. F.; Jones, J. L.; Meng, Y. S. Chem. Mater. 2013 , 25 , 1621 -1629.
9109list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 218.51, 240.0, 19.1]Qian, D.; Xu, B.; Chi, M.; Meng, Y. S. Phys. Chem. Chem. Phys. 2014 , 16 , 14665 -14668.Qian, D.; Xu, B.; Chi, M.; Meng, Y. S. Phys. Chem. Chem. Phys. 2014 , 16 , 14665 -14668.
9110list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 259.02, 239.97, 18.56]Yu, H.; Ishikawa, R.; So, Y. G.; Shibata, N.; Kudo, T.; Zhou, H.; Ikuhara, Y. Angew. Chem., Int. Ed. Engl. 2013 , 52 , 5969 -73.Yu, H.; Ishikawa, R.; So, Y. G.; Shibata, N.; Kudo, T.; Zhou, H.; Ikuhara, Y. Angew. Chem., Int. Ed. Engl. 2013 , 52 , 5969 -73.
9111list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 279.04, 239.99, 28.53]Gu, M.; Belharouak, I.; Genc, A.; Wang, Z.; Wang, D.; Amine, K.; Gao, F.; Zhou, G.; Thevuthasan, S.; Baer, D. R.; Zhang, J. G.; Browning, N. D.; Liu, J.; Wang, C. Nano Lett. 2012 , 12 , 5186 -91.Gu, M.; Belharouak, I.; Genc, A.; Wang, Z.; Wang, D.; Amine, K.; Gao, F.; Zhou, G.; Thevuthasan, S.; Baer, D. R.; Zhang, J. G.; Browning, N. D.; Liu, J.; Wang, C. Nano Lett. 2012 , 12 , 5186 -91.
9112list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 309.03, 240.0, 27.94]Rana, J.; Stan, M.; Kloepsch, R.; Li, J.; Schumacher, G.; Welter, E.; Zizak, I.; Banhart, J.; Winter, M. Adv. Energy Mater. 2014 , 4 , 1300998.Rana, J.; Stan, M.; Kloepsch, R.; Li, J.; Schumacher, G.; Welter, E.; Zizak, I.; Banhart, J.; Winter, M. Adv. Energy Mater. 2014 , 4 , 1300998.
9113list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 339.02, 240.01, 28.59]Li, B.; Gu, M.; Nie, Z. M.; Shao, Y. Y.; Luo, Q. T.; Wei, X. L.; Li, X. L.; Xiao, J.; Wang, C. M.; Sprenlde, V.; Wang, W. Nano Lett. 2013 , 13 , 1330 -1335.Li, B.; Gu, M.; Nie, Z. M.; Shao, Y. Y.; Luo, Q. T.; Wei, X. L.; Li, X. L.; Xiao, J.; Wang, C. M.; Sprenlde, V.; Wang, W. Nano Lett. 2013 , 13 , 1330 -1335.
9114list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.46, 169.0, 240.03, 28.59]Gu, M.; Belharouak, I.; Zheng, J. M.; Wu, H. M.; Xiao, J.; Genc, A.; Amine, K.; Thevuthasan, S.; Baer, D. R.; Zhang, J. G.; Browning, N. D.; Liu, J.; Wang, C. M. ACS Nano 2013 , 7 , 760 -767.Gu, M.; Belharouak, I.; Zheng, J. M.; Wu, H. M.; Xiao, J.; Genc, A.; Amine, K.; Thevuthasan, S.; Baer, D. R.; Zhang, J. G.; Browning, N. D.; Liu, J.; Wang, C. M. ACS Nano 2013 , 7 , 760 -767.
9115list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.46, 389.02, 240.01, 18.56]Breger, J.; Meng, Y. S.; Hinuma, Y.; Kumar, S.; Kang, K.; ShaoHorn, Y.; Ceder, G.; Grey, C. P. Chem. Mater. 2006 , 18 , 4768 -4781.Breger, J.; Meng, Y. S.; Hinuma, Y.; Kumar, S.; Kang, K.; ShaoHorn, Y.; Ceder, G.; Grey, C. P. Chem. Mater. 2006 , 18 , 4768 -4781.
9116list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.46, 368.52, 240.04, 19.1]Yabuuchi, N.; Yoshii, K.; Myung, S. T.; Nakai, I.; Komaba, S. J. Am. Chem. Soc. 2011 , 133 , 4404 -4419.Yabuuchi, N.; Yoshii, K.; Myung, S. T.; Nakai, I.; Komaba, S. J. Am. Chem. Soc. 2011 , 133 , 4404 -4419.
9117list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.46, 198.5, 240.0, 19.09]Zheng, J.; Gu, M.; Xiao, J.; Zuo, P.; Wang, C.; Zhang, J. G. Nano Lett. 2013 , 13 , 3824 -30.Zheng, J.; Gu, M.; Xiao, J.; Zuo, P.; Wang, C.; Zhang, J. G. Nano Lett. 2013 , 13 , 3824 -30.
9118list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 424.53, 239.95, 19.04]Kang, K. S.; Meng, Y. S.; Breger, J.; Grey, C. P.; Ceder, G. Science 2006 , 311 , 977 -980.Kang, K. S.; Meng, Y. S.; Breger, J.; Grey, C. P.; Ceder, G. Science 2006 , 311 , 977 -980.
9119section_headerback_matter_headingFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left:white[255, 255, 255]
white
False[60.49, 399.13, 73.27, 23.65]■ REFERENCES■ REFERENCES
9120list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.46, 409.04, 240.01, 28.53]Armstrong, A. R.; Holzapfel, M.; Novak, P.; Johnson, C. S.; Kang, S. H.; Thackeray, M. M.; Bruce, P. G. J. Am. Chem. Soc. 2006 , 128 , 8694 -8698.Armstrong, A. R.; Holzapfel, M.; Novak, P.; Johnson, C. S.; Kang, S. H.; Thackeray, M. M.; Bruce, P. G. J. Am. Chem. Soc. 2006 , 128 , 8694 -8698.
9121list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 444.54, 239.95, 19.04]Lee, J.; Urban, A.; Li, X.; Su, D.; Hautier, G.; Ceder, G. Science 2014 , 343 , 519 -22.Lee, J.; Urban, A.; Li, X.; Su, D.; Hautier, G.; Ceder, G. Science 2014 , 343 , 519 -22.
9122list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.46, 438.54, 240.0, 19.04]Qian, D.; Xu, B.; Chi, M.; Meng, Y. S. Phys. Chem. Chem. Phys. 2014 , 16 , 14665 -8.Qian, D.; Xu, B.; Chi, M.; Meng, Y. S. Phys. Chem. Chem. Phys. 2014 , 16 , 14665 -8.
9123list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 464.5, 240.0, 19.1]Meng, Y. S.; Arroyo-de Dompablo, M. E. Acc. Chem. Res. 2013 , 46 , 1171 -1180.Meng, Y. S.; Arroyo-de Dompablo, M. E. Acc. Chem. Res. 2013 , 46 , 1171 -1180.
9124list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 458.56, 239.98, 19.04]Guilmard, M.; Croguennec, L.; Denux, D.; Delmas, C. Chem. Mater. 2003 , 15 , 4476 -4483.Guilmard, M.; Croguennec, L.; Denux, D.; Delmas, C. Chem. Mater. 2003 , 15 , 4476 -4483.
9125list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 484.51, 240.0, 18.44]Xu, J.; Lee, D. H.; Meng, Y. S. Funct. Mater. Lett. 2013 , 6 , 1330001.Xu, J.; Lee, D. H.; Meng, Y. S. Funct. Mater. Lett. 2013 , 6 , 1330001.
9126list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 478.99, 240.0, 28.59]Gu, M.; Genc, A.; Belharouak, I.; Wang, D. P.; Amine, K.; Thevuthasan, S.; Baer, D. R.; Zhang, J. G.; Browning, N. D.; Liu, J.; Wang, C. M. Chem. Mater. 2013 , 25 , 2319 -2326.Gu, M.; Genc, A.; Belharouak, I.; Wang, D. P.; Amine, K.; Thevuthasan, S.; Baer, D. R.; Zhang, J. G.; Browning, N. D.; Liu, J.; Wang, C. M. Chem. Mater. 2013 , 25 , 2319 -2326.
9127list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 505.01, 239.96, 28.59]Nam, K. W.; Bak, S. M.; Hu, E. Y.; Yu, X. Q.; Zhou, Y. N.; Wang, X. J.; Wu, L. J.; Zhu, Y. M.; Chung, K. Y.; Yang, X. Q. Adv. Funct. Mater. 2013 , 23 , 1047 -1063.Nam, K. W.; Bak, S. M.; Hu, E. Y.; Yu, X. Q.; Zhou, Y. N.; Wang, X. J.; Wu, L. J.; Zhu, Y. M.; Chung, K. Y.; Yang, X. Q. Adv. Funct. Mater. 2013 , 23 , 1047 -1063.
9128list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 508.55, 240.04, 19.04]Zhang, X. F.; Xu, R.; Li, L.; Yu, C.; Ren, Y.; Belharouak, I. J. Electrochem. Soc. 2013 , 160 , A1079 -A1083.Zhang, X. F.; Xu, R.; Li, L.; Yu, C.; Ren, Y.; Belharouak, I. J. Electrochem. Soc. 2013 , 160 , A1079 -A1083.
9129list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right:white[255, 255, 255]
white
False[328.48, 525.96, 206.3, 11.61]Hillyard, S.; Silcox, J. Ultramicroscopy 1995 , 58 , 6 -17.Hillyard, S.; Silcox, J. Ultramicroscopy 1995 , 58 , 6 -17.
9130list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 535.01, 239.98, 18.56]Sun, Y. K.; Myung, S. T.; Park, B. C.; Prakash, J.; Belharouak, I.; Amine, K. Nat. Mater. 2009 , 8 , 320 -4.Sun, Y. K.; Myung, S. T.; Park, B. C.; Prakash, J.; Belharouak, I.; Amine, K. Nat. Mater. 2009 , 8 , 320 -4.
9131list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 538.54, 240.0, 19.04]Kirkland, E. J.; Loane, R. F.; Silcox, J. Ultramicroscopy 1987 , 23 , 77 -96.Kirkland, E. J.; Loane, R. F.; Silcox, J. Ultramicroscopy 1987 , 23 , 77 -96.
9132list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 555.02, 239.94, 18.56]Ceder, G.; Chiang, Y. M.; Sadoway, D. R.; Aydinol, M. K.; Jang, Y. I.; Huang, B. Nature 1998 , 392 , 694 -696.Ceder, G.; Chiang, Y. M.; Sadoway, D. R.; Aydinol, M. K.; Jang, Y. I.; Huang, B. Nature 1998 , 392 , 694 -696.
9133list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left:white[255, 255, 255]
white
False[64.46, 572.0, 212.14, 11.61]Tarascon, J. M.; Armand, M. Nature 2001 , 414 , 359 -67.Tarascon, J. M.; Armand, M. Nature 2001 , 414 , 359 -67.
9134list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 559.04, 240.0, 18.56]Lu, Z. H.; Beaulieu, L. Y.; Donaberger, R. A.; Thomas, C. L.; Dahn, J. R. J. Electrochem. Soc. 2002 , 149 , A778 -A791.Lu, Z. H.; Beaulieu, L. Y.; Donaberger, R. A.; Thomas, C. L.; Dahn, J. R. J. Electrochem. Soc. 2002 , 149 , A778 -A791.
9135list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 584.52, 239.98, 19.04]Marom, R.; Amalraj, S. F.; Leifer, N.; Jacob, D.; Aurbach, D. J. Mater. Chem. 2011 , 21 , 9938 -9954.Marom, R.; Amalraj, S. F.; Leifer, N.; Jacob, D.; Aurbach, D. J. Mater. Chem. 2011 , 21 , 9938 -9954.
9136list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 578.51, 240.0, 19.1]Noh, H.-J.; Myung, S.-T.; Lee, Y. J.; Sun, Y.-K. Chem. Mater. 2014 , 26 , 5973 -5979.Noh, H.-J.; Myung, S.-T.; Lee, Y. J.; Sun, Y.-K. Chem. Mater. 2014 , 26 , 5973 -5979.
9137list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 605.02, 239.94, 18.56]Thackeray, M. M.; Johnson, C. S.; Vaughey, J. T.; Li, N.; Hackney, S. A. J. Mater. Chem. 2005 , 15 , 2257 -2267.Thackeray, M. M.; Johnson, C. S.; Vaughey, J. T.; Li, N.; Hackney, S. A. J. Mater. Chem. 2005 , 15 , 2257 -2267.
9138list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 598.53, 240.0, 19.04]Pearson, D. H.; Ahn, C. C.; Fultz, B. Phys. Rev. B 1993 , 47 , 8471 -8478.Pearson, D. H.; Ahn, C. C.; Fultz, B. Phys. Rev. B 1993 , 47 , 8471 -8478.
9139list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right:white[255, 255, 255]
white
False[328.48, 615.99, 234.08, 11.61]Wang, Z. L.; Yin, J. S.; Jiang, Y. D. Micron 2000 , 31 , 571 -80.Wang, Z. L.; Yin, J. S.; Jiang, Y. D. Micron 2000 , 31 , 571 -80.
9140list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 625.04, 240.0, 28.53]Zheng, J.; Gu, M.; Genc, A.; Xiao, J.; Xu, P.; Chen, X.; Zhu, Z.; Zhao, W.; Pullan, L.; Wang, C.; Zhang, J. G. Nano Lett. 2014 , 14 , 2628 -35.Zheng, J.; Gu, M.; Genc, A.; Xiao, J.; Xu, P.; Chen, X.; Zhu, Z.; Zhao, W.; Pullan, L.; Wang, C.; Zhang, J. G. Nano Lett. 2014 , 14 , 2628 -35.
9141list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 628.52, 240.0, 19.1]Ohzuku, T.; Kitagawa, M.; Hirai, T. J. Electrochem. Soc. 1990 , 137 , 769 -775.Ohzuku, T.; Kitagawa, M.; Hirai, T. J. Electrochem. Soc. 1990 , 137 , 769 -775.
9142list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 654.54, 239.92, 19.03]Kam, K. C.; Mehta, A.; Heron, J. T.; Doeff, M. M. J. Electrochem. Soc. 2012 , 159 , A1383 -A1392.Kam, K. C.; Mehta, A.; Heron, J. T.; Doeff, M. M. J. Electrochem. Soc. 2012 , 159 , A1383 -A1392.
9143list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 649.02, 240.02, 18.56]Hwang, S.; Chang, W.; Kim, S. M.; Su, D.; Kim, D. H.; Lee, J. Y.; Chung, K. Y.; Stach, E. A. Chem. Mater. 2014 , 26 , 1084 -1092.Hwang, S.; Chang, W.; Kim, S. M.; Su, D.; Kim, D. H.; Lee, J. Y.; Chung, K. Y.; Stach, E. A. Chem. Mater. 2014 , 26 , 1084 -1092.
9144list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 674.55, 239.94, 19.04]Kim, D.; Croy, J. R.; Thackeray, M. M. Electrochem. Commun. 2013 , 36 , 103 -106.Kim, D.; Croy, J. R.; Thackeray, M. M. Electrochem. Commun. 2013 , 36 , 103 -106.
9145list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 669.03, 240.02, 18.56]Thackeray, M. M.; David, W. I. F.; Bruce, P. G.; Goodenough, J. B. Mater. Res. Bull. 1983 , 18 , 461 -472.Thackeray, M. M.; David, W. I. F.; Bruce, P. G.; Goodenough, J. B. Mater. Res. Bull. 1983 , 18 , 461 -472.
9146list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right:white[255, 255, 255]
white
False[328.48, 686.0, 207.79, 11.61]Kresse, G.; Hafner, J. Phys. Rev. B 1993 , 47 , 558 -561.Kresse, G.; Hafner, J. Phys. Rev. B 1993 , 47 , 558 -561.
9147list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 691.96, 240.01, 20.99]Guan, D.; Jeevarajan, J. A.; Wang, Y. Nanoscales 2011 , 3 , 1465 -1469.Guan, D.; Jeevarajan, J. A.; Wang, Y. Nanoscales 2011 , 3 , 1465 -1469.
9148list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:page_body:right_crossing:white[255, 255, 255]
white
False[324.45, 698.53, 239.98, 19.04]Hai, B.; Shukla, A. K.; Duncan, H.; Chen, G. Y. J. Mater. Chem. A 2013 , 1 , 759 -769.Hai, B.; Shukla, A. K.; Duncan, H.; Chen, G. Y. J. Mater. Chem. A 2013 , 1 , 759 -769.
9149list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left_crossing:white[255, 255, 255]
white
False[60.49, 714.52, 239.96, 19.1]Lu, Z. H.; MacNeil, D. D.; Dahn, J. R. Electrochem Solid St. 2001 , 4 , A191 -A194.Lu, Z. H.; MacNeil, D. D.; Dahn, J. R. Electrochem Solid St. 2001 , 4 , A191 -A194.
9150list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:page_body:left:white[255, 255, 255]
white
False[64.46, 731.98, 214.38, 11.61]Wang, Y.; Cao, G. Z. Adv. Mater. 2008 , 20 , 2251 -2269.Wang, Y.; Cao, G. Z. Adv. Mater. 2008 , 20 , 2251 -2269.
9151list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:body_region:0p9:bottom_margin:left_crossing:white[255, 255, 255]
white
False[60.49, 744.99, 239.94, 19.05]Meng, Y. S.; Ceder, G.; Grey, C. P.; Yoon, W. S.; Jiang, M.; Bre ́ ger, J.; Shao-Horn, Y. Chem. Mater. 2005 , 17 , 2386 -2394.Meng, Y. S.; Ceder, G.; Grey, C. P.; Yoon, W. S.; Jiang, M.; Bre ́ ger, J.; Shao-Horn, Y. Chem. Mater. 2005 , 17 , 2386 -2394.
9152page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:bottom_margin:left_crossing:white[255, 255, 255]
white
False[306.48, 774.02, 11.95, 6.54]522522
9153page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp9:bottom_margin:right:white[255, 255, 255]
white
False[411.19, 773.27, 153.29, 7.74]dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522dx.doi.org/10.1021/nl5038598 | Nano Lett. 2015, 15, 514 -522