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这里对齐真实图表资产提取链路。caption_source=embedded_table_cell 表示表注来自 Docling table cell，不会出现在 text block 审计差集里；caption_continuation_used_by_asset 表示某个 text block 已被图表 caption 吸收，不应按普通 metadata 解读。
| # | type | label | page | caption source | suppressed | duplicate reason | rescue reason | group | confidence | bbox | caption |
|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | figure | Fig. 1 | 2 | region_rescue_caption | expanded_partial_docling_crop | 0.82 | [72.3, 71.17, 445.27, 174.36] | Figure 1. a) Charge-discharge profi les of Li 2 MnO 3 when cycled between 2.0 V and 5.0 V during the fi rst and 33 rd cycles. b) Charge-discharge capacities obtained during each cycle along with electrochemical effi ciency. | |||
| 2 | figure | Fig. 1 | 2 | region_rescue_caption | expanded_partial_docling_crop | 0.82 | [72.3, 71.17, 445.27, 174.36] | Figure 1. a) Charge-discharge profi les of Li 2 MnO 3 when cycled between 2.0 V and 5.0 V during the fi rst and 33 rd cycles. b) Charge-discharge capacities obtained during each cycle along with electrochemical effi ciency. | |||
| 3 | figure | Fig. 2 | 2 | region_rescue_caption | expanded_partial_docling_crop | 0.82 | [90.0, 521.38, 409.88, 160.32] | Figure 2. a) Normalized absorption spectra for various manganese reference compounds with the inset showing an enlarged pre-edge region of four compounds. b) Variation in the position of the 1s → 4p peak (dashed blue line) and the average metal-ligand bond length (solid red line) for these compounds. | |||
| 4 | figure | Fig. 2 | 2 | region_rescue_caption | expanded_partial_docling_crop | 0.82 | [90.0, 521.38, 409.88, 160.32] | Figure 2. a) Normalized absorption spectra for various manganese reference compounds with the inset showing an enlarged pre-edge region of four compounds. b) Variation in the position of the 1s → 4p peak (dashed blue line) and the average metal-ligand bond length (solid red line) for these compounds. | |||
| 5 | figure | Fig. 3 | 3 | direct_caption_ref | 0.82 | [61.65, 70.31, 218.87, 174.4] | Figure 3. Normalized absorption spectra for various Li 2 MnO 3 samples along with those of Mn 3 + and Mn 4 + reference compounds. The inset shows the pre-edge region. | ||||
| 6 | figure | Fig. 4 | 3 | region_rescue_caption | expanded_partial_docling_crop | 0.82 | [76.38, 518.92, 445.39, 172.8] | Figure 4. a) k 3 -weighted EXAFS signals χ ( k ) and b) their Fourier transforms for Li 2 MnO 3 samples in the pristine state (solid black line), when charged to 5 V during the fi rst cycle (dashed red line) and when charged to 5 V during the 33 rd cycle (dotted blue line). | |||
| 7 | figure | Fig. 4 | 3 | region_rescue_caption | expanded_partial_docling_crop | 0.82 | [76.38, 518.92, 445.39, 172.8] | Figure 4. a) k 3 -weighted EXAFS signals χ ( k ) and b) their Fourier transforms for Li 2 MnO 3 samples in the pristine state (solid black line), when charged to 5 V during the fi rst cycle (dashed red line) and when charged to 5 V during the 33 rd cycle (dotted blue line). | |||
| 8 | figure | Fig. 5 | 4 | direct_caption_ref | 0.82 | [65.55, 70.58, 457.31, 174.05] | Figure 5. a) k 3 -weighted EXAFS signals χ ( k ) and b) their Fourier transforms for Li 2 MnO 3 samples in the pristine state (solid black line), when discharged to 2 V during the fi rst cycle (dashed red line) and when discharged to 2 V during the 33 rd cycle (dotted blue line). | ||||
| 9 | figure | Fig. 6 | 4 | direct_caption_ref | 0.82 | [58.3, 518.52, 218.23, 172.54] | Figure 6. EXAFS fi t to the data of Li 2 MnO 3 sample in the pristine state. The dotted lines indicate the fi tting range. | ||||
| 10 | figure | Fig. 7 | 5 | direct_caption_ref | 0.82 | [74.56, 70.32, 447.4, 175.64] | Figure 7. EXAFS fi ts to the data of Li 2 MnO 3 samples a) when charged to 5 V and b) when discharged to 2 V during the fi rst cycle. | ||||
| 11 | figure | Fig. 8 | 5 | direct_caption_ref | 0.82 | [317.7, 278.81, 218.0, 175.49] | Figure 8. EXAFS data of the LiMn 2 O 4 spinel. | ||||
| 12 | figure | Fig. 9 | 5 | nearby_text_caption | 0.82 | [72.74, 531.7, 451.84, 174.0] | Figure 9. EXAFS fi ts to the data of Li 2 MnO 3 samples a) when charged to 5 V and b) when discharged to 2 V during the 33 rd cycle. | ||||
| 13 | figure | Fig. 10 | 6 | direct_caption_ref | 0.82 | [57.97, 69.93, 217.96, 175.31] | Figure 10. Comparison of the metal-ligand bond length for the electrochemically cycled Li 2 MnO 3 samples during the fi rst and 33 rd cycles. The asterisk (*) represents the charged-discharged samples during the 33 rd cycle. The solid line indicates the average Mn 4 + -O bond length obtained by fi tting the EXAFS data of the MnO 2 reference compound and dotted lines indicate statistical uncertainties of the fi tted value. | ||||
| 14 | figure | Fig. 11 | 6 | direct_caption_ref | 0.82 | [70.98, 527.24, 445.98, 174.41] | Figure 11. Structural disorder in charged-discharged samples of Li 2 MnO 3 a) during the fi rst cycle and b) during the 33 rd cycle. | ||||
| 15 | figure | Fig. 12 | 8 | direct_caption_ref | 0.82 | [78.11, 68.94, 435.14, 142.68] | Figure 12. Stacking sequence of close-packed oxygen layers in a) O3 structure of Li 2 MnO 3 ( C2 / m ) [ 22 ] and b) P3 structure ( R 3 m ) of proton-exchanged material. [ 59 ] Note that O-H-O bonds are asymmetric in the P3 structure. |
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| 1 | 4 | text | affiliation | False | medium | front_matter_author_line | front_matter_author_line | p1:body_region:0 | p1:page_body:column_1_of_2:white | [255, 255, 255] white | False | [51.06, 130.55, 448.73, 29.6] | Jatinkumar Rana ,* Marian Stan , Richard Kloepsch , Jie Li , Gerhard Schumacher , Edmund Welter , Ivo Zizak , John Banhart ,* and Martin Winter | Jatinkumar Rana ,* Marian Stan , Richard Kloepsch , Jie Li , Gerhard Schumacher , Edmund Welter , Ivo Zizak , John Banhart ,* and Martin Winter | ||
| 1 | 5 | text | body | True | body_before_non_intro_heading | body_before_non_intro_heading | p1:body_region:0 | p1:page_body:column_1_of_2:gray | [209, 210, 211] gray | False | [51.03, 204.49, 311.76, 216.26] | Structural changes in Li 2 MnO 3 cathode material for rechargeable Li-ion batteries are investigated during the fi rst and 33 rd cycles. It is found that both the participation of oxygen anions in redox processes and Li… | Structural changes in Li 2 MnO 3 cathode material for rechargeable Li-ion batteries are investigated during the fi rst and 33 rd cycles. It is found that both the participation of oxygen anions in redox processes and Li… | |||
| 1 | 6 | section_header | body_heading | False | low | body_heading | body_heading | p1:body_region:0 | p1:page_body:column_1_of_2:white | [255, 255, 255] white | False | [51.01, 449.89, 73.83, 9.74] | 1 . Introduction | 1 . Introduction | ||
| 1 | 7 | text | body | True | body | body | p1:body_region:0 | p1:page_body:column_1_of_2:white | [255, 255, 255] white | False | [51.01, 467.9, 243.2, 52.52] | The exploration of electrochemical activation in Li 2 MnO 3 is important for two main reasons: fi rst, to enhance the fundamental understanding concerning the electrochemistry of Mn 4 + -containing cathode materials: an… | The exploration of electrochemical activation in Li 2 MnO 3 is important for two main reasons: fi rst, to enhance the fundamental understanding concerning the electrochemistry of Mn 4 + -containing cathode materials: an… | |||
| 1 | 8 | text | metadata | False | medium | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:page_body:column_1_of_2:white | [255, 255, 255] white | False | [51.01, 546.37, 182.72, 153.79] | Dr. J. Rana, Dr. G. Schumacher, Dr. I. Zizak, Prof. J. Banhart Helmholtz-Zentrum Berlin für Materialien und Energie Hahn-Meitner-Platz 1 , 14109 , Berlin , Germany E-mail: jatinkumar.rana@helmholtz-berlin.de ; banhart@h… | Dr. J. Rana, Dr. G. Schumacher, Dr. I. Zizak, Prof. J. Banhart Helmholtz-Zentrum Berlin für Materialien und Energie Hahn-Meitner-Platz 1 , 14109 , Berlin , Germany E-mail: jatinkumar.rana@helmholtz-berlin.de ; banhart@h… | ||
| 1 | 9 | text | metadata | False | low | first_page_metadata | first_page_metadata | p1:body_region:0 | p1:page_body:column_1_of_2:white | [255, 255, 255] white | False | [51.01, 710.51, 119.31, 7.62] | DOI: 10.1002/aenm.201300998 | DOI: 10.1002/aenm.201300998 | ||
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| 1 | 11 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p1:body_region:0 | p1:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [51.06, 743.21, 104.16, 5.94] | Adv. Energy Mater . 2014 , 4 , 1300998 | Adv. Energy Mater . 2014 , 4 , 1300998 | ||
| 1 | 12 | text | body | True | body | body | p1:body_region:1 | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [385.68, 191.69, 163.65, 196.72] | cathode materials, [ 1-9 ] in which Li 2 MnO 3 is an important component. Li 2 MnO 3 has an O3 structure where close-packed oxygen layers are stacked in an ABCABC sequence. In a layer notation, Li 2 MnO 3 can be written… | cathode materials, [ 1-9 ] in which Li 2 MnO 3 is an important component. Li 2 MnO 3 has an O3 structure where close-packed oxygen layers are stacked in an ABCABC sequence. In a layer notation, Li 2 MnO 3 can be written… | |||
| 1 | 13 | text | body | True | body | body | p1:body_region:1 | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [385.68, 390.89, 163.65, 53.71] | Over the past few years, several mechanisms concerning electrochemical activation of Li 2 MnO 3 during the fi rst charge have been postulated. It has been proposed that Li extraction from Li 2 MnO 3 | Over the past few years, several mechanisms concerning electrochemical activation of Li 2 MnO 3 during the fi rst charge have been postulated. It has been proposed that Li extraction from Li 2 MnO 3 | |||
| 1 | 14 | text | body | True | body | body | p1:body_region:1 | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [306.13, 444.69, 243.2, 108.72] | occurs with the simultaneous release of oxygen. [ 11 ] Later, it was observed that Li extraction occurs via two competitive processes, namely oxygen removal and Li + -H + exchange. [ 13-15 ] The presence of structural d… | occurs with the simultaneous release of oxygen. [ 11 ] Later, it was observed that Li extraction occurs via two competitive processes, namely oxygen removal and Li + -H + exchange. [ 13-15 ] The presence of structural d… | |||
| 1 | 15 | text | body | True | body | body | p1:body_region:1 | p1:page_body:column_2_of_2:white | [255, 255, 255] white | False | [306.13, 555.89, 243.2, 162.52] | We study structural modifi cations in Li 2 MnO 3 cathode material during the fi rst and 33 rd cycles by X-ray absorption spectroscopy (XAS). The elemental selectivity of XAS provides a unique opportunity to probe chemic… | We study structural modifi cations in Li 2 MnO 3 cathode material during the fi rst and 33 rd cycles by X-ray absorption spectroscopy (XAS). The elemental selectivity of XAS provides a unique opportunity to probe chemic… | |||
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| 2 | 21 | text | page_margin_header | False | low | page_margin_header | page_margin_header | p2:body_region:1 | p2:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [457.98, 53.43, 83.44, 6.78] | www.MaterialsViews.com | |||
| 2 | 22 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p2:body_region:0 | p2:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 254.03, 498.08, 17.53] | Figure 1. a) Charge-discharge profi les of Li 2 MnO 3 when cycled between 2.0 V and 5.0 V during the fi rst and 33 rd cycles. b) Charge-discharge capacities obtained during each cycle along with electrochemical effi cie… | Figure 1. a) Charge-discharge profi les of Li 2 MnO 3 when cycled between 2.0 V and 5.0 V during the fi rst and 33 rd cycles. b) Charge-discharge capacities obtained during each cycle along with electrochemical effi cie… | ||
| 2 | 23 | text | body | True | body | body | p2:body_region:0 | p2:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 293.79, 243.2, 41.52] | manganese reference compounds, while structural changes such as the number of nearest neighbors, interatomic distances, and structural disorder are quantifi ed by fi tting a theoretical model to the EXAFS data. | manganese reference compounds, while structural changes such as the number of nearest neighbors, interatomic distances, and structural disorder are quantifi ed by fi tting a theoretical model to the EXAFS data. | |||
| 2 | 24 | section_header | body_heading | False | low | body_heading | body_heading | p2:body_region:0 | p2:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 363.28, 49.62, 9.74] | 2 . Results | 2 . Results | ||
| 2 | 25 | text | body | True | body | body | p2:body_region:0 | p2:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 381.29, 243.2, 118.52] | As shown in Figure 1 a, the cell delivered a specifi c capacity of 388 mAh g -1 when charged to 5 V and of 200 mAh g -1 when discharged to 2 V with a fi rst cycle effi ciency of ≈ 50% (Figure 1 b). The long plateau abov… | As shown in Figure 1 a, the cell delivered a specifi c capacity of 388 mAh g -1 when charged to 5 V and of 200 mAh g -1 when discharged to 2 V with a fi rst cycle effi ciency of ≈ 50% (Figure 1 b). The long plateau abov… | |||
| 2 | 26 | text | body | True | body | body | p2:body_region:1 | p2:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [302.03, 293.79, 243.2, 42.13] | in Figure 1 b, the electrochemical performance of Li 2 MnO 3 degrades upon cycling. During the 33 rd cycle, the cell delivers a specifi c capacity of ≈ 110 mAh g -1 both during charge and discharge, which is just ≈ 55% … | in Figure 1 b, the electrochemical performance of Li 2 MnO 3 degrades upon cycling. During the 33 rd cycle, the cell delivers a specifi c capacity of ≈ 110 mAh g -1 both during charge and discharge, which is just ≈ 55% … | |||
| 2 | 27 | section_header | body_heading | False | low | body_heading | body_heading | p2:body_region:1 | p2:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [302.03, 358.41, 45.23, 7.62] | 2.1 . XANES | 2.1 . XANES | ||
| 2 | 28 | text | body | True | body | body | p2:body_region:1 | p2:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [302.03, 381.29, 243.21, 118.52] | As shown in Figure 2 a, the absorption edge is characterized by a variety of edge-features such as 1) an absorption threshold (or the fi rst peak in the derivative spectrum, not shown), 2) a 1s → 3d transition, correspo… | As shown in Figure 2 a, the absorption edge is characterized by a variety of edge-features such as 1) an absorption threshold (or the fi rst peak in the derivative spectrum, not shown), 2) a 1s → 3d transition, correspo… | |||
| 2 | 29 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p2:body_region:0 | p2:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 691.43, 498.08, 25.79] | Figure 2. a) Normalized absorption spectra for various manganese reference compounds with the inset showing an enlarged pre-edge region of four compounds. b) Variation in the position of the 1s → 4p peak (dashed blue li… | Figure 2. a) Normalized absorption spectra for various manganese reference compounds with the inset showing an enlarged pre-edge region of four compounds. b) Variation in the position of the 1s → 4p peak (dashed blue li… | ||
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| 2 | 32 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p2:body_region:1 | p2:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [236.51, 742.89, 169.97, 6.29] | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | ||
| 2 | 33 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p2:body_region:1 | p2:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [440.0, 743.21, 103.42, 5.94] | Adv. Energy Mater. 2014 , 4 , 1300998 | Adv. Energy Mater. 2014 , 4 , 1300998 | ||
| 3 | 34 | text | page_margin_header | False | low | page_margin_header | page_margin_header | p3:body_region:0 | p3:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [51.01, 53.34, 83.44, 6.78] | www.MaterialsViews.com | |||
| 3 | 35 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p3:body_region:0 | p3:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [50.78, 253.26, 242.95, 25.79] | Figure 3. Normalized absorption spectra for various Li 2 MnO 3 samples along with those of Mn 3 + and Mn 4 + reference compounds. The inset shows the pre-edge region. | Figure 3. Normalized absorption spectra for various Li 2 MnO 3 samples along with those of Mn 3 + and Mn 4 + reference compounds. The inset shows the pre-edge region. | ||
| 3 | 36 | text | body | True | body | body | p3:body_region:0 | p3:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 301.3, 243.2, 97.71] | Figure 2 a shows an enlarged pre-edge region of these spectra. In order to enhance the visibility of the pre-edge peaks of other reference compounds, the intense pre-edge peak of KMnO 4 is omitted from the inset. The pr… | Figure 2 a shows an enlarged pre-edge region of these spectra. In order to enhance the visibility of the pre-edge peaks of other reference compounds, the intense pre-edge peak of KMnO 4 is omitted from the inset. The pr… | |||
| 3 | 37 | text | body | True | body | body | p3:body_region:0 | p3:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 400.3, 243.21, 107.52] | Inner d-orbitals are more tightly bound and, therefore, less sensitive to chemical changes than loosely bound outer p-orbitals. Thus, chemical shifts observed at the position of the 1s → 4p peak are more pronounced than… | Inner d-orbitals are more tightly bound and, therefore, less sensitive to chemical changes than loosely bound outer p-orbitals. Thus, chemical shifts observed at the position of the 1s → 4p peak are more pronounced than… | |||
| 3 | 38 | text | reference | False | low | empty_after_cleaning | empty_after_cleaning | p3:top_margin:column_2_of_2:gray | [229, 229, 229] gray | True | [577.94, 15.66, 4.29, 743.12] | 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… | ||||
| 3 | 39 | text | page_margin_header | False | low | page_margin_header | page_margin_header | p3:body_region:1 | p3:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [473.91, 45.23, 73.35, 6.78] | www.advenergymat.de | |||
| 3 | 40 | page_header | page_header | False | low | docling_page_header | docling_page_header | p3:front_matter:front_panel:gray | [127, 129, 133] gray | True | [571.77, 70.54, 11.89, 80.75] | FULL PAPER | FULL PAPER | |||
| 3 | 41 | text | body | True | body | body | p3:body_region:1 | p3:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 71.43, 243.2, 19.52] | compounds (refer to Figure S1 and Table S1 in the Supporting Information). | compounds (refer to Figure S1 and Table S1 in the Supporting Information). | |||
| 3 | 42 | text | body | True | body | body | p3:body_region:1 | p3:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 93.43, 243.2, 140.52] | As shown in Figure 3 , the absorption spectra for various Li 2 MnO 3 samples appear more complex than those of manganese reference compounds due to the presence of several points of intersection along the main edge wher… | As shown in Figure 3 , the absorption spectra for various Li 2 MnO 3 samples appear more complex than those of manganese reference compounds due to the presence of several points of intersection along the main edge wher… | |||
| 3 | 43 | section_header | body_heading | False | low | body_heading | body_heading | p3:body_region:1 | p3:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 257.05, 43.1, 7.62] | 2.2 . EXAFS | 2.2 . EXAFS | ||
| 3 | 44 | text | body | True | body | body | p3:body_region:1 | p3:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 277.33, 243.2, 132.73] | The comparison between the χ ( k ) signals of various Li 2 MnO 3 samples in Figure 4 a reveals that the EXAFS oscillations are reduced as soon as the cathode is charged to 5 V. In the corresponding Fourier transforms (F… | The comparison between the χ ( k ) signals of various Li 2 MnO 3 samples in Figure 4 a reveals that the EXAFS oscillations are reduced as soon as the cathode is charged to 5 V. In the corresponding Fourier transforms (F… | |||
| 3 | 45 | text | body | True | body | body | p3:body_region:1 | p3:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 409.33, 243.2, 99.12] | As shown in Figure 5 a, every feature of the χ ( k ) signal corresponding to the pristine sample is reproduced when the cathode is discharged to 2 V during the fi rst cycle, however, with reduced amplitudes. This is als… | As shown in Figure 5 a, every feature of the χ ( k ) signal corresponding to the pristine sample is reproduced when the cathode is discharged to 2 V during the fi rst cycle, however, with reduced amplitudes. This is als… | |||
| 3 | 46 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p3:body_region:0 | p3:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 698.84, 498.12, 19.15] | Figure 4. a) k 3 -weighted EXAFS signals χ ( k ) and b) their Fourier transforms for Li 2 MnO 3 samples in the pristine state (solid black line), when charged to 5 V during the fi rst cycle (dashed red line) and when ch… | Figure 4. a) k 3 -weighted EXAFS signals χ ( k ) and b) their Fourier transforms for Li 2 MnO 3 samples in the pristine state (solid black line), when charged to 5 V during the fi rst cycle (dashed red line) and when ch… | ||
| 3 | 47 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p3:body_region:0 | p3:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [51.06, 743.21, 104.16, 5.94] | Adv. Energy Mater . 2014 , 4 , 1300998 | Adv. Energy Mater . 2014 , 4 , 1300998 | ||
| 3 | 48 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p3:body_region:1 | p3:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [494.77, 741.91, 67.86, 7.64] | (3 of 12) 1300998 | (3 of 12) 1300998 | ||
| 3 | 49 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p3:body_region:0 | p3:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [185.77, 742.91, 169.97, 6.29] | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | ||
| 3 | 50 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p3:body_region:1 | p3:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [388.05, 743.22, 64.38, 5.93] | wileyonlinelibrary.com | wileyonlinelibrary.com | ||
| 4 | 51 | text | page_margin_header | False | low | page_margin_header | page_margin_header | p4:body_region:0 | p4:top_margin:column_1_of_2:white | [255, 255, 255] white | True | [46.91, 45.16, 73.33, 6.78] | www.advenergymat.de | |||
| 4 | 52 | page_header | page_header | False | low | docling_page_header | docling_page_header | p4:page_body:column_1_of_2:gray | [164, 165, 168] gray | True | [10.31, 70.11, 11.89, 80.75] | FULL PAPER | FULL PAPER | |||
| 4 | 53 | page_header | page_header | False | low | docling_page_header | docling_page_header | p4:top_margin:column_2_of_2:white | [253, 253, 253] white | False | [577.94, 15.66, 4.29, 743.12] | 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… | ||||
| 4 | 54 | text | page_margin_header | False | low | page_margin_header | page_margin_header | p4:body_region:1 | p4:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [457.98, 53.43, 83.44, 6.78] | www.MaterialsViews.com | |||
| 4 | 55 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p4:body_region:0 | p4:page_body:column_1_of_2:white | [255, 255, 255] white | False | [46.88, 251.21, 496.08, 19.15] | Figure 5. a) k 3 -weighted EXAFS signals χ ( k ) and b) their Fourier transforms for Li 2 MnO 3 samples in the pristine state (solid black line), when discharged to 2 V during the fi rst cycle (dashed red line) and when… | Figure 5. a) k 3 -weighted EXAFS signals χ ( k ) and b) their Fourier transforms for Li 2 MnO 3 samples in the pristine state (solid black line), when discharged to 2 V during the fi rst cycle (dashed red line) and when… | ||
| 4 | 56 | text | body | True | body | body | p4:body_region:0 | p4:page_body:column_1_of_2:white | [255, 255, 255] white | False | [46.95, 291.36, 243.2, 206.52] | EXAFS data in the pristine state were fi tted by the monoclinic structure of Li 2 MnO 3 ( C2 / m ) [ 22 ] ( Figure 6 ). Best-fi t parameters are reported in Table S2 in the Supporting Information. A product of S 2 0 and… | EXAFS data in the pristine state were fi tted by the monoclinic structure of Li 2 MnO 3 ( C2 / m ) [ 22 ] ( Figure 6 ). Best-fi t parameters are reported in Table S2 in the Supporting Information. A product of S 2 0 and… | |||
| 4 | 57 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p4:body_region:0 | p4:page_body:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 701.12, 242.95, 16.29] | Figure 6. EXAFS fi t to the data of Li 2 MnO 3 sample in the pristine state. The dotted lines indicate the fi tting range. | Figure 6. EXAFS fi t to the data of Li 2 MnO 3 sample in the pristine state. The dotted lines indicate the fi tting range. | ||
| 4 | 58 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p4:body_region:0 | p4:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [32.48, 741.91, 67.86, 7.64] | 1300998 (4 of 12) | 1300998 (4 of 12) | ||
| 4 | 59 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p4:body_region:0 | p4:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [137.77, 743.22, 64.38, 5.93] | wileyonlinelibrary.com | wileyonlinelibrary.com | ||
| 4 | 60 | text | body | True | body | body | p4:body_region:1 | p4:page_body:column_2_of_2:white | [255, 255, 255] white | False | [302.06, 291.39, 243.22, 173.52] | EXAFS signal is due to backscattering of ejected photoelectrons from the nearest neighbors (i.e., O N-N in case of Li 2 MnO 3 ). The contribution from outer coordination shells decreases due to increased inelastic losse… | EXAFS signal is due to backscattering of ejected photoelectrons from the nearest neighbors (i.e., O N-N in case of Li 2 MnO 3 ). The contribution from outer coordination shells decreases due to increased inelastic losse… | |||
| 4 | 61 | text | body | True | body | body | p4:body_region:1 | p4:page_body:column_2_of_2:white | [255, 255, 255] white | False | [302.06, 467.39, 243.2, 151.52] | It has been reported that Li extraction from Li 2 MnO 3 occurs with a simultaneous loss of oxygen, giving rise to the formation of a layered MnO 2 -type structure (trigonal, R 3 m ) with the average valence state of Mn … | It has been reported that Li extraction from Li 2 MnO 3 occurs with a simultaneous loss of oxygen, giving rise to the formation of a layered MnO 2 -type structure (trigonal, R 3 m ) with the average valence state of Mn … | |||
| 4 | 62 | text | body | True | body | body | p4:body_region:1 | p4:page_body:column_2_of_2:white | [255, 255, 255] white | False | [302.06, 621.39, 243.26, 98.2] | It has been proposed that Li re-insertion into layered MnO 2 occurs with the simultaneous reduction of Mn 4 + to Mn 3 + , thus forming LiMnO 2 . [ 6,25 ] Therefore, an attempt was made to fi t the EXAFS data of the samp… | It has been proposed that Li re-insertion into layered MnO 2 occurs with the simultaneous reduction of Mn 4 + to Mn 3 + , thus forming LiMnO 2 . [ 6,25 ] Therefore, an attempt was made to fi t the EXAFS data of the samp… | |||
| 4 | 63 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p4:body_region:1 | p4:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [236.51, 742.89, 169.97, 6.29] | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | ||
| 4 | 64 | page_footer | page_footer | False | low | docling_page_footer | docling_page_footer | p4:body_region:1 | p4:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [440.0, 743.21, 103.42, 5.94] | Adv. Energy Mater. 2014 , 4 , 1300998 | Adv. Energy Mater. 2014 , 4 , 1300998 | ||
| 5 | 65 | text | page_margin_header | False | low | page_margin_header | page_margin_header | p5:body_region:0 | p5:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [51.01, 53.34, 83.44, 6.78] | www.MaterialsViews.com | |||
| 5 | 66 | text | reference | False | low | empty_after_cleaning | empty_after_cleaning | p5:top_margin:column_2_of_2:gray | [229, 229, 229] gray | True | [577.94, 15.66, 4.29, 743.12] | 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… | ||||
| 5 | 67 | text | page_margin_header | False | low | page_margin_header | page_margin_header | p5:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [473.91, 45.23, 73.35, 6.78] | www.advenergymat.de | ||||
| 5 | 68 | text | metadata | False | low | document_ui | document_ui | p5:page_body:column_2_of_2:gray | [127, 129, 133] gray | True | [571.77, 70.54, 11.89, 80.75] | FULL PAPER | FULL PAPER | |||
| 5 | 69 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p5:body_region:0 | p5:page_body:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 253.82, 433.44, 7.92] | Figure 7. EXAFS fi ts to the data of Li 2 MnO 3 samples a) when charged to 5 V and b) when discharged to 2 V during the fi rst cycle. | Figure 7. EXAFS fi ts to the data of Li 2 MnO 3 samples a) when charged to 5 V and b) when discharged to 2 V during the fi rst cycle. | ||
| 5 | 70 | text | body | True | body | body | p5:body_region:0 | p5:page_body:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 280.61, 243.2, 64.71] | It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] Therefore, an attempt was made to refi ne the fraction of such spinel phase in the cycled sam… | It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] Therefore, an attempt was made to refi ne the fraction of such spinel phase in the cycled sam… | |||
| 5 | 71 | text | body | True | body | body | p5:body_region:0 | p5:page_body:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 346.61, 243.2, 174.71] | Qualitatively, the EXAFS data of the cycled samples appear similar to those of their counterparts during the fi rst cycle. As a result, a layered MnO 2 structure was assumed to fi t the data of the cycled-charged sample… | Qualitatively, the EXAFS data of the cycled samples appear similar to those of their counterparts during the fi rst cycle. As a result, a layered MnO 2 structure was assumed to fi t the data of the cycled-charged sample… | |||
| 5 | 72 | caption | caption | False | low | outside_body_flow_caption | outside_body_flow_caption | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 462.93, 150.69, 7.92] | Figure 8. EXAFS data of the LiMn 2 O 4 spinel. | Figure 8. EXAFS data of the LiMn 2 O 4 spinel. | |||
| 5 | 73 | text | back_matter_heading | False | low | back_matter_heading | back_matter_heading | stop_trigger | p5:page_body:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 489.61, 243.2, 31.71] | Supporting Information) with a good agreement with the data as shown in Figure 9 a. Similarly, the EXAFS data of the cycleddischarged sample were explained by a Li 2 MnO 3 structure | Supporting Information) with a good agreement with the data as shown in Figure 9 a. Similarly, the EXAFS data of the cycleddischarged sample were explained by a Li 2 MnO 3 structure | ||
| 5 | 74 | caption | caption | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p5:body_region:0 | p5:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 714.14, 433.62, 9.15] | Figure 9. EXAFS fi ts to the data of Li 2 MnO 3 samples a) when charged to 5 V and b) when discharged to 2 V during the 33 rd cycle. | Figure 9. EXAFS fi ts to the data of Li 2 MnO 3 samples a) when charged to 5 V and b) when discharged to 2 V during the 33 rd cycle. | |
| 5 | 75 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p5:body_region:0 | p5:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [51.06, 743.21, 104.16, 5.94] | Adv. Energy Mater . 2014 , 4 , 1300998 | Adv. Energy Mater . 2014 , 4 , 1300998 | |
| 5 | 76 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p5:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [494.77, 741.91, 67.86, 7.64] | (5 of 12) 1300998 | (5 of 12) 1300998 | ||
| 5 | 77 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p5:body_region:0 | p5:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [185.77, 742.91, 169.97, 6.29] | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | |
| 5 | 78 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p5:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [388.05, 743.22, 64.38, 5.93] | wileyonlinelibrary.com | wileyonlinelibrary.com | ||
| 6 | 79 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:top_margin:column_1_of_2:white | [255, 255, 255] white | True | [46.91, 45.16, 73.33, 6.78] | www.advenergymat.de | ||
| 6 | 80 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:front_matter:front_panel:gray | [164, 165, 168] gray | True | [10.31, 70.11, 11.89, 80.75] | FULL PAPER | FULL PAPER | ||
| 6 | 81 | caption | caption | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 253.7, 242.95, 54.29] | Figure 10. Comparison of the metal-ligand bond length for the electrochemically cycled Li 2 MnO 3 samples during the fi rst and 33 rd cycles. The asterisk (*) represents the charged-discharged samples during the 33 rd c… | Figure 10. Comparison of the metal-ligand bond length for the electrochemically cycled Li 2 MnO 3 samples during the fi rst and 33 rd cycles. The asterisk (*) represents the charged-discharged samples during the 33 rd c… | |
| 6 | 82 | text | affiliation | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 321.28, 243.2, 22.61] | (Figure 9 b). A fi t constraining S 2 0 to 0.76 and O N-N to 4.3, refi ned X eff to 0.61(5) (Table S6 in the Supporting Information). | (Figure 9 b). A fi t constraining S 2 0 to 0.76 and O N-N to 4.3, refi ned X eff to 0.61(5) (Table S6 in the Supporting Information). | |
| 6 | 83 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 345.18, 243.2, 63.52] | A comparison between the metal-ligand bond lengths of various Li 2 MnO 3 samples is shown in Figure 10 . The average Mn-O bond length in the pristine state is slightly higher than that of Mn 4 + -O. As the cathode is ch… | A comparison between the metal-ligand bond lengths of various Li 2 MnO 3 samples is shown in Figure 10 . The average Mn-O bond length in the pristine state is slightly higher than that of Mn 4 + -O. As the cathode is ch… | |
| 6 | 84 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 409.39, 243.2, 98.31] | F 2 is the distribution of the backscattering atoms around their mean position measured with respect to the central absorbing atom. This distribution can be either caused by thermal vibrations (thermal disorder) or by s… | F 2 is the distribution of the backscattering atoms around their mean position measured with respect to the central absorbing atom. This distribution can be either caused by thermal vibrations (thermal disorder) or by s… | |
| 6 | 85 | caption | caption | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 709.82, 421.8, 9.15] | Figure 11. Structural disorder in charged-discharged samples of Li 2 MnO 3 a) during the fi rst cycle and b) during the 33 rd cycle. | Figure 11. Structural disorder in charged-discharged samples of Li 2 MnO 3 a) during the fi rst cycle and b) during the 33 rd cycle. | |
| 6 | 86 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [32.48, 741.91, 67.86, 7.64] | 1300998 (6 of 12) | 1300998 (6 of 12) | |
| 6 | 87 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:0 | p6:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [137.77, 743.22, 64.38, 5.93] | wileyonlinelibrary.com | wileyonlinelibrary.com | |
| 6 | 88 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:top_margin:column_2_of_2:white | [253, 253, 253] white | False | [577.94, 15.66, 4.29, 743.12] | 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… | |||
| 6 | 89 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:1 | p6:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [457.98, 53.43, 83.44, 6.78] | www.MaterialsViews.com | ||
| 6 | 90 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:1 | p6:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 71.43, 243.2, 129.52] | disorder. As shown in Figure 11 a, the pristine sample exhibits the smallest, while the charged sample exhibits the largest disorder for all shells during the fi rst cycle. The structural disorder for the discharged sam… | disorder. As shown in Figure 11 a, the pristine sample exhibits the smallest, while the charged sample exhibits the largest disorder for all shells during the fi rst cycle. The structural disorder for the discharged sam… | |
| 6 | 91 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:1 | p6:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 203.43, 243.2, 41.52] | The statistical EXAFS fi t parameters for various Li 2 MnO 3 samples are reported in Table S7 in the Supporting Information. A good agreement between the data and theory for all samples can be seen by their R -factors, … | The statistical EXAFS fi t parameters for various Li 2 MnO 3 samples are reported in Table S7 in the Supporting Information. A good agreement between the data and theory for all samples can be seen by their R -factors, … | |
| 6 | 92 | section_header | unknown_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:1 | p6:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 267.42, 67.53, 9.74] | 3 . Discussion | 3 . Discussion | |
| 6 | 93 | section_header | body_heading | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:1 | p6:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 287.8, 45.23, 7.62] | 3.1 . XANES | 3.1 . XANES | |
| 6 | 94 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:1 | p6:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 308.08, 243.2, 198.12] | 1s → 3d transitions are forbidden by dipole rules in centrosymmetric confi gurations such as in regular octahedral symmetry. However, with increasing distortion from ideal octahedral symmetry, the probability of a trans… | 1s → 3d transitions are forbidden by dipole rules in centrosymmetric confi gurations such as in regular octahedral symmetry. However, with increasing distortion from ideal octahedral symmetry, the probability of a trans… | |
| 6 | 95 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:1 | p6:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [236.51, 742.89, 169.97, 6.29] | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | |
| 6 | 96 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p6:body_region:1 | p6:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [440.0, 743.21, 103.42, 5.94] | Adv. Energy Mater. 2014 , 4 , 1300998 | Adv. Energy Mater. 2014 , 4 , 1300998 | |
| 7 | 97 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:0 | p7:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [51.01, 53.34, 83.44, 6.78] | www.MaterialsViews.com | ||
| 7 | 98 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:0 | p7:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 71.38, 243.2, 217.52] | The metal-ligand bond length determines the extent to which orbital intermixing takes place. As a result of this intermixing, the repulsive forces between the electrons increase the energies of these orbitals. Thus, met… | The metal-ligand bond length determines the extent to which orbital intermixing takes place. As a result of this intermixing, the repulsive forces between the electrons increase the energies of these orbitals. Thus, met… | |
| 7 | 99 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:0 | p7:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 291.38, 243.2, 261.52] | Empirically, a chemical shift in the absorption spectra can be correlated to the formal valence state of an absorbing atom. [ 20,34 ] However, in addition to the valence of an absorbing atom, chemical shifts are also af… | Empirically, a chemical shift in the absorption spectra can be correlated to the formal valence state of an absorbing atom. [ 20,34 ] However, in addition to the valence of an absorbing atom, chemical shifts are also af… | |
| 7 | 100 | section_header | body_heading | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:0 | p7:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 576.0, 43.1, 7.62] | 3.2 . EXAFS | 3.2 . EXAFS | |
| 7 | 101 | section_header | body_heading | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:0 | p7:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 603.08, 179.46, 7.46] | 3.2.1 . Structural Changes During the First Charge | 3.2.1 . Structural Changes During the First Charge | |
| 7 | 102 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:0 | p7:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 619.28, 243.2, 96.52] | XAS can distinguish between different atom types based on their ability to scatter the ejected photoelectron, which in turn depends on the atomic number, Z . Despite Mn ( Z = 25) having a higher atomic number than O ( Z… | XAS can distinguish between different atom types based on their ability to scatter the ejected photoelectron, which in turn depends on the atomic number, Z . Despite Mn ( Z = 25) having a higher atomic number than O ( Z… | |
| 7 | 103 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:0 | p7:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [51.06, 743.21, 104.16, 5.94] | Adv. Energy Mater . 2014 , 4 , 1300998 | Adv. Energy Mater . 2014 , 4 , 1300998 | |
| 7 | 104 | text | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p7:top_margin:column_2_of_2:gray | [229, 229, 229] gray | True | [577.94, 15.66, 4.29, 743.12] | 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… | |||
| 7 | 105 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:1 | p7:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [473.91, 45.23, 73.35, 6.78] | www.advenergymat.de | ||
| 7 | 106 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p7:front_matter:front_panel:gray | [127, 129, 133] gray | True | [571.77, 70.54, 11.89, 80.75] | FULL PAPER | FULL PAPER | ||
| 7 | 107 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:1 | p7:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 71.4, 243.2, 53.71] | atoms in the second shell (see Table S2 in the Supporting Information). Thus, the ratio of the amplitudes of the fi rst two Fourier transform peaks, i.e., the Mn -O Mn -Mn ratio, being >1 is the EXAFS signature refl ect… | atoms in the second shell (see Table S2 in the Supporting Information). Thus, the ratio of the amplitudes of the fi rst two Fourier transform peaks, i.e., the Mn -O Mn -Mn ratio, being >1 is the EXAFS signature refl ect… | |
| 7 | 108 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:1 | p7:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.14, 126.4, 243.2, 173.52] | A preferential reduction in the amplitude of the fi rst shell of O atoms besides an overall damping of other shells at 5 V (Figure 4 b) is consistent with previous reports [ 18 ] and can be attributed, respectively, to … | A preferential reduction in the amplitude of the fi rst shell of O atoms besides an overall damping of other shells at 5 V (Figure 4 b) is consistent with previous reports [ 18 ] and can be attributed, respectively, to … | |
| 7 | 109 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:1 | p7:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 355.14, 243.2, 174.71] | However, fi tting the EXAFS data of the charged sample refi ned O N-N to 5.6(8) (Table S3 in the Supporting Information), which is high considering the fact that oxygen is released from the material during activation. N… | However, fi tting the EXAFS data of the charged sample refi ned O N-N to 5.6(8) (Table S3 in the Supporting Information), which is high considering the fact that oxygen is released from the material during activation. N… | |
| 7 | 110 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:1 | p7:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 528.44, 243.2, 154.22] | Despite this structural modifi cation, the Mn -O Mn -Mn ratio remains >1 for the charged sample (Figure 7 a), which suggests that the material retains its original Li 2 MnO 3 -like character even upon Li extraction. Thu… | Despite this structural modifi cation, the Mn -O Mn -Mn ratio remains >1 for the charged sample (Figure 7 a), which suggests that the material retains its original Li 2 MnO 3 -like character even upon Li extraction. Thu… | |
| 7 | 111 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:1 | p7:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 682.12, 243.2, 33.54] | The Li + -H + exchange mechanism is also supported in Li 2 MnO 3 by the observed change in the stacking sequence of oxygen layers from O3-type (ABCABC) to P3-type (ABBCCA) | The Li + -H + exchange mechanism is also supported in Li 2 MnO 3 by the observed change in the stacking sequence of oxygen layers from O3-type (ABCABC) to P3-type (ABBCCA) | |
| 7 | 112 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:1 | p7:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [494.77, 741.91, 67.86, 7.64] | (7 of 12) 1300998 | (7 of 12) 1300998 | |
| 7 | 113 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:0 | p7:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [185.77, 742.91, 169.97, 6.29] | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | |
| 7 | 114 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p7:body_region:1 | p7:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [388.05, 743.22, 64.38, 5.93] | wileyonlinelibrary.com | wileyonlinelibrary.com | |
| 8 | 115 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:0 | p8:top_margin:column_1_of_2:white | [255, 255, 255] white | True | [46.91, 45.16, 73.33, 6.78] | www.advenergymat.de | ||
| 8 | 116 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p8:front_matter:front_panel:gray | [164, 165, 168] gray | True | [10.31, 70.11, 11.89, 80.75] | FULL PAPER | FULL PAPER | ||
| 8 | 117 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p8:top_margin:column_2_of_2:white | [253, 253, 253] white | False | [577.94, 15.66, 4.29, 743.12] | 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… | |||
| 8 | 118 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:1 | p8:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [457.98, 53.43, 83.44, 6.78] | www.MaterialsViews.com | ||
| 8 | 119 | caption | caption | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:0 | p8:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [46.88, 221.33, 498.07, 19.07] | Figure 12. Stacking sequence of close-packed oxygen layers in a) O3 structure of Li 2 MnO 3 ( C2 / m ) [ 22 ] and b) P3 structure ( R 3 m ) of proton-exchanged material. [ 59 ] Note that O-H-O bonds are asymmetric in th… | Figure 12. Stacking sequence of close-packed oxygen layers in a) O3 structure of Li 2 MnO 3 ( C2 / m ) [ 22 ] and b) P3 structure ( R 3 m ) of proton-exchanged material. [ 59 ] Note that O-H-O bonds are asymmetric in th… | |
| 8 | 120 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:0 | p8:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 256.2, 243.2, 217.52] | due to the presence of protons in the interslab region and strong O-H-O bonding. [ 14,25 ] For comparison, O3-type and P3-type structures are shown in Figure 12 . The ordered atomic arrangements of O3 structure in the p… | due to the presence of protons in the interslab region and strong O-H-O bonding. [ 14,25 ] For comparison, O3-type and P3-type structures are shown in Figure 12 . The ordered atomic arrangements of O3 structure in the p… | |
| 8 | 121 | section_header | body_heading | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:0 | p8:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 550.5, 189.09, 7.46] | 3.2.2 . Structural Changes During the First Discharge | 3.2.2 . Structural Changes During the First Discharge | |
| 8 | 122 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:0 | p8:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 566.7, 243.2, 151.52] | Several reports have claimed that Li re-insertion into layered MnO 2 gives rise to the formation of LiMnO 2 with a concurrent reduction of Mn 4 + to Mn 3 + . [ 6,25 ] According to these reports, the local structure of t… | Several reports have claimed that Li re-insertion into layered MnO 2 gives rise to the formation of LiMnO 2 with a concurrent reduction of Mn 4 + to Mn 3 + . [ 6,25 ] According to these reports, the local structure of t… | |
| 8 | 123 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:0 | p8:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [32.48, 741.91, 67.86, 7.64] | 1300998 (8 of 12) | 1300998 (8 of 12) | |
| 8 | 124 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:0 | p8:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [137.77, 743.22, 64.38, 5.93] | wileyonlinelibrary.com | wileyonlinelibrary.com | |
| 8 | 125 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:1 | p8:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 256.24, 243.2, 63.52] | Li is re-inserted into the material. This could have happened by exchanging already present H + in the structure with Li + . [ 14 ] Discharge could then involve the reduction of partially oxidized oxygen anions of activ… | Li is re-inserted into the material. This could have happened by exchanging already present H + in the structure with Li + . [ 14 ] Discharge could then involve the reduction of partially oxidized oxygen anions of activ… | |
| 8 | 126 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:1 | p8:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 322.24, 243.2, 229.71] | Qualitative similarities between the EXAFS data of the pristine and discharged samples suggest structural re-ordering upon Li re-insertion. This is consistent with a reduction in the F 2 parameter for the coordination s… | Qualitative similarities between the EXAFS data of the pristine and discharged samples suggest structural re-ordering upon Li re-insertion. This is consistent with a reduction in the F 2 parameter for the coordination s… | |
| 8 | 127 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:1 | p8:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 553.24, 243.2, 118.52] | The Fourier transform peaks between 3 and 4.2 Å representing O atoms of the neighboring slabs reappear upon discharge (Figure 7 b). Correspondingly, F 2 associated with these O atoms (fourth shell) decreases (Figure 11 … | The Fourier transform peaks between 3 and 4.2 Å representing O atoms of the neighboring slabs reappear upon discharge (Figure 7 b). Correspondingly, F 2 associated with these O atoms (fourth shell) decreases (Figure 11 … | |
| 8 | 128 | formula | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:1 | p8:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [302.04, 677.01, 239.02, 29.06] | H + x Mn 4 + O - 2 + * 3 - y ︸ ︷︷ ︸ R ¯ 3 m (P3 - type) + ( x + * )Li + + ( x + * ) e - - Li + + exchange and discharge Li + x + * Mn 4 + O 2 - 3 - y ︸ ︷︷ ︸ C 2 / m (O3 - type) + x H + H | H + x Mn 4 + O - 2 + * 3 - y ︸ ︷︷ ︸ R ¯ 3 m (P3 - type) + ( x + * )Li + + ( x + * ) e - - Li + + exchange and discharge Li + x + * Mn 4 + O 2 - 3 - y ︸ ︷︷ ︸ C 2 / m (O3 - type) + x H + H | |
| 8 | 129 | text | unknown_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:1 | p8:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [532.89, 707.66, 12.31, 8.52] | (3) | (3) | |
| 8 | 130 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:1 | p8:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [236.51, 742.89, 169.97, 6.29] | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | |
| 8 | 131 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p8:body_region:1 | p8:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [440.0, 743.21, 103.42, 5.94] | Adv. Energy Mater. 2014 , 4 , 1300998 | Adv. Energy Mater. 2014 , 4 , 1300998 | |
| 9 | 132 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:0 | p9:top_margin:column_1_of_2:white | [255, 255, 255] white | False | [51.01, 53.34, 83.44, 6.78] | www.MaterialsViews.com | ||
| 9 | 133 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:0 | p9:front_matter:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 71.38, 243.2, 52.52] | The resultant structure upon discharge is similar to that of the parent Li 2 MnO 3 , except that it contains less Li and O. The driving force for such structural reversion is believed to be the relaxation of strained ox… | The resultant structure upon discharge is similar to that of the parent Li 2 MnO 3 , except that it contains less Li and O. The driving force for such structural reversion is believed to be the relaxation of strained ox… | |
| 9 | 134 | section_header | body_heading | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:0 | p9:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 141.98, 142.93, 7.46] | 3.2.3 . Structural Changes Upon Cycling | 3.2.3 . Structural Changes Upon Cycling | |
| 9 | 135 | text | back_matter_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:0 | p9:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 158.18, 243.2, 218.71] | It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] This claim is supported by qualitative similarities between the electrochemical profi les of … | It has been claimed that prolonged cycling of Li 2 MnO 3 gives rise to the formation of LiMn 2 O 4 -type spinel phase. [ 14 ] This claim is supported by qualitative similarities between the electrochemical profi les of … | |
| 9 | 136 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:0 | p9:body_zone:column_1_of_2:white | [255, 255, 255] white | False | [51.04, 378.18, 243.2, 339.71] | The crystallographic difference between the layered Li 2 MnO 3 and spinel LiMn 2 O 4 gives rise to distinct EXAFS signals (Figure 6 and Figure 8 ). A major difference lies in their Mn -O Mn -Mn ratios. Based on this cri… | The crystallographic difference between the layered Li 2 MnO 3 and spinel LiMn 2 O 4 gives rise to distinct EXAFS signals (Figure 6 and Figure 8 ). A major difference lies in their Mn -O Mn -Mn ratios. Based on this cri… | |
| 9 | 137 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:0 | p9:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [51.06, 743.21, 104.16, 5.94] | Adv. Energy Mater . 2014 , 4 , 1300998 | Adv. Energy Mater . 2014 , 4 , 1300998 | |
| 9 | 138 | text | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p9:top_margin:column_2_of_2:gray | [229, 229, 229] gray | True | [577.94, 15.66, 4.29, 743.12] | 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… | |||
| 9 | 139 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:1 | p9:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [473.91, 45.23, 73.35, 6.78] | www.advenergymat.de | ||
| 9 | 140 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p9:front_matter:front_panel:gray | [127, 129, 133] gray | True | [571.77, 70.54, 11.89, 80.75] | FULL PAPER | FULL PAPER | ||
| 9 | 141 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:1 | p9:front_matter:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 71.4, 243.2, 162.52] | and to those of the cycled-discharged sample is by a Li 2 MnO 3 structure. These fi t results suggest that the fraction of electrochemically active material is reduced to ≈ 60-70% up to the 33 rd cycle, which is consist… | and to those of the cycled-discharged sample is by a Li 2 MnO 3 structure. These fi t results suggest that the fraction of electrochemically active material is reduced to ≈ 60-70% up to the 33 rd cycle, which is consist… | |
| 9 | 142 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:1 | p9:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 236.4, 243.2, 206.52] | These results lead us to two major conclusions. First, the structural changes during the 33 rd cycle are similar to those observed during the fi rst, however, the fraction of electrochemically active material is gradual… | These results lead us to two major conclusions. First, the structural changes during the 33 rd cycle are similar to those observed during the fi rst, however, the fraction of electrochemically active material is gradual… | |
| 9 | 143 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:1 | p9:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 445.4, 243.2, 151.52] | The average Mn-O bond length for the cycled samples (Figure 10 ) remains unchanged from that of Mn 4 + -O, which rules out the conventional charge compensation mechanism involving the Mn 3 + /Mn 4 + redox reaction. Ther… | The average Mn-O bond length for the cycled samples (Figure 10 ) remains unchanged from that of Mn 4 + -O, which rules out the conventional charge compensation mechanism involving the Mn 3 + /Mn 4 + redox reaction. Ther… | |
| 9 | 144 | formula | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:1 | p9:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.18, 607.15, 241.73, 30.59] | Li + x + * Mn 4 + O 2 - 3 - y ︸ ︷︷ ︸ C 2 / m (O3 - type) Li + - H + exchange and charge H + - Li + exchange and discharge H + x Mn 4 + O - 2 + * 3 - y ︸ ︷︷ ︸ R ¯ 3 m (P3 - type) + ( x + * )Li + + ( x + * )e - . | Li + x + * Mn 4 + O 2 - 3 - y ︸ ︷︷ ︸ C 2 / m (O3 - type) Li + - H + exchange and charge H + - Li + exchange and discharge H + x Mn 4 + O - 2 + * 3 - y ︸ ︷︷ ︸ R ¯ 3 m (P3 - type) + ( x + * )Li + + ( x + * )e - . | |
| 9 | 145 | text | unknown_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:1 | p9:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [537.03, 639.81, 12.31, 8.52] | (4) | (4) | |
| 9 | 146 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:1 | p9:body_zone:column_2_of_2:white | [255, 255, 255] white | False | [306.15, 654.81, 243.21, 63.52] | Subsequent discharge could involve the reduction of partially oxidized oxygen anions along with electrolyte species and Li reinsertion could occur by displacing already present protons in the material with a concurrent … | Subsequent discharge could involve the reduction of partially oxidized oxygen anions along with electrolyte species and Li reinsertion could occur by displacing already present protons in the material with a concurrent … | |
| 9 | 147 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:1 | p9:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [494.77, 741.91, 67.86, 7.64] | (9 of 12) 1300998 | (9 of 12) 1300998 | |
| 9 | 148 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:0 | p9:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [185.77, 742.91, 169.97, 6.29] | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | |
| 9 | 149 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p9:body_region:1 | p9:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [388.05, 743.22, 64.38, 5.93] | wileyonlinelibrary.com | wileyonlinelibrary.com | |
| 10 | 150 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:0 | p10:top_margin:column_1_of_2:white | [255, 255, 255] white | True | [46.91, 45.16, 73.33, 6.78] | www.advenergymat.de | ||
| 10 | 151 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p10:page_body:column_1_of_2:gray | [164, 165, 168] gray | True | [10.31, 70.11, 11.89, 80.75] | FULL PAPER | FULL PAPER | ||
| 10 | 152 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:0 | p10:page_body:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 71.38, 243.2, 206.52] | subsequent cycle could lead to the loss of crystallinity of the material and consequently to the loss of its intercalation ability during cycling. The observed cleavage in Li 2 MnO 3 particles along the (001) plane [ 35… | subsequent cycle could lead to the loss of crystallinity of the material and consequently to the loss of its intercalation ability during cycling. The observed cleavage in Li 2 MnO 3 particles along the (001) plane [ 35… | |
| 10 | 153 | section_header | unknown_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:0 | p10:page_body:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 305.37, 72.99, 9.74] | 4 . Conclusions | 4 . Conclusions | |
| 10 | 154 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:0 | p10:page_body:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 323.38, 243.2, 272.52] | Both XANES and EXAFS provide complementary information that helps to understand structural changes in Li 2 MnO 3 . The total charge capacity during activation can be attributed to the oxidation of oxygen anions and that… | Both XANES and EXAFS provide complementary information that helps to understand structural changes in Li 2 MnO 3 . The total charge capacity during activation can be attributed to the oxidation of oxygen anions and that… | |
| 10 | 155 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:0 | p10:page_body:column_1_of_2:white | [255, 255, 255] white | False | [46.9, 647.88, 243.2, 66.54] | The proposed Li + -H + exchange during each subsequent charge and discharge could involve a structural fl ip-over between O3-type ( C2 / m ) and P3-type ( R 3 m ) by repeated shearing of oxygen layers. This could deteri… | The proposed Li + -H + exchange during each subsequent charge and discharge could involve a structural fl ip-over between O3-type ( C2 / m ) and P3-type ( R 3 m ) by repeated shearing of oxygen layers. This could deteri… | |
| 10 | 156 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:0 | p10:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [32.48, 741.91, 72.35, 7.64] | 1300998 (10 of 12) | 1300998 (10 of 12) | |
| 10 | 157 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:0 | p10:bottom_margin:column_1_of_2:white | [255, 255, 255] white | False | [137.77, 743.22, 64.38, 5.93] | wileyonlinelibrary.com | wileyonlinelibrary.com | |
| 10 | 158 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p10:top_margin:column_2_of_2:white | [253, 253, 253] white | False | [577.94, 15.66, 4.29, 743.12] | 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… | |||
| 10 | 159 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:1 | p10:top_margin:column_2_of_2:white | [255, 255, 255] white | False | [457.98, 53.43, 83.44, 6.78] | www.MaterialsViews.com | ||
| 10 | 160 | section_header | unknown_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:1 | p10:page_body:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 72.16, 115.78, 9.74] | 5 . Experimental Section | 5 . Experimental Section | |
| 10 | 161 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:1 | p10:page_body:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 89.94, 242.99, 130.29] | Li 2 MnO 3 was synthesized by a modifi ed Pechini method from acetate precursors. [ 49 ] The precursor powders, Mn(OCOCH 3 ) 2 ·4H 2 O and Li(OCOCH 3 )·H 2 O were dissolved in an aqueous mixture of ethylene glycol and c… | Li 2 MnO 3 was synthesized by a modifi ed Pechini method from acetate precursors. [ 49 ] The precursor powders, Mn(OCOCH 3 ) 2 ·4H 2 O and Li(OCOCH 3 )·H 2 O were dissolved in an aqueous mixture of ethylene glycol and c… | |
| 10 | 162 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:1 | p10:page_body:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 222.94, 242.95, 196.79] | The cathodes for electrochemical characterization were prepared by mixing 80 wt% active material, 10 wt% carbon black, and 10 wt% of a solution of polyvinylidene di-fl uoride in N -methyl-2-pyrrolidone acting as a binde… | The cathodes for electrochemical characterization were prepared by mixing 80 wt% active material, 10 wt% carbon black, and 10 wt% of a solution of polyvinylidene di-fl uoride in N -methyl-2-pyrrolidone acting as a binde… | |
| 10 | 163 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:1 | p10:page_body:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 422.44, 242.95, 215.79] | XAS measurements were carried out in the transmission mode at the Mn K-edge of various Li 2 MnO 3 samples. The samples charged and discharged during the fi rst cycle were measured at beamline A1 of the Hamburger Synchro… | XAS measurements were carried out in the transmission mode at the Mn K-edge of various Li 2 MnO 3 samples. The samples charged and discharged during the fi rst cycle were measured at beamline A1 of the Hamburger Synchro… | |
| 10 | 164 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:1 | p10:page_body:column_2_of_2:white | [255, 255, 255] white | False | [302.01, 640.94, 242.95, 74.07] | Various data pre-processing operations such as deglitching, averaging the scans, energy calibration, normalization, background subtraction etc., [ 50 ] were performed using the software ATHENA of the package IFEFFIT . [… | Various data pre-processing operations such as deglitching, averaging the scans, energy calibration, normalization, background subtraction etc., [ 50 ] were performed using the software ATHENA of the package IFEFFIT . [… | |
| 10 | 165 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:1 | p10:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [236.51, 742.89, 169.97, 6.29] | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | |
| 10 | 166 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p10:body_region:1 | p10:bottom_margin:column_2_of_2:white | [255, 255, 255] white | False | [440.0, 743.21, 103.42, 5.94] | Adv. Energy Mater. 2014 , 4 , 1300998 | Adv. Energy Mater. 2014 , 4 , 1300998 | |
| 11 | 167 | text | body_candidate_excluded | False | medium | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left_crossing:white | [255, 255, 255] white | False | [50.63, 70.67, 243.36, 302.53] | using the code FEFF8.2. [ 52 ] The model function was least-square fi tted to the data using the software ARTEMIS of the package IFEFFIT which uses the algorithm FEFFIT. [ 51 ] The fi tting parameters involved a single … | using the code FEFF8.2. [ 52 ] The model function was least-square fi tted to the data using the software ARTEMIS of the package IFEFFIT which uses the algorithm FEFFIT. [ 51 ] The fi tting parameters involved a single … | |
| 11 | 168 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:top_margin:left:white | [255, 255, 255] white | False | [51.01, 53.34, 83.44, 6.78] | www.MaterialsViews.com | ||
| 11 | 169 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left:white | [255, 255, 255] white | False | [51.04, 651.9, 172.03, 6.79] | C. S. Johnson , J. Power Sources 2007 , 165 , 559 . | C. S. Johnson , J. Power Sources 2007 , 165 , 559 . | |
| 11 | 170 | section_header | back_matter_heading | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left:white | [255, 255, 255] white | False | [51.04, 401.12, 115.6, 9.74] | Supporting Information | Supporting Information | |
| 11 | 171 | text | back_matter_heading | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left_crossing:white | [255, 255, 255] white | False | [51.04, 418.9, 242.95, 16.29] | Supporting Information is available from the Wiley Online Library or from the author. | Supporting Information is available from the Wiley Online Library or from the author. | |
| 11 | 172 | section_header | back_matter_heading | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left:white | [255, 255, 255] white | False | [51.04, 463.12, 95.82, 9.74] | Acknowledgements | Acknowledgements | |
| 11 | 173 | text | back_matter_text | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left_crossing:white | [255, 255, 255] white | False | [51.04, 480.9, 242.95, 54.79] | The authors acknowledge fi nancial support from the Europäischer Fonds für regionale Entwicklung (EFRE) under the project BATMAT (No. 200720132/35). R.K. acknowledges fi nancial support from the Hans-L. Merkle Stiftung … | The authors acknowledge fi nancial support from the Europäischer Fonds für regionale Entwicklung (EFRE) under the project BATMAT (No. 200720132/35). R.K. acknowledges fi nancial support from the Hans-L. Merkle Stiftung … | |
| 11 | 174 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:bottom_margin:left:white | [255, 255, 255] white | False | [51.06, 743.21, 104.16, 5.94] | Adv. Energy Mater . 2014 , 4 , 1300998 | Adv. Energy Mater . 2014 , 4 , 1300998 | |
| 11 | 175 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left_crossing:white | [255, 255, 255] white | False | [55.34, 611.9, 238.65, 16.79] | C. S. Johnson , N. Li , J. T . Vaughey , S. A. Hackney , M. M. Thackeray , Electrochem. Commun. 2005 , 7 , 528 . | C. S. Johnson , N. Li , J. T . Vaughey , S. A. Hackney , M. M. Thackeray , Electrochem. Commun. 2005 , 7 , 528 . | |
| 11 | 176 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left_crossing:white | [255, 255, 255] white | False | [55.34, 631.9, 238.65, 16.79] | M. M. Thackeray , S.-H. Kang , C. S. Johnson , J. T . Vaughey , S. A. Hackney , Electrochem. Commun. 2006 , 8 , 1531 . | M. M. Thackeray , S.-H. Kang , C. S. Johnson , J. T . Vaughey , S. A. Hackney , Electrochem. Commun. 2006 , 8 , 1531 . | |
| 11 | 177 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left_crossing:white | [255, 255, 255] white | False | [55.34, 661.9, 238.65, 16.79] | C. S. Johnson , N. Li , C. Lefi ef , M. M. Thackeray , Electrochem. Commun. 2007 , 9 , 787 . | C. S. Johnson , N. Li , C. Lefi ef , M. M. Thackeray , Electrochem. Commun. 2007 , 9 , 787 . | |
| 11 | 178 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left_crossing:white | [255, 255, 255] white | False | [55.34, 681.9, 238.65, 16.79] | M. M. Thackeray , S.-H. Kang , C. S. Johnson , J. T. Vaughey , R. Benedek , S. A. Hackney , J. Mater. Chem. 2007 , 17 , 3112 . | M. M. Thackeray , S.-H. Kang , C. S. Johnson , J. T. Vaughey , R. Benedek , S. A. Hackney , J. Mater. Chem. 2007 , 17 , 3112 . | |
| 11 | 179 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left_crossing:white | [255, 255, 255] white | False | [55.34, 701.9, 238.65, 16.79] | J. Li , R. Klöpsch , M. C. Stan , S. Nowak , M. Kunze , M. Winter , S. Passerini , J. Power Sources 2011 , 196 , 4821 . | J. Li , R. Klöpsch , M. C. Stan , S. Nowak , M. Kunze , M. Winter , S. Passerini , J. Power Sources 2011 , 196 , 4821 . | |
| 11 | 180 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left_crossing:white | [255, 255, 255] white | False | [55.35, 591.9, 238.63, 16.79] | C. S. Johnson , J.-S. Kim , C. Lefi ef , N. Li , J. T . Vaughey , M. M. Thackeray , Electrochem. Commun. 2004 , 6 , 1085 . | C. S. Johnson , J.-S. Kim , C. Lefi ef , N. Li , J. T . Vaughey , M. M. Thackeray , Electrochem. Commun. 2004 , 6 , 1085 . | |
| 11 | 181 | text | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:page_body:left_crossing:white | [255, 255, 255] white | False | [167.56, 547.9, 126.43, 26.79] | Received: August 7, 2013 Revised: October 17, 2013 Published online: December 27, 2013 | Received: August 7, 2013 Revised: October 17, 2013 Published online: December 27, 2013 | |
| 11 | 182 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:body_region:0 | p11:bottom_margin:left_crossing:white | [255, 255, 255] white | False | [185.77, 742.91, 169.97, 6.29] | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | |
| 11 | 183 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.14, 451.92, 242.95, 16.79] | D. Marabello , R. Bianchi , G. Gervasio , F. Cargnoni , Acta Crystallogr., Sect. A: Found. Crystallogr. 2004 , A60 , 494 . | D. Marabello , R. Bianchi , G. Gervasio , F. Cargnoni , Acta Crystallogr., Sect. A: Found. Crystallogr. 2004 , A60 , 494 . | ||
| 11 | 184 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.14, 471.92, 242.94, 16.79] | A. Ito , Y. Sato , T . Sanada , M. Hatano , H. Horie , Y . Ohsawa , J. Power Sources 2011 , 196 , 6828 . | A. Ito , Y. Sato , T . Sanada , M. Hatano , H. Horie , Y . Ohsawa , J. Power Sources 2011 , 196 , 6828 . | ||
| 11 | 185 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.14, 491.92, 226.86, 6.79] | V. B. Sapre , C. Mande , J. Phys. C: Solid State Phys. 1972 , 5 , 793 . | V. B. Sapre , C. Mande , J. Phys. C: Solid State Phys. 1972 , 5 , 793 . | ||
| 11 | 186 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 441.92, 166.39, 6.79] | W. H. Baur , Acta Crystallogr. 1976 , B32 , 2200 . | W. H. Baur , Acta Crystallogr. 1976 , B32 , 2200 . | ||
| 11 | 187 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 391.92, 242.94, 16.79] | A. Deb , U. Bergmann , E. J. Cairns , S. P. Cramer , J. Synchrotron Radiat. 2004 , 11 , 497 . | A. Deb , U. Bergmann , E. J. Cairns , S. P. Cramer , J. Synchrotron Radiat. 2004 , 11 , 497 . | ||
| 11 | 188 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 411.92, 242.94, 16.79] | S. Geller , J. A. Cape , R. W . Grant , G. P. Espinosa , Phys. Lett. A 1967 , 24A , 369 . | S. Geller , J. A. Cape , R. W . Grant , G. P. Espinosa , Phys. Lett. A 1967 , 24A , 369 . | ||
| 11 | 189 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 381.92, 192.4, 6.79] | J. J. Rehr , R. C. Albers , Rev. Mod. Phys. 2000 , 72 , 621 . | J. J. Rehr , R. C. Albers , Rev. Mod. Phys. 2000 , 72 , 621 . | ||
| 11 | 190 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 241.92, 240.94, 16.79] | D. Y. W. Yu , K. Y anagida , Y . Kato , H. Nakamura , J. Electrochem. Soc. 2009 , 156 , A417 . | D. Y. W. Yu , K. Y anagida , Y . Kato , H. Nakamura , J. Electrochem. Soc. 2009 , 156 , A417 . | ||
| 11 | 191 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 311.92, 231.24, 6.79] | P. Strobel , B. Lambert-Andron , J. Solid State Chem. 1988 , 75 , 90 . | P. Strobel , B. Lambert-Andron , J. Solid State Chem. 1988 , 75 , 90 . | ||
| 11 | 192 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 331.92, 242.95, 16.79] | M. H. Rossouw , D. C. Liles , M. M. Thackeray , W . I. F. David , S. Hull , Mater. Res. Bull. 1992 , 27 , 221 . | M. H. Rossouw , D. C. Liles , M. M. Thackeray , W . I. F. David , S. Hull , Mater. Res. Bull. 1992 , 27 , 221 . | ||
| 11 | 193 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 351.92, 242.94, 16.79] | Y. Paik , C. P. Grey , C. S. Johnson , J.-S. Kim , M. M. Thackeray , Chem. Mater. 2002 , 14 , 5109 . | Y. Paik , C. P. Grey , C. S. Johnson , J.-S. Kim , M. M. Thackeray , Chem. Mater. 2002 , 14 , 5109 . | ||
| 11 | 194 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 371.92, 239.87, 6.79] | D. E. Sayers , E. A. Stern , F. W . Lytle , Phys. Rev. Lett. 1971 , 27 , 1204 . | D. E. Sayers , E. A. Stern , F. W . Lytle , Phys. Rev. Lett. 1971 , 27 , 1204 . | ||
| 11 | 195 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 431.92, 236.46, 6.79] | C. Y. Ouyang , S. Q. Shi , M. S. Lei , J. Alloys Compd. 2009 , 474 , 370 . | C. Y. Ouyang , S. Q. Shi , M. S. Lei , J. Alloys Compd. 2009 , 474 , 370 . | ||
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| 11 | 197 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 701.92, 242.94, 16.79] | A. R. Armstrong , A. J. Paterson , A. D. Robertson , P. G. Bruce , Chem. Mater. 2002 , 14 , 710 . | A. R. Armstrong , A. J. Paterson , A. D. Robertson , P. G. Bruce , Chem. Mater. 2002 , 14 , 710 . | ||
| 11 | 198 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 501.92, 242.95, 16.79] | W. Tang , H. Kanoh , X. Y ang , K. Ooi , Chem. Mater. 2000 , 12 , 3271 . | W. Tang , H. Kanoh , X. Y ang , K. Ooi , Chem. Mater. 2000 , 12 , 3271 . | ||
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| 11 | 200 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 611.92, 240.95, 16.79] | M. Moshkovich , M. Cojocaru , H. E. Gottlieb , D. Aurbach , J. Electroanal. Chem. 2001 , 497 , 84 . | M. Moshkovich , M. Cojocaru , H. E. Gottlieb , D. Aurbach , J. Electroanal. Chem. 2001 , 497 , 84 . | ||
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| 11 | 204 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 631.92, 218.87, 6.79] | Q. Feng , Y . Miyai , H. Kanoh , K. Ooi , Langmuir 1992 , 8 , 1861 . | Q. Feng , Y . Miyai , H. Kanoh , K. Ooi , Langmuir 1992 , 8 , 1861 . | ||
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| 11 | 207 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 171.92, 213.89, 6.79] | A. D. Robertson , P. G. Bruce , Chem. Mater. 2003 , 15 , 1984 . | A. D. Robertson , P. G. Bruce , Chem. Mater. 2003 , 15 , 1984 . | ||
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| 11 | 215 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 531.92, 242.95, 16.79] | H. Koga , L. Croguennec , M. Ménétrier , P. Mannessiez , F. Weill , C. Delmas , J. Power Sources 2013 , 236 , 250 . | H. Koga , L. Croguennec , M. Ménétrier , P. Mannessiez , F. Weill , C. Delmas , J. Power Sources 2013 , 236 , 250 . | ||
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| 11 | 217 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right_crossing:white | [255, 255, 255] white | False | [306.15, 581.92, 240.94, 16.79] | K. Kanamura , S. T oriyama , S. Shiraishi , Z.-i. T akehara , J. Electrochem. Soc. 1996 , 143 , 2548 . | K. Kanamura , S. T oriyama , S. Shiraishi , Z.-i. T akehara , J. Electrochem. Soc. 1996 , 143 , 2548 . | ||
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| 11 | 220 | list_item | reference | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right:white | [255, 255, 255] white | False | [310.45, 91.92, 238.65, 16.79] | J. R. Croy , D. Kim , M. Balasubramanian , K. Gallagher , S.-H. Kang , M. M. Thackeray , J. Electrochem. Soc. 2012 , 159 , A781 . | J. R. Croy , D. Kim , M. Balasubramanian , K. Gallagher , S.-H. Kang , M. M. Thackeray , J. Electrochem. Soc. 2012 , 159 , A781 . | ||
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| 11 | 222 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:bottom_margin:right:white | [255, 255, 255] white | False | [388.05, 743.22, 64.38, 5.93] | wileyonlinelibrary.com | wileyonlinelibrary.com | ||
| 11 | 223 | text | page_margin_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:top_margin:right:white | [255, 255, 255] white | False | [473.91, 45.23, 73.35, 6.78] | www.advenergymat.de | |||
| 11 | 224 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:bottom_margin:right:white | [255, 255, 255] white | False | [490.29, 741.91, 72.34, 7.64] | (11 of 12) 1300998 | (11 of 12) 1300998 | ||
| 11 | 225 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:page_body:right:gray | [127, 129, 133] gray | True | [571.77, 70.54, 11.89, 80.75] | FULL PAPER | FULL PAPER | ||
| 11 | 226 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p11:top_margin:right:gray | [229, 229, 229] gray | True | [577.94, 15.66, 4.29, 743.12] | 16146840, 2014, 5, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300998 by Jilin University, Wiley Online Library on [11/07/2026]. See the Terms and Conditions (https://onlinelibrary.wiley… | |||
| 12 | 227 | page_header | page_header | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:page_body:left:gray | [164, 165, 168] gray | True | [10.31, 70.11, 11.89, 80.75] | FULL PAPER | FULL PAPER | ||
| 12 | 228 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:bottom_margin:left:white | [255, 255, 255] white | False | [32.48, 741.91, 72.35, 7.64] | 1300998 (12 of 12) | 1300998 (12 of 12) | ||
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| 12 | 235 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:bottom_margin:left:white | [255, 255, 255] white | False | [137.77, 743.22, 64.38, 5.93] | wileyonlinelibrary.com | wileyonlinelibrary.com | ||
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| 12 | 245 | page_footer | page_footer | False | low | after_back_matter_stop | after_back_matter_stop | after_stop | p12:bottom_margin:right:white | [255, 255, 255] white | False | [440.0, 743.21, 103.42, 5.94] | Adv. Energy Mater. 2014 , 4 , 1300998 | Adv. Energy Mater. 2014 , 4 , 1300998 | ||
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