Docling layout block audit

original.pdf docling.json layout_blocks.json layout_blocks.tsv layout_blocks.jsonl excluded_blocks.html excluded_blocks.tsv final_body_blocks.tsv visual_assets.tsv visual_assets.json

Summary

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Diff Summary

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Truncation

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Page Overlays

Green = final body chunks. Orange/purple asset boxes = actual figure/table assets used by ingestion. Cyan dashed text boxes = text blocks consumed by those assets as caption continuations. Red STOP = truncation trigger. Red boxes = blocks after truncation.

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Visual Assets

这里对齐真实图表资产提取链路。caption_source=embedded_table_cell 表示表注来自 Docling table cell，不会出现在 text block 审计差集里；caption_continuation_used_by_asset 表示某个 text block 已被图表 caption 吸收，不应按普通 metadata 解读。

#typelabelpagecaption sourcesuppressedduplicate reasonrescue reasongroupconfidencebboxcaption
1figureDocling Figure 11missing_caption0.55[196.92, 321.27, 246.16, 181.79]
2figureFig. 12direct_caption_ref0.82[131.0, 691.82, 342.01, 35.22]Fig. 1. The reaction mechanism of eliminating H2O and HF by nitriles.
3figureFig. 24direct_caption_ref0.82[74.37, 66.21, 457.39, 410.28]Fig. 2. (a) The conductivity of commercial electrolytes containing different weight ratios of succinonitrile at temperatures range from 30  C to 80  C. (b) LSV of the 1 M LiPF6/EC/ DEC commercial electrolyte with or without 1wt% SN. Working electrode: Pt, counter and reference electrodes: Li, scan rate: 1 mV s 1 . (c) Frontier molecular orbitals of EC, DEC and SN and their energies of occupied (HOMO) and unoccupied (LUMO) (in Ha). (d) Discharge capacity after 50 cycles of Li/Li1.2Ni0.2Mn0.6O2 half-cells containing various weight ratios of SN.
4figureFig. 34direct_caption_ref0.82[102.73, 543.9, 399.68, 163.5]Fig. 3. Ac impedance spectra of the Li/Li1.2Ni0.2Mn0.6O2 half-cells containing various weight ratios of SN: (a) After 1 cycles, (b) After 5 cycles.
5figureFig. 45direct_caption_ref0.82[107.9, 66.22, 370.32, 148.69]Fig. 4. TGA diagrams and DTG curves of commercial electrolyte (a) and 1wt % SN electrolyte (b).
6figureFig. 55direct_caption_ref0.82[35.06, 528.66, 245.99, 181.36]Fig. 5. Discharge capacities and coulombic ef fi ciencies of the Li/Li1.2Ni0.2Mn0.6O2 half-cells at a 0.1 C current density with or without 1wt % SN at 55  C, the inset displays SEM images of the batteries after 50 cycles.
7figureFig. 66direct_caption_ref0.82[116.85, 66.57, 371.3, 279.88]Fig. 6. Discharge capacities of Li/Li1.2Ni0.2Mn0.6O2 with 1wt% SN-based electrolyte at different cut-off voltages: (a) 2.0 e 4.8 V, (b) 2.0 e 4.9 V, (c) 2.0 e 5.0 V and (d) 2.0 e 5.2 V.
8figureFig. 76direct_caption_ref0.82[131.2, 382.85, 341.58, 172.34]Fig. 7. SEM images of the surface of LNMO cathode after 5 cycles with: (a) commercial electrolyte (b) 1wt% SN.
9figureFig. 87direct_caption_ref0.82[52.24, 66.75, 482.78, 295.51]Fig. 8. XPS spectra of the regions of Li1.2Ni0.2Mn0.6O2 after 50 cycles: (a) N1s with commercial electrolyte, (b) N1s with 1wt% SN-based electrolyte, (c) Mn2p with commercial electrolyte, (d) Mn2p with 1wt% SN-based electrolyte, (e) Ni2p with commercial electrolyte, (f) Ni2p with 1wt% SN-based electrolyte.

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white		False[228.36, 47.78, 129.01, 6.37]Journal of Power Sources 306 (2016) 70 e 77Journal of Power Sources 306 (2016) 70 e 77
11textfront_matter_headingFalselowfirst_page_metadatafirst_page_metadata
p1:page_body:column_2_of_2:gray[229, 229, 229]
gray		False[216.51, 79.77, 156.17, 1.59]Contents lists available at ScienceDirectContents lists available at ScienceDirect
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p1:page_body:column_2_of_2:gray[229, 229, 229]
gray		False[210.56, 98.49, 167.92, 12.99]Journal of Power SourcesJournal of Power Sources
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gray		False[165.09, 135.72, 258.93, 1.59]j o urnal homepage: www.elsevier.com/locate/jpowsourj o urnal homepage:
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p1:page_body:column_1_of_2:white[255, 255, 255]
white		False[32.83, 178.39, 420.44, 29.76]An investigation of functionalized electrolyte using succinonitrile additive for high voltage lithium-ion batteriesAn investigation of functionalized electrolyte using succinonitrile additive for high voltage lithium-ion batteries
15textaffiliationFalsemediumfront_matter_author_linefront_matter_author_line
p1:page_body:column_1_of_2:white[255, 255, 255]
white		False[32.83, 217.13, 438.2, 26.17]Renjie Chen a, b, * , Fan Liu a , Yan Chen a , Yusheng Ye a , Yongxin Huang a , Feng Wu a, b, ** , Li Li a, bRenjie Chen a, b, * , Fan Liu a , Yan Chen a , Yusheng Ye a , Yongxin Huang a , Feng Wu a, b, ** , Li Li a, b
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white		False[32.82, 250.08, 437.89, 15.93]a School of Materials Science & Engineering, Beijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, Chinaa School of Materials Science & Engineering, Beijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
17footnotefootnoteFalselowdocling_footnotedocling_footnote
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white		False[32.83, 267.2, 250.38, 7.37]b Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100081, Chinab Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100081, China
18section_headerfront_matter_headingFalselowfront_matter_headingfront_matter_heading
p1:page_body:column_1_of_2:unknownNone
unknown		False[32.83, 305.29, 86.34, 0.06]h i g h l i g h t sh i g h l i g h t s
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white		False[32.83, 319.33, 133.2, 26.1] The SN-based electrolytes show better thermal stability and wider electrochemical window. The SN-based electrolytes show better thermal stability and wider electrochemical window.
110list_itembodyTruerecovered_body_outside_flowrecovered_body_outside_flow
p1:page_body:column_1_of_2:white[255, 255, 255]
white		False[32.83, 348.01, 133.26, 26.1] The effects of SN on the electrochemical performances of LIBs have been investigated. The effects of SN on the electrochemical performances of LIBs have been investigated.
111list_itembodyTruerecovered_body_outside_flowrecovered_body_outside_flow
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white		False[32.83, 376.76, 133.25, 26.04] The 1 wt % SN-containing electrolyte improves cycle performance of LNMO batteries. The 1 wt % SN-containing electrolyte improves cycle performance of LNMO batteries.
112section_headerfront_matter_headingFalselowfront_matter_headingfront_matter_heading
p1:page_body:column_1_of_2:unknownNone
unknown		False[32.83, 537.0, 95.61, 0.06]a r t i c l e i n f oa r t i c l e i n f o
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white		False[32.83, 558.33, 107.65, 48.74]Article history: Received 16 July 2015 Received in revised form 27 October 2015 Accepted 28 October 2015 Available online 13 December 2015Article history: Received 16 July 2015 Received in revised form 27 October 2015 Accepted 28 October 2015 Available online 13 December 2015
114footnotefootnoteFalselowfirst_page_metadatafirst_page_metadata
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white		False[32.83, 648.88, 251.1, 24.01]* Corresponding author. School of Materials Science & Engineering, Beijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China.* Corresponding author. School of Materials Science & Engineering, Beijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China.
115footnotefootnoteFalselowfirst_page_metadatafirst_page_metadata
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white		False[32.83, 675.13, 251.1, 23.95]** Corresponding author. School of Materials Science & Engineering, Beijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China.** Corresponding author. School of Materials Science & Engineering, Beijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China.
116footnotefootnoteFalselowfirst_page_metadatafirst_page_metadata
p1:page_body:column_1_of_2:white[255, 255, 255]
white		False[32.83, 701.71, 250.98, 14.5]E-mail addresses: chenrj@bit.edu.cn (R. Chen), wufeng863@vip.sina.com (F. Wu).E-mail addresses: chenrj@bit.edu.cn (R. Chen), wufeng863@vip.sina.com (F. Wu).
117page_footerpage_footerFalselowfirst_page_metadatafirst_page_metadata
p1:bottom_margin:column_1_of_2:white[248, 251, 252]
white		False[32.83, 728.64, 144.66, 5.94]http://dx.doi.org/10.1016/j.jpowsour.2015.10.105
118page_footerpage_footerFalselowfirst_page_metadatafirst_page_metadata
p1:bottom_margin:column_1_of_2:white[255, 255, 255]
white		False[32.83, 735.78, 156.13, 7.43]0378-7753/ © 2015 Elsevier B.V. All rights reserved.0378-7753/ © 2015 Elsevier B.V. All rights reserved.
119section_headerbody_headingFalselowbody_headingbody_heading
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unknown		False[197.22, 305.29, 152.63, 0.06]g r a p h i c a l a b s t r a c tg r a p h i c a l a b s t r a c t
120section_headerabstract_headingFalselowabstract_headingabstract_heading
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unknown		False[197.23, 537.0, 67.73, 0.06]a b s t r a c ta b s t r a c t
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white		False[197.23, 551.28, 355.66, 73.58]Succinonitrile (SN) has been used as functional additive to improve the thermal stability and broaden the oxidation electrochemical window of commercial electrolyte 1 M LiPF6/EC/DEC (1:1, by volume) for highvoltage LIBs…Succinonitrile (SN) has been used as functional additive to improve the thermal stability and broaden the oxidation electrochemical window of commercial electrolyte 1 M LiPF6/EC/DEC (1:1, by volume) for highvoltage LIBs…
222textfront_matter_headingFalselowfront_matter_headingfront_matter_heading
p2:body_region:0p2:front_matter:column_1_of_2:white[255, 255, 255]
white		False[42.52, 72.47, 51.66, 31.68]Keywords: Succinonitrile High voltage Thermal stabilityKeywords: Succinonitrile High voltage Thermal stability
223textabstract_candidateFalsemediuminside_abstractinside_abstract
p2:body_region:0p2:front_matter:column_1_of_2:white[255, 255, 255]
white		False[42.52, 106.77, 87.78, 5.94]Cathode electrolyte interfaceCathode electrolyte interface
224section_headerbody_headingFalselowbody_headingbody_heading
p2:body_region:0p2:body_zone:column_1_of_2:white[255, 255, 255]
white		False[42.52, 155.29, 62.12, 7.97]1. Introduction1. Introduction
225textbodyTruebodybody
p2:body_region:0p2:body_zone:column_1_of_2:white[255, 255, 255]
white		False[42.52, 176.64, 251.09, 153.92]Lithium-ion batteries (LIBs) have been widely used in portable electronic devices since their commercialization. To satisfy the forceful motive power requirement of electric vehicle (EVs), hybrid electric vehicles (HEVs…Lithium-ion batteries (LIBs) have been widely used in portable electronic devices since their commercialization. To satisfy the forceful motive power requirement of electric vehicle (EVs), hybrid electric vehicles (HEVs…
226textbodyTruebodybody
p2:body_region:0p2:body_zone:column_1_of_2:white[255, 255, 255]
white		False[42.52, 333.56, 251.16, 185.27]There are mainly two ways to improve high-voltage electrolyte, fi nding new stable solvents and searching for novel functional additives. Fluorinated solvents, nitrile compounds, sulfone compounds, and ionic liquids are…There are mainly two ways to improve high-voltage electrolyte, fi nding new stable solvents and searching for novel functional additives. Fluorinated solvents, nitrile compounds, sulfone compounds, and ionic liquids are…
227textbodyTruebodybody
p2:body_region:0p2:body_zone:column_1_of_2:white[255, 255, 255]
white		False[42.52, 521.84, 251.13, 112.08]Among various high-voltage cathode materials, Li1.2Ni0.2Mn0.6O2 is one of the most promising candidates which can provide much higher capacity than the traditional cathode materials such as LiCoO2 and LiMn2O4 spinel [12…Among various high-voltage cathode materials, Li1.2Ni0.2Mn0.6O2 is one of the most promising candidates which can provide much higher capacity than the traditional cathode materials such as LiCoO2 and LiMn2O4 spinel [12…
228textbodyTruebodybody
p2:body_region:0p2:body_zone:column_1_of_2:white[255, 255, 255]
white		False[42.52, 636.93, 251.07, 28.99]LiPF6 can be easily hydrolyzed when electrolyte exist water and acidic impurities [17]. As shown in Fig. 1, Nitriles can react with water in the acidic condition (H þ ) as shown in the fi rst two steps ofLiPF6 can be easily hydrolyzed when electrolyte exist water and acidic impurities [17]. As shown in Fig. 1, Nitriles can react with water in the acidic condition (H þ ) as shown in the fi rst two steps of
229page_headerpage_headerFalselowdocling_page_headerdocling_page_header
p2:body_region:1p2:top_margin:column_2_of_2:white[255, 255, 255]
white		False[218.72, 47.78, 167.65, 6.37]R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77
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white		False[555.48, 48.2, 7.11, 5.94]7171
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white		False[206.93, 68.66, 355.72, 25.79]formed by interfacial reactions between the LNMO cathode and electrolyte. The outcome of this work and the continuous research on this subject can generate critical knowledge for designing thermal stability electrolytes…formed by interfacial reactions between the LNMO cathode and electrolyte. The outcome of this work and the continuous research on this subject can generate critical knowledge for designing thermal stability electrolytes…
232textmetadataFalselowoutside_body_flow_metadata_lineoutside_body_flow_metadata_line
p2:body_region:1p2:front_matter:column_2_of_2:white[255, 255, 255]
white		False[425.93, 95.74, 136.69, 8.36]© 2015 Elsevier B.V. All rights reserved.© 2015 Elsevier B.V. All rights reserved.
233textbodyTruebodybody
p2:body_region:1p2:body_zone:column_2_of_2:white[255, 255, 255]
white		False[311.53, 155.72, 251.04, 59.75]the equation, then water content drops down which relieves the process of LiPF6 decomposed into HF at the same time. In total, not only does it can eliminate H2O and HF which would promote Mn/ Ni dissolution from the ca…the equation, then water content drops down which relieves the process of LiPF6 decomposed into HF at the same time. In total, not only does it can eliminate H2O and HF which would promote Mn/ Ni dissolution from the ca…
234textbodyTruebodybody
p2:body_region:1p2:body_zone:column_2_of_2:white[255, 255, 255]
white		False[311.53, 218.48, 251.07, 195.76]Above all, previous researches have proved that nitrile-based electrolytes are very suitable for high-voltage cathodes. Yaser proposed that glutaronitrile is suitable for high energy/power Liion batteries as a co-solven…Above all, previous researches have proved that nitrile-based electrolytes are very suitable for high-voltage cathodes. Yaser proposed that glutaronitrile is suitable for high energy/power Liion batteries as a co-solven…
235textbodyTruebodybody
p2:body_region:1p2:body_zone:column_2_of_2:white[255, 255, 255]
white		False[311.53, 417.24, 251.05, 70.18]In this paper we studied succinonitrile (SN) as a commercial electrolyte additive to improve the cycling performance and thermal stability of the Li1.2 Ni 0.2Mn0.6O2/Li system in high cut-off voltage. Furthermore, the c…In this paper we studied succinonitrile (SN) as a commercial electrolyte additive to improve the cycling performance and thermal stability of the Li1.2 Ni 0.2Mn0.6O2/Li system in high cut-off voltage. Furthermore, the c…
236section_headerbody_headingFalselowbody_headingbody_heading
p2:body_region:1p2:body_zone:column_2_of_2:white[255, 255, 255]
white		False[311.53, 511.09, 65.35, 7.97]2. Experimental2. Experimental
237section_headerbody_headingFalselowbody_headingbody_heading
p2:body_region:1p2:body_zone:column_2_of_2:white[255, 255, 255]
white		False[311.53, 532.44, 139.92, 7.42]2.1. Preparation of electrolyte systems2.1. Preparation of electrolyte systems
238textbodyTruebodybody
p2:body_region:1p2:body_zone:column_2_of_2:white[255, 255, 255]
white		False[311.53, 553.36, 251.1, 112.08]The electrolyte of 1 M LiPF6 dissolved in ethylene carbonate (EC): Diethyl carbonate (DEC) (1:1, by volume), which was purchased from Zhangjiagang Guotai Huarong Chemical New Material Co. Ltd (named commercial electroly…The electrolyte of 1 M LiPF6 dissolved in ethylene carbonate (EC): Diethyl carbonate (DEC) (1:1, by volume), which was purchased from Zhangjiagang Guotai Huarong Chemical New Material Co. Ltd (named commercial electroly…
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p2:body_region:1p2:bottom_margin:column_2_of_2:white[255, 255, 255]
white		False[199.33, 737.02, 206.37, 6.38]Fig. 1. The reaction mechanism of eliminating H2O and HF by nitriles.Fig. 1. The reaction mechanism of eliminating H2O and HF by nitriles.
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p3:body_region:0p3:top_margin:column_1_of_2:white[255, 255, 255]
white		False[32.82, 48.21, 7.16, 5.94]7272
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p3:body_region:0p3:body_zone:column_1_of_2:white[255, 255, 255]
white		False[32.83, 66.77, 229.41, 7.42]2.2. Preparation of the electrodes and the construction of cells2.2. Preparation of the electrodes and the construction of cells
342textbodyTruebodybody
p3:body_region:0p3:body_zone:column_1_of_2:white[255, 255, 255]
white		False[32.82, 87.69, 251.08, 70.18]Li1.2Ni0.2Mn0.6O2 electrode material was prepared by coprecipitation according to the previous work [27]. The electrode consisted of Li1.2Ni0.2Mn0.6O2, acetylene black and PVDF in a weight ratio of 8:1:1, coating onto a…Li1.2Ni0.2Mn0.6O2 electrode material was prepared by coprecipitation according to the previous work [27]. The electrode consisted of Li1.2Ni0.2Mn0.6O2, acetylene black and PVDF in a weight ratio of 8:1:1, coating onto a…
343section_headerbody_headingFalselowbody_headingbody_heading
p3:body_region:0p3:body_zone:column_1_of_2:white[255, 255, 255]
white		False[32.83, 171.36, 129.89, 7.42]2.3. Electrochemical measurements2.3. Electrochemical measurements
344textbodyTruebodybody
p3:body_region:0p3:body_zone:column_1_of_2:white[255, 255, 255]
white		False[32.82, 192.28, 251.13, 70.18]The electrolytes oxidation/reduction potentials were tested by an electrochemical workstation (CHI660E, Shanghai Chenhua Company) using a linear sweep voltammogram at a scan rate of 1 mV s 1 at 25  C in the voltage r…The electrolytes oxidation/reduction potentials were tested by an electrochemical workstation (CHI660E, Shanghai Chenhua Company) using a linear sweep voltammogram at a scan rate of 1 mV s 1 at 25  C in the voltage r…
345textbodyTruebodybody
p3:body_region:0p3:body_zone:column_1_of_2:white[255, 255, 255]
white		False[32.82, 265.47, 251.13, 59.75]Electrochemical impedance spectra (EIS) were measured with a Zahner Elektrik IM6e impedance analyzer over the frequency range of 10 3 Hz ~ 10 6 Hz. The electrolyte ionic conductivity was tested by Pt conductance elect…Electrochemical impedance spectra (EIS) were measured with a Zahner Elektrik IM6e impedance analyzer over the frequency range of 10 3 Hz ~ 10 6 Hz. The electrolyte ionic conductivity was tested by Pt conductance elect…
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white		False[32.83, 328.29, 251.06, 60.96]The thermal stability of the electrolytes was measured by using a thermal gravimetric analysis (TGA), performed with a Netzsch 209 F1 thermal analyzer. The samples (about 2 mL) used for measurements were fi lled and sea…The thermal stability of the electrolytes was measured by using a thermal gravimetric analysis (TGA), performed with a Netzsch 209 F1 thermal analyzer. The samples (about 2 mL) used for measurements were fi lled and sea…
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white		False[32.82, 390.52, 251.11, 49.8]The cell charge e discharge performance of the electrolytes were performing by Land battery testing system (CT2001A, Wuhan Lanhe Company) at room temperature, and the coin-type half-cells were galvanostatically cycled a…The cell charge e discharge performance of the electrolytes were performing by Land battery testing system (CT2001A, Wuhan Lanhe Company) at room temperature, and the coin-type half-cells were galvanostatically cycled a…
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white		False[32.83, 453.81, 116.72, 7.42]2.4. Materials characterizations2.4. Materials characterizations
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white		False[32.83, 474.73, 251.07, 28.34]Morphological studies on the cathodes were investigated using a fi eld emission scanning electron microscope (HITACHI S-3500N, Japan) with an accelerating voltage of 20 kV.Morphological studies on the cathodes were investigated using a fi eld emission scanning electron microscope (HITACHI S-3500N, Japan) with an accelerating voltage of 20 kV.
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white		False[32.83, 506.08, 251.13, 49.26]The surface species on the cycled cathodes was tested by X-ray photoelectron spectroscopy (XPS) using a chemical analysis (ESCA) spectrometer (PHI-1600, USA), radiated with a monochromatized AlK a (1486.6 eV) source, an…The surface species on the cycled cathodes was tested by X-ray photoelectron spectroscopy (XPS) using a chemical analysis (ESCA) spectrometer (PHI-1600, USA), radiated with a monochromatized AlK a (1486.6 eV) source, an…
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white		False[32.83, 568.41, 105.41, 7.97]3. Results and discussions3. Results and discussions
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white		False[32.82, 589.76, 251.12, 91.16]Fig. 2(a) shows the ion conductivity of the commercial electrolytes with different ratios of succinonitrile. The ionic conductivity of different ratios of SN electrolytes increased with the elevating temperature ( 40 …Fig. 2(a) shows the ion conductivity of the commercial electrolytes with different ratios of succinonitrile. The ionic conductivity of different ratios of SN electrolytes increased with the elevating temperature ( 40 …
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white		False[32.83, 683.92, 251.11, 59.75]Fig. 2(b) compares the electrochemical stability windows of the commercial electrolyte and 1wt % SN-based electrolyte by linear sweep voltammetry measurements. Comparing with the commercial electrolyte, the oxidation po…Fig. 2(b) compares the electrochemical stability windows of the commercial electrolyte and 1wt % SN-based electrolyte by linear sweep voltammetry measurements. Comparing with the commercial electrolyte, the oxidation po…
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white		False[209.03, 47.78, 167.65, 6.37]R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77
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white		False[301.83, 66.76, 251.06, 59.69]of commercial electrolyte seems high (5 V), in fact, the actual voltage limits of the electrolyte are usually much lower than those obtained with an inert electrode because of the highly catalytic characteristic of the …of commercial electrolyte seems high (5 V), in fact, the actual voltage limits of the electrolyte are usually much lower than those obtained with an inert electrode because of the highly catalytic characteristic of the …
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white		False[301.83, 129.52, 251.06, 112.02]The highest occupied molecular orbital (HOMO) energy level and the lowest unoccupied molecular orbital (LUMO) energy level can be calculated based on the molecular orbital theory, which re fl ects the ability to gain or…The highest occupied molecular orbital (HOMO) energy level and the lowest unoccupied molecular orbital (LUMO) energy level can be calculated based on the molecular orbital theory, which re fl ects the ability to gain or…
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white		False[301.83, 244.02, 251.11, 102.13]Fig. 2(d) shows the charge e discharge performance of Li/ Li1.2Ni0.2Mn0.6O2 half-cells containing electrolyte with different ratios of succinonitrile. It is found that the electrolyte containing 1wt % SN achieved the be…Fig. 2(d) shows the charge e discharge performance of Li/ Li1.2Ni0.2Mn0.6O2 half-cells containing electrolyte with different ratios of succinonitrile. It is found that the electrolyte containing 1wt % SN achieved the be…
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white		False[301.83, 349.21, 251.09, 300.3]The AC impedance spectra of Li/Li1.2Ni0.2Mn0.6O2 cells containing different ratios of SN electrolytes after the 1st and 5th cycles were measured as well (Fig. 3), and the inset graph shows the equivalent circuit of the …The AC impedance spectra of Li/Li1.2Ni0.2Mn0.6O2 cells containing different ratios of SN electrolytes after the 1st and 5th cycles were measured as well (Fig. 3), and the inset graph shows the equivalent circuit of the …
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white		False[301.83, 652.57, 251.12, 92.37]Thermal stability and cycling performance at high temperature Fig. 4(a) and (b) and show the thermal stability of commercial electrolyte and 1wt % SN-based electrolyte. The TG pro fi le indicates that both of two sample…Thermal stability and cycling performance at high temperature Fig. 4(a) and (b) and show the thermal stability of commercial electrolyte and 1wt % SN-based electrolyte. The TG pro fi le indicates that both of two sample…
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white		False[218.72, 47.78, 167.65, 6.37]R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77
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white		False[42.52, 485.86, 520.07, 32.94]Fig. 2. (a) The conductivity of commercial electrolytes containing different weight ratios of succinonitrile at temperatures range from 30  C to 80  C. (b) LSV of the 1 M LiPF6/EC/ DEC commercial electrolyte with or…Fig. 2. (a) The conductivity of commercial electrolytes containing different weight ratios of succinonitrile at temperatures range from 30  C to 80  C. (b) LSV of the 1 M LiPF6/EC/ DEC commercial electrolyte with or…
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white		False[95.02, 716.67, 415.04, 6.98]Fig. 3. Ac impedance spectra of the Li/Li1.2Ni0.2Mn0.6O2 half-cells containing various weight ratios of SN: (a) After 1 cycles, (b) After 5 cycles.Fig. 3. Ac impedance spectra of the Li/Li1.2Ni0.2Mn0.6O2 half-cells containing various weight ratios of SN: (a) After 1 cycles, (b) After 5 cycles.
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white		True[32.82, 48.2, 6.82, 5.94]7474
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white		False[150.29, 225.77, 285.11, 6.38]Fig. 4. TGA diagrams and DTG curves of commercial electrolyte (a) and 1wt % SN electrolyte (b).Fig. 4. TGA diagrams and DTG curves of commercial electrolyte (a) and 1wt % SN electrolyte (b).
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white		False[32.82, 251.88, 251.07, 92.74]main solvent EC (248  C) and DEC (125.8  C), the addition of SN leads to the tiny overall thermal stability improvement. The DTG pro fi le shows the decomposition rate of the electrolyte, and the two peaks respectivel…main solvent EC (248  C) and DEC (125.8  C), the addition of SN leads to the tiny overall thermal stability improvement. The DTG pro fi le shows the decomposition rate of the electrolyte, and the two peaks respectivel…
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white		False[32.82, 347.62, 251.13, 153.86]To further clarify the thermal stability of the mixed electrolyte, the cycle performance of the half-cells at high temperatures (55  C) has been investigated. The cells were placed in a battery-testing incubator and te…To further clarify the thermal stability of the mixed electrolyte, the cycle performance of the half-cells at high temperatures (55  C) has been investigated. The cells were placed in a battery-testing incubator and te…
568captioncaptionFalselowoutside_body_flow_captionoutside_body_flow_caption
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white		False[32.82, 719.9, 251.05, 23.4]Fig. 5. Discharge capacities and coulombic ef fi ciencies of the Li/Li1.2Ni0.2Mn0.6O2 half-cells at a 0.1 C current density with or without 1wt % SN at 55  C, the inset displays SEM images of the batteries after 50 cyc…Fig. 5. Discharge capacities and coulombic ef fi ciencies of the Li/Li1.2Ni0.2Mn0.6O2 half-cells at a 0.1 C current density with or without 1wt % SN at 55  C, the inset displays SEM images of the batteries after 50 cyc…
569page_headerpage_headerFalselowdocling_page_headerdocling_page_header
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white		False[209.03, 47.78, 167.65, 6.37]R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77
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white		False[301.83, 253.51, 251.1, 112.02]derived cathode electrolyte interface (CEI) forming in the fi rst few cycles causes an irreversible capacity loss. The improvement in the thermal stability maybe due to the strong complex formation between the surface m…derived cathode electrolyte interface (CEI) forming in the fi rst few cycles causes an irreversible capacity loss. The improvement in the thermal stability maybe due to the strong complex formation between the surface m…
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white		False[301.83, 368.54, 251.12, 206.19]Fig. 6 shows the discharge capacity of Li/Li1.2Ni0.2Mn0.6O2 halfcells with or without SN under different upper cut-off voltage. Fig. 6(a), (b), (c) and (d) are corresponding to 2.0 e 4.8 V, 2.0 e 4.9 V, 2.0 e 5.0 V and …Fig. 6 shows the discharge capacity of Li/Li1.2Ni0.2Mn0.6O2 halfcells with or without SN under different upper cut-off voltage. Fig. 6(a), (b), (c) and (d) are corresponding to 2.0 e 4.8 V, 2.0 e 4.9 V, 2.0 e 5.0 V and …
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white		False[301.83, 577.79, 251.06, 164.29]Fig. 7(a) and (b) display the SEM images of whole surface of Li1.2 Ni 0.2Mn0.6O2 with or without 1wt % SN after 5 cycles at a voltage range of 2.0 e 5.0 V. The cathode with succinonitrile forms a uniform surface layer w…Fig. 7(a) and (b) display the SEM images of whole surface of Li1.2 Ni 0.2Mn0.6O2 with or without 1wt % SN after 5 cycles at a voltage range of 2.0 e 5.0 V. The cathode with succinonitrile forms a uniform surface layer w…
673page_headerpage_headerFalselowdocling_page_headerdocling_page_header
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white		False[218.72, 47.78, 167.65, 6.37]R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77
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white		False[555.25, 48.21, 7.29, 5.94]7575
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white		False[49.04, 356.3, 506.98, 7.01]Fig. 6. Discharge capacities of Li/Li1.2Ni0.2Mn0.6O2 with 1wt% SN-based electrolyte at different cut-off voltages: (a) 2.0 e 4.8 V, (b) 2.0 e 4.9 V, (c) 2.0 e 5.0 V and (d) 2.0 e 5.2 V.Fig. 6. Discharge capacities of Li/Li1.2Ni0.2Mn0.6O2 with 1wt% SN-based electrolyte at different cut-off voltages: (a) 2.0 e 4.8 V, (b) 2.0 e 4.9 V, (c) 2.0 e 5.0 V and (d) 2.0 e 5.2 V.
676captioncaptionFalselowoutside_body_flow_captionoutside_body_flow_caption
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white		False[137.93, 565.02, 329.18, 6.38]Fig. 7. SEM images of the surface of LNMO cathode after 5 cycles with: (a) commercial electrolyte (b) 1wt% SN.Fig. 7. SEM images of the surface of LNMO cathode after 5 cycles with: (a) commercial electrolyte (b) 1wt% SN.
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white		False[42.52, 592.71, 251.11, 144.02]Fig. 8 shows X-ray photoelectron spectroscopy (XPS) analysis data of the LNMO electrode after 50 cycles with and without SN. The N1s signal was clearly detected at 398.4 eV in the SNcontaining sample, while the peak did…Fig. 8 shows X-ray photoelectron spectroscopy (XPS) analysis data of the LNMO electrode after 50 cycles with and without SN. The N1s signal was clearly detected at 398.4 eV in the SNcontaining sample, while the peak did…
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white		False[311.53, 592.71, 251.1, 143.43]displayed in Fig. 8(e) and (f). A satellite peak (S1) near 860 eV was observed in both two samples, indicating nickel oxides on the cathode surface [33]. However, there is much difference in Ni 2p3/2 signal. The SN-abse…displayed in Fig. 8(e) and (f). A satellite peak (S1) near 860 eV was observed in both two samples, indicating nickel oxides on the cathode surface [33]. However, there is much difference in Ni 2p3/2 signal. The SN-abse…
779page_headerpage_headerFalselowdocling_page_headerdocling_page_header
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white		False[32.82, 48.21, 7.05, 5.94]7676
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white		False[209.03, 47.78, 167.65, 6.37]R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77R. Chen et al. / Journal of Power Sources 306 (2016) 70 e 77
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white		False[32.82, 372.37, 520.08, 14.84]Fig. 8. XPS spectra of the regions of Li1.2Ni0.2Mn0.6O2 after 50 cycles: (a) N1s with commercial electrolyte, (b) N1s with 1wt% SN-based electrolyte, (c) Mn2p with commercial electrolyte, (d) Mn2p with 1wt% SN-based ele…Fig. 8. XPS spectra of the regions of Li1.2Ni0.2Mn0.6O2 after 50 cycles: (a) N1s with commercial electrolyte, (b) N1s with 1wt% SN-based electrolyte, (c) Mn2p with commercial electrolyte, (d) Mn2p with 1wt% SN-based ele…
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white		False[32.83, 408.68, 251.06, 17.86]that SN effectively alleviates Mn/Ni deposition on the cathode to a certain degree.that SN effectively alleviates Mn/Ni deposition on the cathode to a certain degree.
783section_headerbody_headingFalselowbody_headingbody_heading
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white		False[32.83, 441.25, 55.77, 7.97]4. Conclusion4. Conclusion
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white		False[301.83, 408.68, 251.11, 38.78]Foundation of China (21373028), Major achievements Transformation Project for Central University in Beijing, National Key Program for Basic Research of China (2015CB251100) and Beijing Science and Technology Project (D1…Foundation of China (21373028), Major achievements Transformation Project for Central University in Beijing, National Key Program for Basic Research of China (2015CB251100) and Beijing Science and Technology Project (D1…
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white		False[32.82, 462.6, 251.15, 237.54]Succinonitrile-based electrolytes improve the cycling performance and thermal stability of the Li1.2Ni0.2Mn0.6O2/Li system in high cut-off voltage in this paper. By performing linear sweep voltammetry (LSV), thermogravi…Succinonitrile-based electrolytes improve the cycling performance and thermal stability of the Li1.2Ni0.2Mn0.6O2/Li system in high cut-off voltage in this paper. By performing linear sweep voltammetry (LSV), thermogravi…
786list_itemreferenceFalselowoutside_body_flow_referenceoutside_body_flow_reference
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791section_headerback_matter_headingFalselowback_matter_headingback_matter_heading
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