Docling layout block audit

original.pdf docling.json layout_blocks.json layout_blocks.tsv layout_blocks.jsonl excluded_blocks.html excluded_blocks.tsv final_body_blocks.tsv visual_assets.tsv visual_assets.json

Summary

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Diff Summary

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Truncation

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Page Overlays

Green = final body chunks. Orange/purple asset boxes = actual figure/table assets used by ingestion. Cyan dashed text boxes = text blocks consumed by those assets as caption continuations. Red STOP = truncation trigger. Red boxes = blocks after truncation.

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Visual Assets

这里对齐真实图表资产提取链路。caption_source=embedded_table_cell 表示表注来自 Docling table cell，不会出现在 text block 审计差集里；caption_continuation_used_by_asset 表示某个 text block 已被图表 caption 吸收，不应按普通 metadata 解读。

#typelabelpagecaption sourcesuppressedduplicate reasonrescue reasongroupconfidencebboxcaption
1figureFig. 12direct_caption_ref0.82[54.14, 76.62, 481.6, 302.21]Figure 1. Schematic of surface defect engineering and the transformation of surface crystal structures for LRMO materials.
2figureFig. 23nearby_text_caption0.82[53.64, 80.01, 490.61, 487.63]Figure 2. a) The XRD patterns of P0 and NHCO-5 samples with the enlarged images of (003), (101), and (104) peaks, respectively. Refined XRD data of b) P0 and c) NHCO-5. Raman spectra of d) P0 and e) NHCO-5. The TEM and HRTEM images of f,g) P0 and h,i) NHCO-5. j) STEM-EDS mapping of Ni, Co, Mn, and O elements of NHCO-5 samples.
3figureFig. 35nearby_text_caption0.82[53.61, 79.67, 489.62, 396.64]Figure 3. High-resolution XPS spectra of O 1s for a) P0 and b) NHCO-5. c) EPR spectra of P0 and NHCO-5. d) Normalized O K-edge sXAS spectra of P0 and NHCO-5. The XPS spectra of Mn 2p for e) P0 and f) NHCO-5. g) The XPS spectra of Mn 3s for P0, NHCO-3, NHCO-5, and NHCO-8.
4figureFig. 46nearby_text_caption0.82[51.31, 79.48, 489.57, 393.16]Figure 4. The electrochemical performance of P0 and NHCO-5 electrodes: charge-discharge curves of a) P0 electrode and b) NHCO-5 electrode. c) The rate performance. d) Cycling performance. The initial charge and discharge curves at e) 3 C and f) 5 C fast charging rate after three cycle activation. g) Constant current and voltage of charging capacity obtained from the 1st, 50th, and 100th at 5 C charging rate. h) Charging SOC versus time curves at 3 C and 5 C. i) Cycling performance at 5 C charging rate and 1 C discharge rate.
5figureFig. 57nearby_text_caption0.82[53.93, 77.04, 489.51, 474.51]Figure 5. The O 1s XPS spectra at different charging/discharging states of a) P0 electrode and b) NHCO-5 electrode. The normalized O pre K-edge and Mn pre L-edge XAS spectra for c,e) P0 electrode and d,f) NHCO-5 electrode. Ex situ XRD patterns of g) P0 electrode and h) NHCO-5 electrode in the initial cyclic process. Density of states of the i) P0 and j) NHCO-5 sample. Maps of ELF for the k) P0 and l) NHCO-5; circles show there are more delocalized electrons around the transition metal.
6figureFig. 69direct_caption_ref0.82[52.66, 77.52, 493.42, 389.48]Figure 6. The analysis of P0 and NHCO-5 electrodes after 200 cycles: a) The comparison of XRD pattern. b) Raman spectra. The SEM images of c) P0 and e) NHCO-5. HRTEM images of d) P0 and f) NHCO-5. g) The schematic of the crystal structure deterioration for P0 electrode.

Blocks

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white		True[50.81, 28.94, 126.19, 12.11]RESEARCH ARTICLERESEARCH ARTICLE
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white		False[472.46, 49.98, 74.39, 8.02]www.afm-journal.de
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white		False[50.81, 77.5, 441.13, 63.65]Local Electronic Structure Modulation Enables Fast-Charging Capability for Li-Rich Mn-Based Oxides Cathodes With Reversible Anionic Redox ActivityLocal Electronic Structure Modulation Enables Fast-Charging Capability for Li-Rich Mn-Based Oxides Cathodes With Reversible Anionic Redox Activity
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white		False[50.81, 160.21, 487.97, 30.54]Xianggang Gao, Haiyan Zhang, Shihao Li, Shuai Zhang, Chaohong Guan, Xiaoping Hu, Juanlang Guo, Yanqing Lai,* and Zhian Zhang*Xianggang Gao, Haiyan Zhang, Shihao Li, Shuai Zhang, Chaohong Guan, Xiaoping Hu, Juanlang Guo, Yanqing Lai,* and Zhian Zhang*
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gray		False[50.81, 227.68, 312.83, 241.82]Anionic and cationic redox chemistries boost ultrahigh specific capacities of Li-rich Mn-based oxides cathodes (LRMO). However, irreversible oxygen evolution and sluggish kinetics result in continuous capacity decay and…Anionic and cationic redox chemistries boost ultrahigh specific capacities of Li-rich Mn-based oxides cathodes (LRMO). However, irreversible oxygen evolution and sluggish kinetics result in continuous capacity decay and…
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white		False[50.81, 504.82, 188.74, 7.2]X. Gao, H. Zhang, S. Li, S. Zhang, J. Guo, Y. Lai, Z. ZhangX. Gao, H. Zhang, S. Li, S. Zhang, J. Guo, Y. Lai, Z. Zhang
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white		False[50.81, 513.78, 127.19, 7.2]School of Metallurgy and EnvironmentSchool of Metallurgy and Environment
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white		False[50.81, 522.75, 234.43, 25.14]Hunan Province Key Laboratory of Nonferrous Value-Added Metallurgy Engineering Research Center of the Ministry of Education for Advanced Battery MaterialsHunan Province Key Laboratory of Nonferrous Value-Added Metallurgy Engineering Research Center of the Ministry of Education for Advanced Battery Materials
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white		False[50.81, 549.65, 80.2, 7.2]Central South UniversityCentral South University
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white		False[50.81, 558.61, 125.23, 7.2]Changsha, Hunan 410083, P. R. ChinaChangsha, Hunan 410083, P. R. China
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white		False[50.81, 567.58, 191.32, 7.2]E-mail: laiyanqingcsu@163.com; zhangzhian@csu.edu.cnE-mail: laiyanqingcsu@163.com; zhangzhian@csu.edu.cn
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white		False[50.81, 616.4, 216.68, 7.2]University of Michigan-Shanghai Jiao Tong University Joint InstituteUniversity of Michigan-Shanghai Jiao Tong University Joint Institute
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white		False[68.79, 690.25, 222.97, 16.17]The ORCID identification number(s) for the author(s) of this article can be found under https://doi.org/10.1002/adfm.202304065The ORCID identification number(s) for the author(s) of this article can be found under
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white		True[50.81, 712.5, 114.86, 8.02]DOI: 10.1002/adfm.202304065DOI: 10.1002/adfm.202304065
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white		False[50.81, 745.71, 105.61, 6.3]Adv. Funct. Mater. 2023 , 33 , 2304065Adv. Funct. Mater. 2023 , 33 , 2304065
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white		False[384.63, 219.54, 70.41, 10.25]1. Introduction1. Introduction
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white		False[384.63, 238.89, 162.26, 249.54]Recently, Li-rich Mn-based oxides cathodes (LRMO) written as x Li2MnO3 · (1 -x )LiTMO2 (TM = Nickel, Cobalt and Manganese) have attracted extensive research due to its ultrahigh capacity ( > 250 mAh · g -1 ) and low cos…Recently, Li-rich Mn-based oxides cathodes (LRMO) written as x Li2MnO3 · (1 -x )LiTMO2 (TM = Nickel, Cobalt and Manganese) have attracted extensive research due to its ultrahigh capacity ( > 250 mAh · g -1 ) and low cos…
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white		False[305.92, 490.95, 240.96, 139.94]anionic redox such as oxygen loss has caused structural degradation, while contributing to ultrahigh capacity. For example, oxygen release can trigger irreversible migration of transition metal ions, severe side reactio…anionic redox such as oxygen loss has caused structural degradation, while contributing to ultrahigh capacity. For example, oxygen release can trigger irreversible migration of transition metal ions, severe side reactio…
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white		False[305.92, 633.41, 240.95, 85.16]In order to address the above issues, plenty of modification strategies including surface coating, elemental doping, and surface defect/heterostructure engineering have been raised to suppress oxygen loss, severe side r…In order to address the above issues, plenty of modification strategies including surface coating, elemental doping, and surface defect/heterostructure engineering have been raised to suppress oxygen loss, severe side r…
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white		False[266.69, 744.38, 64.3, 8.02]2304065 (1 of 11)2304065 (1 of 11)
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white		False[469.66, 745.82, 77.21, 6.3]©2023 Wiley-VCH GmbH©2023 Wiley-VCH GmbH
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white		False[47.98, 388.13, 405.37, 7.2]Figure 1. Schematic of surface defect engineering and the transformation of surface crystal structures for LRMO materials.Figure 1. Schematic of surface defect engineering and the transformation of surface crystal structures for LRMO materials.
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white		False[47.98, 416.06, 240.96, 304.33]inactive substances. Therefore, surface defect engineering has received wide attention in the past few years. Surface defects such as lithium and oxygen vacancies can be incorporated into the crystal structure during th…inactive substances. Therefore, surface defect engineering has received wide attention in the past few years. Surface defects such as lithium and oxygen vacancies can be incorporated into the crystal structure during th…
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white		False[47.98, 745.71, 105.61, 6.3]Adv. Funct. Mater. 2023 , 33 , 2304065Adv. Funct. Mater. 2023 , 33 , 2304065
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white		False[303.09, 416.06, 240.96, 107.07]constructed oxygen vacancy and Li4Mn5O12 on the surface of Lirich oxide layered cathodes by using a facile oxalic acid assisted delithiation process. [ 10] The irreversible release of oxygen and voltage decay were obvio…constructed oxygen vacancy and Li4Mn5O12 on the surface of Lirich oxide layered cathodes by using a facile oxalic acid assisted delithiation process. [ 10] The irreversible release of oxygen and voltage decay were obvio…
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white		False[303.09, 525.65, 240.96, 194.74]Herein, as shown in Figure 1 , a moderate surface defects construction strategy with ammonium oxalate thermal treatment is successfully realized for manufacturing oxygen vacancies and spinel-like structure on the surfac…Herein, as shown in Figure 1 , a moderate surface defects construction strategy with ammonium oxalate thermal treatment is successfully realized for manufacturing oxygen vacancies and spinel-like structure on the surfac…
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white		False[466.82, 745.82, 77.21, 6.3]©2023 Wiley-VCH GmbH©2023 Wiley-VCH GmbH
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white		False[50.81, 575.36, 496.07, 26.13]Figure 2. a) The XRD patterns of P0 and NHCO-5 samples with the enlarged images of (003), (101), and (104) peaks, respectively. Refined XRD data of b) P0 and c) NHCO-5. Raman spectra of d) P0 and e) NHCO-5. The TEM and …Figure 2. a) The XRD patterns of P0 and NHCO-5 samples with the enlarged images of (003), (101), and (104) peaks, respectively. Refined XRD data of b) P0 and c) NHCO-5. Raman spectra of d) P0 and e) NHCO-5. The TEM and …
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white		False[50.81, 624.27, 240.96, 41.32]cycling performance with excellent rate performance and fastcharging capability. The present work provides some references to enhance fast-charging capability of LRMO with reversible anionic redox via surface defect eng…cycling performance with excellent rate performance and fastcharging capability. The present work provides some references to enhance fast-charging capability of LRMO with reversible anionic redox via surface defect eng…
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white		False[50.81, 681.93, 122.45, 10.25]2. Results and Discussion2. Results and Discussion
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white		False[50.81, 701.29, 240.94, 19.41]Li-rich Mn-based oxides cathodes treated with 3wt%, 5wt%, and 8wt% of ammonium oxalate are denoted as NHCO-3, NHCO-5,Li-rich Mn-based oxides cathodes treated with 3wt%, 5wt%, and 8wt% of ammonium oxalate are denoted as NHCO-3, NHCO-5,
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white		False[50.81, 745.71, 105.61, 6.3]Adv. Funct. Mater. 2023 , 33 , 2304065Adv. Funct. Mater. 2023 , 33 , 2304065
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white		False[305.92, 624.27, 240.97, 96.11]and NHCO-8 samples, respectively. The pristine LRMO without any modification is marked as P0 sample. Figure 2 a shows the XRDpatterns of P0 and NHCO-5 samples. The narrow and sharp peaks of both the samples demonstrate …and NHCO-8 samples, respectively. The pristine LRMO without any modification is marked as P0 sample. Figure 2 a shows the XRDpatterns of P0 and NHCO-5 samples. The narrow and sharp peaks of both the samples demonstrate …
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white		False[469.66, 745.82, 77.21, 6.3]©2023 Wiley-VCH GmbH©2023 Wiley-VCH GmbH
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white		False[47.98, 76.43, 240.96, 413.93]ammonium oxalate thermal treatment. What is more, the well splitting of (006)/(102) and (108)/(110) peaks for all the samples demonstrates the well-formed layered ordering structure without any destruction after surface…ammonium oxalate thermal treatment. What is more, the well splitting of (006)/(102) and (108)/(110) peaks for all the samples demonstrates the well-formed layered ordering structure without any destruction after surface…
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white		False[47.98, 492.87, 240.96, 227.62]Further, transmission electron microscopy (TEM) and highresolution TEM (HRTEM) characterizations were conducted to explore the surface crystal structure changes after surface modification. The relevant results are depic…Further, transmission electron microscopy (TEM) and highresolution TEM (HRTEM) characterizations were conducted to explore the surface crystal structure changes after surface modification. The relevant results are depic…
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white		False[47.98, 745.71, 105.61, 6.3]Adv. Funct. Mater. 2023 , 33 , 2304065Adv. Funct. Mater. 2023 , 33 , 2304065
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white		False[303.09, 75.54, 240.95, 86.05]structure can boost the fast Li + diffusion, enhance the rate performance and fast-charging capability of LRMO. These results provide strong evidences of the existence of spinel phase, well consistent with the results f…structure can boost the fast Li + diffusion, enhance the rate performance and fast-charging capability of LRMO. These results provide strong evidences of the existence of spinel phase, well consistent with the results f…
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white		False[303.09, 164.11, 240.97, 479.67]Surface defect engineering usually can result in the obvious changes of elemental chemical compositions and metal valence, exerting a significant impact on the electrochemical properties of LRMO. Therefore, relevant cha…Surface defect engineering usually can result in the obvious changes of elemental chemical compositions and metal valence, exerting a significant impact on the electrochemical properties of LRMO. Therefore, relevant cha…
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white		False[303.09, 646.29, 240.96, 74.2]With respect to electrochemical performance, to evaluate the cyclic stability, rate performance, and fast-charging properties of P0 and NHCO-5, all the assembled electrodes are initially activated at a low rate of 0.1 C…With respect to electrochemical performance, to evaluate the cyclic stability, rate performance, and fast-charging properties of P0 and NHCO-5, all the assembled electrodes are initially activated at a low rate of 0.1 C…
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white		False[50.81, 486.36, 496.05, 16.66]Figure 3. High-resolution XPS spectra of O 1s for a) P0 and b) NHCO-5. c) EPR spectra of P0 and NHCO-5. d) Normalized O K-edge sXAS spectra of P0 and NHCO-5. The XPS spectra of Mn 2p for e) P0 and f) NHCO-5. g) The XPS …Figure 3. High-resolution XPS spectra of O 1s for a) P0 and b) NHCO-5. c) EPR spectra of P0 and NHCO-5. d) Normalized O K-edge sXAS spectra of P0 and NHCO-5. The XPS spectra of Mn 2p for e) P0 and f) NHCO-5. g) The XPS …
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white		False[50.81, 525.64, 240.96, 194.75]( < 4.5 V) and a long plateau ( ≈ 4.5 V) correspond to the oxidation process of transition metals and electrochemical activation of Li 2 MnO3, respectively. [22] In contrast, NHCO-5 electrode delivers increasing dischar…( < 4.5 V) and a long plateau ( ≈ 4.5 V) correspond to the oxidation process of transition metals and electrochemical activation of Li 2 MnO3, respectively. [22] In contrast, NHCO-5 electrode delivers increasing dischar…
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white		False[50.81, 745.71, 105.61, 6.3]Adv. Funct. Mater. 2023 , 33 , 2304065Adv. Funct. Mater. 2023 , 33 , 2304065
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white		False[305.92, 525.64, 240.96, 139.95]rates of 0.1, 0.2, 0.5, 1, 2, and 5 C, respectively. However, NHCO-5 electrode exhibits superior rate performance with low voltage polarization. The capacities of NHCO-5 electrode are 292.9, 278.1, 256.7, 240.7, 219.9, …rates of 0.1, 0.2, 0.5, 1, 2, and 5 C, respectively. However, NHCO-5 electrode exhibits superior rate performance with low voltage polarization. The capacities of NHCO-5 electrode are 292.9, 278.1, 256.7, 240.7, 219.9, …
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white		False[305.92, 668.11, 240.96, 52.27]To further examine the fast-charging properties of modified material, both the electrodes were charged at 3 or 5 C and discharged at 1 C for the fast-charging performance assessment. Figure 4e-i; Figure S5c-f, Supportin…To further examine the fast-charging properties of modified material, both the electrodes were charged at 3 or 5 C and discharged at 1 C for the fast-charging performance assessment. Figure 4e-i; Figure S5c-f, Supportin…
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white		False[469.66, 745.82, 77.21, 6.3]©2023 Wiley-VCH GmbH©2023 Wiley-VCH GmbH
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white		False[47.98, 482.35, 496.08, 35.6]Figure 4. The electrochemical performance of P0 and NHCO-5 electrodes: charge-discharge curves of a) P0 electrode and b) NHCO-5 electrode. c) The rate performance. d) Cycling performance. The initial charge and discharg…Figure 4. The electrochemical performance of P0 and NHCO-5 electrodes: charge-discharge curves of a) P0 electrode and b) NHCO-5 electrode. c) The rate performance. d) Cycling performance. The initial charge and discharg…
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white		False[47.98, 536.6, 240.96, 183.79]Supporting Information, shows the first and last charge and discharge curves at 3 and 5 C charging rate, respectively. There is no obvious difference as charged at 3 C for the two electrodes. However, P0 electrode shows…Supporting Information, shows the first and last charge and discharge curves at 3 and 5 C charging rate, respectively. There is no obvious difference as charged at 3 C for the two electrodes. However, P0 electrode shows…
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white		False[47.98, 745.71, 105.61, 6.3]Adv. Funct. Mater. 2023 , 33 , 2304065Adv. Funct. Mater. 2023 , 33 , 2304065
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white		False[303.09, 536.61, 240.96, 183.78]and less than P0 ( ≈ 11 min), as seen in the Figure 4h. Figure S5f, Supporting Information; Figure 5 i show the comparison of the cycling performance of P0 and NHCO-5 electrodes at 3 and 5 C fast-charging rate. P0 and N…and less than P0 ( ≈ 11 min), as seen in the Figure 4h. Figure S5f, Supporting Information; Figure 5 i show the comparison of the cycling performance of P0 and NHCO-5 electrodes at 3 and 5 C fast-charging rate. P0 and N…
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white		False[50.81, 561.36, 496.06, 35.6]Figure 5. The O 1s XPS spectra at different charging/discharging states of a) P0 electrode and b) NHCO-5 electrode. The normalized O pre K-edge and Mn pre L-edge XAS spectra for c,e) P0 electrode and d,f) NHCO-5 electro…Figure 5. The O 1s XPS spectra at different charging/discharging states of a) P0 electrode and b) NHCO-5 electrode. The normalized O pre K-edge and Mn pre L-edge XAS spectra for c,e) P0 electrode and d,f) NHCO-5 electro…
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white		False[50.81, 624.27, 240.97, 96.11]As far as mechanisms of the improved rate performance and fast-charging capability are concerned, previous reports have demonstrated that oxygen redox chemistry results in sluggish kinetics with low Li + diffusion rate …As far as mechanisms of the improved rate performance and fast-charging capability are concerned, previous reports have demonstrated that oxygen redox chemistry results in sluggish kinetics with low Li + diffusion rate …
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white		False[50.81, 745.71, 105.61, 6.3]Adv. Funct. Mater. 2023 , 33 , 2304065Adv. Funct. Mater. 2023 , 33 , 2304065
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white		False[305.92, 624.27, 240.96, 96.11]shows the EIS Nyquist plots of P0 and NHCO-5 electrodes before electrochemical cycles. All the curves include three regions. Asmall interrupt in the high frequency represents the Ohmic resistance ( R s ) of the cell. On…shows the EIS Nyquist plots of P0 and NHCO-5 electrodes before electrochemical cycles. All the curves include three regions. Asmall interrupt in the high frequency represents the Ohmic resistance ( R s ) of the cell. On…
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white		False[47.97, 76.43, 240.96, 172.83]impedance of NHCO-5 with surface defect construction. [17c] The GITT measurement is also conducted to compare the kinetic performance of P0 and NHCO-5 electrodes after five cycles at 0.04 C (Figure S6b, Supporting Infor…impedance of NHCO-5 with surface defect construction. [17c] The GITT measurement is also conducted to compare the kinetic performance of P0 and NHCO-5 electrodes after five cycles at 0.04 C (Figure S6b, Supporting Infor…
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white		False[47.97, 251.77, 240.97, 468.71]The O 1s XPS spectra of P0 and NHCO-5 electrodes at charging and discharging state in the first cycle are conducted for exploring the mechanisms of oxygen redox (Figure 5a,b). Three obvious peaks appearing at ≈ 529.5, ≈…The O 1s XPS spectra of P0 and NHCO-5 electrodes at charging and discharging state in the first cycle are conducted for exploring the mechanisms of oxygen redox (Figure 5a,b). Three obvious peaks appearing at ≈ 529.5, ≈…
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white		False[47.98, 745.71, 105.61, 6.3]Adv. Funct. Mater. 2023 , 33 , 2304065Adv. Funct. Mater. 2023 , 33 , 2304065
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white		False[303.09, 76.42, 240.93, 30.37]results successfully demonstrate the surface oxygen vacancies, and spinel phase can enhance the reversible anionic redox and suppress irreversible oxygen release.results successfully demonstrate the surface oxygen vacancies, and spinel phase can enhance the reversible anionic redox and suppress irreversible oxygen release.
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white		False[303.09, 109.3, 240.96, 293.38]Ex situ XRD is applied to figure out the influence of the surface treatment on the crystal structural evolution of LRMO. The associated results are displayed in Figure 5g,h. The shift of (003) peak can directly reflect …Ex situ XRD is applied to figure out the influence of the surface treatment on the crystal structural evolution of LRMO. The associated results are displayed in Figure 5g,h. The shift of (003) peak can directly reflect …
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white		False[303.09, 405.2, 240.96, 315.29]To further demonstrate and understand the influencing mechanisms of surface defect structure on the electrochemical performance, first principles calculations are conducted for studying the electronic structure of P0 an…To further demonstrate and understand the influencing mechanisms of surface defect structure on the electrochemical performance, first principles calculations are conducted for studying the electronic structure of P0 an…
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white		False[50.81, 473.35, 496.06, 16.67]Figure 6. The analysis of P0 and NHCO-5 electrodes after 200 cycles: a) The comparison of XRD pattern. b) Raman spectra. The SEM images of c) P0 and e) NHCO-5. HRTEM images of d) P0 and f) NHCO-5. g) The schematic of th…Figure 6. The analysis of P0 and NHCO-5 electrodes after 200 cycles: a) The comparison of XRD pattern. b) Raman spectra. The SEM images of c) P0 and e) NHCO-5. HRTEM images of d) P0 and f) NHCO-5. g) The schematic of th…
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white		False[50.81, 514.68, 240.95, 41.32]increasing electrical conductivity, facilitating lithium ion diffusion and fast charge transfer, but also suppressing oxygen release and promoting the charge compensation of both cationic and anionic redox.increasing electrical conductivity, facilitating lithium ion diffusion and fast charge transfer, but also suppressing oxygen release and promoting the charge compensation of both cationic and anionic redox.
9107textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
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white		False[50.81, 558.52, 240.96, 161.87]To explore the structural evolution of P0 and NHCO-5 electrodes after 200 cycles, relevant characterizations were employed to study the changes of crystal structure and morphology. Figure 6 a shows the comparison of XRD…To explore the structural evolution of P0 and NHCO-5 electrodes after 200 cycles, relevant characterizations were employed to study the changes of crystal structure and morphology. Figure 6 a shows the comparison of XRD…
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white		False[50.81, 745.71, 105.61, 6.3]Adv. Funct. Mater. 2023 , 33 , 2304065Adv. Funct. Mater. 2023 , 33 , 2304065
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white		False[305.92, 513.64, 240.97, 206.75]bonds. [5b] The smaller area ratio of spinel-like component for NHCO-5 suggests that minor structural transformation occurs from layer to spinel/rock-salt phase. It is mainly ascribed to be the fact that surface defect …bonds. [5b] The smaller area ratio of spinel-like component for NHCO-5 suggests that minor structural transformation occurs from layer to spinel/rock-salt phase. It is mainly ascribed to be the fact that surface defect …
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white		False[266.69, 744.38, 64.3, 8.02]2304065 (9 of 11)2304065 (9 of 11)
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white		False[469.66, 745.82, 77.21, 6.3]©2023 Wiley-VCH GmbH©2023 Wiley-VCH GmbH
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white		False[47.98, 50.12, 120.78, 8.02]www.advancedsciencenews.com
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white		False[47.97, 76.43, 240.96, 337.21]S8b, Supporting Information. Both P0 and NHCO-5 show the high content of Mn in comparison with Co, which demonstrates that Mn dissolves in the electrolyte more easily. In addition, the dissolution content of Mn and Co f…S8b, Supporting Information. Both P0 and NHCO-5 show the high content of Mn in comparison with Co, which demonstrates that Mn dissolves in the electrolyte more easily. In addition, the dissolution content of Mn and Co f…
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white		False[47.98, 440.84, 64.45, 10.25]3. Conclusion3. Conclusion
10115textbody_candidate_excludedFalsemediumafter_back_matter_stopafter_back_matter_stop
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white		False[47.98, 460.19, 240.95, 260.51]In summary, a facile surface defect construction strategy is proved to address the issues of irreversible oxygen release and sluggish kinetic for Li-rich Mn-based oxides cathodes, resulting in the excellent rate perform…In summary, a facile surface defect construction strategy is proved to address the issues of irreversible oxygen release and sluggish kinetic for Li-rich Mn-based oxides cathodes, resulting in the excellent rate perform…
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white		False[47.98, 745.71, 105.61, 6.3]Adv. Funct. Mater. 2023 , 33 , 2304065Adv. Funct. Mater. 2023 , 33 , 2304065
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off_white		False[579.16, 15.65, 4.41, 751.61]16163028, 2023, 43, Downloaded from https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202304065 by Jilin University, Wiley Online Library on [12/07/2026]. See the Terms and Conditions (https://onlinelibrary.wile…
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white		False[469.62, 50.12, 74.39, 8.02]www.afm-journal.de
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white		False[303.09, 76.58, 112.02, 10.25]Supporting InformationSupporting Information
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white		False[303.09, 95.35, 240.96, 16.67]Supporting Information is available from the Wiley Online Library or from the author.Supporting Information is available from the Wiley Online Library or from the author.
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white		False[303.09, 136.03, 92.58, 10.25]AcknowledgementsAcknowledgements
10122textback_matter_textFalselowafter_back_matter_stopafter_back_matter_stop
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white		False[303.09, 154.8, 240.95, 35.6]The authors acknowledge the financial support of the National Natural Science Foundation of China (52274309). This work also was supported by the Beamlines MCD-A and MCD-B (Soochow Beamline for Energy Materials) at NSRL.The authors acknowledge the financial support of the National Natural Science Foundation of China (52274309). This work also was supported by the Beamlines MCD-A and MCD-B (Soochow Beamline for Energy Materials) at NSRL.
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white		False[303.09, 214.4, 87.65, 10.25]Conflict of InterestConflict of Interest
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white		False[303.09, 233.17, 139.61, 7.2]The authors declare no conflict of interest.The authors declare no conflict of interest.
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white		False[303.09, 264.37, 128.2, 10.25]Data Availability StatementData Availability Statement
10126textmetadataFalselowafter_back_matter_stopafter_back_matter_stop
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white		False[303.09, 283.15, 240.92, 16.67]The data that support the findings of this study are available from the corresponding author upon reasonable request.The data that support the findings of this study are available from the corresponding author upon reasonable request.
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white		False[303.09, 323.81, 45.87, 10.25]KeywordsKeywords
10128textunknown_textFalselowafter_back_matter_stopafter_back_matter_stop
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white		False[303.09, 342.59, 240.96, 16.67]anionic redox, electronic structure modulation, fast-charging, Li-rich Mnbased oxides cathodes, oxygen vacancyanionic redox, electronic structure modulation, fast-charging, Li-rich Mnbased oxides cathodes, oxygen vacancy
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white		False[465.28, 373.47, 78.77, 16.67]Received: April 12, 2023 Revised: May 22, 2023Received: April 12, 2023 Revised: May 22, 2023
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white		False[440.13, 392.41, 103.92, 7.2]Published online: June 21, 2023Published online: June 21, 2023
10131list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp10:body_region:1p10:front_matter:column_2_of_2:white[255, 255, 255]
white		False[307.08, 434.21, 236.97, 37.09]a) S. Li, H. Zhang, H. Li, S. Zhang, B. Zhu, S. Wang, J. Zheng, F. Liu, Z. Zhang, Y. Lai, ACS Appl. Mater. Interfaces 2021 , 13 , 39480; b) H. Zheng, Z. Hu, P. Liu, W. Xu, Q. Xie, W. He, Q. Luo, L. Wang, D. Gu, B. Qu, Z…a) S. Li, H. Zhang, H. Li, S. Zhang, B. Zhu, S. Wang, J. Zheng, F. Liu, Z. Zhang, Y. Lai, ACS Appl. Mater. Interfaces 2021 , 13 , 39480; b) H. Zheng, Z. Hu, P. Liu, W. Xu, Q. Xie, W. He, Q. Luo, L. Wang, D. Gu, B. Qu, Z…
10132list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp10:body_region:1p10:body_zone:column_2_of_2:white[255, 255, 255]
white		False[307.08, 474.05, 236.96, 27.13]Y. Li, L. Xie, Z. Zheng, Z.-W. Yin, J. Li, M. Weng, J. Liu, J. Hu, K. Yang, G. Qian, B. Cao, Z. Li, S. Xu, W. Zhao, S. Li, J. Sun, M. Zhang, F. Pan, Nano Energy 2020 , 77 , 105157.Y. Li, L. Xie, Z. Zheng, Z.-W. Yin, J. Li, M. Weng, J. Liu, J. Hu, K. Yang, G. Qian, B. Cao, Z. Li, S. Xu, W. Zhao, S. Li, J. Sun, M. Zhang, F. Pan, Nano Energy 2020 , 77 , 105157.
10133list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp10:body_region:1p10:body_zone:column_2_of_2:white[255, 255, 255]
white		False[307.08, 503.94, 236.97, 37.09]a) Y. Yang, G. Sun, Q. Zhu, Y . Jiang, W. Ke, P. Wang, Y . Zhao, W. Zhang, Z. Wang, J. Mater. Chem. A 2022 , 10 , 24018; b) J. Xu, J. Wan, W. Zhang, Y. Li, F. Cheng, Z. Cheng, Y. Xu, S. Sun, Q. Li, C. Fang, J. Han, Adv.…a) Y. Yang, G. Sun, Q. Zhu, Y . Jiang, W. Ke, P. Wang, Y . Zhao, W. Zhang, Z. Wang, J. Mater. Chem. A 2022 , 10 , 24018; b) J. Xu, J. Wan, W. Zhang, Y. Li, F. Cheng, Z. Cheng, Y. Xu, S. Sun, Q. Li, C. Fang, J. Han, Adv.…
10134list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp10:body_region:1p10:body_zone:column_2_of_2:white[255, 255, 255]
white		False[307.08, 543.79, 236.97, 57.02]a) J. Zhao, Y . Liang, X. Zhang, Z. Zhang, E. Wang, S. He, B. Wang, Z. Han, J. Lu, K. Amine, H. Yu, Adv. Funct. Mater. 2020 , 31 , 2009192; b) Y. Liu, H. Zhu, H. Zhu, Y. Ren, Y. Zhu, Y . Huang, L. Dai, S. Dou, J. Xu, C.…a) J. Zhao, Y . Liang, X. Zhang, Z. Zhang, E. Wang, S. He, B. Wang, Z. Han, J. Lu, K. Amine, H. Yu, Adv. Funct. Mater. 2020 , 31 , 2009192; b) Y. Liu, H. Zhu, H. Zhu, Y. Ren, Y. Zhu, Y . Huang, L. Dai, S. Dou, J. Xu, C.…
10135list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp10:body_region:1p10:bottom_margin:column_2_of_2:white[255, 255, 255]
white		False[307.08, 603.57, 236.97, 116.79]a) C. Yan, Q. Shao, Z. Yao, M. Gao, C. Zhang, G. Chen, Q. Sun, W. Sun, Y. Liu, M. Gao, H. Pan, Small 2022 , 18 , 2107910; b) Z. Feng, H. Song, W. Su, M. Liu, Y. Li, R. Chen, S. Xu, Y. Lyu, D. Xiao, B. Guo, Chem. Eng. J.…a) C. Yan, Q. Shao, Z. Yao, M. Gao, C. Zhang, G. Chen, Q. Sun, W. Sun, Y. Liu, M. Gao, H. Pan, Small 2022 , 18 , 2107910; b) Z. Feng, H. Song, W. Su, M. Liu, Y. Li, R. Chen, S. Xu, Y. Lyu, D. Xiao, B. Guo, Chem. Eng. J.…
10136page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp10:bottom_margin:column_2_of_2:white[255, 255, 255]
white		False[261.61, 744.38, 68.79, 8.02]2304065 (10 of 11)2304065 (10 of 11)
10137page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
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white		False[466.82, 745.82, 77.21, 6.3]©2023 Wiley-VCH GmbH©2023 Wiley-VCH GmbH
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white		False[50.81, 50.12, 120.78, 8.02]www.advancedsciencenews.com
11139list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[54.8, 77.35, 236.96, 37.09]a) P. Liu, H. Zhang, W. He, T. Xiong, Y . Cheng, Q. Xie, Y . Ma, H. Zheng, L. Wang, Z. Z. Zhu, Y. Peng, L. Mai, D. L. Peng, J. Am. Chem. Soc. 2019 , 141 , 10876; b) Y. Bao, J. Wang, Y. Qian, Y. Deng, X. Yang, G. Chen, E…a) P. Liu, H. Zhang, W. He, T. Xiong, Y . Cheng, Q. Xie, Y . Ma, H. Zheng, L. Wang, Z. Z. Zhu, Y. Peng, L. Mai, D. L. Peng, J. Am. Chem. Soc. 2019 , 141 , 10876; b) Y. Bao, J. Wang, Y. Qian, Y. Deng, X. Yang, G. Chen, E…
11140list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[54.8, 117.2, 236.96, 17.17]Y. Zhang, Z. Chen, X. Shi, C. Meng, P. Das, S. Zheng, F. Pan, Z. S. Wu, Adv. Energy Mater. 2022 , 13 , 2203045.Y. Zhang, Z. Chen, X. Shi, C. Meng, P. Das, S. Zheng, F. Pan, Z. S. Wu, Adv. Energy Mater. 2022 , 13 , 2203045.
11141list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[54.8, 137.12, 236.96, 57.02]a) Y . Pei, Q. Chen, M. Wang, B. Li, P. Wang, G. Henkelman, L. Zhen, G. Cao, C.-Y. Xu, Nano Energy 2020 , 71 , 104644; b) Z. Huang, T. Xiong, X. Lin, M. Tian, W. Zeng, J. He, M. Shi, J. Li, G. Zhang, L. Mai, S. Mu, J. P…a) Y . Pei, Q. Chen, M. Wang, B. Li, P. Wang, G. Henkelman, L. Zhen, G. Cao, C.-Y. Xu, Nano Energy 2020 , 71 , 104644; b) Z. Huang, T. Xiong, X. Lin, M. Tian, W. Zeng, J. He, M. Shi, J. Li, G. Zhang, L. Mai, S. Mu, J. P…
11142list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[50.81, 196.9, 240.95, 17.17]G. Zhang, M. Chen, C. Li, B. Wu, J. Chen, W. Xiang, X. Wen, D. Zhang, G. Cao, W. Li, Chem. Eng. J. 2022 , 443 , 136434.G. Zhang, M. Chen, C. Li, B. Wu, J. Chen, W. Xiang, X. Wen, D. Zhang, G. Cao, W. Li, Chem. Eng. J. 2022 , 443 , 136434.
11143list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[50.81, 216.82, 240.94, 17.17]S. L. Xianggang Gao, H. Zhang, S. Zhang, S. Chang, H. Li, S. Li, Y. Lai, Zhian Zhang, Mater. Today Energy 2022 , 30 , 101152.S. L. Xianggang Gao, H. Zhang, S. Zhang, S. Chang, H. Li, S. Li, Y. Lai, Zhian Zhang, Mater. Today Energy 2022 , 30 , 101152.
11144list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[50.81, 236.75, 240.92, 17.17]L. Bao, L. Wei, N. Fu, J. Dong, L. Chen, Y. Su, N. Li, Y. Lu, Y. Li, S. Chen, F. Wu, J. Energy Chem. 2022 , 66 , 123.L. Bao, L. Wei, N. Fu, J. Dong, L. Chen, Y. Su, N. Li, Y. Lu, Y. Li, S. Chen, F. Wu, J. Energy Chem. 2022 , 66 , 123.
11145list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[50.81, 256.67, 240.95, 17.17]Z. Ye, B. Zhang, T. Chen, Z. Wu, D. Wang, W. Xiang, Y. Sun, Y. Liu, Y. Liu, J. Zhang, Y . Song, X. Guo, Angew. Chem., Int. Ed. 2021 , 60 , 23248.Z. Ye, B. Zhang, T. Chen, Z. Wu, D. Wang, W. Xiang, Y. Sun, Y. Liu, Y. Liu, J. Zhang, Y . Song, X. Guo, Angew. Chem., Int. Ed. 2021 , 60 , 23248.
11146list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[50.81, 276.6, 240.94, 17.16]Z. Lin, L. Dong, H. Xie, F. Tan, X. Ding, J. Cui, X. Xie, C. Liu, Angew. Chem., Int. Ed. 2022 , 61 , 202203698.Z. Lin, L. Dong, H. Xie, F. Tan, X. Ding, J. Cui, X. Xie, C. Liu, Angew. Chem., Int. Ed. 2022 , 61 , 202203698.
11147list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[50.81, 296.52, 240.95, 37.09]a) P. Zhang, Y. He, H. Huang, B. Chen, X. Zhai, J. Zhou, J. Dong, Z. Guo, Appl. Surf. Sci. 2021 , 554 , 149626; b) Z. Chen, J. Meng, Y. Wang, Q. Ma, F. Lai, Z. Li, Q. Zhang, D. Li, S. Zhong, Electrochim. Acta 2021 , 378…a) P. Zhang, Y. He, H. Huang, B. Chen, X. Zhai, J. Zhou, J. Dong, Z. Guo, Appl. Surf. Sci. 2021 , 554 , 149626; b) Z. Chen, J. Meng, Y. Wang, Q. Ma, F. Lai, Z. Li, Q. Zhang, D. Li, S. Zhong, Electrochim. Acta 2021 , 378…
11148list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[50.81, 336.37, 240.95, 37.09]a) W. He, F. Ye, J. Lin, Q. Wang, Q. Xie, F. Pei, C. Zhang, P. Liu, X. Li, L. Wang, B. Qu, D. L. Peng, Nano-Micro Lett. 2021 , 13 , 205; b) W. Wang, W. Cheng, Y. Huang, Y. Wang, Y. Wei, Q. Liu, Appl. Surf. Sci. 2022 , 6…a) W. He, F. Ye, J. Lin, Q. Wang, Q. Xie, F. Pei, C. Zhang, P. Liu, X. Li, L. Wang, B. Qu, D. L. Peng, Nano-Micro Lett. 2021 , 13 , 205; b) W. Wang, W. Cheng, Y. Huang, Y. Wang, Y. Wei, Q. Liu, Appl. Surf. Sci. 2022 , 6…
11149list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[50.81, 376.22, 240.95, 47.06]a) C. Zheng, Z. Yang, J. Feng, J. Zhong, Z. Wei, J. Li, J. Mater. Chem. A 2022 , 10 , 16046; b) X. Ding, D. Luo, J. Cui, H. Xie, Q. Ren, Z. Lin, Angew. Chem. 2020 , 132 , 7852; c) Z. Li, H. Li, S. Cao, W. Guo, J. Liu, J…a) C. Zheng, Z. Yang, J. Feng, J. Zhong, Z. Wei, J. Li, J. Mater. Chem. A 2022 , 10 , 16046; b) X. Ding, D. Luo, J. Cui, H. Xie, Q. Ren, Z. Lin, Angew. Chem. 2020 , 132 , 7852; c) Z. Li, H. Li, S. Cao, W. Guo, J. Liu, J…
11150list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[50.81, 426.04, 240.95, 17.17]W. Guo, C. Zhang, Y. Zhang, L. Lin, W. He, Q. Xie, B. Sa, L. Wang, D. L. Peng, Adv. Mater. 2021 , 33 , 2103173.W. Guo, C. Zhang, Y. Zhang, L. Lin, W. He, Q. Xie, B. Sa, L. Wang, D. L. Peng, Adv. Mater. 2021 , 33 , 2103173.
11151list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_1_of_2:white[255, 255, 255]
white		False[50.81, 445.96, 240.95, 17.17]Q. X. Ma, Z. J. Chen, S. W. Zhong, J. X. Meng, F. L. Lai, Z. F. Li, C. Cheng, L. Zhang, T. F. Liu, Nano Energy 2021 , 81 , 105622.Q. X. Ma, Z. J. Chen, S. W. Zhong, J. X. Meng, F. L. Lai, Z. F. Li, C. Cheng, L. Zhang, T. F. Liu, Nano Energy 2021 , 81 , 105622.
11152page_footerpage_footerFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:bottom_margin:column_1_of_2:white[255, 255, 255]
white		False[50.81, 745.71, 105.61, 6.3]Adv. Funct. Mater. 2023 , 33 , 2304065Adv. Funct. Mater. 2023 , 33 , 2304065
11153page_headerpage_headerFalselowafter_back_matter_stopafter_back_matter_stop
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white		False[472.46, 50.12, 74.39, 8.02]www.afm-journal.de
11155list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.92, 77.34, 240.94, 27.13]B. Qiu, M. Zhang, L. Wu, J. Wang, Y. Xia, D. Qian, H. Liu, S. Hy, Y. Chen, K. An, Y. Zhu, Z. Liu, Y. S. Meng, Nat. Commun. 2016 , 7 , 12108.B. Qiu, M. Zhang, L. Wu, J. Wang, Y. Xia, D. Qian, H. Liu, S. Hy, Y. Chen, K. An, Y. Zhu, Z. Liu, Y. S. Meng, Nat. Commun. 2016 , 7 , 12108.
11156list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.92, 107.23, 240.96, 37.09]a) Q. Li, Ning, D. W., K. An, Y . Tang, D. Zhou, G. Schuck, Z. Chen, N. Zhang, X. Liu, Nat. Commun. 2022 , 13 , 1123; b) T. Lin, T. U. Schulli, Y. Hu, X. Zhu, Q. Gu, B. Luo, B. Cowie, L. Wang, Adv. Funct. Mater. 2020 , …a) Q. Li, Ning, D. W., K. An, Y . Tang, D. Zhou, G. Schuck, Z. Chen, N. Zhang, X. Liu, Nat. Commun. 2022 , 13 , 1123; b) T. Lin, T. U. Schulli, Y. Hu, X. Zhu, Q. Gu, B. Luo, B. Cowie, L. Wang, Adv. Funct. Mater. 2020 , …
11157list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.93, 147.08, 240.95, 17.17]W. He, C. Zhang, M. Wang, B. Wei, Y. Zhu, J. Wu, C. Liang, L. Chen, P. Wang, W. Wei, Adv. Funct. Mater. 2022 , 32 , 2200322.W. He, C. Zhang, M. Wang, B. Wei, Y. Zhu, J. Wu, C. Liang, L. Chen, P. Wang, W. Wei, Adv. Funct. Mater. 2022 , 32 , 2200322.
11158list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.93, 167.01, 240.96, 17.17]Y. Kang, X. Guo, Z. Guo, J. Li, Y. Zhou, Z. Liang, C. Han, X. He, Y. Zhao, N. Tavajohi, B. Li, J. Energy Chem. 2021 , 62 , 538.Y. Kang, X. Guo, Z. Guo, J. Li, Y. Zhou, Z. Liang, C. Han, X. He, Y. Zhao, N. Tavajohi, B. Li, J. Energy Chem. 2021 , 62 , 538.
11159list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.93, 186.93, 240.95, 17.17]X. Wu, Y. Bai, Z. Li, J. Liu, K. Zhao, Z. Du, J. Energy Chem. 2021 , 56 , 121.X. Wu, Y. Bai, Z. Li, J. Liu, K. Zhao, Z. Du, J. Energy Chem. 2021 , 56 , 121.
11160list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.93, 206.86, 240.96, 17.17]J. Hwang, S. Myeong, W. Jin, H. Jang, G. Nam, M. Yoon, S. H. Kim, S. H. Joo, S. K. Kwak, M. G. Kim, J. Cho, Adv. Mater. 2020 , 32 , 2001944.J. Hwang, S. Myeong, W. Jin, H. Jang, G. Nam, M. Yoon, S. H. Kim, S. H. Joo, S. K. Kwak, M. G. Kim, J. Cho, Adv. Mater. 2020 , 32 , 2001944.
11161list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.93, 226.78, 240.94, 17.17]C. Huang, Z. Wang, H. Wang, D. Huang, Y.-b. He, S.-X. Zhao, Mater. Today Energy 2022 , 29 , 101116.C. Huang, Z. Wang, H. Wang, D. Huang, Y.-b. He, S.-X. Zhao, Mater. Today Energy 2022 , 29 , 101116.
11162list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.92, 246.71, 240.96, 7.2]B. Xu, C. R. Fell, M. Chi, Y . S. Meng, Energy Environ. Sci. 2011 , 4 , 2223.B. Xu, C. R. Fell, M. Chi, Y . S. Meng, Energy Environ. Sci. 2011 , 4 , 2223.
11163list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.92, 256.67, 240.95, 17.17]X.-Y. Li, F. Yu, W. Ke, Y .-S. Jiang, l. Que, L. Zhao, S.-E. Hao, Z.-B. Wang, J. Mater. Chem. A 2023 , 11 , 2252.X.-Y. Li, F. Yu, W. Ke, Y .-S. Jiang, l. Que, L. Zhao, S.-E. Hao, Z.-B. Wang, J. Mater. Chem. A 2023 , 11 , 2252.
11164list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.92, 276.6, 240.96, 37.09]a) K. Chai, J. Zhang, Q. Li, D. Wong, L. Zheng, C. Schulz, M. Bartkowiak, D. Smirnov, X. Liu, Small 2022 , 18 , 2201014; b) D. Dixon, S. Mangold, M. Knapp, H. Ehrenberg, A. Bhaskar, Adv. Energy Mater. 2021 , 11 , 210047…a) K. Chai, J. Zhang, Q. Li, D. Wong, L. Zheng, C. Schulz, M. Bartkowiak, D. Smirnov, X. Liu, Small 2022 , 18 , 2201014; b) D. Dixon, S. Mangold, M. Knapp, H. Ehrenberg, A. Bhaskar, Adv. Energy Mater. 2021 , 11 , 210047…
11165list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.93, 316.45, 240.92, 17.17]G.-J. Xu, W. Ke, F.-D. Yu, J. Feng, Y .-S. Jiang, L.-F. Que, L. Zhao, Z.-B. Wang, J. Energy Chem. 2022 , 75 , 117.G.-J. Xu, W. Ke, F.-D. Yu, J. Feng, Y .-S. Jiang, L.-F. Que, L. Zhao, Z.-B. Wang, J. Energy Chem. 2022 , 75 , 117.
11166list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.93, 336.37, 240.96, 27.13]Q. Li, D. Ning, D. Zhou, K. An, D. Wong, L. Zhang, Z. Chen, G. Schuck, C. Schulz, Z. Xu, G. Schumacher, X. Liu, J. Mater. Chem. A 2020 , 8 , 7733.Q. Li, D. Ning, D. Zhou, K. An, D. Wong, L. Zhang, Z. Chen, G. Schuck, C. Schulz, Z. Xu, G. Schumacher, X. Liu, J. Mater. Chem. A 2020 , 8 , 7733.
11167list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.93, 366.26, 240.97, 27.13]Z. Lun, B. Ouyang, D. A. Kitchaev, R. J. Clément, J. K. Papp, M. Balasubramanian, Y. Tian, T. Lei, T. Shi, B. D. McCloskey, J. Lee, G. Ceder, Adv. Energy Mater. 2018 , 9 , 1802959.Z. Lun, B. Ouyang, D. A. Kitchaev, R. J. Clément, J. K. Papp, M. Balasubramanian, Y. Tian, T. Lei, T. Shi, B. D. McCloskey, J. Lee, G. Ceder, Adv. Energy Mater. 2018 , 9 , 1802959.
11168list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.93, 396.15, 240.95, 17.17]Y. C. Zhuo Yao, C. Liu, H. Chen, S. Wu, D. Luo, Z. Lin, S. Zhang, J. Energy Chem. 2023 , 82 , 513.Y. C. Zhuo Yao, C. Liu, H. Chen, S. Wu, D. Luo, Z. Lin, S. Zhang, J. Energy Chem. 2023 , 82 , 513.
11169list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.93, 416.07, 240.95, 17.17]L. Zeng, H. Liang, B. Qiu, Z. Shi, S. Cheng, K. Shi, Q. Liu, Z. Liu, Adv. Funct. Mater. 2023 , 2213260.L. Zeng, H. Liang, B. Qiu, Z. Shi, S. Cheng, K. Shi, Q. Liu, Z. Liu, Adv. Funct. Mater. 2023 , 2213260.
11170list_itemreferenceFalselowafter_back_matter_stopafter_back_matter_stop
after_stopp11:page_body:column_2_of_2:white[255, 255, 255]
white		False[305.93, 436.0, 240.95, 27.13]a) Z. Feng, H. Song, Y. Li, Y. Lyu, D. Xiao, B. Guo, ACS Appl. Mater. Interfaces 2022 , 14 , 5308; b) J. Yang, P. Li, F. Zhong, X. Feng, W. Chen, X. Ai, H. Yang, D. Xia, Y . Cao, Adv. Energy Mater. 2020 , 10 , 1904264.a) Z. Feng, H. Song, Y. Li, Y. Lyu, D. Xiao, B. Guo, ACS Appl. Mater. Interfaces 2022 , 14 , 5308; b) J. Yang, P. Li, F. Zhong, X. Feng, W. Chen, X. Ai, H. Yang, D. Xia, Y . Cao, Adv. Energy Mater. 2020 , 10 , 1904264.
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